Carotenoid Composition of Strawberry Tree (Arbutus Unedo L.) Fruits
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(12) Patent Application Publication (10) Pub. No.: US 2014/0155647 A1 Dubois (43) Pub
US 2014O155647A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2014/0155647 A1 Dubois (43) Pub. Date: Jun. 5, 2014 (54) METHOD FOR THE SYNTHESIS OF DIACIDS Publication Classification OR DESTERS FROMINATURAL FATTY ACDS AND/ORESTERS (51) Int. Cl. C07C 67/303 (2006.01) (71) Applicant: Arkema France, Colombes (FR) CD7C5L/36 (2006.01) (52) U.S. Cl. (72) Inventor: Jean-Luc Dubois, Millery (FR) CPC ............... C07C 67/303 (2013.01); C07C 51/36 (2013.01) (21) Appl. No.: 13/946,292 USPC ........................................... 560/190; 562/592 (57) ABSTRACT (22) Filed: Jul.19, 2013 Disclosed herein a process for the synthesis of diacids or diesters of general formula ROOC (CH)x-COOR, in O O which in represents an integer between 5 and 14 and R is either Related U.S. Application Data H or an alkyl radical of 1 to 4 carbon atoms, starting from (63) Continuation of application No. 12/664,182, filed on long-chain natural monounsaturated fatty acids or esters Apr. 21, 2010, now abandoned, filed as application No. comprising at least 10 adjacent carbonatoms per molecule, of PCT/FR2008/051038 on Jun. 11, 2008. formula CH (CH)n-CHR—CH2—CH=CH-(CH2)p- COOR, in which R represents Horan alkyl radical compris (30) Foreign Application Priority Data ing from 1 to 4 carbon atoms, R is either H or OH, and n and p, which are identical or different, are indices between 2 and Jun. 13, 2007 (FR) ....................................... O755733 11. US 2014/O 155647 A1 Jun. 5, 2014 METHOD FOR THE SYNTHESIS OF DACDS -continued OR DESTERS FROMINATURAL FATTY ACDS AND/ORESTERS 0001. -
Sustainable Synthesis of Omega-3 Fatty Acid Ethyl Esters from Monkfish Liver Oil
Preprints (www.preprints.org) | NOT PEER-REVIEWED | Posted: 2 September 2020 doi:10.20944/preprints202009.0020.v1 Article Sustainable synthesis of omega-3 fatty acid ethyl esters from monkfish liver oil Johanna Aguilera-Oviedo 1,2, Edinson Yara-Varón 1,2, Mercè Torres 2,3, Ramon Canela-Garayoa 1,2,*and Mercè Balcells 1,2 1 Department of Chemistry, University of Lleida, Avda. Alcalde Rovira Roure 191, 25198 Lleida, Spain; [email protected] (J.A.-O.); [email protected] (E.Y.-V.); [email protected] (M.B.) 2 Centre for Biotechnological and Agrofood Developments (Centre DBA), University of Lleida, Avda. Alcalde Rovira Roure 191, 25198 Lleida, Spain; [email protected] 3 Department of Food Technology, University of Lleida, Avda. Alcalde Rovira Roure 191, 25198 Lleida, Spain. * Correspondence: [email protected];Tel.: (+34-973702841) Received: date; Accepted: date; Published: date Abstract: The search for economical and sustainable sources of PUFAs within the framework of the circular economy is encouraged by their proven beneficial effects on health. The extraction of monkfish liver oil (MLO) for the synthesis of omega-3 ethyl esters was performed evaluating two blending systems and four green solvents. Moreover, the potential solubility of the MLO in green solvents was studied using the predictive simulation software COSMO-RS. The production of the ethyl esters was performed by one or two step reactions. Novozym 435, two resting cells (Aspergillus flavus and Rhizopus oryzae) obtained in our laboratory and mix of them were used as biocatalysts in a solvent-free system. The yields for Novozym 435, R. -
Altered Xanthophyll Compositions Adversely Affect Chlorophyll Accumulation and Nonphotochemical Quenching in Arabidopsis Mutants
