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Orange Oil None 8008-57-9 Food and Industrial Applications Other Names EINECS No

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Orange Oil None 8008-57-9 Food and Industrial Applications Other Names EINECS No MATERIAL SAFETY DATA SHEET Medina Agriculture Products Co. CHEMTREC 24-HOUR EMERGENCY RESPONSE P.O. Box 309 TOLL FREE NUMBER: (800) 424-9300 4360 Highway 90 West INTERNATIONAL CALLS: COLLECT (202) 483-7616 Hondo, TX 78861 CHEMTREC should only be contacted in the event of chemical emergencies 830-426-3011 involving a spill, leak, fire, exposure, or accident involving chemicals. 830-426-2288 1. PRODUCT IDENTIFICATION (Produced in U.S.A., Brazil & Mexico) Product Name Synonyms CAS No. Use Medina Orange Oil None 8008-57-9 Food and industrial applications Other Names EINECS No. UN No. FEMA No. FDA-GRAS List No. Orange Peel Oil 2319 2633 21 CFR 182-20 232-433-8 Cold Pressed Orange Oil 2. HAZARDOUS INGREDIENTS Hazardous Components % OSHA PEL ACGIH TLV Other Limits D-Limonene >95 N/A N/A N/A Terpene Hydrocarbons <3 N/A N/A N/A Oxygenated Terpenes <2 N/A N/A N/A 3. HAZARD IDENTIFICATION NFPA Codes: Health: 1 Fire: 2 Reactivity: 0 (Degree of Hazard: 4=Extreme 3=High 2=Moderate 1=Slight 0=Insignificant) Health Effects: On Skin: Irritant, may cause temporary redness. Mild local irritation and sensitization. Intensive or continuous contact with skin may cause dermatitis. On Eyes: Irritant, may cause burning, redness, pain. By Accidental Ingestion: Harmful if ingested, gastrointestinal irritation. Abdominal pain, nausea, vomiting, dizziness. By Inhalation: Irritant to respiratory tract, sore throat, coughing, shortness of breath, dizziness, nausea. By Pressure Injection: Injection of all products will cause severe internal damage if not properly treated. Other: Kidney damage may occur (route of exposure not reported). 4. FIRST AID MEASURES EMERGENCY AND FIRST AID PROCEDURES: Skin Contact: Wash affected area with copious amounts of soap and water. Eye Contact: Remove any contact lenses at once. Flush eyes well with large quantities of water for at least 15 min. See physician immediately. Accidental For small amounts, give milk of magnesia or a glass or two of water or milk. For Ingestion: large quantities, consult a physician. Inhalation: If symptoms of overexposure are experienced, evacuate to fresh air. If symptoms persist, seek medical attention. MEDINA ORANGE OIL MAY 2007 5. FIRE & EXPLOSION HAZARD DATA Flash Point: 113 to 121°F (45 to 49°C) Identification No.: UN 2319 Extinguishing Media: Regular Foam, CO2, Dry Chemical (Class B) Flammable Limits (% by volume): Not Available Special Fire Fighting Procedures and Equipment: Do NOT use water. As with any fire situation, full face, self-contained breathing apparatus and appropriate protective clothing should be worn. Under fire conditions, this product may release CO, CO2, smoke, and other decomposition products of undetermined hazard, but it is NOT an oxygen donor. Water is unsuitable for use on burning material, but may be used to cool containers exposed to heat. Incompatible with strong oxidizing agents. NFPA Codes: Health: 1 Fire: 2 Reactivity: 0 (Degree of Hazard: 4=Extreme 3=High 2=Moderate 1=Slight 0=Insignificant) 6. SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Use protective solvent resistant gloves to avoid skin contact. Small spills can be wiped up with vermiculite or other suitable absorbent material and removed to an approved disposal container. Large spills should be absorbed by dirt, sand, or other suitable absorbents for disposal. Do not hose spills down drains. Move leaking containers to well ventilated area. No Smoking. Eliminate any source of ignition. Avoid inhalation. Use NIOSH-approved respiratory protection device. 7. SPECIAL PRECAUTIONS Handling and Storage Precautions: Store in closed containers away from heat or sources of ignition and oxidizing materials. Protect against physical damage to containers. Avoid inhalation and contact with skin and eyes. Other Precautions: Do not dispose of solvent or oil-soaked combustible materials (rags, paper, etc.) in an open container or trash can. Place rags in approved waste cans or soak with water. 8. OCCUPATIONAL PROTECTIVE MEASURES Respiratory Protection: Not normally needed in well ventilated areas. If vapor concentration is high, use NIOSH-approved respiratory protection device. Ventilation: General mechanical ventilation (to reduce fumes). Protective Gloves: Neoprene or Rubber. Eye Protection: OSHA-approved safety glasses with side shields. Other Protective Equipment: Eye bath and safety shower. Work/Hygienic Practices: Good personal hygiene practices should be used. Wash after any contact, before eating, and at the end of the work period. 