Dishwashing Powder Revision Date: 27/11/2014

WHIRLPOOL

Dishwashing Powder Revision date: 27/11/2014

SAFETY DATA SHEET

SECTION 1. Identification of the substance or mixture and of the company / undertaking

1.1. Product identifier Code: [DWP125] 484000008386 - [DWP129] 484000008854 - [DWP127] 484000008827 Name Powder dishwasher - Dishwashing powder

1.2. Relevant identified uses of the substance or mixture and uses advised against Description / Use powdered detergent for household dishwashers.

1.3 Details of the supplier of the safety data sheet Company CHEMICAL SRL FLACER Location Address Bellaria 31 / A District and Country 40036 Vado (Bo) Italy tel. 0516778202 fax 0515063724 e-mail address of the competent person responsible for the safety data sheet [email protected]

1.4 Emergency telephone number For urgent safety information call the Anti-Poison Center of your country. Check the emergency list on page 10.

SECTION 2. Hazards Identification.

2.1. Classification of the substance or mixture.

The product is classified as hazardous according to the provisions of Regulation (EC) 1272/2008 (CLP) (and subsequent amendments). SDS121200550UK The product thus requires a safety data sheet complies with the provisions of Regulation (EC) 1907/2006 and subsequent amendments. Further information on the risks to health and / or the environment are given in sections. 11 and 12 of this sheet.

2.1.1. Regulation 1272/2008 (CLP) and subsequent amendments. Classification and hazard statements: Eye Irrit. 2 H319 Skin Irrit. 2 H315

2.1.2. Directives 67/548 / EEC and 1999/45 / EC and following amendments and adjustments. Hazard symbols: Xi Phrases: 36

The full text of risk phrases (R) and hazard (H) is given in section 16.

2.2. Label’s elements. Danger labeling under Regulation (EC) 1272/2008 (CLP) and subsequent amendments.

Hazard pictograms:

warning

DISHWASHING POWDER Flacer - page 1 of 10 Hazard statements: H319 Causes serious eye irritation. H315 Causes skin irritation.

Precautionary statements: P101 If medical advice is needed, have the product container or label P102 Keep out of reach of children. P264 Wash hands thoroughly after use. P310 Immediately call a POISON CENTER or physician. P332 + P313 In case of skin irritation: consult a doctor .. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue to rinse. P337 + P313 attention if irritation of the eyes persists, consult a physician.

CHEMICAL COMPOSITION OF THE PRODUCT (Reg. 648/2004 / EC) Nonionic surfactants, Polycarboxylates, phosphonates, <5% Oxygen-based bleaching> 5% but <15% Phosphates> 15% but <30% Other components: enzymes (Amylase, Protease), perfume

2.3. Other hazards. No one.

SECTION 3. Composition / information on ingredients.

3.1. Substances. Information not relevant.

3.2. Mixtures. contains:

Identification Conc. %. Classification 67/548/CEE. Classification 1272/2008 (CLP). SODIUM CARBONATE CAS. 497-19-8 30 - 50 Xi R36 Eye Irrit. 2 H319 CE. 207-838-8 INDEX. 011-005-00-2 Nr. Reg. 01-2119485498-19 DISODIUM CARBONATE, COMPOUND WITH HYDROGEN PEROXIDE (2:3) Ox. Sol. 3 H272, Acute Tox. 4 H302, Eye Dam. O R 8, Xn R22, Xi R41 CAS. 15630-89-4 5 - 9 1 H318 CE. 239-707-6 INDEX. - Nr. Reg. 01-2119457268-30 SODIUM METASILICATE PENTAHYDRATE CAS. 10213-79-3 1 - 3 C R34, Xi R37 Skin Corr. 1B H314, STOT SE 3 H335 CE. 229-912-9 INDEX. 014-010-00-8 Nr. Reg. 01-2119449811-37

Note: Value of the upper range excluded.

The full text of risk phrases (R) and hazard (H) is given in section 16. T + = Very Toxic (T +), T = Toxic (T), Xn = Harmful (Xn), C = Corrosive (C), Xi = Irritant (Xi), O = Oxidizing (O), E = Explosive (E), F + = Extremely Flammable (F +), F = Highly Flammable (F), N = Dangerous for the Environment (N)

SECTION 4. First aid measures.

4.1. Description of first aid measures. EYES: Remove contact lenses. Wash immediately with plenty of water for at least 30-60 minutes, opening her eyelids. Consult a physician immediately. SKIN: Take off contaminated clothing. Take a shower immediately. Consult a physician immediately. Ingestion: to drink water as much as possible. Consult a physician immediately. Do not induce vomiting unless expressly authorized by the physician. Inhalation: Call a physician immediately. Move to fresh air, away from the accident site. If breathing has stopped, administer artificial respiration. Take adequate precautions to the rescuer.

