Petrology, Geochemistry and Geochronology of Late Triassic Volcanics, Kunlun Orogenic Belt, Western China: Implications for Tectonic Setting and Petrogenesis
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Geochemical Journal, Vol. 39, pp. 1 to 20, 2005 Petrology, geochemistry and geochronology of late Triassic volcanics, Kunlun orogenic belt, western China: Implications for tectonic setting and petrogenesis HONGTAO LIU* Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, PR China (Received November 27, 2003; Accepted April 28, 2004) The Qimantage volcanic suite (QVS) of late Triassic age, dominated by dacitic to rhyolitic lavas and pyroclastic rocks with minor basaltic andesites, outcrops mainly in the middle segment of Qimantage Mt. region, Kunlun orogenic belt, which extends along the northern margin of Tibetan plateau, western China. Petrological and geochemical studies indicate that the volcanic rocks are of typical calc-alkaline affinity with silica contents ranging from ~53 to ~80 wt%, exhibiting a medium- to high-K characteristics. Major element variations define relatively smooth compositional trends, while large ion lithophile (LIL) trace elements correlate positively with increasing SiO2. Chondrite-normalized incompatible trace element spidergram shows conspicuous sparks at Rb and Th, but pronounced Nb and Ti depletion. The chondrite- normalized REE patterns of QVS are generally paralleled to each other, exhibiting highly fractionated LREE/HREE spec- tra with small to pronounced negative Eu anomalies. Two whole-rock Rb-Sr isochrons yield ages of ca. 209 and ca. 225 Ma, respectively, indicating the volcanic suite was emplaced during the late Triassic. The initial 87Sr/86Sr ratios (0.708– 0.709) and initial eNd(t) values (–2.05~–2.35) imply that the magmas were derived from a slightly enriched mantle source with considerable crustal contamination. Considering its petrological, geochemical and isotopic characteristics in a re- gional geological background, it is proposed that QVS was generated upon an active continental margin during the late Triassic north-directed subduction event. Both the volcanics and the closely-related coeval granitoid plutons collectively make up the late Triassic arc magmatic belt on the paleogeographically southern margin of the Tarim continent. Keywords: calc-alkaline volcanic, active continental margin, Kunlun orogen, western China would be very helpful in elucidating the tectonic evolu- INTRODUCTION tion of the Kunlun orogen. A voluminous terrestrial volcanic rocks of late Triassic age, covering an area of about 1800 km2, distributed in REGIONAL GEOLOGY the middle portion of the Qimantage Mt. region (Fig. 1), Kunlun orogenic belt (Jiang et al., 1992), which lies along Within the Qimantage Mt. region and adjacent areas, the northern margin of the Tibetan plateau, western China. stratigraphy underlying QVS comprises pre-Triassic meta- The volcanic rocks are dominated by dacite and rhyolite morphic and non-metamorphic sequences (QPGB, 1985), lavas, subordinate andesites and minor basaltic andesites, including Neoproterozoic, upper Ordovician, upper with vast accumulation of ignimbrites, volcanic breccias Devonian, Carboniferous and Lower Permian and agglomerates of dacitic to rhyolitic composition, in- stratigraphic sequences. The Neoproterozoic Jinshuikou truded by late Mesozoic granitoid plutons and dykes. Group is the oldest stratigraphic unit in the region, com- Because of its geographical remoteness and high altitudes, posed mainly of granulites, plagioclase gneisses, two- few detailed studies on the volcanic rocks have been re- mica plagioclase gneisses, quartz schists, biotite- corded previously. The merely documented but not pub- actinolite schists with some quartzite interlayers. Con- lished data regarding the volcanics are the stratigraphical formably overlying the Jinshuikou Group is the and lithological descriptions by Qinghai Provincial Geo- Neoproterozoic Langyashan Group that is dominated logical Bureau in a regional mapping program scaled at lithologically by marbles, dolomites and quartzites, with 1:200,000 in the early 1980’s (QPGB, 1985). Since QVS minor quartz schists and low-grade metamorphic clastic is an integral part of the Kunlun orogenic belt, detailed sediments, i.e., metasandstones and metasiltstones. petrological, geochemical and geochronological studies Unconformably overlying the Langyashan Group is the Tieshidasi Group of late Ordovician age, which can be subdivided into three sub-units: the lower is mainly of *E-mail address: [email protected]) metaclastic sediments with subordinate metavolcanics, the Copyright © 2005 by The Geochemical Society of Japan. middle part dominated by metavolcanics including 1 the Lower Permian strata. They usually have a very lim- ited distribution and mainly composed of limestones and dolomitic