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Chemical Reference Materials: Setting the Standards for Ocean Science Chemical Reference Materials: Setting the Standards for Ocean Science Committee on Reference Materials for Ocean Science, National Research Council ISBN: 0-309-50083-4, 144 pages, 6 x 9, (2002) This free PDF was downloaded from: http://www.nap.edu/catalog/10476.html Visit the National Academies Press online, the authoritative source for all books from the National Academy of Sciences, the National Academy of Engineering, the Institute of Medicine, and the National Research Council: • Download hundreds of free books in PDF • Read thousands of books online for free • Purchase printed books and PDF files • Explore our innovative research tools – try the Research Dashboard now • Sign up to be notified when new books are published Thank you for downloading this free PDF. 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Chemical Reference Materials: Setting the Standards for Ocean Science http://www.nap.edu/catalog/10476.html CHEMICAL REFERENCE MATERIALS SETTING THE STANDARDS FOR OCEAN SCIENCE Committee on Reference Materials for Ocean Science Ocean Studies Board Division on Earth and Life Studies THE NATIONAL ACADEMIES PRESS Washington, D.C. www.nap.edu Copyright © National Academy of Sciences. All rights reserved. Chemical Reference Materials: Setting the Standards for Ocean Science http://www.nap.edu/catalog/10476.html THE NATIONAL ACADEMIES PRESS • 500 Fifth Street, NW • Washington, DC 20001 NOTICE: The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Institute of Medicine. The members of the committee re- sponsible for the report were chosen for their special competences and with re- gard for appropriate balance. This material is based upon work supported by the National Science Founda- tion (NSF grant number OCE-0096792). Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation. International Standard Book Number: 0-309-08500-4 Additional copies of this report are available from: The National Academies Press 500 Fifth Street, N.W. Box 285 Washington, DC 20055 (800) 624-6242 (202) 334-3313 (in the Washington metropolitan area) http://www.nap.edu Copyright 2002 by the National Academy of Sciences. All rights reserved. Printed in the United States of America. Copyright © National Academy of Sciences. All rights reserved. Chemical Reference Materials: Setting the Standards for Ocean Science http://www.nap.edu/catalog/10476.html The National Academy of Sciences is a private, nonprofit, self-perpetuating society of distinguished scholars engaged in scientific and engineering research, dedi- cated to the furtherance of science and technology and to their use for the general welfare. Upon the authority of the charter granted to it by the Congress in 1863, the Academy has a mandate that requires it to advise the federal government on scientific and technical matters. Dr. Bruce M. Alberts is president of the National Academy of Sciences. The National Academy of Engineering was established in 1964, under the charter of the National Academy of Sciences, as a parallel organization of outstanding engi- neers. It is autonomous in its administration and in the selection of its members, sharing with the National Academy of Sciences the responsibility for advising the federal government. The National Academy of Engineering also sponsors engi- neering programs aimed at meeting national needs, encourages education and research, and recognizes the superior achievements of engineers. Dr. Wm. A. Wulf is president of the National Academy of Engineering. The Institute of Medicine was established in 1970 by the National Academy of Sciences to secure the services of eminent members of appropriate professions in the examination of policy matters pertaining to the health of the public. The Institute acts under the responsibility given to the National Academy of Sciences by its congressional charter to be an adviser to the federal government and, upon its own initiative, to identify issues of medical care, research, and education. Dr. Harvey V. Fineberg is president of the Institute of Medicine. The National Research Council was organized by the National Academy of Sciences in 1916 to associate the broad community of science and technology with the Academy’s purposes of furthering knowledge and advising the federal govern- ment. Functioning in accordance with general policies determined by the Acad- emy, the Council has become the principal operating agency of both the National Academy of Sciences and the National Academy of Engineering in providing services to the government, the public, and the scientific and engineering commu- nities. The Council is administered jointly by both Academies and the Institute of Medicine. Dr. Bruce M. Alberts and Dr. Wm. A. Wulf are chair and vice chair, respectively, of the National Research Council. www.national-academies.org Copyright © National Academy of Sciences. All rights reserved. Chemical Reference Materials: Setting the Standards for Ocean Science http://www.nap.edu/catalog/10476.html ❈ This report is dedicated to the memory of our colleague John Hedges and his many contributions to oceanography and organic geochemistry. (1946-2002) ❈ iv Copyright © National Academy of Sciences. All rights reserved. Chemical Reference