Conching Chocolate Is a Prototypical Transition from Frictionally Jammed

Total Page:16

File Type:pdf, Size:1020Kb

Conching Chocolate Is a Prototypical Transition from Frictionally Jammed Conching chocolate is a prototypical transition from frictionally jammed solid to flowable suspension with maximal solid content Elena Blancoa,1, Daniel J. M. Hodgsona,1,2, Michiel Hermesa,b,1, Rut Besselinga,c, Gary L. Hunterd,e, Paul M. Chaikind, Michael E. Catesa,f, Isabella Van Dammeg, and Wilson C. K. Poona aSchool of Physics and Astronomy, The University of Edinburgh, Edinburgh EH9 3FD, United Kingdom; bSoft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, 3584 CC Utrecht, The Netherlands; cInProcess-LSP, 5349 AB Oss, The Netherlands; dCenter for Soft Matter Research, Department of Physics, New York University, New York, NY 10003; eCorporate Strategic Research, ExxonMobil Research and Engineering Company, Annandale, NJ 08801; fDepartment of Applied Mathematics and Theoretical Physics, University of Cambridge, Cambridge CB3 0WA, United Kingdom; and gMars Chocolate UK Ltd., Slough SL1 4JX, United Kingdom Edited by David A. Weitz, Harvard University, Cambridge, MA, and approved April 8, 2019 (received for review February 4, 2019) The mixing of a powder of 10- to 50-µm primary particles into is common to diverse industries that rely on the production of a liquid to form a dispersion with the highest possible solid high-solid-content dispersions. content is a common industrial operation. Building on recent advances in the rheology of such “granular dispersions,” we Shear Thickening Suspensions study a paradigmatic example of such powder incorporation: the We first review, briefly, recent advances in granular suspension conching of chocolate, in which a homogeneous, flowing suspen- rheology (5–14). The viscosity of a high-φ granular suspension sion is prepared from an inhomogeneous mixture of particulates, increases from a low-stress Newtonian value when the applied triglyceride oil, and dispersants. Studying the rheology of a sim- stress, σ, exceeds some onset stress, σ?, reaching a higher New- plified formulation, we find that the input of mechanical energy tonian plateau at σ σ?: The suspension shear thickens. The and staged addition of surfactants combine to effect a consid- PHYSICS low- and high-stress viscosities, η1 and η2, diverge as erable shift in the jamming volume fraction of the system, thus increasing the maximum flowable solid content. We discuss the φ −λ possible microscopic origins of this shift, and suggest that choco- ηr = A 1 − µ , [1] late conching exemplifies a ubiquitous class of powder–liquid φJ (σ) mixing. where ηr = η1,2/η0 with η0 as the solvent viscosity, A ' 1, and λ ' 2 for spheres (15, 16). The jamming point, φJ, is a func- chocolate j rheology j jamming j incorporation tion of both the interparticle friction coefficient, µ, and the applied stress, σ. The latter begins to press particles into con- ? he incorporation of liquid into dry powder with primary par- tact when it exceeds σ . With µ ! 0, no shear thickening is Tticle size in the granular range (∼ 10 µm to 50 µm) to form a observed, and ηr diverges at random close packing, φJ = φrcp. φ 50% At finite µ, the low-stress viscosity η1(φ) still diverges at φrcp, but flowing suspension with solid volume fraction & is impor- µ tant in many industries (1). Often, maximizing solid content is a η2(φ), the high-stress viscosity, now diverges at some φJ = φm < φrcp. For monodisperse hard spheres (Fig. 1A) φrcp ≈ 0:64 and key goal. Cements for building or bone replacement and ceramic µ!1 “green bodies” are important examples, where higher φ improves φm ≈ 0:54 (where “1,” in practice, means µ & 1) (8, 17). material strength (2). Another example is chocolate manufactur- ing, where high solid content [= lower fat (3)] is achieved by Significance “conching.” Conching (4), invented by Rodolphe Lindt in 1879, is impor- Chocolate conching is the process in which an inhomogeneous tant for flavor development, but its major physical function is to mixture of fat, sugar, and cocoa solids is transformed into a turn an inhomogeneous mixture of particulates (including sugar, homogeneous flowing liquid. Despite the popularity of choco- milk solids, and cocoa solids) and cocoa butter (a triglyceride late and the antiquity of the process, until now, there has been mixture) into a homogeneous, flowing suspension (liquid choco- poor understanding of the physical mechanisms involved. late) by prolonged mechanical action and the staged addition Here, we show that two of the main roles of conching are of dispersants. In this paper, we focus on this effect, and seek the mechanical breakdown of aggregates and the reduction to understand how mechanical action and dispersants together of interparticle friction through