McLean, David (1980) Nitrosocarbonyl compounds in synthesis. PhD thesis http://theses.gla.ac.uk/4058/ Copyright and moral rights for this thesis are retained by the author A copy can be downloaded for personal non-commercial research or study, without prior permission or charge This thesis cannot be reproduced or quoted extensively from without first obtaining permission in writing from the Author The content must not be changed in any way or sold commercially in any format or medium without the formal permission of the Author When referring to this work, full bibliographic details including the author, title, awarding institution and date of the thesis must be given Glasgow Theses Service http://theses.gla.ac.uk/
[email protected] NITROSOCARDONY1COMPOUNDS IN SYNTHESIS A thesis presented in part fulfilment of the requirements for the Degree of Doctor of Philosophy by David McLean Department of Organic Chemistry University of Glasgow October, 1980. ACKNOWLEDGMENTS. I would like to take this opportunity to thank Professor Gordon W. Kirby for his friendly advice and discussions during the course of this work and in the preparation of this thesis. I also wish to thank my mum and dad, Maria Pita, Helen Prentice, Elizabeth Breslin and Dr. R. A. Hill. Finally I would like to express my thanks to the Science Research Council for financial assistance and the Staff of the Chemistry Department for technical assistance. CONTENTS. PAGE Smeary ..................................................... 1 Chapter 1 The Chemistry of Electrophilic C-Nitroao-Compounds .............................. 2 Chapter 2 Synthetic Applications of 2,2,2-Trichloroethyl Nitroeofoiate 2.1 Formation and Reduction of Diene/2,2,2-Trichloroethyl Nitrosoformate Adducts .....................................