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William Prout
Educación Química (2015) 26(2), 162-173 educación Química www.educacionquimica.info PARA QUITARLE EL POLVO William Prout Jaime Wisniak Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, Israel Received 19 July 2014; accepted 25 September 2014 KEYWORDS Abstract William Prout (1785-1850) a multifaceted English physician, conducted important Digestion; research in the areas of physiology, meteorology, and chemistry; he studied the processes of Respiration; digestion, respiration, and blood formation, the urinary system, urine and urinary calculi, iden- Blood formation; WLÀHGWKHSUHVHQFHRI+&OLQWKHJDVWULFÁXLGDQGSURSRVHGWKHWKHRU\WKDWWKHDWRPLFZHLJKW Urinary system; of an element is an integer multiple of the atomic weight of hydrogen (Prout’s hypothesis). Urine; All Rights Reserved © 2015 Universidad Nacional Autónoma de México, Facultad de Química. This is Urinary calculi; an open access item distributed under the Creative Commons CC License BY-NC-ND 4.0. *DVWULFÁXLG Prout’s hypothesis William Prout PALABRAS CLAVE Digestión; Resumen William Prout (1785-1850), un médico inglés multifacético, realizó importantes in- Respiración; YHVWLJDFLRQHVHQODViUHDVGHPHGLFLQDÀVLRORJtDPHWHRURORJtD\TXtPLFDHVWXGLyORVSURFHVRV Formación de la de digestión, respiración y formación de la sangre, el sistema urinario, la orina y los cálculos sangre; XULQDULRVLGHQWLÀFyODSUHVHQFLDGH+&OHQHOMXJRJiVWULFR\SURSXVRODWHRUtDTXHORVSHVRV Sistema urinario; atómicos de los elementos eran un múltiplo entero del peso del hidrógeno (hipótesis de Prout). Orina; Derechos Reservados © 2015 Universidad Nacional Autónoma de México, Facultad de Química. Este es Cálculos; XQDUWtFXORGHDFFHVRDELHUWRGLVWULEXLGREDMRORVWpUPLQRVGHOD/LFHQFLD&UHDWLYH&RPPRQV&&%< Fluido gástrico; NC-ND 4.0. Hipótesis de Prout Life and career school at Wickwar, a neighboring market town, writing and arithmetic at a charity school in Badminton, and also helped William Prout was born on 15 January 1785 at Horton, his parents in farming. -
William Prout
Educación Química (2015) 26(2), 162-172 educación Química www.educacionquimica.info PARA QUITARLE EL POLVO William Prout Jaime Wisniak Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, Israel Received 19 July 2014; accepted 25 September 2014 KEYWORDS Abstract William Prout (1785-1850) a multifaceted English physician, conducted important Digestion; research in the areas of physiology, meteorology, and chemistry; he studied the processes of Respiration; digestion, respiration, and blood formation, the urinary system, urine and urinary calculi, iden- Blood formation; tified the presence of HCl in the gastric fluid, and proposed the theory that the atomic weight Urinary system; of an element is an integer multiple of the atomic weight of hydrogen (Prout’s hypothesis). Urine; All Rights Reserved © 2015 Universidad Nacional Autónoma de México, Facultad de Química. This is Urinary calculi; an open access item distributed under the Creative Commons CC License BY-NC-ND 4.0. Gastric fluid; Prout’s hypothesis William Prout PALABRAS CLAVE Digestión; Resumen William Prout (1785-1850), un médico inglés multifacético, realizó importantes in- Respiración; vestigaciones en las áreas de medicina, fisiología, meteorología y química; estudió los procesos Formación de la de digestión, respiración y formación de la sangre, el sistema urinario, la orina y los cálculos sangre; urinarios, identificó la presencia de HCl en el jugo gástrico y propuso la teoría que los pesos Sistema urinario; atómicos de los elementos eran un múltiplo entero del peso del hidrógeno (hipótesis de Prout). Orina; Derechos Reservados © 2015 Universidad Nacional Autónoma de México, Facultad de Química. Este es Cálculos; un artículo de acceso abierto distribuido bajo los términos de la Licencia Creative Commons CC BY- Fluido gástrico; NC-ND 4.0. -
The Riches of Uranium Uranium Is Best Known, and Feared, for Its Involvement in Nuclear Energy