2 MEDINA ORANGE OIL MAY 2007 9. PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 347.9 to 352.4°F Odor: Pungent Orange Aroma (763 mm Hg) (175.5 to 178°C) Vapor Pressure 1.0mmHg Melting Point/Range: -89°C to –96.9°C (mm Hg @ 14°C) Specific Gravity: 0.838 to 0.850 g/ml Refractive Index: 1.472 (@ 20 to 25°C) (@ 20°C) Vapor Density: 4.73 Evaporation Rate: <1.0 (Air = 1) (Ether = 1) Volatile fraction by weight: 100% Solubility in Water: Negligible Viscosity @ 20°C: 1.28 cST Heat of Combustion: 1.471 Kcal/mol Aniline Point: -15°C Surface Tension: 25 mN m-1 (@ 22°C) 10. REACTIVITY DATA Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning produces Carbon Monoxide and/or Carbon Dioxide. Hazardous Polymerization: Will not occur. Incompatibilities: Avoid strong oxidizing agents. Avoid exposure to sparks, heat and flames. 11. HEALTH HAZARD DATA Carcinogenicity: N/A NTP: TR347 OSHA: Combustible Liquid IARC: N/A Signs & Symptoms of Acute & Chronic Exposure: Eye, skin and mucous membrane irritation Primary Routes of Entry: Inhalation and Absorption Medical Conditions Aggravated: Eye, skin and upper respiratory inflammation. Acute Effects: LD50, Oral (rat): 4,400 mg/kg. LD50, Dermal (rabbit): >2,000 mg/kg. LD50, Dermal (mice): 5,600 to 6,600 mg/kg. Permissable Exposure Concentration: for d-Limonene Sax Quotes: LPR-Mus TDLo: 4800 mg/kg/8W-I: ETA ORL-Mus TDLo: 67 mg/kg/39W-I: ETA EMERGENCY AND FIRST AID PROCEDURES: Skin Contact: Wash affected area with copious amounts of soap and water. Eye Contact: Remove any contact lenses at once. Flush eyes well with large quantities of water for at least 15 min. See physician immediately. Accidental Ingestion: For small amounts, give milk of magnesia or a glass or two of water or milk. For large quantities, consult a physician. Inhalation: If symptoms of overexposure are experienced, evacuate to fresh air. If symptoms persist, seek medical attention. 12. ECOLOGICAL INFORMATION “Marine Pollutant: Classified as slight hazard for water WGK-1 (self statement)” 3 MEDINA ORANGE OIL MAY 2007 Ecotoxicity: Fish Toxicity: LC-0 = 26 mg/l LC-50 = 33 mg/l LC-100=43 mg/l Daphnia toxicity: not available Alga toxicity: not available Earthworm toxicity: not available Plant toxicity: not available Ozone Depletion Potential: Zero stratospheric Global Warming Potential: Zero Photodegradability: Atmospheric half-life = c.a. 1 hour. (Note: d-Limonene, in common with other terpenes, represent a major sink for the undesirable troposheric ozone, removing the smog-forming catalyst nitrogen oxides and consuming ozone at an increased rate at night. While the material is photoreactive, the benefits of removing ozone and nitrogen oxides outweigh the negative with hydroxyl radical) Biodegradability: d-Limonene is a biodegradable solvent occurring in nature as the main component of peel oil. 100% in 28 days Bio-Accumulation: Not available Other Data: Chemical oxygen demand: 2.850 gO2/l or 3.280 gO2/kg 13. DISPOSAL CONSIDERATIONS Waste Handling & Disposal Method: Dispose of in accordance with Federal, State and Local environmental regulations. In most cases land fill or incineration would apply. There are no uniform EC regulations for the disposal of chemicals or residues. Chemical residues generally are applied as “special waste.” We recommend that you contact either the authorities in charge or approved waste companies which will advise you on how to dispose of special waste. Do not allow to enter drinking water supplier, waste water or soil without municipal authorization. 14. REGULATORY STATUS 1) FDA & FEMA list orange oil which is 95%+ d-Limonene as GRAS - Generally Regarded As Safe. 2) NTP, OSHA, and IARC do NOT list product as carcinogenic to humans. 3) Unused product is NOT listed by EPA as hazardous waste (40 CFR part 26 IQ). 4) d-Limonene is NOT listed on California’s Prop. 65 toxic substance list. 5) d-Limonene is listed on EPA’s Chemical Inventory, PL94-469; however, NOT on EPA’s CORR (Chemicals or Regulatory Rules) list, which contains those materials which pose a health or environmental risk. 6) d-Limonene does NOT contain lead, cadmium, mercury, or hexavalent chromium or come into contact with these chemicals since it is a citrus derived by-product oil produced by steam distillation. 7) The components of this product are included on the EPA TSCA Chemical Substance Inventory. 8) The components of this product are included on Canada’s Domestic Substance List (DSL). 15. OTHER INFORMATION VOC INFORMATION: Since orange oil is categorized as an essential oil, it is excluded from VOC regulation. However, when it is categorized as a solvent, orange oil is reportable as 95% VOC (850 grams per liter, 6.81 lbs. per gallon). ASTM D1364: <0.1% Water EPA 24 DENSITY: 0.8422 Kg/L Density 4 MEDINA ORANGE OIL MAY 2007 The information contained herein is based on data considered to be accurate and reliable. No warranty is expressed or implied regarding the accuracy or correctness of this data. It is the user's obligation to determine the safe use of the product since conditions of use, handling, storage and disposal are beyond our control. 16. REFERENCES 1. R.J. Braddock, F. Temell and K.R. Cadwallader, Citrus Essential Oils-1986 2. Citrus Essential Oils-A Dossier for Material Safety Data Sheets-Food Technology 40 (11) 114-116 3.
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