M/s. Veer Chemie & Aromatics (P) Ltd.
LIST OF CONTENTS
S.NO DESCRIPTION Enclosures PAGE NO & Annexures Enclosures 1 Copy of EC Enclosure - 1 1-4 2 Copy of CFO Enclosure - 2 1-6 3 TSDF Membership Enclosure - 3 1-4 4 Plant Lay out Enclosure - 4 1 Annexures 1 List Of Products Annexure - I 2 2 Manufacturing Process Annexure - II 3-46 3 Water Consumption Details Annexure - III 47 4 Waste water Details Annexure - IV 48 5 Solid & Hazardous waste details Annexure - V 49 6 Stack Emission Details Annexure - VI 50-51 7 Process Emission Details Annexure -VII 52 8 List of Raw materials Annexure - VIII 53-57 9 Solvents Details Annexure - IX 58-59
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Enclosure - 1
Enclosure - 2
Enclosure - 3
Enclosure - 4
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ONfl SUNOSH9I]N M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - I
LIST OF EXISTING PRODUCTS
S. No Product Name Quantity In Quantity In Kg/Month Kg/Day 1 Niacinamide 25000.00 833.33 2 Niacin & its derivatives 25000.00 833.33 3 Isoniazid 6000.00 200.00 56000.00 1866.67
LIST OF PROPOSED PRODUCTS
S. No Product Name Quantity In Quantity In MT/Month MT/Day Group-A 1 Isonicotinic acid 325.00 10.83 2 Nicotinic acid 325.00 10.83 3 Niacinamide 325.00 10.83 Total (Sum of any one or all products 325.00 10.83 Group-B 1 Benzyl Nicotinate 50.00 1.67 2 Ethyl Isonicotinate 50.00 1.67 3 Ethyl Nicotinate 50.00 1.67 4 Hexyl Nicotinate 50.00 1.67 5 Methyl Isonicotinic acid 50.00 1.67 6 Methyl Nicotinate 50.00 1.67 7 Methyl-6-Methyl Nicotinate 50.00 1.67 8 Myristyl nicotinate 50.00 1.67 Total (Sum of any one or all products 50.00 1.67 Total Sum of (Group-A + Group-B) 375.00 12.50
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Annexure - II
Group - A
1. ISONICOTINIC ACID
Process Description
Stage-1
4-cyano pyridine is hydrolysed with Ammnoium hydroxide to yield Ammnoim salt of
Isonicotinic acid which on neutralisation with dilute sulphuric acid gives Isonicotinic
acid.
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ISONICOTINIC ACID
Route of Synthesis
Stage-1
Step-A
N N
+ NaOH + H2O + NH3 CN COONa 17.0 4-cyano-pyridine Sodium Hydroxide 18.0 Sodium Nicotinate C6H4NNaO2 C6H4N2 40.00 104.11 145.09
Step-B N N
2 2 Na2SO4 H SO + + 2 4 COOH COONa Isonicotinic acid Sodium Sulphate Sodium Nicotinate Sulphuric Acid C H NO C6H4NNaO2 98.08 6 5 2 142.04 2X145.09=290.18 2X123.11=246.22
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ISONICOTINIC ACID
Flow Chart
4-Cyanopyridine SS REACTOR Candle SS P.F Activated Carbon (HYDROLYSIS) Filter Sodium hydroxide
Dil. Sulphuric Acid SS Neutralizer
(Neutralization)
Niacin for packing Drying Centrifuging
HTDS Effluent water
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ISONICOTINIC ACID
Material Balance:
Material Balance of Isonicotinic Acid Stage-1 Batch Size: 880.0Kgs Name of the input Quantity Name of the out put Quantity in Kg in Kg 4-cyano pyridine 800.00 Isonicotinic Acid 880.00 Activated carbon 8.00 Effluent water 2826.70 Sodium hydroxide 346.00 (Water-2826.7) Sulfuric acid 424.00 Spent carbon 8.00 Water 2965.00 Inorganic solid waste 614.04 (Sodium sulphate) Process Emission 130.63 (Ammonia) Organic solid waste 83.63 Total 4543.00 Total 4543.00
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2. NICOTINIC ACID
Process Description
Stage-1
3-Cyano pyridine is hydrolysed with sodium hydroxide to yield sodium salt of nicotinate which on neutralisation with dilute sulphuric acid gives Nicotinic acid.