limestones containing abundant early Permian Brachiopoda and Fusulinida fossils. The strata of early to middle Triassic age are absent in the Qimantage Mt. region but are well developed in adjacent areas such as the southern Kunlun region. They consist mainly of marine flysch sediments. As shown in Fig. 1, voluminous Late Paleozoic to Mesozoic granitoid plutons are widely distributed in the Qimantage Mt. region and surrounding areas. Most of those intrusives are elongated in shape and extended along the SE-trending Qimantage Mt. range, indicating fault- controlled plutonic emplacement. Well-developed contact metamorphism between intrusives and country rocks can be frequently observed. It is also recognized that most regional-scaled faults and fractures were developed in the SE direction along the Qimantage Mt. reflecting a unique regional structural pattern. In general, the geology of the Qimantage region is Fig. 1. Geological map of the Qimantage Mt. region. Simpli- characterized by its thick metamorphic and non- fied after Jiao et al. (1988). See text for more description of metamorphic sequences ranging in age from Proterozoic regional geology. to early Triassic, intruded by voluminous late Paleozoic to Mesozoic granitoid plutons (Zhou and Yuan, 2003; Jiang et al., 1999). The most prominent structures in the region are the SE-trending regional faults and fractures. pillowed metabasalts, meta-andesites, and metadacites All these indicate that the region had experienced a long with some intercalations of quartz schists, quartzites and and complicated geological evolution prior to the initia- metasandstones. The upper part consists mainly of lime- tion of the terrestrial volcanism (Jiang et al., 1992; Xu et stones, marbles, dolomites, phyllites and metasiltstones. al., 1994; Xiao et al., 2003). This Group is widely distributed throughout the Qimantage Mt. region and characterized by its consider- PETROGRAPHY able lateral variations in both composition and thickness. The Upper Devonian strata, namely the Qiegaisu Based on field investigation and microscopic studies, Group, are also widely distributed in the region, which is it is recognized that QVS is mainly composed of inter- unconformably over the Tieshidasi Group. It can be mediate to acidic lavas and pyroclastic rocks, with minor lithologically divided into two parts: the lower part is basaltic andesite. The pyroclastic rocks including composed mainly of siltstones, sandstones and calcare- ignimbrites, volcanic breccias and agglomerates of dacite ous siltstones, intercalated with silty limestones, in which to rhyolite compositions make up more than 60 vol% of there are abundant late Devonian fossils; the upper part QVS, indicating relatively strong volcanic eruptions. Due is dominated by lavas and pyroclastic rocks of basaltic- to its considerable lateral variations in both lithology and andesitic-dacitic-rhyolitic compositions, intercalated with thickness, it is very difficult to make a detailed some slate, calcareous siltstone and limestone layers, in lithostratigraphical correlation between adjacent sections. which also contain abundant Brachiopoda and corral fos- The rock colors are also variable ranging from purple- sils of late Devonian. red to greenish-dark with varying grayish hues. Accord- The Carboniferous Dagangou Group is dominated by ing to microscopic examinations and chemical analyses, varying types of limestones intercalated with sandstones the volcanic rocks having red to purple colors are usually and slate layers. A basal conglomerate layer usually oc- dacites to rhyolites, while the rocks with grayish-dark curs. The various limestones including biocalcirudite, colors are commonly andesites and basaltic andesites. In biosparrudite, biopararenite, and silica-bearing limestone, the western area of its distribution, the most common rock contain abundant Carboniferous corral and Brachiopoda types are rhyolites, dacites, and voluminous ignimbrites fossils. The group is also widespread in the Qimantage and volcanic breccias of dacite-rhyolite compositions, Mt. region and possesses pronounced lateral variations with minor andesites and basaltic andesites; whereas in in thickness. Conformably overlying Dagangou Group is the eastern area, although the rock types are similar to 2 H. Liu those in the west, it appears that the pyroclastic rocks are from andesine to oligoclase with varying alteration of more abundant and may reach up to 70 vol%, indicating sericitization and carbonitization. The hornblende and more fiercely explosive eruptions. pyroxene phenocrysts usually exhibit euhedral to In terms of lithologic and facies variations at differ- subhedral shape but partly altered into chlorite and Fe- ent locations, the volcanic activities can be roughly gen- oxide aggregates especially on the rims of the phenocrysts. eralized as following.