Rheology II Transport properties
Patrick Cordier
Mineral Physics Group - UMET - Université Lille 1 & CNRS
CIDER Summer Program: Flow In the Deep Earth Santa Barbara CA July 2016 The unreachable Earth Mechanical properties of wadsleyite
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Nishihara et al., 2008 5000 Kawazoe et al., 2013 Kawazoe et al., 2010 (MPa)σ 4000 Hustoft et al., 2013 Farla et al., 2015 3000
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0 0 500 1000 1500 2000 2500 3000 T (K) Mechanical properties of ringwoodite
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Hustoft et al., 2013 5000 Kavner et al., 2001 Meade and Jeanloz, 1990 (MPa)σ 4000 Miyagi et al., 2014 Nishiyama et al., 2005 3000
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0 0 500 1000 1500 2000 2500 3000 T (K) Mechanical properties of bridgmanite
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Merkel et al. 2003
6000 Meade et al. 1990 (MPa)σ Girard et al. 2015
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0 0 500 1000 1500 2000 2500 3000 T (K) Constitutive equations
Q − ε∝ σ n. e kT
Mackwell, 2008
Also need to take high- pressure into account: Q+PV Extrapolating to natural timescales
Q − ε∝ σ n. e kT
-7.0
-8.0
-9.0 Extrapolation to natural conditions
-10.0
-11.0
-12.0 The pitch drop experiment
The University of Queensland pitch drop experiment (started 1927)
Here featuring, Professor John Mainstone (taken in 1990, two years after the seventh drop and 10 years before the eighth drop fell).
Professor John Mainstone died on 23 August 2013, aged 78, after having watched the experiment 52 years
Bitumen η = 2.3 1011 Pa.s What if….
Galileo Galilei (Leyden 1638) From crystals to mantle flow From flow crystals to mantle
© B. Schuberth Can we bridge bridge scales ? Deforming crystals
transport of matter Diffusion creep
• Nabarro (1948) - Herring (1950) creep
+ − ⎛σ b3 ⎞ C −C C+ C exp = 0 ⎜ ⎟ J = −D gradC ≈ αD ⎝ kT ⎠ v v d C+
3 − ⎛−σ b ⎞ C = C0 exp⎜ ⎟ ⎝ kT ⎠ DsdσΩ - ε! = α C d 2kT
d 2kT σ = ε! αDsdΩ
Newtonian Diffusion creep in the mantle
Glišovic et al. (2015) Shearing crystals
(001) Shearing crystals
Ringwoodite (20 GPa) (110) plane
Easy shear path along the ½[-110] direction
Defines the Burgers vector Ritterbex et al. (2015) Slip systems
Ringwoodite (20 GPa)
Slip along <110> in: {001} {110} {111} Ritterbex et al. (2015) We learnt: Slip systems
Plasticity of crystals - Schmid & Boas (1950)
Uchic et al. 2004 We don’t understand: stresses
τmax/µ = 0.2-0.3
Two to four orders of magnitude too large
Need for defects: dislocations The Volterra defects
Vito Volterra (1860-1940) Vito Volterra, Sur les Distorsions des corps élastiques, Gauthier-Villars, Paris, 1960 Crystal defects: dislocations
Egon Orowan Sir Geoffrey Ingram Taylor Michael Polanyi
1934 Disloca ons duality
Near field: atomistic Far field: elastic
µb σ = f (θ) 2πr Long-range interactions Disloca ons respond to stress
External loading σ
!" F
!" " !" Peach & Koehler (1950) force : F = σ. b × L ! velocity v From disloca ons to plas city: the toolbox
• 3D dislocation dynamics
MgO J. Amodeo et al. Mechanics of Materials 71 (2014) 62–73
• 2.5 D dislocation dynamics
Olivine Boioli et al. (2015) • Orowan equation
Dislocation velocity Strain rate Dislocation density Burgers vector modulus Dislocation velocities: can we measure ?
