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Native PFAS Primary Dilution Standard Solution/Mixture (EPA-537PDS-R1)

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Native PFAS Primary Dilution Standard Solution/Mixture (EPA-537PDS-R1) Native PFAS Primary Dilution Standard Solution/Mixture (EPA-537PDS-R1) Wellington Laboratories Inc. Chemwatch Hazard Alert Code: 4 Version No: 3.4 Issue Date: 09/10/2019 Safety Data Sheet according to WHMIS 2015 requirements Print Date: 09/10/2019 S.GHS.CAN.EN SECTION 1 IDENTIFICATION Product Identifier Product name Native PFAS Primary Dilution Standard Solution/Mixture (EPA-537PDS-R1) Synonyms Methyl alcohol (methanol),Methyl hydrate (methanol),Methylol (methanol) Proper shipping name METHANOL Other means of identification Not Available Recommended use of the chemical and restrictions on use This product is a solution of organic compound(s) in methanol for laboratory use only (see section 3). This material should only be used by those persons trained in the safe handling of hazardous chemicals. Please refer to the Certificate of Analysis (CofA) for further product information. Wellington Relevant identified uses Laboratories Inc. believes the information stated below to be reliable and accurate. This data is solely for reference purposes. Wellington Laboratories Inc. shall not be held liable for damages resulting from handling or contact with the above stated material. Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party Registered company name Wellington Laboratories Inc. Address 345 Southgate Drive Guelph Ontario N1G 3M5 Canada Telephone +1 519 822 2436 Fax +1 519 822 2849 Website www.well-labs.com Email [email protected] Emergency phone number Association / Organisation Wellington Laboratories Inc. Emergency telephone numbers 1-888-CANUTEC (226-8832) (North American) Other emergency telephone 1-613-996-6666 (International) numbers SECTION 2 HAZARD(S) IDENTIFICATION Classification of the substance or mixture NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Blue = Health Red = Fire Yellow = Reactivity White = Special (Oxidizer or water reactive substances) Eye Irritation Category 2A, Acute Toxicity (Dermal) Category 3, Specific target organ toxicity - single exposure Category 1, Flammable Liquid Category 2, Classification Acute Toxicity (Inhalation) Category 3, Reproductive Toxicity Category 1B, Acute Toxicity (Oral) Category 3 Label elements Hazard pictogram(s) SIGNAL WORD DANGER Hazard statement(s) H319 Causes serious eye irritation. Continued... Version No: 3.4 Page 2 of 13 Issue Date: 09/10/2019 Native PFAS Primary Dilution Standard Solution/Mixture (EPA-537PDS-R1) Print Date: 09/10/2019 H311 Toxic in contact with skin. H370 Causes damage to organs. H225 Highly flammable liquid and vapour. H331 Toxic if inhaled. H360 May damage fertility or the unborn child. H301 Toxic if swallowed. Physical and Health hazard(s) not otherwise classified Not Applicable Supplementary statement(s) Not Applicable CLP classification (additional) Not Applicable Precautionary statement(s) Prevention P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. Precautionary statement(s) Response P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician/first aider. P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor/physician/first aider. P321 Specific treatment (see advice on this label). P330 Rinse mouth. P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P337+P313 If eye irritation persists: Get medical advice/attention. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. Precautionary statement(s) Storage P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary statement(s) Disposal P501 Dispose of contents/container in accordance with local regulations. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 67-56-1 98.734 methanol Not Available 0.005 Native Perfluorinated Compounds (total) 7732-18-5 1.26 water 1310-73-2 0.01 sodium hydroxide SECTION 4 FIRST-AID MEASURES Description of first aid measures Continued... Version No: 3.4 Page 3 of 13 Issue Date: 09/10/2019 Native PFAS Primary Dilution Standard Solution/Mixture (EPA-537PDS-R1) Print Date: 09/10/2019 If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Eye Contact Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Immediately flush body and clothes with large amounts of water, using safety shower if available. Skin Contact Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Inhalation Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus. Indication of any immediate medical attention and special treatment needed Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours. For acute and short term repeated exposures to methanol: Toxicity results from accumulation of formaldehyde/formic acid. Clinical signs are usually limited to CNS, eyes and GI tract Severe metabolic acidosis may produce dyspnea and profound systemic effects which may become intractable. All symptomatic patients should have arterial pH measured. Evaluate airway, breathing and circulation. Stabilise obtunded patients by giving naloxone, glucose and thiamine. Decontaminate with Ipecac or lavage for patients presenting 2 hours post-ingestion. Charcoal does not absorb well; the usefulness of cathartic is not established. Forced diuresis is not effective; haemodialysis is recommended where peak methanol levels exceed 50 mg/dL (this correlates with serum bicarbonate levels below 18 meq/L). Ethanol, maintained at levels between 100 and 150 mg/dL, inhibits formation of toxic metabolites and may be indicated when peak methanol levels exceed 20 mg/dL. An intravenous solution of ethanol in D5W is optimal. Folate, as leucovorin, may increase the oxidative removal of formic acid. 4-methylpyrazole may be an effective adjunct in the treatment. 8.Phenytoin may be preferable to diazepam for controlling seizure. [Ellenhorn Barceloux: Medical Toxicology] BIOLOGICAL EXPOSURE INDEX - BEI Determinant Index Sampling Time Comment 1. Methanol in urine 15 mg/l End of shift B, NS 2. Formic acid in urine 80 mg/gm creatinine Before the shift at end of workweek B, NS B: Background levels occur in specimens collected from subjects NOT exposed. NS: Non-specific determinant - observed following exposure to other materials. SECTION 5 FIRE-FIGHTING MEASURES Extinguishing media Water may be an ineffective extinguishing media for methanol fires; static explosions are reported for aqueous solutions as dilute as 30%. Water may be used to cool containers. Alcohol stable foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising
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