Creep Deformation of Ice
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10-1 CHAPTER 10 DEFORMATION 10.1 Stress-Strain Diagrams And
EN380 Naval Materials Science and Engineering Course Notes, U.S. Naval Academy CHAPTER 10 DEFORMATION 10.1 Stress-Strain Diagrams and Material Behavior 10.2 Material Characteristics 10.3 Elastic-Plastic Response of Metals 10.4 True stress and strain measures 10.5 Yielding of a Ductile Metal under a General Stress State - Mises Yield Condition. 10.6 Maximum shear stress condition 10.7 Creep Consider the bar in figure 1 subjected to a simple tension loading F. Figure 1: Bar in Tension Engineering Stress () is the quotient of load (F) and area (A). The units of stress are normally pounds per square inch (psi). = F A where: is the stress (psi) F is the force that is loading the object (lb) A is the cross sectional area of the object (in2) When stress is applied to a material, the material will deform. Elongation is defined as the difference between loaded and unloaded length ∆푙 = L - Lo where: ∆푙 is the elongation (ft) L is the loaded length of the cable (ft) Lo is the unloaded (original) length of the cable (ft) 10-1 EN380 Naval Materials Science and Engineering Course Notes, U.S. Naval Academy Strain is the concept used to compare the elongation of a material to its original, undeformed length. Strain () is the quotient of elongation (e) and original length (L0). Engineering Strain has no units but is often given the units of in/in or ft/ft. ∆푙 휀 = 퐿 where: is the strain in the cable (ft/ft) ∆푙 is the elongation (ft) Lo is the unloaded (original) length of the cable (ft) Example Find the strain in a 75 foot cable experiencing an elongation of one inch. -
Ice Ic” Werner F
Extent and relevance of stacking disorder in “ice Ic” Werner F. Kuhsa,1, Christian Sippela,b, Andrzej Falentya, and Thomas C. Hansenb aGeoZentrumGöttingen Abteilung Kristallographie (GZG Abt. Kristallographie), Universität Göttingen, 37077 Göttingen, Germany; and bInstitut Laue-Langevin, 38000 Grenoble, France Edited by Russell J. Hemley, Carnegie Institution of Washington, Washington, DC, and approved November 15, 2012 (received for review June 16, 2012) “ ” “ ” A solid water phase commonly known as cubic ice or ice Ic is perfectly cubic ice Ic, as manifested in the diffraction pattern, in frequently encountered in various transitions between the solid, terms of stacking faults. Other authors took up the idea and liquid, and gaseous phases of the water substance. It may form, attempted to quantify the stacking disorder (7, 8). The most e.g., by water freezing or vapor deposition in the Earth’s atmo- general approach to stacking disorder so far has been proposed by sphere or in extraterrestrial environments, and plays a central role Hansen et al. (9, 10), who defined hexagonal (H) and cubic in various cryopreservation techniques; its formation is observed stacking (K) and considered interactions beyond next-nearest over a wide temperature range from about 120 K up to the melt- H-orK sequences. We shall discuss which interaction range ing point of ice. There was multiple and compelling evidence in the needs to be considered for a proper description of the various past that this phase is not truly cubic but composed of disordered forms of “ice Ic” encountered. cubic and hexagonal stacking sequences. The complexity of the König identified what he called cubic ice 70 y ago (11) by stacking disorder, however, appears to have been largely over- condensing water vapor to a cold support in the electron mi- looked in most of the literature. -
A Primer on Ice
A Primer on Ice L. Ridgway Scott University of Chicago Release 0.3 DO NOT DISTRIBUTE February 22, 2012 Contents 1 Introduction to ice 1 1.1 Lattices in R3 ....................................... 2 1.2 Crystals in R3 ....................................... 3 1.3 Comparingcrystals ............................... ..... 4 1.3.1 Quotientgraph ................................. 4 1.3.2 Radialdistributionfunction . ....... 5 1.3.3 Localgraphstructure. .... 6 2 Ice I structures 9 2.1 IceIh........................................... 9 2.2 IceIc........................................... 12 2.3 SecondviewoftheIccrystalstructure . .......... 14 2.4 AlternatingIh/Iclayeredstructures . ........... 