the addition of a dispersant. transform a nonflowing, inhomogeneous mixture into a flowing Intriguingly, the underlying physics we describe is related to suspension, a process that has analogs in, e.g., the ceramics and the popular stunt of “running on cornstarch.” pharmaceuticals sectors (1). We find that the key physical processes are friction-dominated Author contributions: M.H., P.M.C., M.E.C., I.V.D., and W.C.K.P. designed research; E.B., flow and jamming. Specifically, two of the key rheological param- D.J.M.H., R.B., and G.L.H. performed research; E.B., D.J.M.H., M.H., R.B., and G.L.H. analyzed data; and D.J.M.H. and W.C.K.P. wrote the paper.y eters in chocolate manufacturing, the yield stress, σy, and the high-shear viscosity, η2, are controlled by how far the volume Conflict of interest statement: This work is, in part, funded by Mars Chocolate UK Ltd.y fraction of solids, φ, of the chocolate formulation is situated This article is a PNAS Direct Submission.y from the jamming volume fraction, φJ. We demonstrate that the This open access article is distributed under Creative Commons Attribution-NonCommercial- first part of the conche breaks apart particulate aggregates, thus NoDerivatives License 4.0 (CC BY-NC-ND).y increasing φJ relative to the fixed mass fraction. In the second Data Deposition: All data plotted in this work can be downloaded from Edinburgh part of the conche, the addition of a small amount of disper- DataShare (https://datashare.is.ed.ac.uk/handle/10283/3281).y 1 E.B., D.J.M.H., and M.H. contributed equally to this work.y sant reduces the interparticle friction and further raises φJ, in 2 turn reducing σy and η2, resulting in fluidization of the sus- To whom correspondence should be addressed. Email: [email protected] pension, i.e., a solid to liquid transition. Such “φJ engineering” www.pnas.org/cgi/doi/10.1073/pnas.1901858116 PNAS Latest Articles j 1 of 6 Downloaded by guest on September 27, 2021 superscript, which, again, we will drop unless needed), and A µ diverges at φm. Competition between friction and adhesion gives rise to a ? range of rheologies (19). If σ /σa 1, the suspension shear thins at σ > σy to the frictional viscosity, η2. The state diagram of such a system is shown schematically in Fig. 1B; Fig. 1B, Inset shows a typical flow curve. However, a suspension with ? σ /σa 1 first shear-thins at σ > σy, and then shear-thickens as σ exceeds σ?. Modifying system additives (e.g., removing poly- ? meric depletants or adding surfactants) can increase σ /σa and change the first type of behavior to the second type (21, 22). Conching Phenomenology We worked with a simplified chocolate formulation of “crumb powder” dispersed in sunflower oil with lecithin (23). For one experiment, we also added a second surfactant, polyglycerol polyricinoleate (PGPR). Crumb is manufactured by drying a water-based mixture of sucrose crystals, milk, and cocoa mass followed by milling (24). To perform a laboratory-scale conche, we used a planetary mixer (Fig. 2) to prepare 500-g batches. The total lecithin added was 0.83 wt%. In the first step, the B “dry conche,” we mixed the solids with the oil and 0.166 wt% of lecithin (20% of the total) in the planetary mixer at ∼ 100 rpm until the material smears around the bowl right after it has cohered into a single lump around the blade. At φ = 0:55, this took ∼ 40 min. Then, for the “wet conche,” the remaining lecithin was added and mixed for a further 20 min. Conched samples were prepared with solid concentrations in the range 0:4 . φ . 0:6, with φ calculated using measured den- sities (see Materials and Methods), so that a weight fraction of 74% converts to φ = 0:55 (assuming all of the fat contained in the crumb melts during conching). In each case, the flow curves of the as-conched sample as well as that of samples succes- sively diluted with pure oil were measured using parallel-plate rheometry (see Materials and Methods). Fig. 3 stages A through H show the phenomenology of conching a mixture with solid volume fraction φ0 = 0:55 (or 74 wt.%) to which, initially, 20% of the final total of 0.83 wt.% of lecithin has been added; the accompanying plots show the power consumption of the planetary mixer as well as mea- sured densities of the sample as conching proceeds. We define Fig. 1. (A) The high-shear viscosity of suspensions of granular hard spheres the solid volume fraction as the ratio of solid volume to total normalized by the solvent viscosity, ηr, plotted against the volume fraction solid plus liquid volume, discounting any air that may be present; φ, with friction coefficient increasing from µ = 0 (red), diverging at φrcp, to this differs from the granulation literature, where the air is typ- µ ! 1 (blue), diverging at φµ!1.( ) The jamming volume fraction, m Inset ically taken into account.