in your element The riches of uranium Uranium is best known, and feared, for its involvement in nuclear energy. Marisa J. Monreal and Paula L. Diaconescu take a look at how its unique combination of properties is now increasingly attracting the attention of chemists. t is nearly impossible to find an uplifting, and can be arrested by the skin, making found about uranium’s superior catalytic funny, or otherwise endearing quote on depleted uranium (composed mainly of 238U) activity may not be an isolated event. The Iuranium — the following dark wisecrack1 safe to work with as long as it is not inhaled organometallic chemistry of uranium was reflects people’s sinister feelings about this or ingested. born during the ‘Manhattan project’ — code element: “For years uranium cost only a few Studying the fundamental chemistry of name of the development of the first nuclear dollars a ton until scientists discovered you uranium is an exotic endeavour, but those who weapon during the Second World War. This could kill people with it”. But, in the spirit of embrace it will reap its benefits. Haber and field truly began to attract interest in 1956 rebranding, it is interesting to note that the Bosch found that uranium was a better catalyst when Reynolds and Wilkinson reported the main source of Earth’s internal heat comes than iron for making ammonia2. The preparation of the first cyclopentadienyl from the radioactive decay of uranium, isolation of an η1-OCO complex derivatives6. The discovery of thorium and potassium-40 that keeps the of uranium3 also showed uranocene electrified the field outer core liquid, induces mantle convection that, even though it is as much as that of ferrocene and, subsequently, drives plate tectonics. -
Early Russian Organic Chemists and Their Legacy
SpringerBriefs in Molecular Science Early Russian Organic Chemists and Their Legacy Bearbeitet von David Lewis 1. Auflage 2012. Taschenbuch. xii, 136 S. Paperback ISBN 978 3 642 28218 8 Format (B x L): 15,5 x 23,5 cm Gewicht: 237 g Weitere Fachgebiete > Chemie, Biowissenschaften, Agrarwissenschaften > Chemie Allgemein > Geschichte der Chemie Zu Inhaltsverzeichnis schnell und portofrei erhältlich bei Die Online-Fachbuchhandlung beck-shop.de ist spezialisiert auf Fachbücher, insbesondere Recht, Steuern und Wirtschaft. Im Sortiment finden Sie alle Medien (Bücher, Zeitschriften, CDs, eBooks, etc.) aller Verlage. Ergänzt wird das Programm durch Services wie Neuerscheinungsdienst oder Zusammenstellungen von Büchern zu Sonderpreisen. Der Shop führt mehr als 8 Millionen Produkte. Chapter 2 Beginnings 2.1 Introduction At the start of the twentieth century, organic chemistry was not yet 75 years old as a separate and legitimate sub-discipline of the science. Considerable progress had been made in these first seven decades, and the stage was set for the dramatic advances in the science to come in the following century. Most practicing organic chemists are familiar with many of the great German, French and English organic chemists whose work helped the fledgling discipline grow, but few are familiar with the role that Russian organic chemists of the nineteenth and early twentieth century played in the development of the science. And this is in spite of the fact that many of the named rules and reactions that one studies in the first course in organic chemistry are, in fact, of Russian origin. It is the intent of this book to help rectify that deficiency. -
Wilhelm Ostwald – the Scientist
ARTICLE-IN-A-BOX Wilhelm Ostwald – The Scientist Friedrich Wilhelm Ostwald was born on September 2, 1853 at Riga, Latvia, Russia to Gottfried Ostwald, a master cooper and Elisabeth Leuckel. He was the second son to his parents who both were descended from German immigrants. He had his early education at Riga. His subsequent education was at the University of Dorpat (now Tartu, Estonia) where he enrolled in 1872. At the university he studied chemistry under the tutelage of Carl ErnstHeinrich Schmidt (1822– 1894) who again was a pupil of Justus von Liebig. Besides Schmidt, Johannes Lemberg (1842– 1902) and Arthur von Oettingen (1836–1920) who were his teachers in physical chemistry were also principal influences. It was in 1877 that he defended his thesis ‘Volumchemische Studien über Affinität’. Subsequently he taught as Privatdozent for a couple of years. During this period, his personal life saw some changes as well. He wedded Helene von Reyher (1854–1946) in 1880. With Helene, he had three sons, and two daughters. Amongst his children, Wolfgang went on to become a famous colloid chemist. On the strength of recommendation from Dorpat, Ostwald was appointed as a Professor at Riga Polytechnicum in 1882. He worked on multiple applications of the law of mass action. He also conducted measurements in chemical reaction kinetics as well as conductivity of solutions. To this end, the pyknometer was developed which was used to determine the density of liquids. He also had a thermostat built and both of these were named after him. He was prolific in his teaching and research which helped establish a school of science at the university. -
