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04. M.SC Chemistry
DEPARTMENT OF CHEMISTRY ANNA UNIVERSITY, CHENNAI VISION The Department of Chemistry at Anna University shall strive towards attaining world class status and recognition by producing students with sound knowledge, professional skills, high levels of integrity and ethical values. The Department shall provide an outstanding ambience for teaching, research and consultancy.The Department shall perform frontier research and create knowledge base in theoretical and appliedchemistry, polymeric and catalytic materials, fuel and energy related processes and materials, environmental chemistry and other transdisciplinary areas of technological importance. MISSION The Department of Chemistry, Anna University shall contribute to the educational, economic and social development: By producing postgraduates and Doctorates who are equipped with thorough knowledge in Chemistry, analytical thinking, practical skills and ethics. By inspiring the students to be creative thinkers, inspirational role models and citizens with environmental and social consciousness. By introducing high quality academic and research programmes in Chemistry and enabling interaction with experts from around the world in the fields of Chemistry. By ensuring a supportive ambience in the Department with dynamic leadership and growth opportunities to meet the needs of the students, faculty and staff. By promoting the development of technologically and socially relevant processes and products in the fields of catalysis, polymers, corrosion resistance coatings and energy conversion through academic and sponsored research, in collaboration with global research groups. By sharing the intellectual resources and infrastructural facilities of the Department of Chemistry among the academic fraternity of the University campus and other Institutions, among the industrial research groups, funding agencies and the Government. By facilitating collaborative partnership with industries and other institutions and catalyseinnovation, transfer of technology and commercialization towards fulfilling societal developments. -
The Direct Electrochemical Synthesis of Selected Group-Iib Organometallic Compounds
University of Windsor Scholarship at UWindsor Electronic Theses and Dissertations Theses, Dissertations, and Major Papers 1-1-1979 THE DIRECT ELECTROCHEMICAL SYNTHESIS OF SELECTED GROUP-IIB ORGANOMETALLIC COMPOUNDS. AKHTAR OSMAN University of Windsor Follow this and additional works at: https://scholar.uwindsor.ca/etd Recommended Citation OSMAN, AKHTAR, "THE DIRECT ELECTROCHEMICAL SYNTHESIS OF SELECTED GROUP-IIB ORGANOMETALLIC COMPOUNDS." (1979). Electronic Theses and Dissertations. 7187. https://scholar.uwindsor.ca/etd/7187 This online database contains the full-text of PhD dissertations and Masters’ theses of University of Windsor students from 1954 forward. These documents are made available for personal study and research purposes only, in accordance with the Canadian Copyright Act and the Creative Commons license—CC BY-NC-ND (Attribution, Non-Commercial, No Derivative Works). Under this license, works must always be attributed to the copyright holder (original author), cannot be used for any commercial purposes, and may not be altered. Any other use would require the permission of the copyright holder. Students may inquire about withdrawing their dissertation and/or thesis from this database. For additional inquiries, please contact the repository administrator via email ([email protected]) or by telephone at 519-253-3000ext. 3208. 492-33 National Library Bibliothfeque nationale CANADIAN THESES THESES CANADtENNES f l * .of Canada ~ du Canada ON MICROFICHE SUB UJCBOFICHE NAME OF AUTHOR/NOM O f L’AUTEUR. A khtar Osman TITLE OF THEStS/7777?£ O f LA THESE- The direct electrochemical synthesis of selected grouo IIB organonetallic compounds. UNIVERSITY/LW/ VERS/ TE. U niversity of ~Windsor. Windsor ..Ontario DEGREE FOR WHICH THESIS WAS PRESENTED/. -
The Synthesis of 2-Methyl Butanal by Reaction of N-Butyl Isocyanide with Secondary-Butylcadmium Bromide, Pt