Recommended publications
  • Premium Ingredients for Exceptional Chocolate Drinks and Desserts
    Premium ingredients for exceptional chocolate drinks and desserts 1 With over 150 years of experience crafting premium chocolate from bean to bar in Northern California, Ghirardelli® Chocolate is trusted by chefs and consumers to deliver quality and flavor. A full line of sauces, powders and chocolate, combined with 93% national brand awareness*, makes Ghirardelli the perfect choice for creating exceptional desserts, coffee drinks, milkshakes, smoothies and hot cocoa. A reputation for rich, intense flavors means consumers overwhelmingly prefer to order Ghirardelli branded products in restaurants and cafés across numerous categories. Make products your customers will crave by using Ghirardelli ingredients. Qualifying products may proudly bear the Ghirardelli name with our “Made With Ghirardelli” program. Source: Relevation Research, January 2011 *Ipsos Chocolate Consumer Monitor, 1001 Consumers, January 2010 Sauces An incredibly versatile product, Ghirardelli sauces add rich and intense flavors when used as an ingredient or topping. With a wide range of package sizes and flavors they are perfect for: • Coffee Drinks • Milkshakes • Ice Cream/Yogurt Toppings • Cocktails • Dessert Toppings An industry standard for specialty coffee, Ghirardelli’s sauces are preferred over competitor brands when tasted in a mocha. A higher cocoa content vs. competitor products, and the addition of Ghirardelli chocolate liquor, makes Ghirardelli’s chocolate sauce thicker with a richer, true chocolate flavor. It’s the perfect topping for desserts or beverages as well as the ideal product for decorating glassware and plates. Available sizes: Large pump bottles, squeeze bottles. Flavors include: Black Label Chocolate, Sweet Ground Chocolate, Caramel and White Chocolate. 3 Sweet Ground Chocolate For over 150 years consumers and chefs have used Ghirardelli Sweet Ground Chocolate to create decadent hot cocoa, coffee drinks and baked goods.
    [Show full text]
  • Welcome to Che: Chocolate Engineering Christi L
    Welcome to ChE: Chocolate Engineering Christi L. Patton, Laura P. Ford, and Daniel W. Crunkleton University of Tulsa, Tulsa, OK Abstract An Introduction to Chemical Engineering course must introduce the student to the language of chemical processes as he learns of the many career options. This must be accomplished in a way that is meaningful to a student with minimal technical background and motivating enough to encourage them to return for another semester. The authors have found that food and fun are excellent motivators with chocolate being a distinct favorite. The freshmen at The University of Tulsa learn about chocolate processing and have the opportunity to sample along the way. Groups of students can roast cocoa beans, break the beans apart and separate the edible portion from the husks, grind the beans, separate the cocoa butter from the solids, and attempt to make edible chocolate. Each step presents unique challenges to the students and encourages them to brainstorm ways to automate and scale up the process. The lessons learned during the freshman year are continued as the sophomores are introduced to mass and energy balances. There the emphasis is on the final products: chocolate covered cookies and chocolate covered coffee beans. The students have an opportunity to demonstrate the lessons learned at the annual e-week Open House for middle school students. University students discuss the food processing steps and relate them to chemical engineering processes. Samples of the cocoa beans at different stages of processing are available to see and smell. The middle school students learn about the product specifications for white, milk and dark chocolate then choose a kind to sample.