Proc. Natl. Acad. Sci. USA Vol. 95, pp. 13324–13329, October 1998 Plant Biology Altered xanthophyll compositions adversely affect chlorophyll accumulation and nonphotochemical quenching in Arabidopsis mutants BARRY J. POGSON*, KRISHNA K. NIYOGI†,OLLE BJO¨RKMAN‡, AND DEAN DELLAPENNA§¶ *Department of Plant Biology, Arizona State University, Tempe, AZ 85287-1601; †Department of Plant and Microbial Biology, University of California, Berkeley, CA 94720-3102; ‡Department of Plant Biology, Carnegie Institution of Washington, Stanford, CA 94305-4101; and §Department of Biochemistry, University of Nevada, Reno, NV 89557-0014 Contributed by Olle Bjo¨rkman, September 4, 1998 ABSTRACT Collectively, the xanthophyll class of carote- thin, are enriched in the LHCs, where they contribute to noids perform a variety of critical roles in light harvesting assembly, light harvesting, and photoprotection (2–8). antenna assembly and function. The xanthophyll composition A summary of the carotenoid biosynthetic pathway of higher of higher plant photosystems (lutein, violaxanthin, and neox- plants and relevant chemical structures is shown in Fig. 1. anthin) is remarkably conserved, suggesting important func- Lycopene is cyclized twice by the enzyme lycopene b-cyclase tional roles for each. We have taken a molecular genetic to form b-carotene. The two beta rings of b-carotene are approach in Arabidopsis toward defining the respective roles of subjected to identical hydroxylation reactions to yield zeaxan- individual xanthophylls in vivo by using a series of mutant thin, which in turn is epoxidated once to form antheraxanthin lines that selectively eliminate and substitute a range of and twice to form violaxanthin. Neoxanthin is derived from xanthophylls. The mutations, lut1 and lut2 (lut 5 lutein violaxanthin by an additional rearrangement (9). -
Identification of Distinct Ph- and Zeaxanthin-Dependent Quenching
RESEARCH ARTICLE Identification of distinct pH- and zeaxanthin-dependent quenching in LHCSR3 from Chlamydomonas reinhardtii Julianne M Troiano1†, Federico Perozeni2†, Raymundo Moya1, Luca Zuliani2, Kwangyrul Baek3, EonSeon Jin3, Stefano Cazzaniga2, Matteo Ballottari2*, Gabriela S Schlau-Cohen1* 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, United States; 2Department of Biotechnology, University of Verona, Verona, Italy; 3Department of Life Science, Hanyang University, Seoul, Republic of Korea Abstract Under high light, oxygenic photosynthetic organisms avoid photodamage by thermally dissipating absorbed energy, which is called nonphotochemical quenching. In green algae, a chlorophyll and carotenoid-binding protein, light-harvesting complex stress-related (LHCSR3), detects excess energy via a pH drop and serves as a quenching site. Using a combined in vivo and in vitro approach, we investigated quenching within LHCSR3 from Chlamydomonas reinhardtii. In vitro two distinct quenching processes, individually controlled by pH and zeaxanthin, were identified within LHCSR3. The pH-dependent quenching was removed within a mutant LHCSR3 that lacks the residues that are protonated to sense the pH drop. Observation of quenching in zeaxanthin-enriched LHCSR3 even at neutral pH demonstrated zeaxanthin-dependent quenching, which also occurs in other light-harvesting complexes. Either pH- or zeaxanthin-dependent quenching prevented the formation of damaging reactive oxygen species, and thus the two *For correspondence: quenching processes may together provide different induction and recovery kinetics for [email protected] (MB); photoprotection in a changing environment. [email protected] (GSS-C) †These authors contributed equally to this work Competing interests: The Introduction authors declare that no Sunlight is the essential source of energy for most photosynthetic organisms, yet sunlight in excess competing interests exist. -