The synthesis of 2-methyl butanal by reaction of n-butyl isocyanide with secondary-butylcadmium bromide, pt. 1 : a study of the reactions between carbon monoxide and the sodium salt of nitroethane, pt. 2 by John M Bruce Jr A THESIS Submitted to the Graduate Committee in partial fulfillment of the requirements for the degree of Master of Science in Chemsitry at Montana State College Montana State University © Copyright by John M Bruce Jr (1949) Abstract: Part I. 2-methyl butanal was prepared by the following sequence of reactions: [Formulas not Captured by OCR] A light yellow liquid was obtained as product. Confirmatory tests were run using small portions of the final product, and close agreement was found to exist between these results and the actual data pertaining to 2-methyl butanal. The 2,4-dinitrophenylhydrazone derivative was prepared from the final product, and its melting point determined. Experimental details of the above procedure ere presented, along with an explanation of the experimental results. Part II A reaction mixture consisting of the sodium salt of nitroethane and nickel carbonyl in a solvent of cyclohexane, was subjected to high pressures of carbon monoxide. This reaction mixture yielded, upon hydrolysis, a substance possessing a solubility which could not readily be accounted for. This substance is not obtained in the absence of nickel carbonyl, or when cyclohexane itself is subjected to carbon monoxide under pressure in the presence of nickel carbonyl. The unidentified substance is decomposed by steam distillation, simple distillation, and vacuum distillation, and cannot be crystallised satisfactorily even at low temperatures. -
Lithium Transport in Crown Ether Polymers
Durham E-Theses Lithium transport in crown ether polymers Collie, Luke E. How to cite: Collie, Luke E. (1995) Lithium transport in crown ether polymers, Durham theses, Durham University. Available at Durham E-Theses Online: http://etheses.dur.ac.uk/5196/ Use policy The full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that: • a full bibliographic reference is made to the original source • a link is made to the metadata record in Durham E-Theses • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders. Please consult the full Durham E-Theses policy for further details. Academic Support Oce, Durham University, University Oce, Old Elvet, Durham DH1 3HP e-mail: [email protected] Tel: +44 0191 334 6107 http://etheses.dur.ac.uk Lithium Transport in Crown Ether Polymers Luke E. Collie BSc. (Hons.) University of Durham Department of Chemistry The copyright of this thesis rests with the author. No quotation from it should be published without his prior written consent and information derived from it should be acknowledged. A Thesis submitted for the degree of Doctor of Philosophy October 1995 1 6 JAN 1996 Statement of Copyright The copyright of this thesis rests with the author. No quotation from it should be published without his prior written consent and information derived from it should be acknowledged. -
List of Publications
List of Publications 316. D. Mishig, M. Gruner, T. Lübken, C. Ganbaatar, D. Regdel, H.-J. Knölker, Sci. Rep. 2021, 11, 13740: Isolation and Structure Elucidation of Pyridine Alkaloids from the Aerial Parts of the Mongolian Medicinal Plant Caryopteris mongolica Bunge. 315. A. K. Solanki, M. R. Biswal, S. Walterhouse, R. Martin, A. A. Kondkar, H.-J. Knölker, B. Rahman, E. Arif, S. Husain, S. R. Montezuma, D. Nihalani, G. P. Lobo, Cells 2021, 10, 1322: Loss of Motor Protein MYO1C Causes Rhodopsin Mislocation and Results in Impaired Visual Function. 314. A. Åslund, M. H. Bokhari, E. Wetterdal, R. Martin, H.-J. Knölker, T. Bengtsson, Mol. Metab. 2021, 53, 101247: Myosin 1c: A Novel Regulator of Glucose Uptake in Brown Adipocytes. 313. F. Puls, P. Linke, O. Kataeva, H.-J. Knölker, Angew. Chem. 2021, 133, 14202–14209; Angew. Chem. Int. Ed. 2021, 60, 14083–14090: Transition Metals in Organic Synthesis, Part 148. Iron- Catalyzed Wacker-type Oxidation of Olefins at Room Temperature with 1,3-Diketones or Neocuproine as Ligands. 312. M. Witting, U. Schmidt, H.-J. Knölker, Anal. Bioanal. Chem. 2021, 413, 2091–2102: UHPLC-IM- Q-ToFMS Analysis of Maradolipids, Found Exclusively in Caenorhabditis elegans Dauer Larvae. 311. H.-J. Knölker, Sitzungsberichte der Sächsischen Akademie der Wissenschaften zu Leipzig – Mathematisch-naturwissenschaftliche Klasse, S. Hirzel, Suttgart/Leipzig, 2021, Band 133, Heft 4, S. 1–30: Katalyse – Eine Renaissance der „Eisenzeit“? 310. S. Vellino, C. Oddou, P. Rivier, C. Boyault, E. Hiriart-Bryant, A. Kraut, R. Martin, Y. Coute, H.-J. Knölker, M. A. Valverde, C. Albigès-Rizo, O. Destaing, J. -