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NICOTINIC ACID
Route of Synthesis
Stage-1
Step-A
N N
CN + NaOH + H2O COONa 3-Cyano pyridine Sodium Hydroxide 18.0 Sodium Nicotinate C6H4N2 40.00 C6H4NNaO2 104.11 145.09
+ NH3 17.0
Step-B
N N 2 2 COONa + H2SO4 COOH + Na2SO4
Sodium Nicotinate Sulphuric Acid Nicotinic acid Sodium C6H4NNaO2 Sulphate 98.08 C6H5NO2 2X145.09=290.18 2X123.11=246.22 142.04
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NICOTINIC ACID
Flow Chart
3-Cyanopyridine SS REACTOR Candle SS P.F Activated Carbon (HYDROLYSIS) Filter Sodium hydroxide
Dil. Sulphuric Acid SS Neutralizer
(Neutralization)
Niacin for packing Drying Centrifuging
HTDS Effluent water
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NICOTINIC ACID
Material Balance:
Material Balance of Nicotinic Acid Stage-1 Batch Size: 880.0Kgs Name of the input Quantity Name of the out put Quantity in Kg in Kg 3-Cyano pyridine 800.00 Nicotinic Acid 880.00 Activated carbon 8.00 Effluent water 2835.18 Sodium hydroxide 346.00 (Water-2826.7,water from Sulphuric acid-8.48) Sulphuric acid (98%) 424.00 Spent carbon 8.00 Water 2965.00 Inorganic solid waste 614.04 (Sodium sulphate) Process Emission 130.63 (Ammonia) Organic solid waste 75.15 Total 4543.00 Total 4543.00
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3. NIACINAMIDE
Process Description:
Stage-1
3-Cyano pyridine undergoes hydrolysed with dilute sodium hydroxide to give Niacinamide
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NIACINAMIDE
Route of Synthesis:
Stage-1:
N N NH2 C + H2O CN O
3-Cyano pyridine 18.00 Niacinamide
C6H4N2 C6H6N2O 104.11 122.13
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NIACINAMIDE
Flowchart:
3-Cyanopyridine Activated Carbon SS REACTOR S.S P.F SS Candle Sodium hydroxide (HYDROLYSIS) Filter Sulphuric acid
3-Cyanopyridine SS Crystallizer
DM water Wash (Crystallization)
Niacinamide for packing Drying Centrifuging
Wash water & ML for recycle
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NIACINAMIDE
Material Balance:
Material Balance of Niacinamide Stage-1 Batch Size: 1070.00 Name of the input Quantity Name of the out put Quantity in Kg in Kg 3-Cyano pyridine 1000.00 Niacinamide 1070.00 Effluent water Recovered 961.03 Sodium hydroxide 14.00 for Recycle Sulphuric acid 17.00 (Water-954.8,Generated water-6.23) Activated carbon 2.00 Spent carbon 2.00 Water 1143.00 Inorganic Residue 24.60 (Sodium sulphate) Process Emission 14.37 (Ammonia) Niacin 104.00 Total 2176.00 Total 2176.00
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Group - B
1. BENZYL NICOTINATE
Process Description
Stage-1
Nicotinyl chloride hydrochloride reacts with benzyl alcohol in presence of Toluene and the reaction mass is neutralised with liquor ammonia to liberate Benzyl
Nicotinate
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BENZYL NICOTINATE
Route of Synthesis:
Stage-1:
Cl HO Toluene HCl + + 2 NH4OH O N
Nicotinyl chloride Hydrochloride Benzyl alcohol Ammonium hydroxide C H O 2X35.05=70.10 C6H4ClNO.HCl 7 8 178.02 108.14
O O
2H O + 2NH4Cl + 2 N
Benzyl nicotinate Ammonium chloride 2X18=36.0
C13H11NO2 2X53.49=106.98 213.23
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BENZYL NICOTINATE