    [Show full text]
  • About Chocolate I
    All about Chocolate Selecting, handling, and storing everyone’s favorite ingredient BY CAROLE BLOOM ’m crazy about chocolate, and I know I’m not Dark chocolates I alone. I spend a good part of my professional are complex like life working with chocolate, and off-duty I cer- fine wines.And like tainly enjoy my share of it. I’ve gained a better coffee, chocolate appreciation for chocolate by learning about its becomes darker in cultivation, processing, and various types. And of color and richer in course, knowing how to handle chocolate prop- flavor with longer erly in the kitchen only adds to the pleasures of roasting. this favor ite ingredient. CHOCOLATE GROWS ON TREES Chocolate may not seem like it comes from a plant, but its source is the fruit of the cocoa tree, Theo broma cacao. It’s primarily cultivated in equatorial regions of the world (where the climate is warm and hu- mid), although some chocolate is now being pro- When ready for harvest, the pods are cut from duced in Hawaii. the trees and the beans are removed along with Cocoa trees that grow in the wild can reach their membrane. The beans are placed on banana heights of up to sixty feet. Cultivated trees, how- leaves or in large vats, covered with leaves, and ever, are raised in the shade of tall, large-leaved left to ferment for a few days, while the membrane “ mother” trees, usually banana trees, rubber trees, evaporates and the beans darken in color. The or coconut palms. These mother trees keep the beans are then sun-dried for several days.
    [Show full text]
  • Volatile Changes Caused by Different Factors in Different Types of Chocolate
    Volatile changes caused by different factors in different types of chocolate THESIS Presented in Partial Fulfillment of the Requirements for the Degree Master of Science in the Graduate School of The Ohio State University By Yi-Hsuan Lin, B.S. Graduate Program in Food Science and Technology The Ohio State University 2010 Master's Examination Committee: Professor Dr. Sheryl A. Barringer, Advisor Professor Dr. W. James Harper Associate Professor Dr. V.M. (Bala) Balasubramaniam Copyright by Yi-Hsuan Lin 2010 ABSTRACT The volatiles change caused by different factors in different chocolate was analyzed by using SIFT-MS (Selected Flow Tube-Mass Spectrometry). During conching, all volatiles initially increased then decreased in unsweetened dark (UDC), dark (DC), unsweetened milk chocolate (UMC). The greatest rate of volatile loss occurred during the first 28h of conching. The total volatile lost was 72- 79% at 48h, and loss was mostly due to methanol. The percent lost of acetic acid was least, about 16-61%. Most volatiles lost 80-95% during conching, but a few volatiles had low percent lost. In storage study, unsweetened dark chocolate at 4˚C, 25˚C, and 50˚C had higher total volatile concentration than unsweetened milk. Samples at 50˚C showed less loss than at 25˚C and 4˚C in total volatile. The low loss of Strecker aldehydes, heptanal, and nonanal may indicate the occurrence of the Maillard reaction and lipid oxidation. In blooming measurement, cocoa mass, unsweetened dark chocolate, and dark chocolate were analyzed. Acetic acid in bloomed samples was significant lower than unbloomed in UDC, DC, and cocoa mass (CM).
    [Show full text]
  • Refining (102) Conching (104) Forming (110)
    US 20080248183A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2008/0248183 A1 BrOWn (43) Pub. Date: Oct. 9, 2008 (54) SUGAR FREE AND REDUCED SUGAR A2.3L. I./22 (2006.01) CHOCOLATE AND METHODS OF A2.3L I/36 (2006.01) MANUFACTURE (76) Inventor: Robert Brown, San Jose (CR) (52) U.S. Cl. ......... 426/588: 426/601; 426/615; 426/632: 426/638; 426/639: 426/629 Correspondence Address: MEREDITH & KEYHANI, PLLC 330 MADISONAVE., 6TH FLOOR NEW YORK, NY 10017 (US) (57) ABSTRACT A method of producing a Sugar free chocolate composition (21) Appl. No.: 11/696,946 comprising the steps of thoroughly mixing at least the fol lowing ingredients: 1 to 60% by weight agave syrup, and 25 (22) Filed: Apr. 5, 2007 to 99% by weight cacao liquor; so as to produce an aqueous O O Solution; conching the aqueous solution; evaporating water Publication Classification from the aqueous solution utilizing an additional water (51) Int. Cl. removal means during the conching step to provide a conched A23C 9/00 (2006.01) chocolate; tempering the conched chocolate to provide a A23D 7700 (2006.01) chocolate product; and forming the chocolate product. Refining (102) Mixing (100) Supplemental Conching (104) evaporation (106) Tempering (108) Forming (110) Patent Application Publication Oct. 9, 2008 Sheet 1 of 4 US 2008/0248183 A1 Refining (102) Mixing (100) Supplemental Conching (104) evaporation (106) Tempering (108) Forming (110) FIGURE 1 Patent Application Publication Oct. 9, 2008 Sheet 2 of 4 US 2008/0248183 A1 Refining (102) COCOa Butter Supplemental evaporation (202) Supplemental evaporation (208) FIGURE 2 Patent Application Publication Oct.