Fatty Acid Composition of Oil from Adapted Elite Corn Breeding Materials Francie G
Food Science and Human Nutrition Publications Food Science and Human Nutrition 9-1995 Fatty Acid Composition of Oil from Adapted Elite Corn Breeding Materials Francie G. Dunlap Iowa State University Pamela J. White Iowa State University, [email protected] Linda M. Pollak United States Department of Agriculture Thomas J. Brumm MBS Incorporated, [email protected] Follow this and additional works at: http://lib.dr.iastate.edu/fshn_hs_pubs Part of the Agronomy and Crop Sciences Commons, Bioresource and Agricultural Engineering Commons, Food Science Commons, and the Nutrition Commons The ompc lete bibliographic information for this item can be found at http://lib.dr.iastate.edu/ fshn_hs_pubs/2. For information on how to cite this item, please visit http://lib.dr.iastate.edu/ howtocite.html. This Article is brought to you for free and open access by the Food Science and Human Nutrition at Iowa State University Digital Repository. It has been accepted for inclusion in Food Science and Human Nutrition Publications by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. Fatty Acid Composition of Oil from Adapted Elite Corn Breeding Materials Abstract The fatty acid composition of corn oil can be altered to meet consumer demands for “healthful” fats (i.e., lower saturates and higher monounsaturates). To this end, a survey of 418 corn hybrids and 98 corn inbreds grown in Iowa was done to determine the fatty acid composition of readily-available, adapted, elite corn breeding materials. These materials are those used in commercial hybrid production. Eighty-seven hybrids grown in France (18 of which also were grown in lowa) were analyzed to determine environmental influence on fatty acid content. -
Identification of 1 Distinct Ph- and Zeaxanthin-Dependent Quenching in LHCSR3 from Chlamydomonas Reinhardtii
Identification of 1 distinct pH- and zeaxanthin-dependent quenching in LHCSR3 from chlamydomonas reinhardtii The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Citation Troiano, Julianne M. et al. “Identification of 1 distinct pH- and zeaxanthin-dependent quenching in LHCSR3 from chlamydomonas reinhardtii.” eLife, 10 (January 2021): e60383 © 2021 The Author(s) As Published 10.7554/eLife.60383 Publisher eLife Sciences Publications, Ltd Version Final published version Citable link https://hdl.handle.net/1721.1/130449 Terms of Use Creative Commons Attribution 4.0 International license Detailed Terms https://creativecommons.org/licenses/by/4.0/ RESEARCH ARTICLE Identification of distinct pH- and zeaxanthin-dependent quenching in LHCSR3 from Chlamydomonas reinhardtii Julianne M Troiano1†, Federico Perozeni2†, Raymundo Moya1, Luca Zuliani2, Kwangyrul Baek3, EonSeon Jin3, Stefano Cazzaniga2, Matteo Ballottari2*, Gabriela S Schlau-Cohen1* 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, United States; 2Department of Biotechnology, University of Verona, Verona, Italy; 3Department of Life Science, Hanyang University, Seoul, Republic of Korea Abstract Under high light, oxygenic photosynthetic organisms avoid photodamage by thermally dissipating absorbed energy, which is called nonphotochemical quenching. In green algae, a chlorophyll and carotenoid-binding protein, light-harvesting complex stress-related (LHCSR3), detects excess energy via a pH drop and serves as a quenching site. Using a combined in vivo and in vitro approach, we investigated quenching within LHCSR3 from Chlamydomonas reinhardtii. In vitro two distinct quenching processes, individually controlled by pH and zeaxanthin, were identified within LHCSR3. The pH-dependent quenching was removed within a mutant LHCSR3 that lacks the residues that are protonated to sense the pH drop. -
