Air Force Research Laboratory Ion-Molecule Reactions in a Nitrogen-Benzene Plasma: Implications for the Destruction of Aromatic Compounds
S. Williams, S. Arnold, A. Viggiano, and R. Morris Air Force Research Laboratory / Space Vehicles Directorate / VSBP
Rajesh Dorai and Mark J. Kushner University of Illinois / Optical and Gas Discharge Physics
52nd Annual Gaseous Electronics Conference Norfolk, VA - 6 October 1999
University of Illinois Air Force Research Laboratory
Introduction
Dielectric barrier discharges (DBDs) are attractive plasma sources for remediation of toxic gases, such as NxOy, SO2, and VOCs, due to their ability to operate at higher pressures with moderate applied voltage. However, the destruction of aromatic compounds in these low temperature plasmas is problematic due to the small rate of ring-cleaving reactions by plasma generated oxidizing radicals at ambient gas temperatures. We report on a combination of laboratory flow tube kinetics measurements and computational modeling to investigate the question of whether a nitrogen plasma can be used for the destruction of waste aromatic compounds based on ion-molecule reactions.
University of Illinois Air Force Research Laboratory Flow Tube Kinetics
v • Ion-molecule reaction X+ + R ® products Buffer Flow
R R R R R R R R R R R R R + + + R R R X R + R • Rate = -d[X ]/dt = k[X ][R] X R RR R R R R R R R R R – R is present in a large excess R R R R RR X+ R R R R R
– Pseudo first order kinetics L 9 æ ö + • k = 1 lnç [Xo] ÷ [R] t ç [X+]÷ 8
è ø ] + X [ 7 – The reaction time is t = L/vion ln 6 • Plot ln[X+] vs [R] and the slope = -kt 5 0 1 2 3 4 5 6 [R] (x1011 cm-3) University of Illinois Air Force Research Laboratory Selected Ion Flow Tube (SIFT)
University of Illinois Air Force Research Laboratory
High Temp Flowing Afterglow
Ceramic tube-1800 K Quartz tube-1400 K University of Illinois Air Force Research Laboratory
C6H6 Ion-Molecule Reactions
Reactant Reco mbinat ion Temperature Ion Ene rgy (eV) Range NO + 9.26 300 – 500 + O 2 12.07 300 – 140 0 + N4 12.9 300 – 500 O + 13.62 300 – 500 + 2 Kr ( P3/2) 14.00 300 – 500 N + 14.53 300 – 500 + 2 Kr ( P 1/2) 14.66 300 – 500 + N2 15.58 250 – 140 0 Ar+ 15.76 300 – 500 F+ 17.42 300 Ne + 21.56 300 – 500 University of Illinois Air Force Research Laboratory
+ X + C6H6 ® Products
X = N4 N N2 Ar Ne RE (eV) = 12.9 14.5 15.6 15.8 21.6 Ion Products (300K) + C6H6 1.0 0.68 0.12 0.08 0.01 + C6H5 0.07 0.24 0.18 0.02 + C6H4 0.01 0.04 0.03 0.02 + C5H4 0.07 + C5H3 0.02 0.03 0.02 + l-C4H4 0.02 0.36 0.48 + c-C4H4 0.03 0.05 0.07 + C4H3 0.59 + C4H2 0.09 + c-C3H3 0.12 0.17 0.13 0.11 + C2H3 0.07 + C2H2 0.07 Rate (molecule-cm3-s-1) 1.2 x 10-9 2.0 x 10-9 1.6 x 10-9 1.3 x 10-9 1.6 x 10-9
University of Illinois Air Force Research Laboratory
Benzene Breakdown Diagram
Total Energy = REIon + EInt + ETrans 100
+ 80 C H 6 n + N + 60 C H 5 n
+ C H 40 4 n
+ + F C H 20 3 n
Relative Abundance (%) 0 12 14 16 18 20 22 Total Energy (eV) University of Illinois Air Force Research Laboratory Kinetics Summary
• Series of benzene reactions all proceed at collisional rate.