    [Show full text]
  • San Francisco Since 1852
    SAN FRANCISCO PREMIUM SINCE 1852 CHOCOLATE GOLDEN GATE OCEAN BEACH Banana Split A trio of vanilla, strawberry and Ghirardelli® Chocolate Sea Salt Caramel Sundae ice cream each paired with perfect toppings - crushed ORLD FAMOU Vanilla ice cream smothered with creamy caramel, W S handmade hot fudge and sea salt. Perfectly pineapple, sliced strawberries and handmade hot GE fudge. Finished with a fresh banana, whipped cream, T FUD SUNDA topped with whipped cream, creamy caramel, chopped almonds and a cherry. 12.45 HO E sea salt and a Ghirardelli® SQUARES Vanilla ice cream overflowing with our Milk Chocolate. 11.95 handmade hot fudge, whipped cream, chopped almonds and a cherry. 11.95 Any sundae served in a H wl and ffle Bo made Wa ! for just $1 more 1090 cal LANDS END STRIKE IT RICH Salted Caramel Brownie Sundae Butterscotch Hot Fudge Sundae Butter pecan ice cream smothered with butterscotch Two large scoops of vanilla ice cream flanked by a and golden almond nuggets under a layer of Ghirardelli® Chocolate Brownie and smothered with creamy vanilla ice cream and our handmade hot caramel, handmade hot fudge and sea salt. Perfectly TREASURE ISLAND fudge. Topped with whipped cream, chopped topped with whipped cream and a cherry. 14.50 almonds and a cherry. 11.95 Warm Brownie Sundae Vanilla ice cream paired with our warm Ghirardelli® Chocolate Brownie and smothered with handmade hot fudge. Topped with whipped cream, chopped almonds and a cherry. 11.95 CRISSY FIELD Cookie Bits Sundae PAINTED LADIES Vanilla ice cream nestled between cookies‘n cream ice Family Favorite • Serves 4 cream and smothered with our handmade hot Eight scoops of ice cream, fresh bananas and eight ® delicious toppings.
    [Show full text]
  • Chocolate Consumption, Manufacturing and Quality in Western Europe and the United States
    Kingdom – eat on average about ten kilograms of GEOGRAPHY Chocolate chocolate per person every year (Zackowitz, VOLUME 91(3) 2004). Why do Western Europeans consume so PAGES 218-226 much more chocolate on average than Americans? Consumption, Why do Americans and the British have a different understanding of what constitutes quality Manufacturing and chocolate from continental Europeans? We argue that the history of chocolate manufacturing in Europe explains how and why different notions Quality in Western of quality developed. Each innovation in the manufacturing process influenced under- Geography © 2006 standings of quality in the chocolate industry in Europe and the the country in which the innovation was made. These understandings of what constitutes quality chocolate, in turn, influence how chocolate is United States manufactured and marketed in the respective countries. Finally, traditions in marketing and HEIKE C. ALBERTS AND manufacturing shape and are shaped by JULIE L. CIDELL consumer preferences, showing that cultural and economic processes are at work simul- taneously. Our analysis suggests that continental ABSTRACT: In this article we examine why European chocolate manufacturers’ dual focus on chocolate consumption patterns and traditional understandings of quality on the one understandings of quality vary significantly hand, and innovation in terms of flavours on the between the United States and Western Europe other hand, make their chocolate bars so popular. on the one hand, and among western European In both the United States and in Europe, countries on the other hand. We argue that mass-market chocolate makes up the lion’s share different attitudes towards chocolate and of the chocolate market, with gourmet chocolates different marketing strategies by chocolate only accounting for 3.2% in the United States manufacturers explain much of the difference (Hopkins, 2005).