The Occurrence of Very Long-Chain Fatty Acids in Oils from Wild Plant Species Originated from Kivu, Democratic Republic of the Congo
JOURNAL OF ADVANCEMENT IN MEDICAL AND LIFE SCIENCES Journal homepage: http://scienceq.org/Journals/JALS.php Research Article Open Access The Occurrence of Very Long-Chain fatty acids in oils from Wild Plant species Originated from Kivu, Democratic Republic of the Congo M. Kazadi1, P.T. Mpiana2*, M.T. Bokota3, KN Ngbolua2, S. Baswira4 and P. Van Damme5 1Dapartement de Biologie, Centre de Recherches en Sciences Naturelles, Lwiro, Sud Kivu, D.R.Congo 2 Faculté des Sciences B.P. 190, Université de Kinshasa, Kinshasa XI, D.R. Congo 3Faculté des Sciences, Université de Kisangani, Kisangani, D.R. Congo 4Department de Chimie, Institut Supérieur Pédagogique de Bukavu, D.R. Congo 5Department of Plant Production, Tropical & Subtropical Agriculture & Ethno-botany, Gent University, Belgium. *Corresponding author: P.T. Mpiana, Contact no: +243818116019, E-mail: [email protected] Received: September 8, 2014, Accepted: October 28, 2014, Published: October 29, 2014. ABSTRACT Fatty acids C20-C26 are important for use in oleo-chemical industry whereas they also allow assessing chemotaxonomic relationships among plant taxa. There are however, comparatively few common vegetable fats which contain them in appreciable amounts.Using gas chromatography this type of very long-chain fatty acids was analyzed in oils from Pentaclethra macrophylla (Fabaceae), Millettia dura (Fabaceae), Tephrosia vogelii (Fabaceae),Cardiospermum halicacabum (Sapindaceae), Maesopsis eminii (Rhamnaceae), Podocarpus usambarensis (Podocarpaceae) and Myrianthus arboreus and M. holstii (Moraceae),wild plant species from Kahuzi-Biega National Park and adjacent areas in D.R. Congo. These plants are used by the local population mainly for nutrition and medical purposes.The percentage of very-long chain fatty acids in the analyzed oils ranged from 1.2 to 21.3%. -
Genetic Modification of Tomato with the Tobacco Lycopene Β-Cyclase Gene Produces High Β-Carotene and Lycopene Fruit
Z. Naturforsch. 2016; 71(9-10)c: 295–301 Louise Ralley, Wolfgang Schucha, Paul D. Fraser and Peter M. Bramley* Genetic modification of tomato with the tobacco lycopene β-cyclase gene produces high β-carotene and lycopene fruit DOI 10.1515/znc-2016-0102 and alleviation of vitamin A deficiency by β-carotene, Received May 18, 2016; revised July 4, 2016; accepted July 6, 2016 which is pro-vitamin A [4]. Deficiency of vitamin A causes xerophthalmia, blindness and premature death, espe- Abstract: Transgenic Solanum lycopersicum plants cially in children aged 1–4 [5]. Since humans cannot expressing an additional copy of the lycopene β-cyclase synthesise carotenoids de novo, these health-promoting gene (LCYB) from Nicotiana tabacum, under the control compounds must be taken in sufficient quantities in the of the Arabidopsis polyubiquitin promoter (UBQ3), have diet. Consequently, increasing their levels in fruit and been generated. Expression of LCYB was increased some vegetables is beneficial to health. Tomato products are 10-fold in ripening fruit compared to vegetative tissues. the most common source of dietary lycopene. Although The ripe fruit showed an orange pigmentation, due to ripe tomato fruit contains β-carotene, the amount is rela- increased levels (up to 5-fold) of β-carotene, with negli- tively low [1]. Therefore, approaches to elevate β-carotene gible changes to other carotenoids, including lycopene. levels, with no reduction in lycopene, are a goal of Phenotypic changes in carotenoids were found in vegeta- plant breeders. One strategy that has been employed to tive tissues, but levels of biosynthetically related isopre- increase levels of health promoting carotenoids in fruits noids such as tocopherols, ubiquinone and plastoquinone and vegetables for human and animal consumption is were barely altered. -