16 3 Ice II structure 17 Draft: February 22, 2012, do not distribute i CONTENTS CONTENTS Draft: February 22, 2012, do not distribute ii Chapter 1 Introduction to ice Water forms many different crystal structures in its solid form. These provide insight into the potential structures of ice even in its liquid phase, and they can be used to calibrate pair potentials used for simulation of water [9, 14, 15]. In crowded biological environments, water may behave more like ice that bulk water. The different ice structures have different dielectric properties [16]. There are many crystal structures of ice that are topologically tetrahedral [1], that is, each water molecule makes four hydrogen bonds with other water molecules, even though the basic structure of water is trigonal [3]. Two of these crystal structures (Ih and Ic) are based on the same exact local tetrahedral structure, as shown in Figure 1.1. Thus a subtle understanding of structure is required to differentiate them. We refer to the tetrahedral structure depicted in Figure 1.1 as an exact tetrahedral structure. In this case, one water molecule is in the center of a square cube (of side length two), and it is hydrogen bonded to four water molecules at four corners of the cube. -
Arxiv:2004.08465V2 [Cond-Mat.Stat-Mech] 11 May 2020
Phase equilibrium of liquid water and hexagonal ice from enhanced sampling molecular dynamics simulations Pablo M. Piaggi1 and Roberto Car2 1)Department of Chemistry, Princeton University, Princeton, NJ 08544, USA a) 2)Department of Chemistry and Department of Physics, Princeton University, Princeton, NJ 08544, USA (Dated: 13 May 2020) We study the phase equilibrium between liquid water and ice Ih modeled by the TIP4P/Ice interatomic potential using enhanced sampling molecular dynamics simulations. Our approach is based on the calculation of ice Ih-liquid free energy differences from simulations that visit reversibly both phases. The reversible interconversion is achieved by introducing a static bias potential as a function of an order parameter. The order parameter was tailored to crystallize the hexagonal diamond structure of oxygen in ice Ih. We analyze the effect of the system size on the ice Ih-liquid free energy differences and we obtain a melting temperature of 270 K in the thermodynamic limit. This result is in agreement with estimates from thermodynamic integration (272 K) and coexistence simulations (270 K). Since the order parameter does not include information about the coordinates of the protons, the spontaneously formed solid configurations contain proton disorder as expected for ice Ih. I. INTRODUCTION ture forms in an orientation compatible with the simulation box9. The study of phase equilibria using computer simulations is of central importance to understand the behavior of a given model. However, finding the thermodynamic condition at II. CRYSTAL STRUCTURE OF ICE Ih which two or more phases coexist is particularly hard in the presence of first order phase transitions. -
Effect of Shear Rate on the Orientation and Relaxation of a Vanillic Acid Based Liquid Crystalline Polymer
polymers Article Effect of Shear Rate on the Orientation and Relaxation of a Vanillic Acid Based Liquid Crystalline Polymer Gijs W. de Kort 1, Nils Leoné 1, Eric Stellamanns 2, Dietmar Auhl 3,*, Carolus H. R. M. Wilsens 1,* ID and Sanjay Rastogi 1 1 Aachen-Maastricht Institute of Biobased Materials (AMIBM), Faculty of Science and Engineering, Maastricht University, Brightlands Chemelot Campus, 6167 RD Geleen, The Netherlands; [email protected] (G.W.d.K.); [email protected] (N.L.); [email protected] (S.R.) 2 Deutsches Elektronen-Synchrotron (DESY), Notkestr. 85, 22607 Hamburg, Germany; [email protected] 3 Technische Universität Berlin; Fachgebiet Polymertechnik/Polymerphysik, Sekr. PTK Fasanenstr. 90, 10623 Berlin, Germany * Correspondence: [email protected] (D.A.); [email protected] (C.H.R.M.W.) Received: 27 July 2018; Accepted: 17 August 2018; Published: 22 August 2018 Abstract: In this study, we report on the visco-elastic response during start-up and cessation of shear of a novel bio-based liquid crystal polymer. The ensuing morphological changes are analyzed at different length scales by in-situ polarized optical microscopy and wide-angle X-ray diffraction. Upon inception of shear, the polydomain texture is initially stretched, at larger strain break up processes become increasingly important, and eventually a steady state texture is obtained. The shear stress response showed good coherence between optical and rheo-X-ray data. The evolution of the orientation parameter coincides with the evolution of the texture: the order parameter increases as the texture stretches, drops slightly in the break up regime, and reaches a constant value in the plateau regime. -