Iron Catalysis in Organic Chemistry
Iron Catalysis in Organic Chemistry Reactions and Applications Edited by Bernd Plietker Iron Catalysis in Organic Chemistry Edited by Bernd Plietker Related Titles Cornils, B., Herrmann, W. A., Muhler, M., Wong, C.-H. (eds.) Catalysis from A to Z A Concise Encyclopedia 2007 ISBN: 978-3-527-31438-6 Tietze, L. F., Brasche, G., Gericke, K. M. Domino Reactions in Organic Synthesis 2006 SBN: 978-3-527-29060-4 Yudin, A. K. (ed.) Aziridines and Epoxides in Organic Synthesis 2006 ISBN: 978-3-527-31213-9 Cornils, B., Herrmann, W. A., Horvath, I. T., Leitner, W., Mecking, S., Olivier-Bourbigou, H., Vogt, D. (eds.) Multiphase Homogeneous Catalysis 2005 ISBN: 978-3-527-30721-0 Christoffers, J., Baro, A. (eds.) Quaternary Stereocenters Challenges and Solutions for Organic Synthesis 2005 ISBN: 978-3-527-31107-1 Dyker, G. (ed.) Handbook of C-H Transformations Applications in Organic Synthesis 2005 ISBN: 978-3-527-31074-6 Knochel, P. (ed.) Handbook of Functionalized Organometallics Applications in Synthesis 2005 ISBN: 978-3-527-31131-6 Iron Catalysis in Organic Chemistry Reactions and Applications Edited by Bernd Plietker The Editor All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and Prof. Dr. Bernd Plietker publisher do not warrant the information contained Institut für Organische Chemie in these books, including this book, to be free of Universität Stuttgart errors. Readers are advised to keep in mind that Pfaffenwaldring 55 statements, data, illustrations, procedural details or 70569 Stuttgart other items may inadvertently be inaccurate. Germany Library of Congress Card No.: applied for British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library. -
Durham E-Theses
Durham E-Theses The synthesis and potential applications of asymmetric silacycles Matthews, Jennifer Louise How to cite: Matthews, Jennifer Louise (1994) The synthesis and potential applications of asymmetric silacycles, Durham theses, Durham University. Available at Durham E-Theses Online: http://etheses.dur.ac.uk/5504/ Use policy The full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that: • a full bibliographic reference is made to the original source • a link is made to the metadata record in Durham E-Theses • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders. Please consult the full Durham E-Theses policy for further details. Academic Support Oce, Durham University, University Oce, Old Elvet, Durham DH1 3HP e-mail: [email protected] Tel: +44 0191 334 6107 http://etheses.dur.ac.uk The Synthesis and Potential Applications of Asymmetric Silacycles The copyright of this thesis rests with the author. No quotation from it should be published without his prior written consent and information derived from it should be acknowledged. Jennifer Louise Matthews, B.Sc. (Hons) Ph.D. Thesis University of Durham November 1994 COPYRIGHT The copyright of this work rests with the author. No quotation from it should be published without prior consent. Information derived from this thesis should be acknowledged. DECLARATION The work contained in this thesis was carried out in the Department of Chemistry at the University of Durham between October 1991 and September 1994. -
Iron Complexes and (Dienyl)Iron Cations in Organic Synthesis William Donaldson Marquette University, [email protected]
