Pesticides in Washington State Sediments Pilot Study
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Data Report Pilot Study of Pesticides in Washington State Stream Sediments December 2018 AGR PUB 102-741 (N/12/18) Pesticides in Washington State Sediments Pilot Study This report is available on the Department of Agriculture’s website: http://agr.wa.gov/FP/Pubs/NaturalResourcesAssessmentPubs.aspx Contact Information: Lead Author: Abigail Nickelson Natural Resource Assessment Section Phone: (509) 895-9338 21 N 1st Avenue Yakima, WA 98902 [email protected] Communications Director: Hector Castro Phone: (360) 902-1815 P.O. Box 42560 Olympia, WA 98504-2560 [email protected] Any use of product or firm names in this publication is for descriptive purposes only and does not imply endorsement by the author or the Department of Agriculture. Do you need this publication in a different format? Contact the WSDA receptionist at (360) 902-1976 or TTY (800) 833-6388 1 Pesticides in Washington State Sediments Pilot Study Pilot Study of Pesticides in Washington State Stream Sediments Abigail Nickelson Natural Resources Assessment Section Washington State Department of Agriculture Olympia, Washington December 2018 2 Pesticides in Washington State Sediments Pilot Study Acknowledgements Brandi Lubliner, Washington State Department of Ecology for review and cooperative agreement coordinator Rich Sheibley and United States Geological Survey personnel for sample collection Stormwater Action Monitoring, a stormwater monitoring program, for study collaboration Manchester Environmental Laboratory for sample analysis King County Environmental Laboratory for sample analysis Yakama Nation: Elizabeth Sanchey, Environmental Management Program Manager for sampling assistance and technical expertise The Washington State Department of Agriculture, Natural Resources Assessment Section staff including; Matthew Bischof, Joel Demory, George Tuttle, and Margaret Drennan for internal peer-review of this data report. Brian Scott, Jaclyn Hancock and Katie Hurlburt for sampling assistance. Kelly McLain for internal peer review and cooperative agreement coordination. 3 Pesticides in Washington State Sediments Pilot Study Table of Contents Acknowledgements ......................................................................................................................... 3 Table of Contents ............................................................................................................................ 4 List of Figures ................................................................................................................................. 6 List of Tables .................................................................................................................................. 6 Executive Summary ........................................................................................................................ 7 Introduction ..................................................................................................................................... 8 Study Area .................................................................................................................................... 10 WSDA Sites ...............................................................................................................................10 Lower Bertrand Creek.............................................................................................................11 Upper Big Ditch ......................................................................................................................11 Thornton Creek .......................................................................................................................11 Marion Drain ...........................................................................................................................11 Brender Creek .........................................................................................................................11 SAM Sites ...................................................................................................................................12 Study Methodology ....................................................................................................................... 13 Study Design ..............................................................................................................................13 Field Procedures .........................................................................................................................13 Laboratory Analysis ...................................................................................................................14 Data Quality ...............................................................................................................................14 Data Quality Measures ............................................................................................................14 Reporting Methods..................................................................................................................15 Data Analysis ..........................................................................................................................15 Toxic Unit and Analysis .............................................................................................................15 Assessment Criteria and Washington State Sediment Standards ...............................................16 Assessment Criteria in Sediments ...........................................................................................16 Washington State Sediment Management Standards .............................................................18 Results ........................................................................................................................................... 19 Quality Assurance & Quality Control (QA/QC) ........................................................................19 Sediment Pesticide Concentration Results .................................................................................19 Detection Summary ................................................................................................................19 4 Pesticides in Washington State Sediments Pilot Study Comparison to Washington State Sediment Management Standards .....................................20 Comparison to Assessment Criteria ........................................................................................20 Comparison to water detections ..............................................................................................23 Conclusion and Recommendations ............................................................................................... 26 References ..................................................................................................................................... 28 Appendices .................................................................................................................................... 30 Appendix A: Supplemental Information ....................................................................................30 Site List ...................................................................................................................................30 Results Data ............................................................................................................................39 Appendix B: Glossary, Acronyms, Abbreviations ....................................................................... 41 Glossary ..................................................................................................................................41 Acronyms and Abbreviations .................................................................................................43 Units of Measure .....................................................................................................................44 Appendix C: Laboratory Data Quality .......................................................................................... 45 Lower Practical Quantitation Limits ..........................................................................................49 Quality Assurance and Quality Control Samples .......................................................................53 Quality Assurance Samples ....................................................................................................53 Quality Control Samples .........................................................................................................62 5 Pesticides in Washington State Sediments Pilot Study List of Figures Figure 1 Map of Washington State subbasins containing one or more sediment sampling sites . 10 Figure 2 Map of samples with calculated ∑TU or TU values >0.1 ............................................... 23 List of Tables Table 1: Analytical methods summary ......................................................................................... 14 Table 2: Assessment criteria ......................................................................................................... 17 Table 3: WA State Sediment Management Standards .................................................................. 18 Table 4: Detection summary ......................................................................................................... 20 Table 5: SMS criteria exceedances 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