New approack based on nanomechanical testing of olivine in the TEM Nanomechanical testing in the TEM The Push-to-Pull device (Hysitron®)
Collaboration with H. Idrissi Antwerpen, Belgium & C. Bollinger, Bayreuth, Germany
Hair Nanomechanical testing in the TEM
Nanomechanical testing in the TEM
Nanomechanical testing in the TEM
Dislocation velocities: can we calculate ? Dislocation core modeling
Perovskite MgSiO3 : orthorhombic: 20 atoms / unit cell
LAMMPS molecular statics
30 000 atoms
Antoine Kraych’s PhD Atomic structure of dislocations
[100] x
[001]
[010] [100] screw dislocation in bridgmanite at 30GPa
Density of Burgers vector in (010) planes (30GPa)
Dislocation position along [001] (Å) Dislocation gallery
Bridgmanite
[100](010)
[010](1 OO) Dislocation gallery
l/2<111>{101} Wadsleyite
Stacking fault
1h [111](101) Dislocation gallery
(100)(010) Wadsleyite Dislocation gallery
1/2<110>{110}
112<110>{1 ll} P>lJ ... _ 1 Ringwoodite Dislocation gallery
Post-perovskite
[100](010) Stop 2
• We know: the << crystallography of defects >>
/ '\. [\' ' • We don't know: their << dynamics >>
Questions: • Do dislocations move easily when stress is applied ? • What is their velocity • How doest it depend on stress ? temperature ? Lattice friction: the brutal force
150 (a)
-> 100 <.--' ...... ,0 llJ 50
Peierls stress
o.oos O.OIS Lattice friction
0,7 0,6 (1) : 0 GPa 0,5 [100](010) in bridgmanite at 30 GPa "O>< 0,4 ...... ~ 0,3 0,2 0,1 0 1----....,,,,,,,~~:__-1--~-L--~~~:::=~..... ---1 (2): 2.1 GPa
(3): ·'-"' GPa
o.oos E 0.01 O.OIS
(4)
- 20 - 15 - 10 -5 0 5 10 15 20 x(Â) Lattice friction: calculation of the Peierls potential
The "Nudged Elastic Band" (NEB) method ~ energy barrier
--0-· (100)(010) 1.4 ...... [010)(100) 1.2
'::ô' 1 ...... > ..!.. 0.8 o.. :;::.;: 0.6
0.4
0.2
Qr..L:-~-----'~~-----L~~----'-~~----L..~~-31<1 0 0.2 0.4 0.6 0.8 xl a' Kraych et al. EPSL in revision Dislocations: how they move
6 (a) [100](010) 5
-~4:a ~ ~ ~ 3 -u > u~ 2 V,. ~ cc 1
(1) (2) (3) (4) (5) (6) 0 -----'(1) - 15 - 10 - 5 0 5
---...... (2)
(4)
5 10 Dislocation position (Â) Kraych et al. EPSL in revision Wadsleyite: Peierls stresses
10000 [100](010) • 9000 E
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7000 - %[111](101)
6000 CU - Nishihara et al., 2008 ~ :!! 5000 iiKawazoe et al. , 2013 -t:> .a. Kawazoe et al. , 2010 4000 XHustoft et al. , 2013
~~ Faria et al., 2015 3000
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0 0 500 1000 1500 2000 2500 3000 T (K} Ringwoodite: Peierls stresses Lattice friction in MgSi03 Perovskite
35 [010](001)
30 [100] (001) T •••. / ._T'/ .• .?' 25 T'~· ,. /~ --...---. T' i ~--...~ "- I =... 20 û) ...... ,._ - 1 15 . _..- .