    [Show full text]
  • Chocolate FAQ
    Chocolate FAQ What is chocolate? In the U.S., chocolate we know (Hershey’s, Reese’s etc) are actually NOT chocolate, they are candy. Real chocolate (fine chocolate) contains no more than 5 ingredients usually in this order: 1) Chocolate, cocoa, or cocoa mass (mashed up bean) 2) option: extra cocoa butter 3) granulated cane sugar (more traditional and pure of taste) 4) optional: true vanilla orchid seed pod not "vanillian" not real deal - lumber by product 5) optional: soy lecithin (emulsifier) What does the word “chocolate” mean? (Still in debate, the most cited version) The word Chocolate comes from the Aztec word chocolātl. This word comes from the Mayan word xocolātl meaning "bitter water". Chocolate was drunk bitter by the Aztecs. How did the Aztec and Mayans use chocolate? The Aztec way of making chocolate was very similar to that of the Mayans. Priests presented cocoa beans as offerings to the gods and served cocoa drinks during sacred ceremonies like weddings. Cocoa was used as a gift to the deities, presented at royal burials to ensure comfort in the afterlife. Chocolate was also used as a medicine. All of the areas that were conquered by the Aztecs that grew cocoa beans were ordered to pay them as a tax, or as the Aztecs called it, a "tribute". What is the difference between “cacao” and “cocoa”? "Cacao" is the bean that comes from the cacao tree, which is known by the scientific name of Theobroma cacao. "Cocoa" is what the bean is called after it has been processed. But most people today use the words intertwine-ly.
    [Show full text]
  • Application Notenote Particle Sizing of Chocolate AN138
    ApplicationApplication NoteNote Particle Sizing of Chocolate AN138 Particle size measurement of chocolate samples is a Production Process vital factor in producing a consistent and attractive final product. Several stages of manufacturing are Beans are harvested and fermented for a period of 5-6 controlled by particle size and the particle size of days in the country where they were grown. After arrival cocoa powder used in chocolate affects color and at the production facility the beans are roasted for 10- flavor strength. 115 minutes depending on the quality. Next the shells are removed by a process known as winnowing, where History of Cocoa shells are removed using compressed air. The nib is what remains; this is the meat of the seed. As long ago as the 600AD the Maya Indians were enjoying the delights of the cocoa bean on the Yucatan peninsula. Milling of the nib takes place in a steel pin mill or a By the 1300s the Aztecs in what is now Mexico City made vertical ball mill. The nib is ground until the friction and a drink form the cocoa bean described as ‘finely ground, heat of the milling reduces it to a thick chocolate colored soft, foamy, reddish, and bitter, added to the mix was liquid, known as mass or liquor. The chocolate liquor aromatic flowers, vanilla and wild bee honey’. contains 50-58% cocoa butter and cocoa particles with a median around 100 microns. Depending on how the Chocolate remained a drink until 1849 when the liquor is processed it is either made into cocoa powder first chocolate for eating was produced.
    [Show full text]
  • Mysteries of Conching Revealed Carly Meck Blommer Chocolate
    Mysteries of Conching Revealed Carly Meck Blommer Chocolate START SLIDESHOW > Conching is a Vital Step in the Chocolate Making Process NEXT > Conching has a Long and Accidental History 1800’s First solid eating chocolate Ancient Mesoamerica appeared – not desirable • Cocoa beans used as currency due to texture • Royals drank a bitter frothy cocoa beverage 1879 • Rudolphe Lindt 1600’s discovered conching. Chocolate was The results were smooth, solely consumed less bitter chocolate as a beverage Image from Brooklyncacao.com NEXT > Design Matters Longitudinal Conche Melanger Refiner Conche Refiner Conche Forced Air Conche & Paddles Ball Mill Infeed Recirculation Continuous Conche Chocolate Flow In Rotating Paddles Cooled Water Jacket Chocolate Flow Out High Shear Conche Mixing and Cutting Shearing Two Shaft High Sheer Three Shaft High Sheer NEXT > Chocolate Transforms at Different Stages of the Conching Process Phases of Conching Dry Phase Phases of Conching Plastic Phase Phases of Conching Liquid Phase NEXT > Volatile Molecules are Reduced Volatile Reduction Total VOC Emitted During Conching 16 14 12 10 8 High Shear Dark Choc PPM 6 High Shear Milk Choc Melanger - Dark 4 2 0 1 2 3 4 5 6 7 8 9 10 HOURS Filling - Dry Conching - Liquifying NEXT > Moisture is Reduced Moisture Reduction NEXT > Texture and Mouthfeel are Improved Crystalline Network PreRefining Crystalline Network Conching Images Glicerina, Virginia, et al. “The Influence of Different Processing Stages on Particle Size, Microstructure, and Appearance of Dark Chocolate.” Journal