Jökulhlaups in Skaftá: a Study of a Jökul- Hlaup from the Western Skaftá Cauldron in the Vatnajökull Ice Cap, Iceland
Jökulhlaups in Skaftá: A study of a jökul- hlaup from the Western Skaftá cauldron in the Vatnajökull ice cap, Iceland Bergur Einarsson, Veðurstofu Íslands Skýrsla VÍ 2009-006 Jökulhlaups in Skaftá: A study of jökul- hlaup from the Western Skaftá cauldron in the Vatnajökull ice cap, Iceland Bergur Einarsson Skýrsla Veðurstofa Íslands +354 522 60 00 VÍ 2009-006 Bústaðavegur 9 +354 522 60 06 ISSN 1670-8261 150 Reykjavík [email protected] Abstract Fast-rising jökulhlaups from the geothermal subglacial lakes below the Skaftá caul- drons in Vatnajökull emerge in the Skaftá river approximately every year with 45 jökulhlaups recorded since 1955. The accumulated volume of flood water was used to estimate the average rate of water accumulation in the subglacial lakes during the last decade as 6 Gl (6·106 m3) per month for the lake below the western cauldron and 9 Gl per month for the eastern caul- dron. Data on water accumulation and lake water composition in the western cauldron were used to estimate the power of the underlying geothermal area as ∼550 MW. For a jökulhlaup from the Western Skaftá cauldron in September 2006, the low- ering of the ice cover overlying the subglacial lake, the discharge in Skaftá and the temperature of the flood water close to the glacier margin were measured. The dis- charge from the subglacial lake during the jökulhlaup was calculated using a hypso- metric curve for the subglacial lake, estimated from the form of the surface cauldron after jökulhlaups. The maximum outflow from the lake during the jökulhlaup is esti- mated as 123 m3 s−1 while the maximum discharge of jökulhlaup water at the glacier terminus is estimated as 97 m3 s−1. -
Genesis and Geographical Aspects of Glaciers - Vladimir M
HYDROLOGICAL CYCLE – Vol. IV - Genesis and Geographical Aspects of Glaciers - Vladimir M. Kotlyakov GENESIS AND GEOGRAPHICAL ASPECTS OF GLACIERS Vladimir M. Kotlyakov Institute of Geography, Russian Academy of Sciences, Moscow, Russia Keywords: Chionosphere, cryosphere, equilibrium line, firn line, glacial climate, glacier, glacierization, glaciosphere, ice, seasonal snow line, snow line, snow-patch Contents 1. Introduction 2. Properties of natural ice 3. Cryosphere, glaciosphere, chionosphere 4. Snow-patches and glaciers 5. Basic boundary levels of snow and ice 6. Measures of glacierization 7. Occurrence of glaciers 8. Present-day glacierization of the Arctic Glossary Bibliography Biographical Sketch Summary There exist ten crystal variants of ice and one amorphous form in Nature, however only one form ice-1 is distributed on the Earth. Ten other ice variants steadily exist only under a certain combinations of pressure, specific volume and temperature of medium, and those are not typical for our planet. The ice density is less than that of water by 9%, and owing to this water reservoirs are never totally frozen., Thus life is sustained in them during the winter time. As a rule, ice is much cleaner than water, and specific gas-ice compounds called as crystalline hydrates are found in ice. Among the different spheres surrounding our globe there are cryosphere (sphere of the cold), glaciosphere (sphere of snow and ice) and chionosphere (that part of the troposphere where the annual amount of solid precipitation exceeds their losses). The chionosphere envelopes the Earth with a shell 3 to 5 km in thickness. In the present epoch, snow and ice cover 14.2% of the planet’s surface and more than half of the land surface. -
Engineering Viscoelasticity