Project Note Weston Solutions, Inc
PROJECT NOTE WESTON SOLUTIONS, INC. To: Canadian Radium & Uranium Corp. Site File Date: June 5, 2014 W.O. No.: 20405.012.013.2222.00 From: Denise Breen, Weston Solutions, Inc. Subject: Determination of Significant Lead Concentrations in Sediment Samples References 1. New York State Department of Environmental Conservation. Technical Guidance for Screening Contaminated Sediments. March 1998. [45 pages] 2. U.S. Environmental Protection Agency (EPA) Office of Emergency Response. Establishing an Observed Release – Quick Reference Fact Sheet. Federal Register, Volume 55, No. 241. September 1995. [7 pages] 3. International Union of Pure and Applied Chemistry, Inorganic Chemistry Division Commission on Atomic Weights and Isotopic Abundances. Atomic Weights of Elements: Review 2000. 2003. [120 pages] WESTON personnel collected six sediment samples (including one environmental duplicate sample) from five locations along the surface water pathway of the Canadian Radium & Uranium Corp. (CRU) site in May 2014. The sediment samples were analyzed for Target Analyte List (TAL) Metals and Stable Lead Isotopes. 1. TAL Lead Interpretation: In order to quantify the significance for Lead, Thallium and Mercury the following was performed: 1. WESTON personnel tabulated all available TAL Metal data from the May 2014 Sediment Sampling event. 2. For each analyte of concern (Lead, Thallium, and Mercury), the highest background concentration was selected and then multiplied by three. This is the criteria to find the significance of site attributable release as per Hazard Ranking System guidelines. 3. One analytical lead result (2222-SD04) of 520 mg/kg (J) was qualified with an unknown bias. In accordance with US EPA document “Using Data to Document an Observed Release and Observed Contamination”, 2222-SD03 lead concentration was adjusted by dividing by the factor value for lead of 1.44 to equal 361 mg/kg. -
Biobibliogrāfija (1.247Mb)
LZ LATVIJAS ZINĀTNIEKI Scientific Library Rīgas Tehniskās universitātes of Riga Technical University Zinātniskā bibliotēka LZ LZ LATVIJAS LATVIJAS ZINĀTNIEKI ZINĀTNIEKI Full Member of Latvijas Latvian Academy of Zinātņu akadēmijas Sciences, Professor akadēmiķis, profesors RAIMONDS RAIMONDS VALTERS VALTERS Biobibliography Biobibliogrāfija Rīga, 2008 Rīga, 2008 UDK 016:547 Va 434 Sastādītājas Maija Neilande, Ilze Veldruma (līdz 1988. g.) Bibliogrāfiskā redaktore Larisa Levinoka © RTU Zinātniskā bibliotēka, 2008 ISBN 978-9984-538-94-5 © Latvijas Akadēmiskā bibliotēka, 2008 PRIEKŠVĀRDS Latvijas Zinātņu akadēmijas akadēmiķa Dr. habil. chem. profe- sora Raimonda Valtera biobibliogrāfijā apkopoti viņa publicēto un nepublicēto, rediģēto un recenzēto darbu, izgudrojumu autorapliecību un viņa vadībā izstrādāto disertāciju bibliogrāfiskie apraksti. Uzrādīta arī literatūra par viņa dzīvi, zinātnisko un sabiedrisko darbību laikā no 1959. gada līdz 2008. gada martam. Biobibliogrāfiju ievada īsas ziņas par R. Valteru un LZA senāta priekš sēdētāja akadēmiķa J. Stradiņa raksts “Par kolēģi Raimondu Valteru”, kā arī autobiogrāfisks apcerējums “Autora stāsts par ve cā kiem, skolotājiem, kolēģiem un sevi” latviešu un angļu valodā. Biogrāfisko daļu noslēdz R. Valtera zinātniskā darba apskats un fo to attēli kopā ar ģimenes locekļiem, kolēģiem un ievērojamiem cilvēkiem. Bibliogrāfija veidota pēc autora dotās informācijas un sastādītāju apzinātajām publikācijām. Bibliogrāfiskais materiāls grupēts sistemātiski nodaļās. Nodaļu ietvaros izmantots hronoloģiskais -
Between National and Academic Agendas Ethnic Policies and ‘National Disciplines’ at the University of Latvia, 1919–1940