Flow Chart
Nicotinyl chloride HCl Liq.Ammonia
Benzyl Alcohol Toluene Toluene for Recycle
Organic Layer SS Vacuum SS Rector GLR Distillation Vessel
Aq.Solution for Ammonium Pure Benzyl Nicotinate chloride recovery
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BENZYL NICOTINATE
Material Balance:
Material Balance of Benzyl Nicotinate Stage-1 Batch Size: 100.0 Kg’s Name of the input Quantity Name of the out put Quantity in Kg in Kg Nicotinyl chloride Benzyl Nicotinate 100.00 112.00 Hydrochloride Benzyl alcohol 68.00 Toluene Recovery 106.05 Toluene 119.00 Toluene Loss 5.95 Methanol 234.00 Methanol Recovery 215.30 Nitric acid 60% 55.00 Methanol Loss 11.70 Ammonium hydroxide 166.00 Effluent water 1043.54 (Water-840,Nitric acid-33, Water from Nitric acid-22, Water 840.00 Generated water-22.64, Ammonium hydroxide-121.9, Toluene-2,Methanol-2) Inorganic solid waste 67.30 (Ammonium chloride) Organic Solid waste 44.16 (Organic impurities-34.16,
Toluene-5,Methanol-5) Total 1594.00 Total 1594.00
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2. ETHYL ISONICOTINATE
Process Description
Stage-1
Isonicotinic acid reacts with Ethyl alcohol in presence of Sulphuric acid as a catalyst to give Ethyl Isonicotinate sulphate which one neutralisation with liquor ammonia liberates Ethyl Isonicotinate which is extraction with Toluene. Toluene is distilled out from the extract. The crude ester is subjected for vacuum distillation to give pure
Ethyl Isonicotinate.
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ETHYL ISONICOTINATE
Route of Synthesis:
Stage-1:
CH3 HO O Toluene N + H O N + C2H5OH 2 H2SO4 O O
Isonicotinic acid Ethanol Ethyl Isonicotinate 18.00 C H O C6H5NO2 2 6 C8H9NO2 46.07 123.11 151.16
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ETHYL ISONICOTINIC ACID
Flow Chart
Ethanol Liq.Ammonia Toluene for Recycle Toluene H2SO4
G.L.R (Reactor) Neutralisation Distillation Isonicotinic acid Extractor (S.S) Esterification (S.S) Vessel (S.S)
Aqueous solution for Deep Vacuum ammonium sulphate recovery Distillation Vessel
Pure Ethyl ester of Isonicotinic acid
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ETHYL ISONICOTINATE
Material Balance:
Material Balance of Ethyl Isonicotinate Stage-1 Batch Size: 450.0 Kg’s Name of the input Quantity Name of the out put Quantity in Kg in Kg Isonicotinic acid 500.00 Ethyl Isonicotinate 450.00 Ethanol 500.00 Toluene Recovery 468.00 Toluene 500.00 Toluene Loss 25.00 Sulphuric acid 700.00 Ethanol Recovery 362.85 Ammonia 238.00 Effluent water 1245.58 Water 1190.00 (Water-1190,Generated water-53.58,Toluene-2) Inorganic solid waste 923.33 (Ammonium sulphate) Isonicotinic acid Recovery 133.50 Organic Residue 19.74 (Organic impurities-14.74,
Toluene-5) Total 3628.00 Total 3628.00
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3. ETHYL NICOTINATE
Process Description
Stage-1
Nicotinic acid reacts with Ethyl alcohol in presence of Sulphuric acid as a catalyst to give Ethyl nicotinate sulphate which one neutralisation with liquor ammonia liberates
Ethyl nicotinate which is extraction with Toluene. Toluene is distilled out from the extract. The crude ester is subjected for vacuum distillation to give pure Ethyl
Nicotinate.
