Lithium from Exploration to End-User
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Breakthrough Chemistry Simulations for Lithium Processing Contents
think simulation | getting the chemistry right Breakthrough chemistry simulations for lithium processing Using simulation to maximize your investment return in lithium extraction and processing Contents Introduction ............................................................................................................................................ 2 Process simulation deficiencies ................................................................................................................ 2 OLI Systems electrolyte thermodynamics .................................................................................................2 OLI Systems lithium initiative .................................................................................................................... 2 Lithium phase 1 and potash chemistry is complete ................................................................................... 2 Fundamental sulfate – chloride systems .............................................................................................. 3 Fundamental hydroxide and carbonate systems .................................................................................. 3 Lithium in acid environments for processing and recycling ................................................................... 3 Lithium borate systems for Li production ............................................................................................. 4 Systems related to Li hydrometallurgical processing, purifications and recycling .................................. -
Zinnwald Lithium Project
Zinnwald Lithium Project Report on the Mineral Resource Prepared for Deutsche Lithium GmbH Am St. Niclas Schacht 13 09599 Freiberg Germany Effective date: 2018-09-30 Issue date: 2018-09-30 Zinnwald Lithium Project Report on the Mineral Resource Date and signature page According to NI 43-101 requirements the „Qualified Persons“ for this report are EurGeol. Dr. Wolf-Dietrich Bock and EurGeol. Kersten Kühn. The effective date of this report is 30 September 2018. ……………………………….. Signed on 30 September 2018 EurGeol. Dr. Wolf-Dietrich Bock Consulting Geologist ……………………………….. Signed on 30 September 2018 EurGeol. Kersten Kühn Mining Geologist Date: Page: 2018-09-30 2/219 Zinnwald Lithium Project Report on the Mineral Resource TABLE OF CONTENTS Page Date and signature page .............................................................................................................. 2 1 Summary .......................................................................................................................... 14 1.1 Property Description and Ownership ........................................................................ 14 1.2 Geology and mineralization ...................................................................................... 14 1.3 Exploration status .................................................................................................... 15 1.4 Resource estimates ................................................................................................. 16 1.5 Conclusions and Recommendations ....................................................................... -
Used at Rocky Flats
. TASK 1 REPORT (Rl) IDENTIFICATION OF CHEMICALS AND RADIONUCLIDES USED AT ROCKY FLATS I PROJECT BACKGROUND ChemRisk is conducting a Rocky Flats Toxicologic Review and Dose Reconstruction study for The Colorado Department of Health. The two year study will be completed by the fall of 1992. The ChemRisk study is composed of twelve tasks that represent the first phase of an independent investigation of off-site health risks associated with the operation of the Rocky Flats nuclear weapons plant northwest of Denver. The first eight tasks address the collection of historic information on operations and releases and a detailed dose reconstruction analysis. Tasks 9 through 12 address the compilation of information and communication of the results of the study. Task 1 will involve the creation of an inventory of chemicals and radionuclides that have been present at Rocky Flats. Using this inventory, chemicals and radionuclides of concern will be selected under Task 2, based on such factors as the relative toxicity of the materials, quantities used, how the materials might have been released into the environment, and the likelihood for transport of the materials off-site. An historical activities profile of the plant will be constructed under Task 3. Tasks 4, 5, and 6 will address the identification of where in the facility activities took place, how much of the materials of concern were released to the environment, and where these materials went after the releases. Task 7 addresses historic land-use in the vicinity of the plant and the location of off-site populations potentially affected by releases from Rocky Flats. -
Report on the Sonora Lithium Project