BETWEEN NATIONAL AND ACADEMIC AGENDAS Ethnic Policies and ‘National Disciplines’ at the University of Latvia, 1919–1940 PER BOLIN Other titles in the same series Södertörn Studies in History Git Claesson Pipping & Tom Olsson, Dyrkan och spektakel: Selma Lagerlöfs framträdanden i offentligheten i Sverige 1909 och Finland 1912, 2010. Heiko Droste (ed.), Connecting the Baltic Area: The Swedish Postal System in the Seventeenth Century, 2011. Susanna Sjödin Lindenskoug, Manlighetens bortre gräns: tidelagsrättegångar i Livland åren 1685–1709, 2011. Anna Rosengren, Åldrandet och språket: En språkhistorisk analys av hög ålder och åldrande i Sverige cirka 1875–1975, 2011. Steffen Werther, SS-Vision und Grenzland-Realität: Vom Umgang dänischer und „volksdeutscher” Nationalsozialisten in Sønderjylland mit der „großgermanischen“ Ideologie der SS, 2012. Södertörn Academic Studies Leif Dahlberg och Hans Ruin (red.), Fenomenologi, teknik och medialitet, 2012. Samuel Edquist, I Ruriks fotspår: Om forntida svenska österledsfärder i modern historieskrivning, 2012. Jonna Bornemark (ed.), Phenomenology of Eros, 2012. Jonna Bornemark och Hans Ruin (eds), Ambiguity of the Sacred, 2012. Håkan Nilsson (ed.), Placing Art in the Public Realm, 2012. Lars Kleberg and Aleksei Semenenko (eds), Aksenov and the Environs/Aksenov i okrestnosti, 2012. BETWEEN NATIONAL AND ACADEMIC AGENDAS Ethnic Policies and ‘National Disciplines’ at the University of Latvia, 1919–1940 PER BOLIN Södertörns högskola Södertörns högskola SE-141 89 Huddinge www.sh.se/publications Cover Image, taken from Latvijas Universitāte Illūstrācijās, p. 10. Gulbis, Riga, 1929. Cover: Jonathan Robson Layout: Jonathan Robson and Per Lindblom Printed by E-print, Stockholm 2012 Södertörn Studies in History 13 ISSN 1653-2147 Södertörn Academic Studies 51 ISSN 1650-6162 ISBN 978-91-86069-52-0 Contents Foreword ...................................................................................................................................... -
RBRC-32 BNL-6835.4 PARITY ODD BUBBLES in HOT QCD D. KHARZEEV in This ~A~Er We Give a Pedawwicalintroduction~0 Recent Work Of
RBRC-32 BNL-6835.4 PARITY ODD BUBBLES IN HOT QCD D. KHARZEEV RIKEN BNL Research Center, Br$ookhauenNational Laboratory, . Upton, New York 11973-5000, USA R.D. PISARSKI Department of Physics, Brookhaven National Laboratoy, Upton, New York 11973-5000, USA M.H.G. TYTGAT Seruice de Physique Th&orique, (7P 225, Uniuersitc4Libre de Bruzelles, B[ud. du !t%iomphe, 1050 Bruxelles, Belgium We consider the topological susceptibility for an SU(N) gauge theory in the limit of a large number of colors, N + m. At nonzero temperature, the behavior of the topological susceptibility depends upon the order of the reconfining phrrse transition. The meet interesting possibility is if the reconfining transition, at T = Td, is of second order. Then we argue that Witten’s relation implies that the topological suscepti~lfity vanishes in a calculable fdion at Td. Ae noted by Witten, this implies that for sufficiently light quark messes, metaetable etates which act like regions of nonzero O — parity odd bubbles — can arise at temperatures just below Td. Experimentally, parity odd bubbles have dramatic signature% the rI’ meson, and especially the q meson, become light, and are copiously produced. Further, in parity odd bubbles, processes which are normally forbidden, such as q + rr”ro, are allowed. The most direct way to detect parity violation is by measuring a parity odd global seymmetry for charged pions, which we define. 1 Introduction In this .-~a~er we give a Pedawwicalintroduction~0 recent work of ours? We I consider an SU(IV) gau”ge t~e~ry in the limit of a large number of colors, N + co, This is, of course, a familiar limit? We use the large N expansion I to investigate the behavior of the theory at nonzero temperature, especially for the topological susceptibility. -
Platinum Group Metals Technology Gmelin Handbook of Inorganic Chemistry, 8Th Edition, Platinum, Suppl
Platinum Group Metals Technology Gmelin Handbook of Inorganic Chemistry, 8th Edition, Platinum, Suppl. Vol. A 1 EDITED BY G. J. K. ACRES AND K. SWARS, Springer-verlag, Berlin, 1986, 340 pages, ISBN 3-540-93528-2,DM 1,225 History records that in 1822 Leopold Gmelin by first considering the methods used to refine (1788-1853)~then Professor of Chemistry at the metals. It then goes on to review the various Heidelberg University made a modest contribu- purification routes and the methods of deter- tion to the advancement of the chemistry of the mining impurities. platinum metals by his discovery, in collabora- Although the electrodeposition of platinum tion with Fredrich Wohler, of the double has been practised for over 150 years, the sub- potassium cyanides of both platinum and ject still attracts considerable interest as users palladium. A more notable and lasting achieve- strive to exploit the properties of certain of the ment was, of course, the