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Fire Department City of New York FIRE DEPARTMENT ● CITY OF NEW YORK STUDY MATERIAL FOR THE EXAMINATION FOR CERTIFICATE OF FITNESS FOR SUPERVISING NON-PRODUCTION CHEMICAL LABORATORIES C-14 © 12/2010 New York City Fire Department - All rights reserved ® NOTICE OF EXAMINATION ....................................................................................... I STUDY MATERIAL AND TEST DESCRIPTION ...................................................... II INTRODUCTION .......................................................................................................... 1 PART I ........................................................................................................................... 4 1. DEFINITIONS.............................................................................................................................................4 2. CLASSIFICATIONS ..................................................................................................................................9 A. Laboratory Unit Hazard Classification....................................................................... 9 B. Class of Flammable and Combustible Liquids ........................................................... 9 C. General Rule of Hazard Classes................................................................................ 10 D. NFPA Diamond Sign.................................................................................................. 11 E. Class of Organic Peroxide......................................................................................... 13 PART II........................................................................................................................ 14 1. GENERAL FIRE CODE REQUIREMENTS......................................................................................14 A. Fire Department Permit ........................................................................................... 14 B. General Operations, Housekeeping and Good Work Practices................................ 15 C. Material Safety Data Sheets (MSDS) ........................................................................ 20 2. LABORATORY UNIT HAZARD CLASSIFICATION, DESIGN AND STORAGE...................21 A. Flammable & Combustible Liquids Quantity Limitation for Different Laboratory Units.......................................................................................................................... 21 B. Other Laboratory Hazardous Material Quantity Limitations .................................. 22 C. Prohibitions .............................................................................................................. 24 D. Laboratory Safety Requirement ............................................................................... 25 3. CHEMICAL STORAGE, HANDLING, AND WASTE DISPOSAL...............................................34 A. Chemical Storage and Handling ............................................................................... 34 B. Storage of Class I and Class II Liquids in Refrigerators .......................................... 38 C. Liquid Dispensing ..................................................................................................... 40 D. Waste, Handling and Disposal .................................................................................. 40 4. FIRE PREVENTION AND PROTECTION SYSTEMS ..................................................................40 A. Fire Alarm Systems .................................................................................................. 41 B. Sprinkler System and Standpipe System ................................................................ 41 C. Portable Fire Extinguishers...................................................................................... 42 5. EMERGENCY PLANNING AND PREPAREDNESS.......................................................................45 A. Emergency Procedures ............................................................................................. 45 B. Penalties for Non-compliance with Fire Code ......................................................... 45 PART III ...................................................................................................................... 46 A 1. CORROSIVE MATERIALS...................................................................................................................46 A. Storage and Use Requirements ................................................................................ 46 2. COMPRESSED AND LIQUEFIED GASES.......................................................................................46 A. General Requirement................................................................................................ 47 B. Storing Containers.................................................................................................... 47 C. Cryogenic Liquid....................................................................................................... 49 PART IV....................................................................................................................... 50 RENEWAL FORM....................................................................................................... 52 APPENDIX A............................................................................................................... 53 1. COMPRESSED AND LIQUEFIED GASES.......................................................................................53 2. FLAMMABLE SOLID..............................................................................................................................55 3. CORROSIVE MATERIALS...................................................................................................................55 4. HIGHLY TOXIC AND TOXIC MATERIALS....................................................................................56 5. UNSTABLE REACTIVES (INSTABILITY HAZARD).....................................................................57 6. OXIDIZERS AND ORGANIC PEROXIDES .....................................................................................58 7. WATER-REACTIVE SOLID & LIQUIDS ..........................................................................................61 8. PYROPHORICS MATERIALS .............................................................................................................62 APPENDIX B............................................................................................................... 63 APPENDIX C............................................................................................................... 67 APPENDIX D............................................................................................................... 70 APPENDIX E............................................................................................................... 71 APPENDIX F............................................................................................................... 72 B NOTICE OF EXAMINATION Title: Examination for Certificate of Fitness for Supervising Non-production Chemical Laboratories (C-14) Date of Test: Written tests are conducted Monday through Friday (except legal holidays) 8:30 AM to 2:30 PM QUALIFICATION REQUIREMENTS 1. Applicant must be at least 18 years of age. 2. Applicant must have a reasonable understanding of the English language. 3. Applicant must present a letter of recommendation from his/her employer. The letter must be on official letterhead and must state the applicant’s full name, character, physical condition, experience, and address of premises where applicant will be employed. 4. Applicant must present one (1) form of satisfactory identification i.e., driver’s license or passport. 5. Applicant must have one of the following • A B.S or M.S or Doctorate degree in Chemistry, Biology, Biochemistry, Environmental or Health Sciences, Medical Technology and Chemical, Environmental, Mechanical or Biomedical Engineering, or related field or • License as a Clinical Laboratory Director from the NYS Dept. of Health; or • Doctor of Medicine or Dental Surgery (DDS) Or • An A.A.S or A.S degree in Chemistry, Biology, Biochemistry, Environmental or Health Sciences, Medical Technology and Chemical, Environmental, Mechanical or Biomedical Engineering, or related field and a completion of a course on laboratory safety provided by the employer or • 60 credits with minimum of 21 credits in applicable science or engineering courses and a completion of a course on laboratory safety provided by the employer or • NY State Permanent Certification as a Chemistry or Biology (7-12) Teacher. 6. Applicant must present evidence of academic degree(s) indicating specific course of study and/or transcript to verify college science courses. 7. Degree issued from outside USA shall be evaluated by an independent evaluation service accepted by NYC Department of Citywide Administrative Services. http://home2.nyc.gov/html/dcas/downloads/pdf/misc/foreigneducation.pdf APPLICATION INFORMATION Application Fees: $25.00 for originals and $15.00 for renewals. The fee may be paid by credit card (no debit), in cash, money order, or personal check payable to New York City Fire Department. The $25.00 fee must be payable by all applicants prior to taking the Certificate of Fitness test. Application forms are available at the Public Certification Unit, 1st floor, 9 Metro Tech Center, Brooklyn, NY 11201. TEST INFORMATION Test: The test will be of the written, multiple choice
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