    [Show full text]
  • Finest Cocoa Unique Roasting and Grinding Process the Lindt Invention Best Ingredients Product Perfection
    Lindt Difference – What makes Lindt chocolate so exceptional? FINEST COCOA UNIQUE ROASTING AND GRINDING PROCESS THE LINDT INVENTION BEST INGREDIENTS PRODUCT PERFECTION LINDT & SPRÜNGLI MAÎTRE CHOCOLATIER SUISSE DEPUIS 1845 ANNUAL REPORT 2016 DOSSIER LINDT DIFFERENCE — 50 Lindt Difference – What makes Lindt chocolate so exceptional? FINEST COCOA The secret of Lindt’s unique taste lies in the careful selection and blending of premium cocoa beans from the world’s most exclusive regions of origin, coupled with highly skilled production methods. UNIQUE ROASTING AND GRINDING PROCESS THE LINDT INVENTION BEST INGREDIENTS PRODUCT PERFECTION LINDT & SPRÜNGLI MAÎTRE CHOCOLATIER SUISSE DEPUIS 1845 ANNUAL REPORT 2016 DOSSIER LINDT DIFFERENCE — 50 FINEST COCOA BEANS FROM THE MOST RENOWNED REGIONS Lindt & Sprüngli sources its premium cocoa beans from the world’s very best regions of origin, such as Ghana, Latin America (mainly Ecuador), the Caribbean, Madagascar, and Papua New Guinea. In our recipes, we use special blends of cocoa varieties from different regions. These bean combinations are a closely guarded secret and are what give our chocolates their exquisite taste. LINDT & SPRÜNGLI MAÎTRE CHOCOLATIER SUISSE DEPUIS 1845 ANNUAL REPORT 2016 DOSSIER LINDT DIFFERENCE — 52 R ESPONSIBLE WAY OF PRODUCING SUSTAINABLE COCOA Lindt & Sprüngli sources its cocoa beans from the world’s The quality of the cocoa beans is tested in our internal most renowned regions. laboratories on the basis of very strict guidelines. Lindt & Sprüngli is one of the few “bean-to-bar” chocolate LINDT & SPRÜNGLI makers in the world, with full control of the production FARMING PROGRAM chain, from the selection of cocoa beans to the end ­product.
    [Show full text]
  • 2000 the Flavor of Milk Chocolate Changes Caused by Processing
    The Flavor of Milk Chocolate Changes Caused by Processing Marlene Stauffer Blommer Chocolate Company he purpose of this paper is to discuss Formulations using a single bean vari- Tand demonstrate flavor differences ety versus a blend of beans may make dra- among milk chocolates that are formulated matic flavor differences in a chocolate for- with a constant recipe, altering only the mula. To date, much of the understanding processing parameters. A product devel- of chocolate flavor has been based on gas opment team worked together to develop chromatographic and mass spectral data a protocol.The ground rules were set.The of the volatile aroma fraction of dried first step was to establish the formula, then and/or roasted cocoa beans and the result- determine processing techniques, focus on ing formulated chocolate. More than 400 what processing techniques to alter, ana- compounds have been found in cocoa fol- lyze the product and finally to evaluate the lowing fermentation, drying, roasting and Stauffer is the sensory effects of the process changes. conching. Some flavor elements in choco- director of quality The goal was to maintain the formula in late are highly volatile compounds con- assurance and new Figure 1 throughout the test process. tributing sour notes; moderately volatile product develop- Certain assumptions that would affect compounds contributing roasted or flow- ment at Blommer flavor were made prior to any samples actu- ery notes; and low volatile compounds con- Chocolate. She has ally being manufactured. Roasting, the type tributing milky or caramel notes. The been with Blommer and amount of raw materials, the refining ensemble of all these flavor components since 1982.
    [Show full text]