10 2 easiest slip systems: [100](010) 5 [010](100)
o i--~~--~~~---~~----....-~~--~~~---~~----.~___. 20 40 60 80 100 120 140 Pressure (GPa) Lattice friction in MgSi03: from bridgmanite to post-perovskite
18 16 Mantle
14 pv [100](01 O) a..ro <.9 12 "'C -a. t:> 10 < en '+' en Q) "'C L.. "'C .+J 8 en < en L.. Q) 6 Q) a.. 4
2 ppv [100](01 O) + 0 20 40 60 80 100 120 140 Pressure, GPa Stop 3
• We know: the intrinsic resistance that the crystal opposes to dislocation motion: the
Peierls stress s -;;- "r o.. J 0 ~~ l ~ .,.. l- i
E 0.01 O.OIS / '\. ~ • We don't know: how temperature helps to overcome this lattice friction
(/) (/) ...... ~ Cf)
Temperature Modeling dislocation mobility
• Core structure Stress assisted thermal activation : (i;, T} • Peierls Potential
Kink pair mechanism : /1 v
Modeling rare events:
Wadsleyite; 1700K, 1 GPa: 1OOps MgSi03 perovskite: kink pair mechanism
20 w
1 - 16 ... 0.8 ~ 0.6
0.4
0.2
0 2 4 6 ' 10 12 14 16 18 20 22 24 26 28 30 32 xla
4
o l____L_____L~_J_____L_~L____L_____L~_J__--=~ 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 't l 'tp
Transient state theory
, L vvb ( Afl*(r)) v = a · w * ( r) · w * (r) ·exp - kT
Antoine Kraych's PhD Dislocation velocities
5 10 PV T =2000 K P=30 GPa Rwd T =1800 K P=20 GPa 1 OO 01 T =1600 K P= 0 GPa ...-.. en 5 ._..--E 1 o- ~ +-' () 0 1 o-10 -Q) > Q) "'O 1 o-15 - CJ 10-20
1 o-25 ------500 1000 1500 2000 2500 3000 3500 Resolved shear stress 't (MPa) From dislocations to plasticity: a ractical exam le
Orowan equation i = p b v(r, T) Kraych et al. EPSL submitted
0 1 ' '. 10 Il"",,. .. » Zl" •• !) tt
'b2 r;; C = -k ln (vv a v.P~î • • 2 2w*2 E ,,L.~------'-._,/ The strain rate is here Dislocation Glide in Ringwoodite (20 GPa)
18 Kavner et al., 2001 1 • Hustoft et al., 2013 1 M 1
16 Miyagi et al., 2014 1 >< Nishiyama et al., 2005 1 e 1
14 Meade and Jeanloz, 1990 • i -Cl) Cl) Q.) " +-' . 10-s -1 Cl) 10 E= S 0) c 1/2<110>{111} ·-"- 8 Q.) Q.) c 6 ·-0) c w 4
2 ,,,,,,,,,,, ,,,,,.,, ..... ,,,,,,.,, ..... u,,,,, ...... • •••• 0 --~--~----~--~--~~--··_... _... _ .. ___. _···-··-··-· ----- 0 500 1000 1500 2000 2500 3000 3500 4000 T (K) Ritterbex et al. (2015) PEPI Dislocation Glide in Wadsleyite (15 GPa)
10 Hustoft et al., 2013 1 1 Kawazoe et al., 2010 -•-- [100](010) screw Kawazoe et al., 2013 • ~ 8 -a.. Nishihara et al., 2008 ...,..,---+----t (!) Faria et al., 2015 ...,..,---+----t en -en Q) 6 ~ ...... en . 10-s S -1 O> E= c ~ 4 Q) Q) c ·-0> c w 2 ...... screw ······ •·········· ······· ······· 0 •• ·•·····•···· ········ 0 500 1000 1500 2000 2500 3000 3500 4000 4500 T (K) Ritterbex et al. Am. Mineralogist in press MgSi03 perovskite (30 GPa)
14 _...... P = ___ 30 __. GPa___ _...... ,....; i = ___10- ,...... _5 s ______- 1 ; p = 1013 m- 2 _...... ,.... ___ ,...... _____..
