(19) United States (12) Patent Application Publication (10) Pub

US 20100034767A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2010/0034767 A1 Trabelsi (43) Pub. Date: Feb. 11, 2010

(54) COMPOSITION FOR MAKING UP THE LIPS (30) Foreign Application Priority Data

(75) Inventor: Vanessa Trabelsi, Villemomble Jan. 23, 2007 (FR) ...... 07/00457 (FR) Publication Classi?cation Correspondence Address: YOUNG 8‘ THOMPSON (51) .I4n6tiI€l§1/74 (2006 01) 209 Madison Street, Suite 500 A61Q 90/00 (2009'01) Alexandria, VA 22314 (US) ' (52) US. Cl...... 424/78.03 (73) Assignee: CHANEL PARFUMS BEAUTE, Neuilly Sur Seine (FR) (57) ABSTRACT

21 A l. N .: 12/524 108 A cosmetic com p osition in the form of a Water-in-oil emul ( ) pp 0 ’ sion includes a fatty phase and an aqueous phase, the fatty (22) PCT Filed: Jam 23, 2008 phase of Which includes at least one hydrocarbon oil, at least one ?rst copolymer of ethylene and of propylene and at least (86) PCT NO; PCT/EP08/50780 one second copolymer of styrene and of at least one ole?n other than styrene. A cosmetic method for caring for or mak § 371 (0X1), ing up skin or the lips, and the topical application to the lips of (2), (4) Date: Jul. 22, 2009 this composition are also disclosed. US 2010/0034767 A1 Feb. 11, 2010

COMPOSITION FOR MAKING UP THE LIPS copolymer of ethylene and of propylene, and at least one second copolymer of styrene and of at least one ole?n other than styrene. [0014] For greater transparency, the refractive index of the [0001] The present invention relates to a cosmetic compo sition in the form of a Water-in-oil emulsion comprising at aqueous phase can advantageously be increased by providing for the aqueous phase to include at least one polyol. Polyg least one non volatile hydrocarbon oil, at least one ?rst copolymer of ethylene and of propylene, and at least one lycerol-6 is preferred in so far as it brings about a big increase second copolymer of styrene and of at least one ole?n other in the refractive index of the aqueous phase. than styrene. Non Volatile Hydrocarbon Oil [0002] It also relates to a cosmetic method for caring or making up the face comprising the topical application of this [0015] As indicated above, the composition includes at composition on the keratinous material. least one non volatile hydrocarbon oil. [0003] The present invention deals With compositions for [0016] Within the meaning of the present invention, the making up the skin, nails, eyelashes, eyebroWs, or the lips, term “oil” is understood to mean a compound Which is liquid such as foundations, eyeshadoWs, lipsticks, lip gloss prod at ambient temperature (25° C.) and Which, When it is intro ucts, products for concealing rings under the eyes, blushers, duced in a proportion of at least 1% by Weight into Water at mascaras, eyeliners, lip pencils, eyeliner pencils, nail var 25° C., is not at all soluble in Water or soluble to a level ofless nishes. than 10% by Weight, With respect to the Weight of oil intro duced into the Water. [0004] According preferred embodiments, the cosmetic [0017] The term “hydrocarbon oil” is understood to mean composition is a lip gloss product, a foundation base or a product for the styling of eyebroWs. an oil comprising hydrogen and carbon atoms, and containing no silicon atoms. [0005] One aim of the present invention is to provide a [0018] Within the meaning of the present invention, the cosmetic composition giving a fresh feeling upon application, term “non volatile oil” is understood to mean an oil Which has having a good Wear during the day, and having a good level of a vapour pressure at ambient temperature and atmospheric transparency. pressure, loWer that 0.13 Pa (10'3 mm Hg). [0006] The product is preferably non opaque, it means it is [0019] Hydrocarbon