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ETHYL NICOTINATE
Route of Synthesis:
Stage-1:
HO C2H5O Toluene + H O + C2H5OH 2 H SO O N 2 4 O N Nicotinic acid Ethanol Ethyl Nicotinate 18.00 C H O C6H5NO2 2 6 C8H9NO2 123.11 46.07 151.16
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ETHYL NICOTINATE
Flow Chart
Nicotinic Acid Methanol H2SO4 Liq.Ammonia Toluene Toluene for recycle
G.L.R Distillation Deep Vacuum Esterification Neutralisation Extractor (S.S) Vessel Distillation Cooling Reactor (S.S)
Aqueous Solution for Packing Ammonium Sulphate recovery
Testing
Release
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ETHYL NICOTINATE
Material Balance:
Material Balance of Ethyl nicotinate Stage-1 Batch Size: 450.0 Kgs Name of the input Quantity Name of the out put Quantity in Kg in Kg Nicotinic acid 500.00 Ethyl nicotinate 450.00 Ethanol 500.00 Toluene Recovery 468.00 Toluene 500.00 Toluene Loss 25.00 Sulphuric acid 700.00 Ethanol Recovery 312.89 Ammonia 238.00 Effluent water 1265.10 Water (Water-1190,Generated 1190.00 water-73.10,Toluene-2) Inorganic solid waste 923.35 (Ammonium sulphate) Nicotinic acid Recovery 133.50 Organic Residue 50.16 (Organic impurities-45.16,
Toluene-5) Total 3628.00 Total 3628.00
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4. HEXYL NICOTINATE
Process Description
Stage-1
Nicotinyl chloride hydrochloride reacts with Hexyl alcohol in presence of Toluene and the reaction mass is neutralised with liquor ammonia to liberate Hexyl Nicotinate
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HEXYL NICOTINATE
Route of Synthesis:
Stage-1:
Cl Toluene + 2NH OH HCl HO CH3 + 4 O N Nicotinoyl chloride Hexyl alcohol Ammonium hydroxide
C6H4ClNO.HCl C6H14O 2X35.05=70.10 178.02 102.17
O
O CH3 + 2NH4Cl + 2H2O N
2X18=36.0 Hexyl Nicotinate Ammonium chloride
C12H17NO2 2X53.49=106.98 207.27
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HEXYL NICOTINATE
Flow Chart
Nicotinyl chloride HCl Liq.Ammonia
Hexyl Alcohol Toluene Toluene for Recycle
Organic Layer SS Vacuum SS Rector GLR Distillation Vessel
Aq.Solution for Ammonium Pure Hexyl Nicotinate chloride recovery
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HEXYL NICOTINATE
Material Balance:
Material Balance of Hexyl Nicotinate Stage-1 Batch Size: 100.0 Kgs Name of the input Quantity Name of the out put Quantity in Kg in Kg Nicotinyl chloride Hexyl Nicotinate 100.00 112.00 Hydrochloride Hexyl alcohol 60.00 Toluene Recovery 100.25 Nitric acid60% 115.00 Toluene Loss 5.75 Ammonium hydroxide 20% 166.00 Methanol Recovery 210.75 Toluene 115.00 Methanol Loss 11.25 Methanol 225.00 Effluent water 1073.45 Water 800.00 (Water-800,Generated water- 22.65,Nitric acid-69,water from Nitric acid-46,Water from Ammonium hyroxide-132.8, Toluene-2,Methanol-1) Inorganic Residue 50.67 (Ammonium chloride) Organic Solid waste 40.88 (Organic impurities-31.88,
Toluene-7,Methanol-2) Total 1593.00 Total 1593.00
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5. METHYL ISONICOTINIC ACID
Process Description
Stage-1:
Isonicotinic acid undergoes esterification with Methanol in presence of Sulphuric acid neutralisation with Liquor ammonia and extraction with Toluene .Toluene is distilled off to obtain crude ester which on vacuum distillation pure product is obtained
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METHYL ISONICOTINIC ACID
Route of Synthesis:
Stage-1:
H3C O HO Toluene N + H2O N + CH3OH H2SO4 O O 18.00 Isonicotinic acid Methanol Methyl Isonicotinate C7H7NO2 C6H5NO2 32.04 137.14 123.11
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METHYL ISONICOTINIC ACID