4.2. Most important symptoms and effects, both acute and delayed. In the absence of experimental toxicological data on the product itself, the potential risks of the product to health were evaluated based on the properties of substances, according to criteria provided by the reference standard for classificazione.Considerare therefore the concentration of each substance dangerous possibly mentioned in sect. Third, to evaluate the toxicological effects deriving dall`esposizione product. Acute effects: contact with eyes causes irritation; Symptoms may include: redness, swelling, pain and tearing. Inhalation of vapors may cause moderate irritation of the upper respiratory tract; contact with the skin may cause slight irritation.

DISHWASHING POWDER Flacer - page 2 of 10 Ingestion may cause health problems, including stomach pain and sting, nausea and vomiting. Acute effects: contact with skin may cause irritation, erythema, edema, dryness and chapped skin. Inhalation of vapors may cause moderate irritation of the upper respiratory tract. Ingestion may cause health problems, including stomach pain and sting, nausea and vomiting.

4.3. Indication of any immediate medical attention and special treatment. If swallowed, follow your doctor’s instructions. In case of accident or unwell seek medical advice immediately (if possible show directions for use or the safety data sheet). treatment: symptomatic treatment

SECTION 5. Fire-fighting measures.

5.1. Extinguishing. SUITABLE EXTINGUISHING Extinguishing the conventional kind: carbon dioxide, foam, powder and water spray. EXTINGUISHING MEDIA NOT SUITABLE None in particular.

5.2. Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN CASE OF FIRE Do not breathe combustion products.

5.3. Advice for firefighters to firefighting. General information Cool by spraying with water the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention. Collect extinguishing water must not be discharged into drains. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. EQUIPMENT Normal clothing to fight the fire, like a compressed air breathing apparatus open circuit (EN 137), complete with flame retardant (EN469), flame-resistant gloves (EN 659) and boots Firefighter (HO A29 or A30).

SECTION 6. Measures in case of accidental release.

6.1. Personal precautions, protective equipment and procedures in case of emergency. Avoid formation of dust spraying the product with water if there are no contraindications. Avoid breathing vapors / mists / gas. Wear suitable protective equipment (including personal protective equipment referred to in section 8 of the safety data sheet) to prevent any contamination of the skin, eyes and personal clothing. These indications are valid both for the employees to work for the emergency interventions.

6.2. Environmental precautions. Prevent product from entering the sewers, surface water, ground water.

6.3. Methods and materials for containment and cleaning. Collect mechanically sparking the leaked product and place in containers for recovery or disposal. Discard the residue with water spray if there are no contraindications. Ensure adequate ventilation of the area affected by the loss. Verify any incompatibilities for the material of the containers in section 7. The disposal of contaminated material must be made in accordance with the provisions of section 13.

6.4. Reference to other sections. Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage.

7.1. Precautions for safe handling. Handle the product after consulting all other sections of this MSDS. Avoid dispersal of the product in the environment. Do not eat, drink or smoke while handling it. Remove contaminated clothing and protective equipment before entering areas where you eat.

7.2. Conditions for safe storage, including any incompatibilities. Store only in the original container. Store closed containers in a well ventilated place, away from direct sunlight. Store containers away from any incompatible materials, and found section 10.

7.3. Specific end use. Powder detergent for household dishwashers.

SECTION 8. Exposure controls / personal protection.

8.1. Control parameters. Standards:

Italian Legislative Decree 9 April 2008 n.81. Switzerland Valeurs limites d`exposition aux postes de travail 2012. OEL EU Directive 2009/161 / EU; Directive 2006/15 / EC; Directive 2004/37 / EC; Directive 2000/39 / EC. ACGIH TLV-ACGIH 2012

DISHWASHING POWDER Flacer - page 3 of 10 SODIUM CARBONATE Components with limit values that require monitoring at the workplace: Total dust: OEL, 10 mg / m³ Health - Derived No effect - DNEL / DMEL Effects on consumers. Effects on workers Route of Exposure Acute Systemic acute Local Local Local Chronic Systemic chronic acute Systemic acute chronic Local Systemic chronic Inhalation. 10 mg / m3 VND 10 mg / m3 VND

DISODIUM CARBONATE, COMPOUND WITH HYDROGEN PEROXIDE (2: 3) Expected concentration of not `environmental effect - PNEC. Reference value in freshwater 0,035 mg / l Reference value in sea water 0.035 mg / l Reference value for microorganisms STP 16,24 mg / l Health - Derived No effect - DNEL / DMEL Effects on consumers. Effects on workers Route of Exposure Acute Systemic acute Local Local Local Chronic Systemic chronic acute Systemic acute chronic Local Systemic chronic Inhalation. 5 mg / m3 VND Dermal. VND 6.4 mg 6.4 mg / m2 VND 12.8 mg / cm2 VND 12.8 mg / cm2 VND

SODIUM METASILICATE PENTAHYDRATE Occupational Exposure Limits: Has not been assigned any occupational exposure limit, it is recommended an exposure limit of 2 mg / m3 (15 min TWA) by analogy with sodium hydroxide.

legend: (C) = CEILING; INALAB = Inhalable fraction; RESPIR = Respirable fraction; Torac = Fraction Thoracic. VND = hazard identified but no DNEL / PNEC available; NEA = no anticipated exposure; NPI = no danger identified. It is recommended to consider in the process of risk assessment of occupational exposure limit values provided dall` ACGIH for inert powders not otherwise classified (PNOC respirable fraction: 3 mg / mc; PNOC inhalable fraction: 10 mg / mc). If these limits are exceeded is recommended l`utilizzo a filter type P, the class (1, 2 or 3) must be chosen based all`esito risk assessment.