oils having a loW or moderate polarity transparent or translucent. are preferred, such as ester oils bearing no polar groups and [0007] A Way to obtain cosmetic products having a good hydrocarbure oils. Wear on keratinous materials is usually to include signi?cant [0020] When intended for lip application, the hydrocarbon proportions of volatile oils. Nevertheless, such large amount oil preferably have a high refractive index, typically above of volatile oils decrease comfort and gloss of said composi 1.45, or even above 1.47. tions. [0021] The non volatile hydrocarbon oil present in the com [0008] One aim of the present invention is to provide a position according to the invention may be chosen from cosmetic composition giving a fresh fccling upon application, hydrocarbures, i.e. oils made of carbon and hydrogen atoms. having a good Wear during the day, and having a minimum It can in particular be chosen from polybutene, hydrogenated gloss effect. According one embodiment, the composition polyisobutene and hydrogenated polydecene. It is preferably according to the invention contains loW amounts of volatile hydrogenated polydecene. oils and still performs good Wear on lips or skin. [0022] According to the invention, the non volatile hydro [0009] In this context, the aim of the present invention is to carbon oils can also be chosen chosen from esters of mono provide a composition for making up the skin, the eyebroWs carboxylic acids preferably monoesters. or the lips, Which is translucent or transparent, and provides a [0023] Advantageously, said esters correspond to the fol freshening feeling to the consumer When applied on the kera loWing formula (I): tinous material. [0010] In order to solve this problem, the Applicant has Where R1 represents a linear or branched alkyl radical of 1 to looked for a Water-in-oil emulsion containing non volatile 40 carbon atoms, preferably of 7 to 19 carbon atoms, option hydrocarbon. He has surprisingly found that the mixture of ally comprising one or more ethylenic double bonds, and tWo speci?c copolymers makes it possible to loWer the refrac optionally substituted, tive index of a fatty phase comprising a non volatile hydro [0024] R2 represents a linear or branched alkyl radical of 1 carbon oil to bring it closer to that of an aqueous phase. to 40 carbon atoms, preferably of 3 to 30 carbon atoms and [0011] The aim of the present invention is achieved by the even better of 3 to 20 carbon atoms, optionally comprising use, in an emulsion of Water-in-oil type comprising a non one or more ethylenic double bonds. volatile hydrocarbon oil, of a combination of at least tWo [0025] R2 can also represent an aryl radical, for example speci?c copolymers. benZyl. [0012] A subject-matter of the present invention is thus a [0026] The number of carbon of said ester preferably goes cosmetic composition in the form of a Water-in-oil emulsion from 10 to 40, and is typically around 20. comprising at least one non volatile hydrocarbon oil, at least [0027] R1 may represent the residue of a preferably higher, one ?rst copolymer of ethylene and of propylene and at least linear or, preferably branched fatty acid comprising from 1 to one second copolymer of styrene and of at least one ole?n 40 and even better from 7 to 19 carbon atoms and R2 may other than styrene. represent a linear or preferably branched hydrocarbon chain [0013] The Water-in-oil emulsion includes a fatty phase and containing from 1 to 40, preferably from 3 to 30 and even an aqueous phase, and the fatty phase preferably comprises at better from 3 to 20 carbon atoms. Examples of R1 groups are least one non volatile hydrocarbon oil, at least one ?rst those derived from fatty acids chosen from the group consist US 2010/0034767 A1 Feb.11, 2010