• Meade et al. 1990 12 A Merkel et al. 2003 • Girard et al. 2016
...... _ ...... [100) (010) ...... - ...... - -- ...... MgO - --- ..... 2 ~(110){100} ...... !(110}{110} ~-----~:_ ___J o c:::~~~~~...=:::::::=:::::d 0 500 1000 1500 2000 2500 3000 T(K) Kraych et al. EPSL submitted - Results on MgO from Amedeo et al. Phil. Mag. 2012 Stop4
• We know: the intracrystalline flow properties of major high pressure minerais
l 12.. . t ~ .... :I
. - • ,. ''°' ,,.. - Vit - Tiit) Courtesy J. Girard / " ~ • We don't know the mechanical properties of the << rock >> From the grain to the aggregate
Collaboration with O. Castelnau & K. Derrien ENSAM, Paris • Visco Plastic Self Consistent modelling
• Finite Elements modelling
Equivalent strain
Building an aggregate From the grain to the aggregate
Collaboration with O. Castelnau & K. Derrien 10000 ENSAM, Paris
9000
8000 work in progress ! 7000
6000 -ca Nishihara et al. , 2008 a. iiKawazoe et al., 2013 :E 5000 Kawazoe et al., 2010 -b 4000 X Hustoft et al., 2013 Faria et al. , 2015 3000 • This study
2000
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0 0 500 1000 1500 2000 2500 3000 3500 4000 4500 T (K} Stop 5
• We can model (and we agree with) mechanical data obtained in laboratory conditions ----~ - 1• - l 16 ...... 2 1• ...... ----- i 12 1 +rW- -·· 1 10 ( :ll"".1 - ···t1·- ·-- i : t 111'<11~lll) I 'f.i- • ï1 ;.1·. ... • 112<110>4uq . -- - -Tl'Q- - - -- 2 o.____.__._~~-...... 1 0 500 1000 1500 2000 2500 ~ - 4000 T1K1 • But we can do the same at mantle strain rates (no extrapolation !) Dislocation Glide in Wadsleyite (15 GPa)
1000 [100] (010) screw
800 1 1h<111>{101} screw ! 1 -«S 1 a.. 600 1 ~ 1 . 10-16 -1 1 E = S -(/) 1 1 (/) ! Upper ! ~ransition! a: 400 1 1 0 i Zone i 1 1 200 1
0 L-~.&..-~..L-~..L_~...L-~...... __~...... :===...... --=::::::..... ~ 1000 1200 1400 1600 1800 2000 2200 2400 2600 T (K) Ritterbex et al. Am. Mineralogist in press Dislocation Glide in Ringwoodite (20 GPa)
1200 \ . 10- 16 - 1 \ E= S 1000
800 1/2<110>{111}
-li) 600 li) a:: u 400 "\ 1 '\ 1 1/2<110>{110} .,__ ! Lower Î ' . ! Tra;:~:on i! 200 '··""!1 1
i i i~ .i 0 i b·-··- 1000 1200 1400 1600 1800 2000 2200 2400 2600 T (K) Ritterbex et al. (2015) PEPI MgSi03 perovskite (30 GPa)
4.5 P = 30 GPa 4
3.5
3 ,,,,.-._ ...... ro ...... ~ 2.5 ...... Cl ...... ~ ...... \/). 2 ... \/)...... [100] (010) ~ Bg ...... u 1.5 ...... _ 1 -- 0.5 [010] (100) ------0 ~~~~~ 1000 1500 2000 2500 3000 T(K) Kraych et al. EPSL submitted - Results on MgO from Amedeo et al. Phil. Mag. 2012 MgSi03 perovskite (60 GPa)
P= 60 GPa
3.5
3 [010] (100) ~ es 2.5 ...._.., r/J 2 r/J ~ u 1.5 MgO 1 ~( 110 ) {110} 0.5 li ~ (110 ) { 100} o ~~~~------...J---4-_._~___J__._~--'-~ 1000 1500 2000 2500 3000 T(K) Kraych et al. EPSL submitted - Results on MgO from Amedeo et al. Phil. Mag. 2012 MgSi03 post-perovskite (120 GPa)
1.0 ----...... ------.------.------.------E = 10·14 s·1 8 2 0.8 p = 10 m· ro P5 0.6
(j)- (j) 5 0.4 [110](1 OO) MgO 100 GPa 0.2 [100](010) ppv 120 GPa
ÜL------'-~""------'---'---'----l..----l---'--==c==J 0 500 1000 1500 2000 2500 Temperature, K A. Goryaeva in prep Which mechanism ?
Diffusion creep ? Stop 6
• We understand, model, quantify dislocation glide
/ '\. ~ • But creep in the mantle would involve glide and climb ! What is climb ?