Materials: Setting the Standards for Ocean Science http://www.nap.edu/catalog/10476.html COMMITTEE ON REFERENCE MATERIALS FOR OCEAN SCIENCE ANDREW DICKSON Chair, Scripps Institution of Oceanography, La Jolla, California ROBERT BIDIGARE, University of Hawaii, Honolulu JOHN HEDGES, University of Washington, Seattle* KENNETH JOHNSON, Monterey Bay Aquarium Research Institute, Moss Landing, California DENISE LEBLANC, National Research Council of Canada, Nova Scotia, Canada CINDY LEE, Stony Brook University, Stony Brook, New York ANN McNICHOL, Woods Hole Oceanographic Institution, Woods Hole, Massachusetts FRANK MILLERO, University of Miami, Miami, Florida JAMES MOFFET, Woods Hole Oceanographic Institution, Woods Hole, Massachusetts WILLARD MOORE, University of South Carolina, Columbia EDWARD PELTZER, Monterey Bay Aquarium Research Institute, Moss Landing, California STAN VAN DEN BERG, University of Liverpool, United Kingdom Staff JOANNE BINTZ, Ocean Studies Board, Study Director DARLA KOENIG, Ocean Studies Board, Senior Project Assistant The work of this committee was overseen by the Ocean Studies Board. * Deceased July 2002 v Copyright © National Academy of Sciences. All rights reserved. Chemical Reference Materials: Setting the Standards for Ocean Science http://www.nap.edu/catalog/10476.html OCEAN STUDIES BOARD NANCY RABALAIS (Chair), Louisiana Universities Marine Consortium, Chauvin ARTHUR BAGGEROER, Massachusetts Institute of Technology, Cambridge JAMES COLEMAN, Louisiana State University, Baton Rouge LARRY CROWDER, Duke University, Beaufort, North Carolina G. BRENT DALRYMPLE, Oregon State University RICHARD B. DERISO, Scripps Institution of Oceanography, La Jolla, California EARL DOYLE, Shell Oil (Retired), Sugar Land, Texas ROBERT DUCE, Texas A&M University, College Station WAYNE R. GEYER, Woods Hole Oceanographic Institution, Massachusetts D. JAY GRIMES, University of Southern Mississippi, Ocean Springs MIRIAM KASTNER, Scripps Institution of Oceanography, La Jolla, California CINDY LEE, Stony Brook University, Stony Brook, New York RALPH S. LEWIS, Connecticut Geological Survey, Hartford BONNIE MCCAY, Rutgers University, New Brunswick, New Jersey JULIAN P. McCREARY, Jr., University of Hawaii, Honolulu JACQUELINE MICHEL, Research Planning, Inc., Columbia, South Carolina RAM MOHAN, Gahagan & Bryant Associates, Inc., Baltimore, Maryland SCOTT NIXON, University of Rhode Island, Narragansett JON SUTINEN, University of Rhode Island, Kingston NANCY TARGETT, University of Delaware, Lewes PAUL TOBIN, Armed Forces Communications and Electronics Association, Fairfax, Virginia Staff MORGAN GOPNIK, Director SUSAN ROBERTS, Senior Program Officer DAN WALKER, Senior Program Officer JOANNE C. BINTZ, Program Officer JENNIFER MERRILL, Program Officer TERRY SCHAEFER, Program Officer JOHN DANDELSKI, Research Associate ROBIN MORRIS, Financial Officer vi Copyright © National Academy of Sciences. All rights reserved. Chemical Reference Materials: Setting the Standards for Ocean Science http://www.nap.edu/catalog/10476.html SHIREL SMITH, Office Manager JODI BACHIM, Senior Project Assistant NANCY CAPUTO, Senior Project Assistant DENISE GREENE, Senior Project Assistant DARLA KOENIG, Senior Project Assistant JULIE PULLEY, Project Assistant ALISON SCHRUM, Project Assistant vii Copyright © National Academy of
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    Introduction 1 1 Introduction Tetrapyrroles belong to a group of molecules with a common structure. They are synthesized in a branched pathway, in which various end products are formed to different amounts. The most abundant cyclic tetrapyrroles are chlorophyll (Chl) and heme, which are characterized by a chelated magnesium and ferrous ion, respectively. Chlorophyll is involved in light absorption and energy transduction during photosynthesis. Heme is a cofactor of hemoglobin, cytochromes, P450 mixed-function oxygenases, and catalases. Other members of the class of tetrapyrroles include siroheme (the prosthetic group of nitrite and sulphite reductases) and phytochromobilin, the chromophore of phytochrome, which is involved in light perception. Tetrapyrrole biosynthesis has been the subject of numerous studies over several decades. But genetic and biochemical characterization of tetrapyrrole biosynthesis has progressed by using approaches to genetically dissect the tetrapyrrole biosynthetic pathway. Pigment-deficient mutants and antisense technology have proved to be useful for examining the mechanisms of metabolic control or for analyzing biochemically the enzymatic steps which are affected by the mutation or by the antisense RNA expression. Tetrapyrrole intermediates are highly photoreactive. They can easily be excited and transfer the energy or electrons to O2. Then reactive oxygen species (ROS) are produced upon exposure to light and oxygen. Under normal growth conditions the risk of photooxidative damage from intermediates in tetrapyrrole biosynthesis is low. Excessive accumulation of such intermediates is the result of deregulation of tetrapyrrole biosynthesis. Toxic effects of porphyrins are evident in human patients with deficiencies of one of the enzymes of heme biosynthesis. These patients are suffering from metabolic diseases, which are called porphyrias (Moore, 1993).
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