ing of acetic, propionic, butyric, caproic, caprylic, pelargonic, dients of the composition. Said non volatile hydrocarbon oil capric, undecanoic, lauric, myristic, palmitic, stearic, isos can be one of the oils described hereabove. tearic, arachidic, behenic, oleic, linolenic, linoleic, oleo [0050] As an example, second copolymer can be a blend of stearic, arachidonic and erucic acids, and mixtures thereof. ethylene/propylene/ styrene copolymer and butylene/ethyl [0028] Examples of esters Which can be used in the fatty ene/ styrene copolymer. phases of the compositions of the invention are for example [0051] The ?rst and second copolymers are preferably purcellin oil (cetostearyl octanoate), isononyl isononanoate, included in the fatty phase of the Water-in-oil emulsion isopropyl myristate, isopropyl palmitate, 2-ethylhexyl palmi according to the invention. tate, C12-C15 ester benZoate, 2-octyldodecyl stearate, 2-oc [0052] The ratio of second to ?rst copolymer goes advan tyldodecyl erucate, isostearyl isostearate, and heptanoates, tageously from 1/ 10 to 20/ 1, more preferably from 1/ 2 to 5/ 1, octanoates, decanoates or ricinoleates of alcohols or polyal preferably from 1/1 to 2/ 1. cohols, for example of fatty alcohols. [0053] The amount of second copolymer goes advanta [0029] The ester oil Will be preferably chosen from the geously from 0.1 to 10% by Weight of the total Weight of the following compounds: composition, preferably from 0.5 to 5%. [0030] isononyl isononanoate, [0031] isopropyl palmitate, Other Ingredients [0032] isostearyl isostearate. [0054] Apart from the non volatile hydrocarbon oil, the [0033] The non volatile hydrocarbon oil amount advanta Water-in-oil emulsion according to the invention can include geously goes from 5 to 35% by Weight of the total Weight of at least one other oil chosen in particular from: the composition, preferably from 10 to 30% by Weight of the [0055] synthetic (poly)esters and (poly)ethers, vegetable total Weight of the composition. oils, branched and/or unsaturated fatty acids, such as octyl First Copolymer dodecanol, branched and/or unsaturated fatty alcohols, sili cone oils, such as linear polydimethylsiloxanes, Which are [0034] The ?rst copolymer can be an ethylene/propylene optionally phenylated, or cyclic polydimethylsiloxanes, ?uo copolymer in dispersion in a non volatile hydrocarbon oil. rosilicone oils, ?uorinated oils, and their mixtures. Said non volatile hydrocarbon oil can be one of the oils [0056] The amount of oils present in the composition described hereabove. including said non volatile hydrocarbon oil preferably repre [0035] As an example, ?rst copolymer can be an ethylene/ sents more than 20%, more preferably more than 25%, of the propylene copolymer in dispersion in hydrogenated poly total Weight of this composition, for example betWeen 20 and decene, such as those sold inparticular by Creations Couleurs 50%, preferably betWeen 25 and 40%, more preferably under the trade name Creagel® crystal, and in particular betWeen around 30% and around 35%. Creagel® crystal AF. [0057] Among the oils of the composition, it is preferable to [0036] The amount of ?rst copolymer goes advantageously use, in the present invention, at least one glossy oil, that is to from 0.1 to 10% by Weight of the total Weight of the compo say an oil exhibiting a refractive index of greater than 1 .45 and sition, preferably from 0.5 to 5%. preferably of greater than 1.47. [0058] Examples of glossy oils are in particular phenylated Second Copolymer silicone oils, such as those identi?ed by the INCI name “phe nyl trimethicone”, an example of Which is composed of the [0037] The second copolymer can more particularly be a silicone available under the trade name Mirasil PTM from diblock or triblock copolymer or a copolymer comprising Rhodia, those identi?ed by the INCI name “phenylpropy radial blocks. These copolymers generally do not comprise a ldimethylsiloxysilicate”, an example of Which is composed of monomer other than ole?ns, so that they are preferably cho the silicone available under the trade name Silshine 151 from sen from ole?n copolymers comprising a styrene monomer. General Electric, and those identi?ed by the INCI name “tri [0038] The second copolymer can in particular comprise, methyl pentaphenyl trisiloxane”, an example of Which is as ole?n other than styrene, at least one ole?n chosen from composed of the silicone available under the trade name DC ethylene, propylene, butylene, butadiene and isoprene, With PH 1555 HRI from Dow Coming. out this list being limiting. [0059] Mention may also be made, as glossy oils, of the [0039] The second copolymer can in particular be chosen ?uorinated silicones identi?ed by the INCI name “per?uo from rononyl dimethicone”, an example of Which is composed of [0040] ethylene/propylene/ styrene, the silicone available under the trade name Pecosil FS (FSU, [0041] butylene/ethylene/ styrene, ESL, and the like) from Phoenix and another example of [0 042] butadiene/ styrene, Which is composed of the silicone available under the trade [0 043] isoprene/ styrene, name Biosil Basics (Fluorosil LE, 14, and the like) from [0044] styrene/butadiene/ styrene, Biosil Technologies. [0045] styrene/isoprene/ styrene, [0060] Other examples of glossy oils are natural oils and in [0046] styrene/ ethylene/butylene/ styrene copolymers, particular castor seed oil; mono- and polyesters of fatty acids [0047] and their blends. and/or of fatty alcohols, the fatty chain of Which includes [0048] The second copolymer can in particular be chosen from 6 to 20 carbon atoms, in particular: mono- and polyes from copolymers sold by Shell under the trade name Kra ters of hydroxy acids and of fatty alcohols, such as diisos ton®: Kraton G1701 X, G1652, D1102, D1107, D116, or by tearyl malate, esters of benZoic acid and of fatty alcohols, Penreco under the trade name Versagel®: Versagel® MN, such as Clz-Cl5 alkyl benZoate, polyesters of polyols and in ME, MP, ML. particular of (di)pentaerythritol, such as pentaerythrityl tet [0049] The second copolymer can be dispersed in a non raisostearate, dipentaerythrityl pentaisononanoate and dipen volatile hydrocarbon oil, before mixing With the other ingre taerythrityl C5-C9 esters, or of polyglycerol, such as that US 2010/0034767 A1 Feb. 11, 2010