Report on the Sonora Lithium Project (Pursuant to National Instrument 43-101 of the Canadian Securities Administrators) Huasabas - Bacadehuachi Area (Map Sheet H1209) Sonora, Mexico o o centered at: 29 46’29”N, 109 6’14”W For 330 – 808 – 4th Avenue S. W. Calgary, Alberta Canada T2P 3E8 Tel. +1-403-237-6122 By Carl G. Verley, P. Geo. Martin F. Vidal, Lic. Geo. Geological Consultant Vice-President, Exploration Amerlin Exploration Services Ltd. Bacanora Minerals Ltd. 2150 – 1851 Savage Road Calle Uno # 312 Richmond, B.C. Canada V6V 1R1 Hermosillo, Mexico Tel. +1-604-821-1088 Tel. +52-662-210-0767 Ellen MacNeill, P.Geo. Geological Consultant RR5, Site25, C16 Prince Albert, SK Canada S6V 5R3 Tel. +1-306-922-6886 Dated: September 5, 2012. Bacanora Minerals Ltd. Report on the Sonora Lithium Project, Sonora, Mexico Date and Signature Page Date Dated Effective: September 5, 2012. Signatures Carl G. Verley, P.Geo. ____________________ Martin F. Vidal, Lic. Geo. Ellen MacNeill, P.Geo. Amerlin Exploration Services Ltd. - Consulting mineral exploration geologists ii Bacanora Minerals Ltd. Report on the Sonora Lithium Project, Sonora, Mexico Table of Contents 1.0 Summary ................................................................................................................................... 1 2.0 Introduction ............................................................................................................................... 3 3.0 Reliance on Other Experts ....................................................................................................... -
Lithium Exploration Commences at Broken Hill
ASX ANNOUNCEMENT 3 June 2016 Lithium Exploration Commences at Broken Hill Exploration for lithium in pegmatites at Broken Hill has commenced Extensive zones of outcropping pegmatite in Silver City tenements covering some 100 square kilometres No systematic exploration for lithium ever undertaken at Broken Hill Important anomalous lithium indicator elements already identified in Waukeroo tin field Broken Hill mining centre provides logistical advantage to new discoveries Silver City Minerals Limited (ASX: SCI) (“Silver City” or “the Company”) has commenced a program of mineral exploration specifically targeting lithium hosted in pegmatites at Broken Hill (ASX Release 11 May 2016). Initial field programs have begun with systematic rock chip sampling and geological mapping of pegmatites associated with areas of tin mineralisation and evaluation of existing airborne hyperspectral data. The purpose of the program is to locate pegmatites which contain lithium minerals with a particular emphasis on spodumene (LiAlSi2O6), the dominant commercial lithium mineral. Current exploration is focussed on pegmatites located within granted exploration tenure on the northern and southern extensions of the Waukeroo tin field. SCI holds title to ten granted exploration licences and three licence applications. Next Steps SCI considers that, through systematic sampling and mineralogical studies, potential for discovery of lithium minerals at Waukeroo and elsewhere in the district is high. Work has commenced with field teams sampling and mapping, including re-sampling of drill chips from the previous tungsten resource drilling. Sampling has also been initiated in areas of the Western zone where extensive pegmatite outcrops have similarly never been assessed for lithium. SILVER CITY MINERALS LIMITED A study using an existing airborne hyperspectral (HyMap) survey is underway to assess the potential for remotely differentiating spodumene in the spectral data. -
Mesoscopic Rydberg-Blockaded Ensembles in the Superatom Regime and Beyond
LETTERS PUBLISHED ONLINE: 12 JANUARY 2015 | DOI: 10.1038/NPHYS3214 Mesoscopic Rydberg-blockaded ensembles in the superatom regime and beyond T. M. Weber, M. Höning, T. Niederprüm, T. Manthey, O. Thomas, V. Guarrera†, M. Fleischhauer, G. Barontini† and H. Ott* The control of strongly interacting many-body systems of a Bose–Einstein condensate of 87Rb atoms. We first load the enables the creation of tailored quantum matter with complex condensate into a one-dimensional optical lattice with a spacing of properties. Atomic ensembles that are optically driven to a 532 nm, to suppress the axial movement of the atoms. We subse- Rydberg state provide many examples for this: atom–atom quently compress the atomic sample in the radial direction to reduce entanglement1,2, many-body Rabi oscillations3, strong its size below the blockade radius and empty all but three (or more) photon–photon interaction4 and spatial pair correlations5. lattice sites using a focused electron beam8–10 (Fig. 1a and Methods). In its most basic form Rydberg quantum matter consists of The atom number within the ensemble (N) can be adjusted between an isolated ensemble of strongly interacting atoms spatially 100 and 500 at a temperature of T D .3.5 0.5/ µK and the typical confined to the blockade volume—a superatom. Here we size of the sample is ≤3 µm in diameter (Fig. 1b). Our preparation demonstrate the controlled creation and characterization scheme is readily scalable to arrays of superatoms (Fig. 1d). of an isolated mesoscopic superatom by means of accurate After preparation we excite the atomic ensemble with a density engineering and excitation to Rydberg p-states. -
Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: a Review
