polymers Article Effect of Shear Rate on the Orientation and Relaxation of a Vanillic Acid Based Liquid Crystalline Polymer Gijs W. de Kort 1, Nils Leoné 1, Eric Stellamanns 2, Dietmar Auhl 3,*, Carolus H. R. M. Wilsens 1,* ID and Sanjay Rastogi 1 1 Aachen-Maastricht Institute of Biobased Materials (AMIBM), Faculty of Science and Engineering, Maastricht University, Brightlands Chemelot Campus, 6167 RD Geleen, The Netherlands;
[email protected] (G.W.d.K.);
[email protected] (N.L.);
[email protected] (S.R.) 2 Deutsches Elektronen-Synchrotron (DESY), Notkestr. 85, 22607 Hamburg, Germany;
[email protected] 3 Technische Universität Berlin; Fachgebiet Polymertechnik/Polymerphysik, Sekr. PTK Fasanenstr. 90, 10623 Berlin, Germany * Correspondence:
[email protected] (D.A.);
[email protected] (C.H.R.M.W.) Received: 27 July 2018; Accepted: 17 August 2018; Published: 22 August 2018 Abstract: In this study, we report on the visco-elastic response during start-up and cessation of shear of a novel bio-based liquid crystal polymer. The ensuing morphological changes are analyzed at different length scales by in-situ polarized optical microscopy and wide-angle X-ray diffraction. Upon inception of shear, the polydomain texture is initially stretched, at larger strain break up processes become increasingly important, and eventually a steady state texture is obtained. The shear stress response showed good coherence between optical and rheo-X-ray data. The evolution of the orientation parameter coincides with the evolution of the texture: the order parameter increases as the texture stretches, drops slightly in the break up regime, and reaches a constant value in the plateau regime.