• Mechanism changes from association to non-dissociative and then dissociative charge transfer with increasing reactant ion energy.
• Primary and secondary dissociation product ions are observed.
+ + + • Isomeric form of C3H3 , C4H4 , and C5H3 product ions was determined. • Temp dependent branching fractions were converted to product ion breakdown curves. Pressure effect observed due to collisional stabiliztion of the charge transfer complex by He buffer.
• N+ reaction with benzene involves many non-charge transfer processes.
Thanks to AFOSR
University of Illinois Air Force Research Laboratory
DBD Model Description
• The basis of the model is to integrate the nonlinear ordinary differential equations describing the reaction chemistry over the residence time with the simultaneous solution of the equations for the circuit parameters.
• The rate coefficients for the electron impact reactions are obtained from a lookup table produced by an offline Boltzmann solver.
dN(t) dt Offline Lookup Table of LSODE ODE Boltzmann k vs. T SOLVER Solver e Circuit Module
N(t+Dt), V, I
University of Illinois Air Force Research Laboratory
Dominating Reactions
+ c-C3H3 + C2H2 + HCN Ar+ C6H6 C6H6 N+ Ar Ar+ C6H6 N
N 2 C6H6+
C H C H + + H 6 6 N C6H6 6 5 + + 2 + C6H6 N4 N2 I-C4H4+ + C2H2
N2 N2 c-C3H3+ + C3H3
C H + + C H 4 3 2 3 Ne Ne+ C4H2+ + C2H4
C6H6 Ne+
University of Illinois Air Force Research Laboratory Dissociative Recombination
• Thermal rate coefficients are Reaction Rate (molecule-cm3-s-1) listed. The model assumes a T-0.5 -7 E + C6H6+ = C6H5 + H 5.00 x 10 temperature dependence. -7 E + C6H6+ = products 5.00 x 10 • The category "products" signifies -7 E + C6H5+ = C6H4 + H 2.76 x 10 species lacking a six membered -7 E + C6H5+ = products 8.27 x 10 aromatic ring -7 E+C6H4+ = products 11.0 x 10 • Rates in red are estimated. -7 E+C5H4+ = products 9.00 x 10 • Rates in black are measured (see -7 E+C5H3+ = products 9.00 x 10 references). -7 E + l-C4H4+ = products 5.77 x 10 References: -7 E + c-C4H4+ = products 5.77 x 10 1) Lehfaoui et al., J. Chem. Phys. -7 E + C4H3+ = products 6.20 x 10 106:5406-5412 (1997). -7 E + C4H2+ = products 5.77 x 10 2) Rebrion-Rowe et al., J. Chem. -7 E + c-C3H3+ = products 7.00 x 10 Phys. 108:7185-7189 (1998). -7 E + C2H3+ = products 4.50 x 10 3) Mitchell and Rebrion-Rowe, Int. -7 E + C2H2+ = products 2.70 x 10 Rev. Phys. Chem. 16:201-213 (1997).
University of Illinois Air Force Research Laboratory Experimental Setup Modeled
• A pulsed low pressure discharge has been modeled as follows: •Dielectric discharge height = 2.5 mm.
•Reactor pressure = 1 Torr
•Operating temperature = 300 K
•Single pulse input (ca. 100 ns duration)
•Input benzene = 0.1% • Key assumptions are as follows: •The dissociative recombination rates of many organic molecular ions have been measured, but the product distributions have not. It is assumed here that for + - + - C6H6 + e and C6H5 + e only only 50% and 25%, respectively, of the reactions produce products with the six membered ring intact. The remainder of the species are classified as “products”. University of Illinois Air Force Research Laboratory Effect of Energy on Benzene
Removal (Ar/N2/C6H6) l Most of the benzene removal involves breaking of the aromatic ring since the + + reaction of Ar with C6H6 predominantly produced l-C4H4 and other lower order hydrocarbons
250 4 ]
3.5 Benzene removed ] 94.9 % Ar 6
ppm Removed 94.9 % Ar 200 5.0 % N 2 H 5.0 % N 3 6 2 0.1% C 6H 6 0.1% C 6H 6 150 2.5
2 Products 100 1.5 Formed
/molecule C 1 50 eV 0.5
0 Concentration at 0.2 s [ 0 0.0002 0.0004 0.0006 0.0008 0.001 0 0.0002 0.0004 0.0006 0.0008 0.001 Energy Deposition [ J/L ] Energy Deposition [ J/L ] W-Value [ University of Illinois Air Force Research Laboratory
Effect of N2 on Benzene
Removal (Ar/N2/C6H6) + + l End products mainly included the recombination products of l-C4H4 , C6H5 + c-C3H3 .