Flow Chart
Methanol Liq.Ammonia Toluene for Recycle Toluene H2SO4
G.L.R (Reactor) Neutralisation Distillation Isonicotinic acid Extractor (S.S) Esterification (S.S) Vessel (S.S)
Aqueous solution for Deep Vacuum ammonium sulphate recovery Distillation Vessel
Pure Ethyl ester of Isonicotinic acid
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METHYL ISONICOTINIC ACID
Material Balance:
Material Balance of Methyl Isonicotinic acid Stage-1 Batch Size: 450.0 Kg’s Name of the input Quantity Name of the out put Quantity in Kg in Kg Isonicotinic acid 500.00 Methyl Isonicotinic acid 450.00 Methanol 500.00 Methanol Recovery 370.25 Sulphuric acid 700.00 Methanol Loss 19.75 Ammonia 238.00 Toluene Recovery 463.00 Toluene 500.00 Toluene Loss 25.00 Water 1190.00 Isonicotinic acid Recovery 96.00 Effluent water 1252.06 (Water-1190,Generated water-59.06,Toluene-2, Methanol-1) Inorganic Solid waste 923.35 (Ammonium sulphate) Organic Residue 28.59 (Organic impurities-18.59
Methanol-4,Toluene-10) Total 3628.00 Total 3628.00
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6. METHYL NICOTINATE
Process Description
Stage-1
Nicotinic acid undergoes etherification with Methanol in presence of Sulphuric acid neutralisation with Liquor ammonia and extraction with toluene .Toluene is distilled off to obtain crude ester which on vacuum distillation pure product is obtained
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METHYL NICOTINATE
Route of Synthesis:
Stage-1:
HO H3CO Toluene + H O + CH3OH 2 H SO O N 2 4 O N 18.00 Nicotinic acid Methanol Methyl Nicotinate C H NO C6H5NO2 32.04 7 7 2 123.11 137.14
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METHYL NICOTINATE
Flow Chart
Nicotinic Acid Methanol H2SO4 Liq.Ammonia Toluene Toluene for recycle
G.L.R Distillation Deep Vacuum Esterification Neutralisation Extractor (S.S) Vessel Distillation Cooling Reactor (S.S)
Aqueous Solution for Packing Ammonium Sulphate recovery
Testing
Release
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METHYL NICOTINATE
Material Balance:
Material Balance of Methyl Nicotinate Stage-1 Batch Size: 450.0 Kgs Name of the input Quantity Name of the out put Quantity in Kg in Kg Nicotinic acid 500.00 Methyl Nicotinate 450.00 Methanol 500.00 Methanol Recovery 347.50 Sulphuric acid 700.00 Methanol Loss 18.50 Ammonia 238.00 Toluene Recovery 463.00 Toluene 500.00 Toluene Loss 25.00 Water 1190.00 Effluent water 1253.06 (Water-1190,Generated water-59.06,Toluene- 2,Methanol-2) Nicotinic acid Recovery 96.00 Inorganic Residue 923.35 (Ammonium sulphate) Organic Residue 51.59 (Organic impurities-39.59,
Toluene-10,Methanol-2) Total 3628.00 Total 3628.00
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7. METHYL-6-METHYL NICOTINATE
Process Description
Stage-1
6-methyl nicotinic acid sulphate undergoes esterification in presence of Methanol followed by neutralization in with Ammonium hydroxide and extraction with
Chloroform. Crude ester is obtained after distilled off Chloroform which on Vacuum distillation pure product is obtained.
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METHYL-6-METHYL NICOTINATE
Route of Synthesis:
Stage-1:
H3C N H2SO4 Methanol COOH + CH3OH + 2 NH4OH
6-Methyl Nicotinic acid sulfate Methanol Ammonium hydroxide 2X35.05=70.10 C7H9NO6S 32.04 235.21
H3C N
COOCH 3 + (NH4)2SO4 + 3 H2O
Methyl-6-Methyl Nicotinate Ammonium sulphate 54.00 C8H9NO2 132.14 151.16
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METHYL-6-METHYL NICOTINATE
Flow Chart
6-Methyl Nicotinic acid sulphate
Esterification Neutralisation Extraction
Purification
Packing
Pure Methyl 6-Methyl Nicotinate