known under the INCI name “bis-diglyceryl polyacyladipate least one fatty-phase structuring agent, such as a Wax, a paste, 1” and sold by Sasol under the trade name Softisan 645, or of a lipophilic gelling agent or their mixtures. trimethylolpropane, such as trimethylolpropane triethylhex [0070] The term “Wax” is understood to mean a fatty sub anoate, Which is sold in particular by Kokyu Alcohol Kogyo stance Which has a melting point of greater than 30° C. and under the trade name Kak TTO, or of propylene glycol, such generally of less than 90° C., Which is liquid under the con as propylene glycol dibenZoate, Which is sold in particular by ditions of preparation of the composition and Which exhibits, Inolex under the trade name Lexfeel Shine, and isocetyl in the solid state, an anisotropic crystalline arrangement. stearoyl stearate; and polyesters of hydrogenated castor oil, Examples of Waxes are in particular vegetable, mineral or such as the esters sold by Kokyu Alcohol Kogyo under the synthetic Waxes, it being possible for the latter advanta trade names Risocast DA-H and Risocast DA-L. geously to be hydrocarbon or silicone Waxes. Mention may [0061] It is clearly understood that the composition accord thus be made of camauba Wax, candelilla Wax, beesWax (Cera ing to the invention can comprise mixtures of the oils men alba), polyethylene Wax and paraf?n Wax, as Well as oZoker tioned above. ites and triesters of CS-C2O acids and of glycerol, such as [0062] The composition employed according to the inven glyceryl tribehenate, and their mixtures, Without this list tion can additionally include at least one volatile oil. The being limiting. amount of volatile oil is preferably loW, typically loWer than [0071] Examples of lipophilic gelling agents are in particu 15% by Weight of the total Weight of the composition, more lar silicone polymers and more particularly organopolysilox preferably loWer than 10% by Weight of the total Weight of the ane elastomers. Mention may be made, among these, of the at composition, even more preferably betWeen 5 and 8% by least partially crosslinked polymers resulting from the reac Weight of the total Weight of the composition. The composi tion of an organopolysiloxane carrying unsaturated groups, tion may be free of volatile oil. such as vinyl or allyl groups, situated at the end of or in the [0063] The term “volatile oil” is understood to mean an oil middle of the chain, preferably on a silicon atom, With another Which has a nonZero vapour pres sure at ambient temperature reactive silicone compound, such as an organohydropolysi and atmospheric pressure, in particular Which has a vapour loxane. These polymers are usually available in gel form in a pressure ranging from 0.13 Pa to 40 000 Pa (10-3 to 300 volatile or non-volatile silicone solvent or in a hydrocarbon mmHg), preferably ranging from 1.3 Pa to 13 000 Pa (0.01 to solvent. Examples of such elastomers are sold in particular by 100 mmHg) and preferentially ranging from 1 .3 Pa to 1300 Pa Shin-Etsu under the trade names KSG-6, KSG-16, KSG-31, (0.01 to 10 mmHg). KSG-32, KSG-41, KSG-42, KSG-43 and KSG-44 and by [0064] The volatile oil can be a silicone oil, a hydrocarbon Dow Corning under the trade names DC 9040 and DC 9041. oil, a ?uorinated oil or a mixture of such oils. Another oily gelling agent is composed of a silicone polymer, obtained by self polymeriZation in the presence of a catalyst [0065] The term “silicone oil” is understood to mean an oil of an organopolysiloxane functionaliZed by epoxy groups comprising at least one silicon atom and in particular at least and hydrosilylated, Which is available commercially from one Si4O group. General Electric under the trade name Velvesil 125. Another [0066] Examples of volatile silicone oils or volatile sili lipophilic gelling agent is composed of a cyclic vinyldime cones are in particular the linear or cyclic silicone oils having thicone/dimethicone copolymer, such as that sold by Jeen a viscosity of less than 8 centistokes (8><10_6 mVs) and under the trade name Jeesilc PS (including PS-VH, including in particular from 2 to 10 silicon atoms, more PS-VHLV, PS-CM, PS-CMLV and PS-DM). particularly from 2 to 7 silicon atoms, these silicones option [0072] Another type of lipophilic gelling agent is com ally comprising alkyl or alkoxy groups comprising from 1 to posed of polyamides, such as those identi?ed by the INCI 10 carbon atoms. Mention may in particular be made, as name polyamide-3 and in particular the SylvaclearAF 1900V volatile silicone oil Which can be used in the invention, of and PA 1200V polymers available from Arizona Chemicals, some dimethicones With a viscosity of 5 and 6 cSt, octameth and also those identi?ed by the INCI name “Ethylenedi ylcyclotetrasiloxane, decamethylcyclopentasiloxane, amine/ Hydrogenated Dimer Dilinoleate Copolymer Bis-Di dodecamethylcyclohexasiloxane, heptamethylhexyltrisilox C14-18 Alkyl Amide” and available, for example, under the ane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, trade name Sylvaclear A200V or Sylvaclear A2614V from octamethyltrisiloxane, decamethyltetrasiloxane, dodecam Arizona Chemical. In an alternative form, the lipophilic gel ethylpentasiloxane, the compounds identi?ed by the INCI ling agent can be a bentone or a sucrose ester, such as that names methyl trimethicone and caprylyl methicone, and their denoted by the INCI name “Sucrose tetrastearate triacetate”. mixtures. Cyclic silicone oils are preferred in the present [0073] The fatty phase can also include one or more pasty invention. compounds, that is to say lipophilic fatty substances Which, [0067] Volatile hydrocarbon oils can be chosen from like the Waxes, are capable of undergoing a reversible liquid/ hydrocarbon oils comprising from 8 to 16 carbon atoms, in solid change in state and have, in the solid state, an anisotropic particular branched CS-Cl6 alkanes (also known as isoparaf crystalline arrangement but Which differ from the Waxes in ?ns), such as isododecane (also knoWn as 2,2,4,4,6-pentam that they include, at a temperature of 23° C., a liquid fraction ethylheptane), isodecane or isohexadecane. and a solid fraction. [0068] The term “?uorinated oil” is understood to mean an [0074] In addition, it can comprise at least one ?lm-forming oil comprising at least one ?uorine atom, such as nona?uo polymer capable of introducing hold and/ or transfer-free romethoxybutane, per?uoromethylcyclopentane, per?uo properties and/ or gloss to the makeup conferred by the com rodimethylcyclohexane, per?uoroperhydrophenanthrene, position. It can in particular be a silicone polymer optionally per?uorodecalin, and their mixtures, Without this list being modi?ed by urethane or ?uorine or acrylate, such as the limiting. (meth)acrylate silicones sold by Shin-Etsu under the trade [0069] The fatty phase of the Water-in-oil emulsion accord names KP-545, KP-561 and KP-562, or the polymers sold by ing to the invention can in addition advantageously include at DoW Corning under the trade names DC FA 4002 ID and DC US 2010/0034767 A1 Feb. 11, 2010