Fatty Acid Composition of Cosmetic Argan Oil: Provenience and Authenticity Criteria
molecules Article Fatty Acid Composition of Cosmetic Argan Oil: Provenience and Authenticity Criteria Milena BuˇcarMiklavˇciˇc 1, Fouad Taous 2, Vasilij Valenˇciˇc 1, Tibari Elghali 2 , Maja Podgornik 1, Lidija Strojnik 3 and Nives Ogrinc 3,* 1 Science and Research Centre Koper, Institute for Olive Culture, 6000 Koper, Slovenia; [email protected] (M.B.M.); [email protected] (V.V.); [email protected] (M.P.) 2 Centre National De L’énergie, Des Sciences Et Techniques Nucleaires, Rabat 10001, Morocco; [email protected] (F.T.); [email protected] (T.E.) 3 Department of Environmental Sciences, Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia; [email protected] * Correspondence: [email protected]; Tel.: +386-1588-5387 Academic Editor: George Kokotos Received: 17 July 2020; Accepted: 3 September 2020; Published: 7 September 2020 Abstract: In this work, fatty-acid profiles, including trans fatty acids, in combination with chemometric tools, were applied as a determinant of purity (i.e., adulteration) and provenance (i.e., geographical origin) of cosmetic grade argan oil collected from different regions of Morocco in 2017. The fatty acid profiles obtained by gas chromatography (GC) showed that oleic acid (C18:1) is the most abundant fatty acid, followed by linoleic acid (C18:2) and palmitic acid (C16:0). The content of trans-oleic and trans-linoleic isomers was between 0.02% and 0.03%, while trans-linolenic isomers were between 0.06% and 0.09%. Discriminant analysis (DA) and orthogonal projection to latent structure—discriminant analysis (OPLS-DA) were performed to discriminate between argan oils from Essaouira, Taroudant, Tiznit, Chtouka-Aït Baha and Sidi Ifni. -
(12) United States Patent (10) Patent No.: US 9,023,626 B2 Dubois (45) Date of Patent: May 5, 2015
USOO9023626B2 (12) United States Patent (10) Patent No.: US 9,023,626 B2 Dubois (45) Date of Patent: May 5, 2015 (54) METHODS FOR THE SYNTHESIS OF FATTY FOREIGN PATENT DOCUMENTS DACDS BY THE METATHESIS OF UNSATURATED DACDS OBTANED BY GB 2043052 10, 1980 FERMENTATION OF NATURAL FATTY OTHER PUBLICATIONS ACDS Eschenfeldt, W. H. et al., Transformation of Fatty Acids Catalyzed by Cytochrome P450 Monooxygenase Enzymes of Candida (75) Inventor: Jean-Luc Dubois, Millery (FR) tropicalis, Applied and Environmental Microbiology, Oct. 2003, pp. 5992-5999. (73) Assignee: Arkema France, Colombes (FR) Schaverien, C.J., et al., A Well-Characterized Highly Active Lewis Acid Free Olefin Metathesis Catalyst, J. Am. Chem. Soc., 1986, 108, (*) Notice: Subject to any disclaimer, the term of this pp. 2771-2773. patent is extended or adjusted under 35 Couturier, J.-L. et al., A Cyclometalated Arloxy(chloro) U.S.C. 154(b) by 667 days. neopentylidene-tungsten Complex: A Highly Active and Steroselec tive Catalyst for the Metathesis of cis- and trans-2-Pentene, Norborene, 1-Methyl-norborene, and Ethyl Pleate, Angew. Chem. (21) Appl. No.: 12/678,366 Int. Ed. Engl., 31. No. 5, 1992, pp. 628-631. Schwab, P. et al., A Seris of Well-Defined Metathesis Catalysts (22) PCT Filed: Sep. 17, 2008 Synthesis of RuCl2(=CHR)(PR3)2 and Its Reactions, Angew. Chem. Int. Ed. Engl., 34, No. 18, 1995, pp. 2039-2041. (86). PCT No.: PCT/FR2008/OS 1664 Scholl, M. et al., Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3- S371 (c)(1), Dimestyl-4,5-dihydroimidazol-2-ylidene Lignads, Organic Letters, (2), (4) Date: Mar. -