CORE Metadata, citation and similar papers at core.ac.uk Provided by epublications@Marquette Marquette University e-Publications@Marquette Chemistry Faculty Research and Publications Chemistry, Department of 8-1-2009 Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis William Donaldson Marquette University, [email protected] Subhabrata Chaudhury Marquette University Accepted version. European Journal of Organic Chemistry, Volume 2009, Issue 23 (August 2009). pp 3831-3843. DOI: 10.1002/ejoc.200900141 © 2009 Wiley-VCH Verlag. Used with permission. This is the pre-peer reviewed version of the article, which has been published in final form. NOT THE PUBLISHED VERSION; this is the author’s final, peer-reviewed manuscript. The published version may be accessed by following the link in the citation at the bottom of the page. Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis William A. Donaldson Department of Chemistry, Marquette University Milwaukee, WI Subhabrata Chaudhury Department of Chemistry, Marquette University Milwaukee, WI Abstract: Complexation of (tricarbonyl)iron to an acyclic diene serves to protect the ligand against oxidation, reduction and cycloaddition reactions while the steric bulk of this adjunct serves to direct the approach reagents to unsaturated groups attached to the diene onto the face opposite to iron. Furthermore, the Fe(CO)3 moiety can serve to stabilize carbocation centers adjacent to the diene (i.e. pentadienyl-iron cations). Recent applications of these reactivities to the synthesis of polyene, cyclopropane, cycloheptadiene and cyclohexenone containing natural products or analogs will be presented. Keywords: Diene ligands, Iron, Synthetic methods, Regioselective nucleophilic addition. -
Synthesis, Properties Characterization and Applications of Various Organobismuth Compounds
Molecules 2011, 16, 4191-4230; doi:10.3390/molecules16054191 OPEN ACCESS molecules ISSN 1420-3049 www.mdpi.com/journal/molecules Review Synthesis, Properties Characterization and Applications of Various Organobismuth Compounds Jingfei Luan *, Lingyan Zhang and Zhitian Hu State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China; E-Mails: [email protected] (L.Z.), [email protected] (Z.H.) * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +86-135-8520-6718; Fax: +86-25-8370-7304. Received: 15 April 2011; in revised form: 9 May 2011 / Accepted: 12 May 2011 / Published: 20 May 2011 Abstract: Organobismuth chemistry was emphasized in this review article due to the low price, low toxicity and low radioactivity characteristics of bismuth. As an environmentally- friendly class of organometallic compounds, different types of organobismuth compounds have been used in organic synthesis, catalysis, materials, etc. The synthesis and property characterization of many organobismuth compounds had been summarized. This review article also presented a survey of various applications of organobismuth compounds in organic transformations, as reagents or catalysts. The reactivity, reaction pathways and mechanisms of reactions with organobismuths were discussed. Less common and limiting aspects of organobismuth compounds were also briefly mentioned. Keywords: organobismuth compounds; synthesis; properties; reagent; catalyst 1. Introduction Organometallic compounds such as organoboron, organotin, organosilicon, organoantimony, organolead, etc. have been widely applied in organic synthesis in the past several decades [1-3]. A number of reports [4-8] on these compounds have mentioned their positive role in a variety of synthetic transformations or polymerizations, acting as reagents or catalysts. -
REGIOCHEMISTRY of DIALKYL CADMIUM ADDITION to Cis- AND
REGIOCHEMISTRY OF DIALKYL CADMIUM ADDITION TO cis- AND trans-HEXAHYDROPHTHALIC ANHYDRIDES By VASUDHA BALASUBRAMANIAN h Master of Science Pune University Pune,India 1982 Submitted to the Faculty of the Graduate College of the Oklahoma State University in partial fulfillment of the requirements for the Degree of MASTER OF SCIENCE December,l987 Tk~\o() \9~1 'B\1 \ r (.op. d REGIOCHEMISTRY OF DIALKYL CADMIUM ADDITION TO cis- AND trans-HEXAHYDROPHTHALIC ANHYDRIDES Dean of the Graduate College ii 129086"/ ACKNOWLEDGEMENTS I wish to express my gratitude to Dr.E.J.Eisenbraun for his guidance,understanding and encouragement throughout this study. Many thanks also go to Dr.J.P.Devlin and Dr.I.D.Eubanks for serving on my graduate committee. I also wish to thank the members of the faculty and the staff of the Chemistry Department for their assistance during the course of this work. I would also like to thank Mr.Stan Sigle for his help in obtaining NMR spectra. My deepest gratitude to my parents,-for their constant and unstinting love,understanding and support. iii TABLE OF CONTENTS Chapter Page I. INTRODUCTION AND HISTORICAL 1 II. RESULTS AND DISCUSSION 16 III. EXPERIMENTAL ..... 33 cis-2-Acetylcyclohexanecarboxylic Acid (3a). 34 a. Grignard Reaction • . • • . • . 34 b. Methyl Lithium Reaction . 35 c. Synthesis of the Dimethyl Cadmium Reagent . • . • . 37 d. Reaction with Dimethyl Cadmium . 37 trans-2-Acetylcyclohexanecarboxylic Acid (3b). 39 a. Reaction with Dimethyl Cadmium • . • 39 b. Epimerization Reaction . 40 cis-2-Trimethylacetylcyclohexanecarboxylic- .h::::id (~ • • • • • • • • • • • • • • • 41 a. synthesis of the Di-tert-butyl Cadmium Reagent . 42 b. Reaction with Di-tert-butyl Cadmium . -
