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Supplementary Bibliography of Kinetic Data on Gas Phase Reactions of Nitrogen, Oxygen, and Nitrogen Oxides (1972 - 1973)

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Supplementary Bibliography of Kinetic Data on Gas Phase Reactions of Nitrogen, Oxygen, and Nitrogen Oxides (1972 - 1973) REFERENCE REFERENCE NAT'L INST. OF STAND & TECH Z NBS SPECIAL PUBLICATION 371 AlllDb 3bQSM7 NBS Publi- cations U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards Supplementari Bibliography of Kinetic Dati» on Gas Phase Reactions oi Nitrogen, Oxygen, Nitrogen Oxidei : NATIONAL BUREAU OF STANDARDS The National Bureau of Standards' was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute for Applied Technology, the Institute for Computer Sciences and Technology, and the Office for Information Programs. THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consistent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essential services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry, and commerce. The Institute consists of a Center for Radiation Research, an Office of Meas- urement Services and the following divisions: Applied Mathematics — Electricity — Mechanics — Heat — Optical Physics — Nuclear Sciences - — Applied Radiation " — Quantum Electronics — Electromagnetics " — Time " and Frequency — Laboratory Astrophysics " — Cryogenics ". THE INSTITUTE FOR MATERIALS RESEARCH conducts materials research leading to improved methods of measurement, standards, and data on the properties of well-characterized materials needed by industry, commerce, educational institutions, and Government; provides advisory and research services to other Government agencies; and develops, produces, and distributes standard reference materials. The Institute consists of the Office of Standard Reference Materials and the following divisions: Analytical Chemistry — Polymers — Metallurgy — Inorganic Materials — Reactor Radiation — Physical Chemistry. THE INSTITUTE FOR APPLIED TECHNOLOGY provides technical services to promote the use of available technology and to facilitate technological innovation in industry and Government; cooperates with public and private organizations leading to the development of technological standards (including mandatory safety standards), codes and methods of test; and provides technical advice and services to Government agencies upon request. The Institute consists of a Center for Building Technology and the following divisions and offices: Engineering and Product Standards — Weights and Measures — Invention and Innova- tion — Product Evaluation Technology — Electronic Technology — Technical Analysis — Measurement Engineering — Structures, Materials, and Life Safety * — Building Environment* —• Technical Evaluation and Application* — Fire Technology. THE INSTITUTE FOR COMPUTER SCIENCES AND TECHNOLOGY conducts research and provides technical services designed to aid Government agencies in improving cost effec- tiveness in the conduct of their programs through the selection, acquisition, and effective utilization of automatic data processing equipment; and serves as the principal focus within the executive branch for the development of Federal standards for automatic data processing equipment, techniques, and computer languages. The Institute consists of the following divisions Computer Services — Systems and Software — Computer Systems Engineering — Informa- tion Technology. THE OFFICE FOR INFORMATION PROGRAMS promotes optimum dissemination and accessibility of scientific information generated within NBS and other agencies of the Federal Government; promotes the development of the National Standard Reference Data System and a system of information analysis centers dealing with the broader aspects of the National Measurement System; provides appropriate services to ensure that the NBS staff has optimum accessibility to the scientific information of the world. The Office consists of the following organizational units: Office of Standard Reference Data — Office of Information Activities — Office of Technical Publications — Library — Office of International Relations. ^ Headquarters and Laboratories at Gaithersburg, Maryland, unless otherwise noted; mailing address Washington, D.C. 20234. ' Part of the Center for Radiation Research. > Located at Boulder, Colorado 80302. * Part of the Center for Building Technology. BUREAU Of STAfMRDS jUN 1 3 1975 ^cjoo Supplementaiy Bibliography of Kinetic aj' 1 Data on Gas Pliase Reactions of Nitrogen, Oxygen, and Nitrogen Oxides (1972-1973) Francis