FA 4001 CM. Other examples of ?lm-forming polymers are [0082] In particular, the polyglycerol can comprise from silicone resins and in particular MQ resins, such as trimeth tWo to ten glycerol units on average. Polyglycerol-6 is pre ylsiloxysilicates, and MT resins, such as silsesquioxane ferred derivatives and in particular polymethylsilsesquioxanes, sold [0083] The polyglycerol content is advantageously com in particular by Shin-Etsu, and also the polypropylsilsesqui prised betWeen 1 and 10% by Weight, typically around 5% by oxanes sold by DoW Corning under the trade name DC 670 or Weight of the Weight of the composition. the phenylpropylpolysilsesquioxane sold by Wacker under [0084] The polyol or mixture of polyol can represent from the trade name Belsil SPR45VP. Another example is com 5 to 40% by Weight, preferably 10 to 35%, for example from posed of ?uorosilicone polymers identi?ed by the INCI name 25 to 30% by Weight of the total Weight of the composition. “Tri?uoropropyldimethylsiloxy Triethylsiloxysilicate”, such [0085] In addition to Water and the possible polyols as that sold by General Electric under the trade name X866 described above, the aqueous phase of the Water-in-oil emul B8226. Use may also be made, as ?lm-forming polymers, of sion according to the invention can comprise hydrophilic or bioadhesive polymers obtained, for example, by polyconden lipophilic active principles, hydrophilic latexes or at least one sation of dimethiconol and of MQ silicate resin in a solvent, hydrophilic gelling agent. The hydrophilic gelling agent is such as heptane, Which are sold in particular by DoW Corning preferably a hydrocolloid Which can in particular be chosen under the trade names DC7-4405 loW tack and DC7-4505 from: homo- and copolymers of acrylic acid and/or of salts or high tack. Other examples of ?lm-forming polymers are poly of esters of acrylic acid, such as carbomers, homo- and (cyclic ole?ns), such as polycyclopentadiene, sold in particu copolymers of acrylamide, homo- and copolymers of acry lar by Kobo under the trade name Koboguard 5400, or also loylamidomethylpropanesulphonic acid (AMPS), such as polydicyclopentadiene. Yet other examples of ?lm-forming Aristo?ex® AVC or HMB from Clariant, guar or xanthan polymers are composed of copolymers of vinylpyrrolidone gums and cellulose derivatives, Without this list being limit (VP) and/or of linear ole?ns, such as VP/hexadecene and ing. VP/eicosene copolymers, including Antaron V216 and [0086] The composition according to the invention can also Antaron V220 from ISP, or also ethylene/vinyl acetate comprise one or more Water-in-oil emulsi?ers preferably copolymers, such as AC 400 from Baerlocher. Other ?lm chosen from non-ionic surfactants, such as polyethoxylated forming polymers capable of being used in this invention are dipolyhydroxystearate (30 E0), sold in particular under the polyacrylates, such as poly(ethyl acrylate), sold in particular trade nameArlacel® P135 by Uniqema; or also polysiloxanes by Creations Couleurs under the trade name Creasil 7 ID. modi?ed by polyethers, Without this list being limiting. [0075] The Water-in-oil emulsion according to the inven [0087] The composition used according to the invention tion includes, in addition to the fatty phase described above, can additionally include at least one ?ller. This term is under an aqueous phase comprising Water and optionally hydro stood to mean any inorganic or organic particle of any shape philic and/or Water-soluble additives, such as polyol. (in particular spherical or lamellar) Which is insoluble in the [0076] The aqueous phase of the Water-in-oil emulsion composition. Examples of ?llers are talc, mica, silica, kaolin, preferably represents from 30 to 60% by Weight of the total boron nitrite, starch, starch modi?ed by octenylsuccinic Weight of the composition, preferably from 40 to 50% by anhydride, polyamides, silicone resins, poWders derived from Weight of the total Weight of the composition. silicone elastomers and poWders derived from acrylic poly [0077] According to a preferred embodiment, the compo mers, in particular from poly(methyl methacrylate). The ?ll sition according to the invention includes from 5 to 30% by ers can inparticular be composed of several layers of different Weight, preferably from 10 to 20% by Weight, of Water, With chemical nature and/or of different physical form and can in respect to the total Weight of the composition. particular be provided in the form of lamellae coated With spherical ?llers. They can be modi?ed using various surface [0078] For greater transparency, the refractive index of the treatments. An example of a surface-treated ?ller is composed aqueous phase can advantageously be increased by including of silica modi?ed by an ethylene/methacrylate copolymer, at least one polyol in the aqueous phase. Polyol is understood sold in particular by Kobo under the trade names DSPCS to mean a polymeric or nonpolymeric compound including at 20N-l2, DSPCS/3H-l2 and DSPCS-l2. least tWo hydroxyl groups. [0088] The composition can also comprise at least one [0079] Polyol can advantageously be a polyglycerol deriva colouring material chosen from Water-soluble or fat-soluble tive such as an industrially produced, commercially available dyes, ?llers having the effect of colouring and/ or opacifying product, such as polyglycerol #310 (manufactured by Saka the composition and/or of colouring the lips, such as pig moto Yakuhin Kogyo Co., Ltd.), polyglycerol #500 (manu ments, pearlescent agents, lakes (Water-soluble dyes factured by Sakamoto Yakuhin Kogyo Co., Ltd.), polyglyc adsorbed on an inert inorganic carrier), and their mixtures. erol #750 (manufactured by Sakamoto Yakuhin Kogyo Co., These colouring materials can optionally be treated at the Ltd.), diglycerol (manufactured by Sakamoto Yakuhin Kogyo surface With a hydrophobic agent, such as silanes, silicones, Co., Ltd.) fatty acid soaps, C9_ 15 ?uoroalkyl phosphates, acrylate/dime [0080] Polyol Which can be used comprise glycols, such as thicone copolymers, mixed C9_ 15 ?uoroalkyl phosphate/sili propylene glycol, dipropylene glycol and butylene glycol; cone copolymers, lecithins, carnauba Wax, polyethylene, chi glycerol; monosaccharides, such as glucose and fructose; tosan and optionally acylated amino acids, such as lauroyl sorbitol; disaccharides, such as sucrose (or saccharose); lysine, disodium stearoyl glutamate and aluminium acyl homopolymers of glycols, such as poly(ethylene glycol)s and glutamate. The pigments can be inorganic or organic and poly(propylene glycol)s; homopolymers of glycerol or natural or synthetic. Examples of pigments are in particular polyglycerols; and their mixtures. iron, titanium or Zinc oxides, and also composite pigments [0081] Sucrose, polyglycerol and their mixtures are pre and goniochromatic, pearlescent, interferential, photochro ferred for use in the present invention. mic or thermochromic pigments, Without this list being lim US 2010/0034767 A1 Feb. 11, 2010

