Physics of the Solid State, Vol. 46, No. 7, 2004, pp. 1183–1187. Translated from Fizika Tverdogo Tela, Vol. 46, No. 7, 2004, pp. 1153–1157. Original Russian Text Copyright © 2004 by Pleschev, Toporova, Titov, Baranov. METALS AND SUPERCONDUCTORS Structure and Physical Properties of Titanium Diselenide Intercalated with Nickel V. G. Pleschev1, N. V. Toporova1, A. N. Titov2, and N. V. Baranov1, 2 1 Ural State University, pr. Lenina 51, Yekaterinburg, 620083 Russia e-mail:
[email protected],
[email protected] 2 Institute of Metal Physics, Ural Division, Russian Academy of Sciences, ul. S. KovalevskoÏ 18, Yekaterinburg, 620219 Russia Received November 5, 2003 Abstract—The structure, electrical resistivity, thermopower, and magnetic susceptibility of titanium diselenide intercalated with nickel (NxTiSe2) are studied systematically in the nickel concentration range x = 0–0.5. In accordance with a model proposed earlier, strong hybridization of the Ni3d/Ti3d states is observed, giving rise to suppression of the magnetic moment because of delocalization of the nickel d electrons. It is shown that the strain caused by the Ni3d/Ti3d hybridization does not change the local coordination of a titanium atom. © 2004 MAIK “Nauka/Interperiodica”. 1. INTRODUCTION rial will exhibit all properties characteristic of interca- It was shown in [1, 2] that intercalation of titanium lation compounds with an impurity band lying below diselenide with transition and noble metals brings the Fermi level. However, the electrical and magnetic about the formation of an impurity band of hybridized properties of NixTiSe2 and its fine structural features M3d/Ti3d states (M is an intercalated metal). This situ- (the Ni atom position, the effect of intercalation on the ation differs radically from the well-studied case of positions of host atoms, etc.) remain poorly studied.