establishment in 1817 platinum group metals in the most economical of his “Handbook of Theoretical Chemistry” way. Within the 26 pages devoted to elec- which recorded and reviewed progress in that trodeposition, ruthenium, palladium, osmium, subject. Over the intervening years this process iridium and platinum have been reviewed by has continued, and although organic chemistry Ch. J. hub, of Forschungsinstitut fur is no longer included the length and importance Edelmetalle und Metallchemie, and rhodium of the publication has grown remarkably as has by F. Simon of Degussa. The properties of the task of compiling it. Now the responsibility electrodeposited rhodium, which include tar- of the Gmelin Institute for Inorganic nish resistance, good wear resistance, low con- Chemistry, one of the institutes of the Max- tact resistance, high reflectivity and attractive Planck Society for the Advancement of Science, colour, make it a most useful material for both the handbook is currently in its 8th edition. -
German Chemist Friedrich Konrad Beilstein (1838-1906) in the Citation: Sztejnberg A
Firenze University Press www.fupress.com/substantia Historical Articles The Eminent Russian – German Chemist Friedrich Konrad Beilstein (1838-1906) in the Citation: Sztejnberg A. (2021) The Emi- th st nent Russian German Chemist Frie- Literature between the 19 and 21 Centuries drich Konrad Beilstein (1838-1906) in the Literature between the 19th and 21st Centuries. Substantia 5(1): 135-156. doi: 10.36253/Substan- Aleksander Sztejnberg tia-1097 University of Opole, Oleska 48, 45-052 Opole, Poland Received: Sep 12, 2020 E-mail: [email protected] Revised: Nov 30, 2020 Abstract. Friedrich Konrad Beilstein (1838-1906) was one of the most prominent Just Accepted Online: Dec 01, 2020 chemists of the second half of the nineteenth century. His life and scientific achieve- ments were described in the literature published between the 19th and 21st centuries in Published: Mar 01, 2021 different countries. The purpose of this paper is to familiarize readers with the impor- Copyright: © 2021 Sztejnberg A. This is tant events in the life of Beilstein and his research activities, in particular with selected an open access, peer-reviewed article results of his experimental studies. The names of authors of biographical notes or biog- published by Firenze University Press raphies about Beilstein, published in 1890-2018, and literature on his correspondence (http://www.fupress.com/substantia) are given. In addition, a list of his publications is included. and distributed under the terms of the Creative Commons Attribution License, Keyword: F. K. Beilstein, Organic chemistry, Beilstein test, Handbuch der organischen which permits unrestricted use, distri- bution, and reproduction in any medi- Chemie, Russia, Germany – XIX century. -
Hexagon Fall
Redis co very of the Elements The Rare Earth s–The Beginnings I I I James L. Marshall, Beta Eta 1971 , and Virginia R. Marshall, Beta Eta 2003 , Department of Chemistry, University of North Texas, Denton, TX 76203-5070, [email protected] 1 Rare earths —introduction. The rare earths Figure 1. The “rare earths” are defined by IUPAC as the 15 lanthanides (green) and the upper two elements include the 17 chemically similar elements of the Group III family (yellow). These elements have similar chemical properties and all can exhibit the +3 occupying the f-block of the Periodic Table as oxidation state by the loss of the highest three electrons (two s electrons and either a d or an f electron, well as the Group III chemical family (Figure 1). depending upon the particular element). A few rare earths can exhibit other oxidation states as well; for These elements include the 15 lanthanides example, cerium can lose four electrons —4f15d 16s 2—to attain the Ce +4 oxidation state. (atomic numbers 57 through 71, lanthanum through lutetium), as well as scandium (atomic number 21) and yttrium (atomic number 39). The chemical similarity of the rare earths arises from a common ionic configuration of their valence electrons, as the filling f-orbitals are buried in an inner core and generally do not engage in bonding. The term “rare earths” is a misnome r—these elements are not rare (except for radioactive promethium). They were named as such because they were found in unusual minerals, and because they were difficult to separate from one another by ordinary chemical manipula - tions.