iting. The pearlescent agents can be chosen from those con [0102] Phosphodiesterases inhibitors, such as visnadine, ventionally present in makeup products, such as mica esculoside, icarine or extracts containing them, as titanium dioxide products. described in WO 2005/004858; [0089] The composition can comprise pigments, pearls [0103] Flavono'ids or ?avoglycosides; and/ or ?llers. As inorganic pigments Which can be used in the [0104] Glucosides; invention, mention may be made of titanium, Zirconium or [0105] Plant extracts or peptides having vasodilatory cerium oxide, as Well as Zinc, iron or chromium oxide and properties. ferric blue. [0106] Antihypertensive agents can be thiaZides; angio [0090] Among the organic pigments Which can be used in tensin receptor inhibitors, such as losartan or candesartan; the invention, mention may be made of carbon black and prostaglandins for example E prostaglandins and prostacy barium, strontium, calcium (DC Red No. 7) and aluminium clines; ACE inhibitors, such as captopril or ramipril; Potas lakes. sium-channel openers such as minoxidil, cromakalim, diaZ oxide, nicorandil, pinacidil or derivatives thereof; Calcium [0091] Among the pearlescent agents Which can be used in Channel Blockers such as nifedipine, verapamil, diltiaZem, the invention, mention may be made of mica coated With amlodipine; adrenergic receptors blockers such as niacine, titanium oxide, With iron oxide, With natural pigment or With praZosine, hydralaZine; acetylcholine, and muscaric recep bismuth oxychloride, such as coloured titanium mica. tors activators. [0092] The ?llers can be present in a proportion of from 0 to [0107] Flavonoids and ?avoglycosids can be for example 35% of the total Weight of the composition, preferably 0.5 to Ginkgo ?avoglycosids, amento?avone, Gingko biloba ?a 15%. Mention may be made in particular of talc, mica, kaolin, vones in free form or Gingko biloba ?avones complexed With Nylon poWders (Orgasol® in particular) and polyethylene phospholipids as described in WO 2005/0048584; hesperi poWder, Te?on, starch, boron nitride, copolymer micro dine, alpha-G-hesperidine, hesperidine methyl chalcone, spheres such as Expancel® (Nobel Industrie), Polytrap® rutosides (ex: betahydroxyéthyl-rutoside, trimethyl-ruto (Dow Coming) and silicone resin microbeads (Tospearl® side). from Toshiba, for example). [0093] The amount of colouring agent is preferably rather Vasodilatory Plant Extracts: loW, typically beloW 10% by Weight of the total Weight of the [0108] Helichrysum ilalicum extract as described in WO composition, for example between 1 and 5% by Weight, so 03/018730; Ribes nigrum extracts, Epimedium grandi Ora that transparency of the composition be not impaired. extract), Aclinidia chinensis L. extract, Cupressus sempervi [0094] The composition according to the invention can also rens extract, Melissa o?icinalis extract, I/inca minora extract, include sodium saccharinate; antioxidants, such as alkyl or Cenlella asialica extract, Terminalia sericea, Calendulae phosphoryl esters of ascorbic acid, or also tocopherol and its extracts, Arnica extracts, Ammi visnaga extracts. esters; sequestering agents, such as EDTA salts; pH adjusters; preservatives; and fragrances. Vasodilatory Peptides: [0095] The composition according to the invention can also include one or more active ingredients chosen from the fol [0109] CGRP (Calcitonin gene related peptide), substance loWing lists, such as agents stimulating vasodilatation or P (decapeptide liberated by nerve termination) or VIP (Vaso freshening agents. active Intestinal Polypeptide) as described in EP 225 639. [0096] An example of plumping agents is HYALURONIC Other Vasodilatory Agents: FILLING SPHERES. [0097] Hydrating agents can be chosen from: Ceretonia [0110] Niacine and derivatives thereof such as esters of Siliqua fruit extract, Crithmum Maritum extract, Lavender nicotinic acid (xanthinol nicotinate, inositol nicotinate); sali Wax, marine juice, Camellia ?oWer Water, Lotus Water, cylic acid and esters thereof; dihydroergotoxine methane Orange ?oWer Wax (citrus auranlium), Jasmine Wax (jasmi sulfonate; dihydroergocomine méthanesulfonate, dihydroer num grandi?orum), DECOX® (4-decyloxaZolidin-2-one), gocristine méthanesulfonate, cinnariZine, vincamine, HYDRATYL® LS 8453 and Lipofructyl Argan®. pentoxifylline, baméthane sulfate, bencyclane hydrogénofu marate, béta-pyridylcarbinol; Precursors of the Nitric Oxide [0098] Examples of procollagen agents are as folloWs: Donor (NO), non polymeric NO liberators; les stimulateurs Opal PoWder®, Peptides such as M300®, Maxi Lip®, DER de la synthese et/ou de l’activité des NO Synthases (NOS) MICAN®, Pisum salivum extract, Zingiber purpureum rhi Stimulators and mixtures thereof. Zome extract, Guazuma ulmifolia extract, Canarium com [0111] Agents for temperature modulation can be a fresh mune Gum-resin, hydrolyZed soybean protein, ening agent, as for example menthol, mint extracts or mint hydroxyproline, METHYLSILANOL MANNURONATE, essential oils; peppermint oil, Wintergreen oil, menthone, HYDROXYPROSILISILANE, hydrolyzed Cucurbila Pepo menthyl lactate, menthane derivatives, such as menthane car seedcake, Cenlella asialica extract, Keep young commiphora boxamides N-ethyl P-menthane Carboxamide-3,3-(l-meth jasmine Aquaphylline (viola lricolour extract). oxy)-propane-l,2-diol, p-menthane-3,8-diol, menthyl succi [0099] Essential oils can be chosen cinnamon, ginger oil, nate; aloe vera essential oils or ginseng essential oils. black pepper oil, chili pepper leaves oil, pepper mint oil, clove [0112] Freshening agent can comprise an endothermic oil, or one of their mixtures. organic salt such as potassium chloride, or urea. [0100] In particular, agents stimulating vasodilatation, and/ [0113] Agents for temperature modulation can be Warming or having anticoagulant activity and/or antihypertensive agent such as camphor, eucalyptus extract or essential oils, effect can be: ginseng essential oils. [0101] Antihypertensives agents, such as Potassium [0114] Microcirculation activating agents can be chosen channel openers; from Biomoduline (Lenlinus edodes), Ruscogenine, YuZu US 2010/0034767 A1 Feb. 11, 2010