ENGINEERING VISCOELASTICITY David Roylance Department of Materials Science and Engineering Massachusetts Institute of Technology Cambridge, MA 02139 October 24, 2001 1 Introduction This document is intended to outline an important aspect of the mechanical response of polymers and polymer-matrix composites: the field of linear viscoelasticity. The topics included here are aimed at providing an instructional introduction to this large and elegant subject, and should not be taken as a thorough or comprehensive treatment. The references appearing either as footnotes to the text or listed separately at the end of the notes should be consulted for more thorough coverage. Viscoelastic response is often used as a probe in polymer science, since it is sensitive to the material’s chemistry and microstructure. The concepts and techniques presented here are important for this purpose, but the principal objective of this document is to demonstrate how linear viscoelasticity can be incorporated into the general theory of mechanics of materials, so that structures containing viscoelastic components can be designed and analyzed. While not all polymers are viscoelastic to any important practical extent, and even fewer are linearly viscoelastic1, this theory provides a usable engineering approximation for many applications in polymer and composites engineering. Even in instances requiring more elaborate treatments, the linear viscoelastic theory is a useful starting point. 2 Molecular Mechanisms When subjected to an applied stress, polymers may deform by either or both of two fundamen- tally different atomistic mechanisms. The lengths and angles of the chemical bonds connecting the atoms may distort, moving the atoms to new positions of greater internal energy. -
ABSTRACT MA, XIAOLONG. Microstructures and Mechanical
ABSTRACT MA, XIAOLONG. Microstructures and Mechanical Properties of Cu and Cu-Zn Alloys. (Under the direction of Professor Yuntian Zhu and Professor Jagdish Narayan) Strength and ductility are two crucial mechanical properties of structural materials, which, unfortunately, are often mutually exclusive based on the conventional design of microstructures and their deformation physics. This is also true in most nanostructured (NS) metals and alloys although they exhibit record-high strength. However, the disappointingly inadequate ductility becomes the major roadblock to their practical utilities due to the threat of catastrophic failure in load-bearing applications. Therefore, simultaneous improvement of strength and ductility or a well-defined trade-off between these two properties, i.e. increasing either of them without significant loss of the other, in NS materials has garnered extensive efforts from the research community. A few strategies have been explored to handle this long-standing challenge with promise. In this dissertation work, two of those strategies, deformation twins and laminate/gradient structures are specified with particular interests in NS Cu and Cu-Zn alloys. The author believes the observation and the revealed underlying mechanism are fundamental and therefore shed lights on their universal application to other metallic material systems. Deformation twins have been frequently observed in ultra-fined grained (UFG) and NS face-centered cubic (FCC) metals and alloys, which is closely related to the better strengthening and strain hardening in mechanical performance. Previous findings even show that there exist an optimum grain size range within nano scale, where the deformation twins are of most frequency, i.e. most stable in pure FCC metals. -
Oversimplified Viscoelasticity
Oversimplified Viscoelasticity THE MAXWELL MODEL At time t = 0, suddenly deform to constant displacement Xo. The force F is the same in the spring and the dashpot. F = KeXe = Kv(dXv/dt) (1-20) Xe is the displacement of the spring Xv is the displacement of the dashpot Ke is the linear spring constant (ratio of force and displacement, units N/m) Kv is the linear dashpot constant (ratio of force and velocity, units Ns/m) The total displacement Xo is the sum of the two displacements (Xo is independent of time) Xo = Xe + Xv (1-21) 1 Oversimplified Viscoelasticity THE MAXWELL MODEL (p. 2) Thus: Ke(Xo − Xv) = Kv(dXv/dt) with B. C. Xv = 0 at t = 0 (1-22) (Ke/Kv)dt = dXv/(Xo − Xv) Integrate: (Ke/Kv)t = − ln(Xo − Xv) + C Apply B. C.: Xv = 0 at t = 0 means C = ln(Xo) −(Ke/Kv)t = ln[(Xo − Xv)/Xo] (Xo − Xv)/Xo = exp(−Ket/Kv) Thus: F (t) = KeXo exp(−Ket/Kv) (1-23) The force from our constant stretch experiment decays exponentially with time in the Maxwell Model. The relaxation time is λ ≡ Kv/Ke (units s) The force drops to 1/e of its initial value at the relaxation time λ. Initially the force is F (0) = KeXo, the force in the spring, but eventually the force decays to zero F (∞) = 0. 