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METHYL-6-METHYL NICOTINATE
Material Balance:
Material Balance of Methyl-6-Methyl Nicotinate Stage-1 Batch Size: 214.0Kg’s Name of the input Quantity Name of the out put Quantity in Kg in Kg 6-Methyl Nicotinic acid Methyl-6-Methyl Nicotinate 214.00 975.00 Sulphate in sulphuric acid Methanol 870.00 Methanol Recovery 580.20 Chloroform 975.00 Methanol Loss 30.80 Sulphuric acid 180.00 Chloroform Recovery 926.25 Ammonium hydroxide 20% 1600.00 Chloroform Loss 48.75 Water 1000.00 Effluent water 2505.84 (Water-1000,Generated water-223.84,Water from
Ammonium hydroxide- 1280,Methanol-2) Inorganic Residue 603.20 (Ammonium sulphate) Organic Residue 690.96 (Organic impurities-687.96,
Methanol-3) Total 5600.00 Total 5600.00
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8. MYRISTYL NICOTINATE
Process Description
Stage-1
Nicotinyl chloride hydrochloride reacts with Myristyl alcohol in presence of Toluene and the reaction mass is neutralised with liquor ammonia to liberate Myristyl
Nicotinate
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MYRISTYL NICOTINATE
Route of Synthesis:
Stage-1:
Cl Toluene HCl + HO CH3 + 2NH4OH O N Ammonium hydroxide Nicotinoyl chloride Hydrochloride Myristyl alcohol C H O 2X35.05=70.10 C H ClNO.HCl 14 30 6 4 214.39 178.02
O O CH3
+ 2NH4Cl + 2H2O N
Myristyl Nicotinate Ammonium chloride 2X18=36.0 2X53.49=106.98 C20H33NO2 319.48
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MYRISTYL NICOTINATE
Flow Chart
Nicotinyl chloride HCl Liq.Ammonia
Myristyl Alcohol Toluene Toluene for Recycle
Organic Layer SS Vacuum SS Rector GLR Distillation Vessel
Aq.Solution for Ammonium Pure Myristyl Nicotinate chloride recovery
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MYRISTYL NICOTINATE
Material Balance:
Material Balance of Myristyl Nicotinate Stage-1 Batch Size: 150.0 Kgs Name of the input Quantity Name of the out put Quantity in Kg in Kg Nicotinyl chloride Myristyl Nicotinate 150.00 112.00 Hydrochloride Myristyl alcohol 136.00 Toluene Recovery 108.75 Nitric acid 60% 55.00 Toluene Loss 6.25 Ammonium hydroxide20% 166.00 Methanol Recovery 227.50 Toluene 125.00 Methanol Loss 12.50 Methanol 250.00 Effluent water 1060.45 Water 850.00 (Water-850,Generated water- 22.65,Nitric acid-33,Water from Nitric acid-22,Water from Ammonium hydroxide- 132.8) Inorganic Residue 50.67 (Ammonium chloride) Organic Residue 77.88 (Organic impurities-57.88,
Toluene-10,Methanol-10) Total 1694.00 Total 1694.00
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Annexure - III
WATER CONSUMPTION DETAILS
S. No. Purpose Water Input In KLD Process & washings-50.5 +DM water 1 Regeneration-5.05 55.55 2 Boiler make up 12.00 3 Cooling tower make up 64.00 4 Domestic 5.00 5 Scrubbing system 6.00 6 Gardening 5.00 Total 147.55
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Annexure - IV
WASTE WATER DETAILS
S. No Purpose Effluent In KLD
1 Process & washings-72.31 + DM water 77.36 Regeneration-5.05 2 Boiler Blow down 2.00 3 Cooling tower Blow down 13.00 4 Domestic 4.00 5 Scrubbing system 6.00 Total 102.36
HTDS & LTDS DETAILS
S. No Purpose HTDS LTDS Effluent Disposal Method In KLD In KLD In KLD 1 Process & 22.94 54.42 77.36 HTDS Effluent sent to Washings-(72.31) ETP with MEE system. +DM water LTDS effluents treated in regeneration-(5.05) ETP-RO Rejects to MEE 2 Boiler Blow down 2.00 0.00 2.00 system and RO permeate 3 Cooling towers 13.00 0.00 13.00 to reuse, Condensate Blow down from MEE to reuse and 4 Scrubbing system 6.00 0.00 6.00 MEE residue to AFTD. 5 Domestic 0.00 4.00 4.00 Septic tank followed by Soak pit Total 43.94 58.42 102.36