Pigment Palette by Dr
Tree Leaf Color Series WSFNR08-34 Sept. 2008 Pigment Palette by Dr. Kim D. Coder, Warnell School of Forestry & Natural Resources, University of Georgia Autumn tree colors grace our landscapes. The palette of potential colors is as diverse as the natural world. The climate-induced senescence process that trees use to pass into their Winter rest period can present many colors to the eye. The colored pigments produced by trees can be generally divided into the green drapes of tree life, bright oil paints, subtle water colors, and sullen earth tones. Unveiling Overpowering greens of summer foliage come from chlorophyll pigments. Green colors can hide and dilute other colors. As chlorophyll contents decline in fall, other pigments are revealed or produced in tree leaves. As different pigments are fading, being produced, or changing inside leaves, a host of dynamic color changes result. Taken altogether, the various coloring agents can yield an almost infinite combination of leaf colors. The primary colorants of fall tree leaves are carotenoid and flavonoid pigments mixed over a variable brown background. There are many tree colors. The bright, long lasting oil paints-like colors are carotene pigments produc- ing intense red, orange, and yellow. A chemical associate of the carotenes are xanthophylls which produce yellow and tan colors. The short-lived, highly variable watercolor-like colors are anthocyanin pigments produc- ing soft red, pink, purple and blue. Tannins are common water soluble colorants that produce medium and dark browns. The base color of tree leaf components are light brown. In some tree leaves there are pale cream colors and blueing agents which impact color expression. -
Technical Paper Quantitation of Carotenoids in Raw and Processed
Food Sci. Technol. Res., ++ (+), +-ῌ+2, ,**/ Technical paper Quantitation of Carotenoids in Raw and Processed Fruits in Japan +ῌ + + + + Masamichi YANO , Masaya KATO , Yoshinori IKOMA , Akemi KAWASAKI , Yoshino FUKAZAWA , + + , - . Minoru SUGIURA , Hikaru MATSUMOTO , Yumiko OOHARA , Akihiko NAGAO and Kazunori OGAWA + Department of Citrus Research Okitsu, National Institute of Fruit Tree Science, .2/ῌ0 Okitsunakacho, Shimizu-ku, Shizuoka-shi, Shizuoka .,.ῌ*,3,, Japan , Saga Prefectural Fruit Tree Research Station, 3+ Teraura, Ogi-cho, Ogi-gun, Saga 2./ῌ**.+, Japan - National Food Research Institute, ,ῌ+ῌ+, Kannondai, Tsukuba-shi, Ibaraki -*/ῌ20.,, Japan . Okinawa Subtropical Station, Japan International Research Center for Agricultural Sciences, +*3+ῌ+ Maezato, Kawarabaru, Ishigaki-shi, Okinawa 3*1ῌ***,, Japan. (Present address, Department of Citrus Research Okitsu, National Institute of Fruit Tree Science, .2/ῌ0 Okitsunakacho, Shimizu-ku, Shizuoka-shi, Shizuoka .,.ῌ*,3,, Japan) Received June ,+, ,**.; Accepted October ,1, ,**. To obtain the quantitative and qualitative data available for estimating the intake of carotenoids from fruits in Japan, carotenoids were analyzed with reversed phase high-performance liquid chromatography (HPLC). Ten carotenoids were examined in 1/ raw fruits and +/ processed fruits, all of which were harvested or purchased in Japan. Phytoene was detected in /2 of 3* fruit samples; z-carotene, in /* of 3* ; lycopene, in +- of 3*; a-carotene, in +2 of 3*;lutein,in/0 of 3*; b-carotene, in 2* of 3*; b-cryptoxanthin,