Advanced Organic Chemistry PART A: Structure and Mechanisms PART B: Reactions and Synthesis Advanced Organic FIFTH Chemistry EDITION
Advanced Organic FIFTH Chemistry EDITION Part B: Reactions and Synthesis Advanced Organic Chemistry PART A: Structure and Mechanisms PART B: Reactions and Synthesis Advanced Organic FIFTH Chemistry EDITION Part B: Reactions and Synthesis FRANCIS A. CAREY and RICHARD J. SUNDBERG University of Virginia Charlottesville, Virginia 123 Francis A. Carey Richard J. Sundberg Department of Chemistry Department of Chemistry University of Virginia University of Virginia Charlottesville, VA 22904 Charlottesville, VA 22904 Library of Congress Control Number: 2006939782 ISBN-13: 978-0-387-68350-8 (hard cover) e-ISBN-13: 978-0-387-44899-2 ISBN-13: 978-0-387-68354-6 (soft cover) Printed on acid-free paper. ©2007 Springer Science+Business Media, LLC All rights reserved. This work may not be translated or copied in whole or in part without the written permission of the publisher (Springer Science+Business Media, LLC, 233 Spring Street, New York, NY 10013, USA), except for brief excerpts in connection with reviews or scholarly analysis. Use in connection with any form of information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now know or hereafter developed is forbidden. The use in this publication of trade names, trademarks, service marks and similar terms, even if they are not identified as such, is not to be taken as an expression of opinion as to whether or not they are subject to proprietary rights. 98765432(corrected 2nd printing, 2008) springer.com Preface The methods of organic synthesis have continued to advance rapidly and we have made an effort to reflect those advances in this Fifth Edition. -
Iron(III) As Lewis Acid Catalyst in Organosilicon and Carbonyl Chemistry
Risto Savela Iron(III) as Lewis Acid Catalyst in Organosilicon and Carbonyl Chemistry Iron(III) as Lewis Acid Catalyst in Organosilicon and Carbonyl Chemistry Acid Catalyst in Organosilicon Iron(III) as Lewis Risto Savela Johan Gadolin Process Chemistry Centre Laboratory of Organic Chemistry Faculty of Science and Technology Åbo Akademi University ISBN 978-952-12-3205-3 Åbo, Finland Painosalama Oy – Turku, Finland 2015 2015 2015 Iron(III) as Lewis Acid Catalyst in Organosilicon and Carbonyl Chemistry Risto Savela Johan Gadolin Process Chemistry Centre Laboratory of Organic Chemistry Faculty of Science and Technology Åbo Akademi University Åbo, Finland 2015 Supervisor and Custos Professor Reko Leino Laboratory of Organic Chemistry Åbo Akademi University Åbo, Finland Opponent Dr. George Britovsek Department of Chemistry Imperial College London London, United Kingdom Reviewers Professor Timo Repo Laboratory of Inorganic Chemistry University of Helsinki Helsinki, Finland and Professor Hans Adolfsson Department of Organic Chemistry Stockholm University Stockholm, Sweden ISBN 978-952-12-3206-0 Painosalama Oy – Turku, Finland 2015 Remember kids, the only difference between screwing around and science, is writing it down. Adam Savage PREFACE The present work was carried out at the Laboratory of Organic Chemistry, Department of Natural Sciences, Åbo Akademi University between the years 2009 and 2015. Financial support from the former National Graduate School of Organic Chemistry and Chemical Biology, Stiftelsen för Åbo Akademi, Magnus Ehrnrooth foundation, Orion Farmos Research foundation, Rector of Åbo Akademi and Kemian Päivien säätiö is gratefully acknowledged. I wish to express my gratitude to my supervisor Professor Reko Leino for giving me the opportunity to join the research group, giving me a chance to venture into the world of iron catalysis and for his patience and support during these years.