resources Review Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: A Review Laurence Kavanagh * , Jerome Keohane, Guiomar Garcia Cabellos, Andrew Lloyd and John Cleary EnviroCORE, Department of Science and Health, Institute of Technology Carlow, Kilkenny, Road, Co., R93-V960 Carlow, Ireland; [email protected] (J.K.); [email protected] (G.G.C.); [email protected] (A.L.); [email protected] (J.C.) * Correspondence: [email protected] Received: 28 July 2018; Accepted: 11 September 2018; Published: 17 September 2018 Abstract: Lithium is a key component in green energy storage technologies and is rapidly becoming a metal of crucial importance to the European Union. The different industrial uses of lithium are discussed in this review along with a compilation of the locations of the main geological sources of lithium. An emphasis is placed on lithium’s use in lithium ion batteries and their use in the electric vehicle industry. The electric vehicle market is driving new demand for lithium resources. The expected scale-up in this sector will put pressure on current lithium supplies. The European Union has a burgeoning demand for lithium and is the second largest consumer of lithium resources. Currently, only 1–2% of worldwide lithium is produced in the European Union (Portugal). There are several lithium mineralisations scattered across Europe, the majority of which are currently undergoing mining feasibility studies. The increasing cost of lithium is driving a new global mining boom and should see many of Europe’s mineralisation’s becoming economic. The information given in this paper is a source of contextual information that can be used to support the European Union’s drive towards a low carbon economy and to develop the field of research. -
Winter 2003 Gems & Gemology
Winter 2003 VOLUME 39, NO. 4 EDITORIAL _____________ 267 Tomorrow’s Challenge: CVD Synthetic Diamonds William E. Boyajian FEATURE ARTICLES _____________ 268 Gem-Quality Synthetic Diamonds Grown by a Chemical Vapor Deposition (CVD) Method Wuyi Wang, Thomas Moses, Robert C. Linares, James E. Shigley, Matthew Hall, and James E. Butler pg. 269 Description and identifying characteristics of Apollo Diamond Inc.’s facetable, single-crystal type IIa CVD-grown synthetic diamonds. 284 Pezzottaite from Ambatovita, Madagascar: A New Gem Mineral Brendan M. Laurs, William B. (Skip) Simmons, George R. Rossman, Elizabeth P. Quinn, Shane F. McClure, Adolf Peretti, Thomas Armbruster, Frank C. Hawthorne, Alexander U. Falster, Detlef Günther, Mark A. Cooper, and Bernard Grobéty A look at the history, geology, composition, and properties of this new cesium-rich member of the beryl group. 302 Red Beryl from Utah: A Review and Update James E. Shigley, Timothy J. Thompson, and Jeffrey D. Keith A report on the geology, history, and current status of the world’s only known occurrence of gem-quality red beryl. pg. 299 REGULAR FEATURES _____________________ 314 Lab Notes • Chrysocolla “owl” agate • Red coral • Coated diamonds • Natural emerald with nail-head spicules • Emerald with strong dichroism • High-R.I. glass imitation of tanzanite • Large clam “pearl” • Blue sapphires with unusual color zoning • Spinel with filled cavities 322 Gem News International • Comparison of three historic blue diamonds • Natural yellow diamond with nickel-related optical centers -
Ultraviolet Photoacoustic Remote Sensing Microscopy
Ultraviolet Photoacoustic Remote Sensing Microscopy by Nathaniel Haven A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science in Biomedical Engineering Department of Electrical and Computer Engineering University of Alberta © Nathaniel Haven, 2019 Abstract Cancer is currently one of the leading causes of death globally. In dealing with certain cancers, the recommended treatment is often surgery. In order to determine if the entirety of the cancerous mass has been removed, tumor resection margins are assessed after surgical resection, as it is difficult to differentiate cancerous from health tissue without micro-scale observation. Presently, the current gold-standard for tissue biopsy and tumor resection margin analysis is formalin-fixed paraffin-embedded hematoxylin & eosin (H&E) histology. Though, this process is both time consuming and labor intensive as well as being a significant burden on the healthcare economy. Unfortunately, there are currently no intraoperative techniques capable of reproducing reliable post-operative H&E histology output, this results in many patients having to undergo secondary surgeries, leading to unnecessary emotional and physical trauma for patients, as well as higher risks of worsened prognosis. Here we report the development of an ultraviolet excitation photoacoustic remote sensing microscopy system capable of producing images of cell nuclei within cell cultures and tissue samples. This was achieved in two iterations. The first iteration utilized a parabolic focusing element along with mechanical stage scanning to obtain images of sectioned HT1080 CAM tumors, as well as HeLa cell cultures, demonstrating the ability to observe individual cell nuclei with good comparison ii to H&E histology. -
Asx Announcement