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Annexure - V
SOLID WASTE DETAILS
S. No Description Quantity Method Of Disposal In Kg/Day 1 Organic Solid Waste 6306.00 Sent to Cement Industries 2 Inorganic solid waste 12257.00 Sent to TSDF 3 Spent Carbon 98.00 Sent to Cement Industries 4 ETP Sludge 200.00 Sent to TSDF 5 MEE salts 2872.00 Sent to TSDF 6 Solvent distillation Residue 204.00 Sent to Cement Industries
HAZARDOUS WASTE DETAILS
S. No Description Quantity Mode of Disposal
1 Waste Oils & Grease 1000 SPPCB Authorized Agencies for Ltrs/Annum Reprocessing/Recycling 2 Detoxified Containers 500No’s/Month After Detoxification sent back to suppliers/SPPCB Authorized Parties 3 Used Lead Acid 10No’s/Year Send back to suppliers for buyback Batteries of New Batteries
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Annexure - VI
STACK EMISSION DETAILS FOR BOILER
Particulars Units 2.0 TPH Coal fired Boiler
Type of Fuel -- Indian Coal Coal Consumption TPD 5.0 Ash Content % 47 Sulphur Content % 0.8 Nitrogen Content % 1.07 No. of Stacks No 1 Height of stack M 32 Diameter of Stack M 0.60 Temperature of Flue Gas oC 95 Velocity of Flue Gas m/s 6.5 Particulate Matter at outlet of Bag gm/sec 0.21 filter (Based on 115 mg/Nm3 at outlet) Sulphur dioxide emission gm/sec 0.46 Oxides of Nitrogen emission gm/sec 0.57
STACK EMISSIONS FOR THERMOPACK BOILER
Particulars Units 2,00,000 kcal/hr. Thermo pack Boiler Thermo pack Boiler Capacity Kcal/hr. 2,00,000 Type of Fuel -- Coal Stack Temperature Before oC 350 Air preheater Stack Temperature After Air oC 150 preheater Combination Air Temperature oC 110 Efficiency Increased By % 5.0 Stack Height m 13.56 Fuel Consumption per Day TPD 0.43
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Annexure - VI
STACK EMISSION DETAILS FOR D.G.SETS
Capacity Emission Emission Emission Stack Flue Gas Stack Flue gas In KVA of SPM in Of SO2 in of NOx dia. Temp. in Height Velocity Mg/Nm3 Mg/Nm3 in In m OC in (m) In m/sec. Mg/Nm3 125 KVA 60.0 85.0 110.0 0.30 290 10 16.10 (Existing) 62.5 KVA 26.0 13.0 17.0 0.10 80 5 3.75 (Existing) 200 KVA 65.0 110.0 135.0 0.30 220 10 18.50 (Proposed)
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Annexure - VII
PROCESS EMISSION DETAILS
S. No Name of the Gas Quantity Treatment Method In Kg/Day 1 Ammonia 3362.00 Scrubbed by using chilled water media
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Annexure - VIII
Group-A
ISONICOTINIC ACID
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 4-Isocyano pyridine 800.00 9848.53 2 Activated carbon 8.00 98.49 3 Sodium hydroxide 346.00 4259.49 4 Sulfuric acid 424.00 5219.72
NICOTINIC ACID
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 3-Cyano pyridine 800.00 9848.53 2 Activated carbon 8.00 98.49 3 Sodium hydroxide 346.00 4259.49 4 Sulfuric acid (98%) 424.00 5219.72
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NIACINAMIDE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 3-Cyano pyridine 1000.00 10124.67 2 Sodium hydroxide 14.00 141.75 3 Sulphuric acid 17.00 172.12 4 Activated carbon 2.00 20.25
Group-B
BENZYL NICOTINATE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 Nicotinyl chloride Hydrochloride 112.00 1866.67 2 Benzyl alcohol 68.00 1133.33 3 Toluene 119.00 1983.33 4 Methanol 234.00 3900.00 5 Nitric acid 60% 55.00 916.67 6 Ammonium hydroxide 166.00 2766.67
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ETHYL ISONICOTINATE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 Isonicotinic acid 500.00 1851.83 2 Ethanol 500.00 1851.83 3 Toluene 500.00 1851.83 4 Sulphuric acid 700.00 2592.57 5 Sodium hydroxide 560.00 2074.05