Water (cilrusjunos), VISNADEX® (visnadine), Kombuchka, Pycnogenol, manganese gluconate (Givobio GMn® from -continued Seppic), Visnadine (from Indena), lupin extracts (Eclaline from Silab), Epaline® 100 (Laboratoires Carilene), Bigarade INCI name/type Massic % ?owers extract (Remoduline® from Silab), vitamine P as derivatives thereof such as Permethol® (from Sochibios), Octyldodecanol Eutanol G (Cognis) 2.4% Butylene glycol & menthyl PCA & octyl dodecyl PCA 1.2% ruscus extracts, ginseng extracts, ivy extracts, sWeet clover Cryogenyl (Solabia) extracts, caffeine, nicotinate and derivatives thereof, lysine Polyglyceryl-6 5% and derivatives thereof (Asparlyne® from Solabia). Sodium chloride 0.5% [0115] Compositions according to the invention can in Sucrose tetrastearate triacetate Sistema A10E-C (Unipex) 2% addition comprise at least one UV screening agent chosen Preservatives 1.1% from organic and inorganic screening agents and their mix Antioxidants 0.7% tures. Mention may in particular be made, as organic screen UV screening agents 8% ing agents, of dibenZoylmethane derivatives (including butyl Dyes 1.1% methoxydibenZoylmethane), cinnamic acid derivatives (in Sucrose 25% cluding ethylhexyl methoxycinnamic), salicylates, para-ami Water Qsp 100% nobenZoic acids, [3,[3-diphenylacrylates, benZophenones, benZylidenecamphor derivatives, phenylbenZimidaZoles, tri aZines, phenylbenZotriaZoles and anthranilic derivatives. [0122] In a preferred embodiment, ethylene/propylene/sty Mention may in particular be made, as inorganic screening rene copolymer, butylene/ethylene/styrene copolymer, and agents, of screening agents based on inorganic oxides in the ethylene/propylene copolymer are pre-mixed separately or form of pigments or nanopigments Which may or may not be together in hydrogenated polydecene, to form a gel that is coated and in particular based on titanium dioxide or on Zinc further included With the rest of the ingredients. oxide. [0116] Examples of additional adjuvants are mentioned in [0123] For example, a gel of ethylene/propylene copolymer particular in the CTFA dictionary (International Cosmetic in hydrogenated polydecene can be used: such a gel is sold Ingredient Dictionary and Handbook published by The Cos under the reference Creagel Crystal AF by Creations metic, Toiletry and Fragrance Association, 9”’ Edition, 2002). Couleurs. [0117] The composition according to the invention can be provided in particular in the form of a thick ?uid packaged in Sensory Evaluation a container provided With an applicator, generally made of foam, in the form of a ?ne brush or coarse brush. Of course, [0124] The formulation of Example 1, packaged in a small other methods of application are possible, in particular bottle, Was evaluated by a panel of 20 subjects under stan employing applicators of felt type. dardiZed conditions of temperature, hygrometry and light. [0118] Preferably, the composition employed according to [0125] In order to do this, the product Was applied to the the invention is used as product for making up the lips, in loWer lip using the ?ne applicator brush With Which the small particular as lip gloss. bottle is equipped, the outline of the lip being draWn Well. The [0119] Another subject-matter of the present invention is thus a cosmetic method for caring for or making up the lips, ?ne brush Was subsequently immersed in the composition comprising the topical application, to the lips, of the compo before applying the product to the upper lip in the same Way. sition as described above. [0126] The members of the panel evaluated the product on [0120] The invention Will noW be illustrated by the folloW application and after application according to descriptors ing non limiting examples. With Which they Were provided. [0127] The data Were subsequently collected and analysed EXAMPLES using FiZZ softWare according to the statistical methods spe Example 1 ci?c to pro?le tests. The results obtained are collated in the Lip Gloss folloWing table: [0121] A lip gloss Was manufactured in a Way conventional to a person skilled in the art, Which lip gloss has the folloWing composition in Which the proportions of the ingredients are Mean Standard expressed as percentages by Weight: Attribute value (/ 10) deviation Slip on application 7.0 0.6 Softness on application 7.9 0.8 Softness ofthe lips after application 7.3 0.8 INCI name/type Massic % Gloss 6.4 1.4 Tackiness 1.9 1.1 Hydrogenated polydecene 25.1% Opacity on the lips 1.9 1.6 ethylene/propylene/styrene copolymer 2.0% Thickness ofthe ?lm 3.4 1.6 butylene/ethylene/styrene copolymer 0.3% ethylene/propylene copolymer 2.6% Cyclomethicone (D6) 3% [0128] It is thus found that the composition according to the PEG-30 dipolyhydroxystearate Arlacel P135 (Uniqema) 3% Octyldodecanol & disteardimoniurn hectorite & 3% invention is applied to the lips With very good slip and forms, propylene carbonate Bentone Gel EUG V (Elementis) on the lips, a thin, soft, glossy and nontacky ?lm Which leaves the lips visible (translucent). US 2010/0034767 A1 Feb. 11, 2010