•••••••••••••••••••••••••••• • Point defects (vacancies) diffuse •••••••••••••••••••••• •••••••••••••••••••••• toward the dislocations •••••••••••••••••••••• ••••••••••••••••••••••
. ~ .A. I'\. c Î-, T T • They are absorbed (or emitted) I , T > ."'. f-~-< o- ~ -~ ~ -
..., The dislocation moves away from its glide plane 2n Ds/d ( (rn) ) V cumb = ln R/ r c b exp kT - 1 lnterplay between glide and climb [1 OO] dislocations
Olivine 10 1 102 103 104 1o 5 / Ratio v9 vc 1800
1700
.....-.. ~ 1600 r-
1500
1400 0 100 200 300 400 500 cr (MPa) lnterplay between glide and climb [1 OO] dislocations
Unlaxlal tension 2.5 ' glide -- Single slip· + dffmb glide+climb -- 2.0 Po= 1.4 1012m- 2 T= 1600 K ;, 1.5 a= 4-0 MPa •
~0 -a. w 1.0
0.5
o ~-~--~--~-__._--~ 8pm 0 0.5 1.0 1.5 2.5 time (106 s) ~•
10 ~ ,. ' + f "t + 8 A f ,." +
++b X - b 2 4 6 8 10 2 4 6 8 10 X (µm) X yim) Gliae only Initial configuration Boioli et al. Phys Rev B 2015 lnterplay between glide and climb [1 OO] dislocations
Unlaxlal tension 2.5 ' glide -- Single slip· + dffmb glide+climb -- 2.0 Po= 1.4 1012m- 2 T= 1600 K ;, 1.5 a= 4-0 MPa •
~0 -a. w 1.0
0.5
o ~-~--~---'------'---~ 8pm 0 0.5 1.0 1.5 time (106 s) ~•
100 10
50
++b ·50 X - b -100 2 4 6 8 10 2 4 6 8 10 2 4 6 8 10 X (µm) X yim) X (µm) Initial configuration Gliae only Glide + Climb lnterplay between glide and climb [1 OO] dislocations
Unlaxlal tension Single •slip· + dffmb
E .B11m :,.
1.8 At steady state: nearly constant dislocation density u------0 U OA OJe o.8 UJ t.2 tA tîme(1a'I) Boioli et al. Phys Rev B 2015 Activation enthalpy
(a) to.s .,.._____,,...._.,...._____,,._....,...._____...;.---...... ____.. 10"' 10.. 7 -1r ~°'- 1'ftl"Iwi "W 1r1 10"n 1cr12
10~3 ...... ~...... -...... - ...... 5-1 8.2 i&iA 8-8 6.8 '1 7al 1a411i(K)
glide creep diffusion (eV) 5.7 4.7 4.25
nn:iid:et al. Fei et al. Earth Planet. Sei. Lett. 345,95 (2012) Am. l\.1in. (2ffJ7) Fei et al. Nature 498 (2013) Boioli et al. Phys Rev B 2015 Stress exponent
(b) 10-5
10-6
10·1
10-8
~ ~- 10.g 'êoll 10·10
1 o·11
10·12
10·13 10 100 a (MPa)
T(K) 1700 1600 1500 1400 3.1 3.2 3.2 2.9
Boioli et al. Phys Rev B 2015 Olivine rheology at low temperature [001] glide
10-08 10-10 10-12 10-14
M -1 T=lOOO K V) 10-16 -w 10-18 10 T=900 K A 10-20 1
10-22 T=800 K ce======14 1 10-24 10 100 1000 a (MPa) Boioli et al. EPSL 2015 Creep in the lower mantle
(A) Olivine Ratio v I Ve -~ 0 .... 1800
1700
g 1600 ~
1500
1400 0 500 1000 1500 2000 2500 3000 o (MPa)
(B) Ringwoodite 10·10 1o ·6 10·2 102 1o 5 (C) Bridgmanite 10·20 -.----r-r- Ratio Vg / Ve Vg / Vc 2000 2200
1900 2100 g 1800 g 2000 ......