Westley Chemical Kinetics Information Center Institute for Materials Research U'- National Bureau of Standards Washington, D.C. 20234 i This work was supported by the NBS Office of Standard Reference Data and The Naval Ordnance Systems Command Department of the Navy Washington, D.C. 20360 5^ / U.S. DEPARTMENT OF COMMERCE, Rogers C.B. Morton. Secretary NATIONAL BUREAU OF STANDARDS, Richard W. Roberts, D;rec/or Issued June 1975 Library of Congress Catalog Card Number: 726-00272 National Bureau of Standards Special Publication 371-1 Nat. Bur. Stand. (U.S.), Spec. Publ. 371-1, 88 pages (June 1975) CODEN: XNBSAV For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 (Order by SD Catalog No. C13.10 :371-I) . Price $1.4J cents (Add 25 percent additional for other than U.S. mailing). TABLE OF CONTENTS Introduction • l Guidelines for the user 2 Journal and report codens 6 Part I. Reactions Involving N (and O) species 11 N» -> N + hv 11 N + M -> N» + M 11 N + M* -> N» + M... 11 M» + M -> N + M 11 N + N -> N2» 11 N + N + M -> Ng + M * 11 N + N + M -> N^ + M* 11 N + N + M -> N^* + M 11 N + N + M -> Ng* + M* 12 N + N + M->N2 + M + hv 12 N + -> N + N2 (exchange) 12 N + -> Ng + NO 12 N* N^o -> N2 + NO 12 N + NO -> Ng + 0 12 N + NO -> N^ + 0* 12 N + NO -> Ng* + 0 12 N» + NO -> Ng + 0 12 NO M N + + -> N^o + M 12 N + 0 -> NO + hv 12 N + 0 + M -> NO + M 12 N + 0 + M -> NO + M* 12 N + 0 + M -> NO* + M 13 N + Og -> NO •»• 0 13 N + Og -> NO* + 0 13 ^ * °2* -> NO + 0 ' 13 O2 + "> + ° 13 iii N2 -> N + N 13 \* -> N2 + hv 13 Ng** -> N2» + hv 13 + M -> N + N + M \ + M» -> N + N + M 14 -> Ng* + M N + N + M , 14 ^2 + M -> N2* * M (electronic excitation) 14 + M -> + M (vibrational excitation) , 14 ^2 + M* -> N2» + M (electronic energy transfer) 15 ^2 + M* -> N2'^ + M (electronlc-vlbrational energy transfer) 15 -> + M''' + M (viljratlonal energy transfer) 15 "2 + M** -> N2'^ + M* (electronlc-vlbrational energy transfer) 16 \* M -> N2 •» M (electronic relaxation) 15 ^2* •*- M -> N2 + M (rotational relaxation) 16 ^2* + M -> N2 + M (trans la tlonal relaxation) 16 N^^ + M -> + M (vibrational relaxation) 16 ^2* + M -> N2 + M* (electronic energy transfer) 17 Ng* + M -> N2 + M'^ (electronlc-vlbrational energy transfer) 17 ^2^^ M -> + + M* (vlbrational-electronlc energy transfer) ..».• 13 + M -> N2 + M''' (vibrational energy transfer) • ig \* + M -> N2»* + M (electronic transition) 19 ^2* + M* -> N2 + M** (electronic energy transfer) 19 Ng** + M -> N2» + M (electronic transition) 19 N^** + M -> N2''' + (electronlc-vlbrational energy transfer) 19 ^2** + M -> N2* + M* (vibrational energy transfer) 19 ^2* + N2* -> N2 + N2** (electronic energy transfer) • 19 ^ + 0 -> N NO 19 N2 + 0* -> NgO* 20 > 0 + M -> N2O M 20 + 0» + M -> N2O + M 20 1^2 + O2 -> NO + NO 20 N2O -> Ng + 0 20 iv -> N2 )- 0« 20 NgO* -> N2 + 0 20 N2O* "> \0 + hv 20 N2O + hv -> N2 + 0* 20 NjO + M -> I/2N2 + NO + M (overall) 20 N2O + M -> N2 + 0 + M 21 ^20 + M» -> N2 + 0 + M 21 \0 + M* -> N2 + 0* + M 21 NgO M -> N2 + I/2O2 + M (overall) 21 \o + Vi^ ~> + M (vibrational energy transfer) .rt,.,,- ........ 21 NgO* + M -> N2O + M (electronic relaxation) 21 N2O* + M -> NgO + M (rotational relaxation) . • ,, 21 NgO* + M -> NgO ¥ M ( trans lational relaxation) ^t.... 21 U + M -> + M (vibrational relaxation) 22 N^o'^ + M -> NgO + (vibrational enerj^y transfer) 22 NgO + NO -> S2 + NO2 22 -> , >. \0 + 0 N2 + Og . 22 ^*20 + 0 -> N2 + O2* 22 NgO + 0* -> N2 + O2 o., -. 22 N2O 4- 0 -> NO -f m , 22 N2O + 0» -> 110 NO 23 N2O2 -> H2 + O2 23 N2O2 -> NgO + 0 , 23 N2O2 + M3 -> N2 + NO + O2 23 ^202 + NO -> N2O + NO2 23 N2O3 + N2O5 -> 4NO2 • 23 ^204 + M -> NOg + NO2 + M (a.t low and hi^ pressure)... , r..... 23 N2O5 + M -> NO2 + MO3 + M 23 N2O5 + N2O5 -> 4NO2 + O2 (overall) * 23 NO* -> NO + hv 23 N0«* -> NO* + hv , , 23 NO + hv -> K + 0 , 24 V NO + bv ~> ro* 24 NO + M -> N + 0 + M 24 -> 0» NO + M N + + M 24 NO + M -> M* + 0 + M , 24 NO + M* -> IJO* + M (electronic enepj^y traiisfer) , 24 NO + M* -> NO=t + M (electrijQic-vibratiorjal energy transfer) 24 Jfl' -> NO + N0+ + M (vibrational energy tr>ir=sfer) , 24 NO* + M -> I© + M (electronic relaxation) 24 NO* + M -> NO + M (rotational relaxation) 25 N0+ + M -> 10 + M (vibrational relaxation) ». , 25 NO* + M -> NO + M ( trans laticnal relaxation) 25 NO* + M -> NO + H* (electronic energy transfer)..., , , 25 N0+ + M -> NO + (vibrational energy transfer)....,. 25 NO** + M -> NO* + H (electronic transition) 25 N0+^ + M -> N0=^ + (vibration-vibration resonant exchange) 25 NO + NO -> N^ + O2 (overall) 25 NO + NO* -> Ng + O2 25 NO + NO -> NgO + 0 (first
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