2 Oversimplified Viscoelasticity THE MAXWELL MODEL (p. 3) Constant Area A means stress σ(t) = F (t)/A σ(0) ≡ σ0 = KeXo/A Maxwell Model Stress Relaxation: σ(t) = σ0 exp(−t/λ) Figure 1: Stress Relaxation of a Maxwell Element 3 Oversimplified Viscoelasticity THE MAXWELL MODEL (p. -
Modeling the Ice VI to VII Phase Transition
Modeling the Ice VI to VII Phase Transition Dawn M. King 2009 NSF/REU PROJECT Physics Department University of Notre Dame Advisor: Dr. Kathie E. Newman July 31, 2009 Abstract Ice (solid water) is found in a number of different structures as a function of temperature and pressure. This project focuses on two forms: Ice VI (space group P 42=nmc) and Ice VII (space group Pn3m). An interesting feature of the structural phase transition from VI to VII is that both structures are \self clathrate," which means that each structure has two sublattices which interpenetrate each other but do not directly bond with each other. The goal is to understand the mechanism behind the phase transition; that is, is there a way these structures distort to become the other, or does the transition occur through the breaking of bonds followed by a migration of the water molecules to the new positions? In this project we model the transition first utilizing three dimensional visualization of each structure, then we mathematically develop a common coordinate system for the two structures. The last step will be to create a phenomenological Ising-like spin model of the system to capture the energetics of the transition. It is hoped the spin model can eventually be studied using either molecular dynamics or Monte Carlo simulations. 1 Overview of Ice The known existence of many solid states of water provides insight into the complexity of condensed matter in the universe. The familiarity of ice and the existence of many structures deem ice to be interesting in the development of techniques to understand phase transitions. -
First International Conference on Mars Polar Science and Exploration
FIRST INTERNATIONAL CONFERENCE ON MARS POLAR SCIENCE AND EXPLORATION Held at The Episcopal Conference Center at Carnp Allen, Texas Sponsored by Geological Survey of Canada International Glaciological Society Lunar and Planetary Institute National Aeronautics and Space Administration Organizers Stephen Clifford, Lunar and Planetary Institute David Fisher, Geological Survey of Canada James Rice, NASA Ames Research Center LPI Contribution No. 953 Compiled in 1998 by LUNAR AND PLANETARY INSTITUTE The Institute is operated by the Universities Space Research Association under Contract No. NASW-4574 with the National Aeronautics and Space Administration. Material in this volume may be copied without restraint for library, abstract service, education, or personal research purposes; however, republication of any paper or portion thereof requires the written permission of the authors as well as the appropriate acknowledgment of this publication. Abstracts in this volume may be cited as Author A. B. (1998) Title of abstract. In First International Conference on Mars Polar Science and Exploration, p. xx. LPI Contribution No. 953, Lunar and Planetary Institute, Houston. This report is distributed by ORDER DEPARTMENT Lunar and Planetary Institute 3600 Bay Area Boulevard Houston TX 77058-1 113 Mail order requestors will be invoiced for the cost of shipping and handling. LPI Contribution No. 953 iii Preface This volume contains abstracts that have been accepted for presentation at the First International Conference on Mars Polar Science and Exploration, October 18-22? 1998. The Scientific Organizing Committee consisted of Terrestrial Members E. Blake (Icefield Instruments), G. Clow (U.S. Geologi- cal Survey, Denver), D. Dahl-Jensen (University of Copenhagen), K. Kuivinen (University of Nebraska), J.