100 1.1 removed ]
6 1
90 ] H 6 0.9 80 ppm Benzene Removed 0.8 70 0.7
60
/molecule C Products 0.6 Formed eV 50 0.5
0.4 40 Concentration at 0.2 s [ 75 80 85 90 95 100 75 80 85 90 95 100 Ar [ % ] Ar [ % ] W-Value [
University of Illinois Air Force Research Laboratory Effect of Energy on Benzene
Removal (Ne/N2/C6H6)
l Most of the benzene removed resulted in breaking of the aromatic ring structure
110 3.5
94.9 % Ne ] removed ] 100 3 6 5 % N 2 H 6 0.1% C H 90 6 6 ppm 2.5 C Benzene 80 2 Removed Products 70 1.5 Formed molecue / 60 1 94.9 % Ne 5 % N eV 2 50 0.5 0.1% C 6 H 6
40
Concentration at 0.2 s [ 0 0 0.0002 0.0004 0.0006 0.0008 0.001 0 0.0002 0.0004 0.0006 0.0008 0.001 Energy Deposition [ J/L ] Energy Deposition [ J/L ] W-Value [ University of Illinois Air Force Research Laboratory
Effect of N2 on Benzene
Removal (Ne/N2/C6H6)
l Both benzene removal and energy efficiency improve with increasing Ne concentration.
75 1.1 ] removed ] 6 70 1 H 6 ppm
65 0.9 Benzene Removed 60 0.8
Products 55 0.7 /molecule C Formed eV 50 0.6
45 Concentration at 0.2 s [ 0.5 84 86 88 90 92 94 96 98 100 84 86 88 90 92 94 96 98 100 Ne [ % ] Ne [ % ] W-Value [ University of Illinois Air Force Research Laboratory Modeling Summary
• The energy efficiency increases initially with increasing energy deposition and remains constant a higher input energies.
• Benzene removal increases with increasing input energy.
• The best results are obtained for pure Ar and Ne discharges which is due to the + + large rate of ring-cleaving reactions by plasma generated Ar and Ne ions. At lower input energies, Ne discharges are better degraders of benzene.
• The presence of N2 inhibits the benzene degradation efficiency mainly because
the energy efficiency in the absence of N2 is much higher than in the presence of
N2. • Dielectric barrier discharges operating with Ar or Ne show potential as sources for remediation of aromatic compounds.
Thanks to NSF
University of Illinois Air Force Research Laboratory
+ N2 + C6H6
+ 0.6 C H 6 6
+ 0.5 C H 6 5
+ C H 0.4 6 4
+ C H 5 3 0.3 + C H 4 4 0.2 + C H 4 3
0.1 + Branching Fraction C H 4 2
+ 0 C H 0 400 800 1200 1600 3 3 Temperature (K) Air Force Research Laboratory
+ Parent Ion: C6H6
100
all temp data 80 300 K data only
40
20 Relative Abundance (%) 0 12 14 16 18 20 22 Total Energy (eV) Air Force Research Laboratory Reaction Coordinate Diagram
112 114 (c) 110 110 (d) 106 104 102 106 (e) 101 90 ? 87 (a) 87
(b) 80
70
59
50 51 + (a) C H + H 6 5 35 34 + (b) C H + H 6 4 2
+ (c) l-C H + C H 4 4 2 2
+ (d) c-C H + C H 6 4 4 2 2
0 + (e) c-C H + C H 3 3 3 3
H fissure(s) H migration Ring rearrangment and opening