Example 2 Foundation Base [0129]

Phase INCI name % massic

A OCTYLDODECANOL 7.1 CYCLOMETHICONE (DOW CORNING 246) 8 HYDROGENATED POLYDECENE 12.6 ETHYLENE/PROPYLENE/STYRENE COPOLYMER 1.3 BUTYLENE/ETHYLENE/STYRENE COPOLYMER 0.2 ETHYLENE/PROPYLENE COPOLYMER 0.9 PEG-30 DIPOLYHYDROXYSTEARATE (ARLACEL P135) 3 OCTYLDODECANOL & DISTEARDIMONIUM HECTORITE 3 & PROPYLENE CARBONATE (BENTONE GEL EUG V) PEG-8 & TOCOPHEROL & ASCORBYL PALMITATE & 0.2 ASCORBIC ACID & CITRIC ACID (OXYNEX K) preservatives 1 .1 TOCOPHERYL ACETATE 0.5 ETHYLHEXYL METHOXYCINNAMATE (PARSOL MCX) 5 B OCTYLDODECANOL 5 IRON OXIDES 1.55 TITANIUM DIOXIDE 1.65 C SUCROSE TETRASTEARATE TRIACETATE (SISTERNA A10E-C) 3 D WATER Qsp 100 POLYGLYCERIN-6 (polyglycerol #500 from Sakalnoto) 5 SUCROSE 20 SODIUM CHLORIDE 0.5 MICA & IRON OXIDES & TITANIUM DIOXIDE (TIMICA 0.3 GOLDEN BRONZE)

[0130] In a preferred embodiment, ethylene/propylene/sty- 24. Composition according to claim 20, Wherein the ratio rene copolymer, butylene/ethylene/styrene copolymer, and/ of second to ?rst copolymer goes from 1/ 10 to 20/ 1, prefer or ethylene/propylene copolymer are pre-mixed separately or ably from 1/2 to 5/1, preferably from 1/1 to 2/ 1. together in hydrogenated polydecene, to form a gel that is 25. Composition according to claim 20, Wherein the further mixed With the rest of the ingredients. amount of ?rst copolymer goes from 0.1 to 10% by Weight of [0131] For example, a gel of ethylene/propylene copolymer the total Weight of the composition, preferably from 0.5 to in hydrogenated polydecene can be used: such a gel is sold 5%. under the reference Creagel Crystal AF by Creations 26. Composition according to claim 20, Wherein the Couleurs. amount of second copolymer goes from 0.1 to 10% by Weight of the total Weight of the composition, preferably from 0.5 to 1-19. (canceled) 5%. 20. Cosmetic composition in the form of a Water-in-oil 27. Composition according to claim 20, Wherein the non emulsion comprising at least one non Volatile hydrocarbon Volatile hydrocarbon oil amount goes from 5 to 35% by oil, at least one ?rst copolymer of ethylene and of propylene Weight of the total Weight of the composition, preferably from and at least one second copolymer of styrene and of at least 10 to 30% by Weight of the total Weight of the composition. one ole?n other than styrene. 28. Composition according to claim 20, Wherein the non 21. Composition according to claim 20, Wherein at least Volatile hydrocarbon oil is chosen from hydrocarbures and one second copolymer in made of styrene and of at least one esters, such as hydrogenated polydecene, hydrogenated poly ole?n chosen from ethylene, propylene, butylene, butadiene, isobutene, isopropyl palmitate, isononyl isononanoate or isoprene or one of their mixture. C12-C15 alkyl benZoate. 22. Composition according to claim 20, Wherein the sec 29. Composition according to claim 20, Wherein the aque ond copolymer is chosen from ous phase of the Water-in-oil emulsion represents from 30 to 60% by Weight of the total Weight of the composition, pref ethylene/propylene/ styrene, erably from 40 to 50% by Weight of the total Weight of the butyl ene/ ethyl ene/ styrene, composition. butadiene/ styrene, 30. Composition according to claim 20, Wherein the aque isoprene/ styrene, ous phase of the Water-in-oil emulsion includes at least one styrene/butadi ene/ styrene, polyol, Which may be chosen from styrene/isoprene/ styrene, glycols, such as propylene glycol, dipropylene glycol and styrene/ ethylene/butylene/ styrene copolymers, butylene glycol; and homopolymers of glycols, such as and their blends. poly(ethylene glycol)s and poly(propylene glycol)s; 23. Composition according to claim 20, Wherein the sec glycerol and polyglycerol compounds; ond copolymer is a blend of ethylene/propylene/ styrene and monosaccharides, such as glucose and fructose; butylene/ethylene/ styrene copolymers. sorbitol; US 2010/0034767 A1 Feb. 11, 2010

disaccharides, such as sucrose; 33. Composition according to claim 20, Wherein it com and their mixtures. prises at least one Volatile oil in an amount betWeen 5 and 8% Weight by Weight of the composition. 31. Composition according to claim 30, Wherein the polyol 34. Cosmetic method for caring for or making up the lips, is chosen from polyglycerol compounds and their mixtures, the eyebroWs or skin, comprising the topical application, to for instance With sucrose. the lips, the eyebroWs or skin, of the composition according to 32. Composition according to claim 30, Wherein the polyol claim 20. amount is betWeen 25 and 35% Weight by Weight of the composition.