1700 1900
1600 1800 0 500 1000 1500 2000 2500 3000 0 500 1000 1500 2000 2500 3000 a (MPa) a (MPa) lntroducing pure climb creep
• Strain is produced by dislocation climb
• Dislocations act as sources .l. and sinks of point defects (vacancies)
~ • Disloca.tions exchange 1- vacanc1es
• The characteristic diffusion length is determined by the dislocation density
Pure climb creep Modelling pure climb cree~
a (A) Lx (B) 4 t .. 0.05 î=1900 K 0.04 P=24GPa +- -+ t o~ a=40 MPa >. ...J 0.03 Xv=10 5 0 0 ~ 0 a --- 0 J 0.02 0 0 0.01
0 0 0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 + time (108 s)
400 4 * "* 200 3 CO' ~ .. CO' Ê a. E a. 0 0 ~ ::?...... :::1. ~ >- Il >- 2 t:) t::l -200 -200 ... -400 0 0 2 3 4 5 1.5 2 2.5 3 3.5 X (µm) X (µm) Modelling pure climb creep in bridgmanite
T=1900 K; P=24 GPa; Xv=10-5
CLIMB p =1012 m-2 0 •
8 -2 CLIMB Po=10 m ------N-H d=0.1 ------mm ••••••••••••• COBLE d=0.1 mm ••••••••••• • •••••• •••• •••••••••••• ························ ------N-H d=10 mm
•••••••••• CO BLE d=10 mm •••••••••• •• • •• • ••• • •••••• • 10-25 L--~~.i..--.....J~·~··~•••••••••••••...L_L-J....-J...... L_J._~~__..L_~-L-~~-1-.L.....L...LJ 1 10 100 stress (MPa) Pure climb creep: Avery important mechanism for planetary interiors rheology
A few tacts:
• Strain is produced by dislocation climb
.l. • Strain is not produced by shear: no crystal preferred orientations ~1- • No grain size dependence
• Controlled by diffusion, but rheology may not be linear
Pure climb creep Stop 7
• Diffusion creep • Dislocation creep • Pure climb creep
/ " ~ • What about grain boundaries ? Toward a more general elastic field
Collaboration with C. Fressengeas & V. Taupin, Metz theory
-+ - 1= = Displacement field: u Rotation vector: w = --w: X 2
- -+ - Total distortion tensor: U = grad u Curvature tensor: K = grad w
------Cauchy stress: a= C: E Couple stress tensor: M =A: K
Equilibrium condition div a = 0 Equilibrium condition div M = 0
1 Energy: E cauchy = -aiJ EiJ Energy: 2 T oward a more general elasto-plastic field theory
- Compatibility equations: curl U = 0 curl K = 0
Incompatible elasto-plasticity:
Nye's dislocation density tensor: Disclination density tensor: --- a = curl u e = -curl u p 8 = curl K e = -curl K p
Burgers vector: closure defect obtained Frank vector: closure defect obtained by by integrating the incompatible elastic integrating the incompatible elastic distortions along a circuit C curvature along a circuit C T oward a more general elasto-plastic field theory
- curl K = 0
Disclination density tensor: --- Screw 8 = curl K e = -curl K p dislocation
Frank vector: closure defect obtained by integrating the incompatible elastic curvature along a circuit C (e) (/) Disclinations
You remember ? Disclinations
(a) (b) Disclinations were recently evidenced in metals, here Al
Beausir & Fressengeas (2013)
Di5cÎ:inations Dislocation and disclinations analysis by EBSD
OOM - naturally deformed Cordier et al. Nature 2014 T0548 mylonitic harzburgite from Experimentally deformed the Oman ophiolite at 1200°c (Sumail massif)
12p~
f.l mœ
-i!. 1 ~ UD ~ l i i 'Il 'S :a~ i 1 lili. -11 "4'"3 Q.iO 61!JDIJ[ -+Al~GBaM o MG.BSlH '*''TfiPl&pm~ crnJyN A TiîQleiUJWî&n oJdf B :J[ mrnn::-.- :::u: ::u:m Grain boundary modeling based on disclinations
Displacement Dislocation Grain density boundary
Dislocation/ Disclination continuous Rotation Disclination density modeling Atomistic configuration
Sun et al. IJP 2016 Grain boundary modeling based on disclinations
Forsterite: (011 )/[1 OO] tilt grain boundary with misorientation 60.80° (coll S. Jahn)
3.6nm Grain boundary modeling based on disclinations
Forsterite: (011 )/[1 OO] tilt grain boundary with misorientation 60.80° (coll S. Jahn)
• .. •
E 23 1.1 6 0.788 0.42 1 0.0530 .. -0.315 • • -0.682 Si -1.05 • •
Sun et al. Phil Mag 2016
Shear -coupled boundary migration
Œ;tS(m~ 1.mme+9 1.0aae+9 1e~9 1e+9
1e+9' sl ,82e'f9 -1 .82e+9
8a~Crad/m2)
~199.+19 '4ê+19 2ê+19 -0 •2-e+19 ~ l .O!Be>t9 ~œ9 Q.62 118+9 -4Ae+l9' 0.6 OA
le+O D.2 a -0.06 Final stop: Thank you 1
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Funding: ERG advanced grant n°290424 Multiscale Modeling of the Rheo/ogy of the Mantle (RheoMan)