ETHYL NICOTINATE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 Nicotinic acid 500.00 1851.83 2 Ethanol 500.00 1851.83 3 Toluene 500.00 1851.83 4 Sulphuric acid 700.00 2592.57 5 Sodium hydroxide 560.00 2074.05
HEXYL NICOTINATE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 Nicotinyl chloride Hydrochloride 112.00 1866.67 2 Hexyl alcohol 60.00 1000.00 3 Nitric acid60% 115.00 1916.67 4 Ammonium hydroxide 20% 166.00 2766.67 5 Toluene 115.00 1916.67 7 Methanol 225.00 3750.00
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METHYL ISONICOTINIC ACID
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 Isonicotinic acid 500.00 1851.83 2 Methanol 500.00 1851.83 3 Sulphuric acid 700.00 2592.57 4 Sodium hydroxide 560.00 2074.05 5 Toluene 500.00 1851.83
METHYL NICOTINATE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 Nicotinic acid 500.00 1851.83 2 Methanol 500.00 1851.83 3 Sulphuric acid 700.00 2592.57 4 Sodium hydroxide 560.00 2074.05 5 Toluene 500.00 1851.83
METHYL-6-METHYL NICOTINATE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 6-Methyl Nicotinic acid Sulphate in 975.00 7593.30 sulphuric acid 2 Methanol 870.00 6775.56 3 Chloroform 975.00 7593.30 4 Sulphuric acid 180.00 1401.84 5 Ammonium hydroxide 20% 1600.00 12460.80
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MYRISTYL NICOTINATE
LIST OF RAW MATERIALS
S.No. Raw Material Used in Used in Kg’s/Month Kg’s/Day 1 Nicotinyl chloride Hydrochloride 112.00 1244.43 2 Myristyl alcohol 136.00 1511.10 3 Nitric acid 60% 55.00 611.11 4 Ammonium hydroxide20% 166.00 1844.43 5 Toluene 125.00 1388.88 6 Methanol 250.00 2777.75
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Solvents Details Annexure - IX
Quantity in Kgs/Day Solvent Production Solvent Solvent S. No Product Name Solvent Solvent Solvent to Kgs/Day Name to Input Recovery Loss waste Residue water
Group-A 1 Isonicotinic acid 10833.33 No 0.00 0.00 0.00 0.00 0.00 Total 0.00 0.00 0.00 0.00 0.00
2 Nicotinic acid 10833.33 No 0.00 0.00 0.00 0.00 0.00 Total 0.00 0.00 0.00 0.00 0.00
3 Niacinamide 10833.33 No 0.00 0.00 0.00 0.00 0.00 Total 0.00 0.00 0.00 0.00 0.00 Group-B 4 Benzyl Nicotinate 1666.67 Methanol 3900.00 3588.33 195.00 33.33 83.33 Toluene 1983.33 1767.50 99.17 33.33 83.33
Total 5883.33 5355.83 294.17 66.67 166.67
5 Ethyl isonicotinate 1666.67 Toluene 1851.85 1733.33 92.59 7.41 18.52 Total 1851.85 1733.33 92.59 7.41 18.52
6 Ethyl nicotinate 1666.67 Toluene 1851.85 1733.33 92.59 7.41 18.52 Total 1851.85 1733.33 92.59 7.41 18.52 Prepared By Rightsource Industrial Solutions Pvt. Ltd., Page 58
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7 Hexyl Nicotinate 1666.67 Methanol 3750.00 3512.50 187.50 16.67 33.33 Toluene 1916.67 1670.83 95.83 33.33 116.67
Total 5666.67 5183.33 283.33 50.00 150.00
8 Methyl Isonicotinic acid 1666.67 Methanol 1851.85 1371.30 73.15 3.70 14.81 Toluene 1851.83 1714.80 92.59 7.41 37.04
Total 3703.69 3086.09 165.74 11.11 51.85
9 Methyl Nicotinate 1666.67 Methanol 1851.85 1287.04 68.52 7.41 7.41 Toluene 1851.83 1714.80 92.59 7.41 37.04
Total 3703.69 3001.83 161.11 14.81 44.44
10 Methyl-6-Methyl Nicotinate 1666.67 Methanol 6775.70 4518.69 234.27 15.58 23.36 Chloroform 7593.30 7213.64 379.67 0.00 0.00
Total 14369.00 11732.33 613.93 15.58 23.36
11 Myristyl Nicotinate 1666.67 Methanol 2777.78 2527.78 138.89 0.00 111.11 Toluene 1388.88 1208.32 69.44 0.00 111.11
Total 12500.00 4166.65 3736.10 208.33 0.00 222.22
Solvents Grand Total of all 9587.04 8822.50 479.35 81.48 203.70 products
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