ASX ANNOUNCEMENT 3 June 2016 Lithium Exploration Commences at Broken Hill Exploration for lithium in pegmatites at Broken Hill has commenced Extensive zones of outcropping pegmatite in Silver City tenements covering some 100 square kilometres No systematic exploration for lithium ever undertaken at Broken Hill Important anomalous lithium indicator elements already identified in Waukeroo tin field Broken Hill mining centre provides logistical advantage to new discoveries Silver City Minerals Limited (ASX: SCI) (“Silver City” or “the Company”) has commenced a program of mineral exploration specifically targeting lithium hosted in pegmatites at Broken Hill (ASX Release 11 May 2016). Initial field programs have begun with systematic rock chip sampling and geological mapping of pegmatites associated with areas of tin mineralisation and evaluation of existing airborne hyperspectral data. The purpose of the program is to locate pegmatites which contain lithium minerals with a particular emphasis on spodumene (LiAlSi2O6), the dominant commercial lithium mineral. Current exploration is focussed on pegmatites located within granted exploration tenure on the northern and southern extensions of the Waukeroo tin field. SCI holds title to ten granted exploration licences and three licence applications. Next Steps SCI considers that, through systematic sampling and mineralogical studies, potential for discovery of lithium minerals at Waukeroo and elsewhere in the district is high. Work has commenced with field teams sampling and mapping, including re-sampling of drill chips from For personal use only the previous tungsten resource drilling. Sampling has also been initiated in areas of the Western zone where extensive pegmatite outcrops have similarly never been assessed for lithium. SILVER CITY MINERALS LIMITED A study using an existing airborne hyperspectral (HyMap) survey is underway to assess the potential for remotely differentiating spodumene in the spectral data. -
The Use of Lithium to Prevent Or Mitigate Alkali-Silica Reaction in Concrete Pavements and Structures
The Use of Lithium to Prevent or Mitigate Alkali-Silica Reaction in Concrete Pavements and Structures PUBLIcatION NO. FHWA-HRT-06-133 MARCH 2007 Research, Development, and Technology Turner-Fairbank Highway Research Center 6300 Georgetown Pike McLean, VA 22101-2296 Foreword Progress is being made in efforts to combat alkali-silica reaction in portland cement concrete structures—both new and existing. This facts book provides a brief overview of laboratory and field research performed that focuses on the use of lithium compounds as either an admixture in new concrete or as a treatment of existing structures. This document is intended to provide practitioners with the necessary information and guidance to test, specify, and use lithium compounds in new concrete construction, as well as in repair and service life extension applications. This report will be of interest to engineers, contractors, and others involved in the design and specification of new concrete, as well as those involved in mitigation of the damaging effects of alkali-silica reaction in existing concrete structures. Gary L. Henderson, P.E. Director, Office of Infrastructure Research and Development Notice This document is disseminated under the sponsorship of the U.S. Department of Transportation in the interest of information exchange. The U.S. Government assumes no liability for its contents or use thereof. This report does not constitute a standard, specification, or regulation. The U.S. Government does not endorse products or manufacturers. Trade or manufacturers’ names appear herein only because they are considered essential to the objective of this manual. Quality Assurance Statement The Federal Highway Administration (FHWA) provides high-quality information to serve Government, industry, and the public in a manner that promotes public understanding. -
Mineral Potential for Incompatible Element Deposits Hosted In
Prepared in cooperation with the Ministry of Petroleum, Energy and Mines, Islamic Republic of Mauritania Second Projet de Renforcement Institutionnel du Secteur Minier de la République Islamique de Mauritanie (PRISM-II) Mineral Potential for Incompatible Element Deposits Hosted in Pegmatites, Alkaline Rocks, and Carbonatites in the Islamic Republic of Mauritania: Phase V, Deliverable 87 By Cliff D. Taylor and Stuart A. Giles Open-File Report 2013–1280 Chapter Q U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior SALLY JEWELL, Secretary U.S. Geological Survey Suzette M. Kimball, Acting Director U.S. Geological Survey, Reston, Virginia: 2015 For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment—visit http://www.usgs.gov or call 1–888–ASK–USGS For an overview of USGS information products, including maps, imagery, and publications, visit http://www.usgs.gov/pubprod To order this and other USGS information products, visit http://store.usgs.gov Suggested citation: Taylor, C.D., and Giles, S.A., 2015, Mineral potential for incompatible element deposits hosted in pegmatites, alkaline rocks, and carbonatites in the Islamic Republic of Mauritania (phase V, deliverable 87), chap. Q of Taylor, C.D., ed., Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II): U.S. Geological Survey Open-File Report 2013‒1280-Q, 41 p., http://dx.doi.org/10.3133/ofr20131280. [In English and French.] Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S.