8.2. Exposure controls. As the use of adequate technical equipment must always take priority over personal protection equipment, ensure good ventilation in the workplace through effective local aspiration. For the selection of personal protective equipment if necessary, request advice from suppliers of chemicals. The personal protective equipment must bear the CE mercatura certifying their compliance with applicable regulations. Provide emergency shower pan with visoculare.

HAND PROTECTION In case there is a prolonged contact with the product, you should protect your hands with gloves resistant to penetration (ref. Standard EN 374). Final selection of glove material to work you must also evaluate the process of using the product and any other products derived from it. He also recalled that the latex gloves may result in sensitization.

SKIN PROTECTION Wear work clothes with long sleeves and safety footwear for professional use of category II (ref. Directive 89/686 / EEC and standard EN ISO 20344). Wash with soap and water after removing protective clothing.

EYE PROTECTION You should wear protective airtight goggles (ref. Standard EN 166).

RESPIRATORY PROTECTION We recommend l`utilizzo a facial mask filter type P, the class (1, 2 or 3) and actual need, to be defined according all`esito risk assessment (ref. Standard EN 149).

Emissions from production processes, including those from ventilation should be checked for the purposes of compliance with environmental protection.

SECTION 9. Physical and chemical properties.

9.1. Information on basic physical and chemical. Appearance powder white color lemon odor Odour threshold. Not available. pH. 10.5 Melting point (sodium carbonate). 851 ° C. Initial boiling point. Not applicable: solid product Boiling range. Not applicable: solid product. Flash point. Not flammable. Lower explosive limit. Not flammable. Upper explosive limit. Not flammable. Lower explosive limit. Not explosive. Upper explosive limit. Not explosive. Vapor pressure. Not applicable: solid product. Vapour density Not applicable: solid product. Relative density. 1,000 Kg / l Solubility Soluble in water.

DISHWASHING POWDER Flacer - page 4 of 10 Ignition temperature. Not applicable. Decomposition temperature (sodium percarbonate). 70 ° C. Not applicable Viscosity: solid product. Explosive properties Not explosive. The oxidizing properties of sodium percarbonate free oxygen above 50 ° C.

9.2. Other information. No.

SECTION 10. Stability and reactivity.

10.1. Reactivity. There are no particular risks of reaction with other substances in normal conditions of use.

SODIUM METASILICATE PENTAHYDRATE: the aqueous solutions behave as strong bases; can attack aluminum, zinc, tin and their alloys.

10.2. Chemical stability. Relative to sodium percarbonate: The product is stable under conditions of use and storage conditions recommended (see sec. 7-8). Thermal decomposition: with self-accelerating development of O2 from 50 ° C.

10.3. Possibility of hazardous reactions. In normal conditions of use and storage are unpredictable dangerous reactions.

SODIUM METASILICATE PENTAHYDRATE: react violently with acids.

10.4. Conditions to avoid. Relative to sodium percarbonate: Conditions to avoid: moisture, heat, acids, bases, heavy metal salts, reducing agents, organic materials, flammable substances.

10.5. Incompatible materials. Relative to sodium percarbonate: Conditions to avoid: moisture, heat, acids, bases, heavy metal salts, reducing agents, organic materials, flammable substances. Contamination by substances mentioned because the decomposition, with increasing speed with the temperature, and with the possibility of rapidly generating large volumes of oxygen and steam.

10.6. Hazardous decomposition products. Relative to sodium percarbonate: The product is stable under conditions of use and storage conditions recommended (see sec. 7-8). Thermal decomposition: with self-accelerating development of O2 from 50 ° C.

SECTION 11. Toxicological information.

11.1. Information on toxicological effects. In the absence of experimental toxicological data on the product itself, the potential risks of the product to health were evaluated based on the properties of substances, according to criteria provided by the reference standard for classificazione.Considerare therefore the concentration of each substance dangerous possibly mentioned in sect. Third, to evaluate the toxicological effects deriving dall`esposizione product. Acute effects: contact with eyes causes irritation; Symptoms may include: redness, swelling, pain and tearing. Inhalation of vapors may cause moderate irritation of the upper respiratory tract; contact with the skin may cause slight irritation. Ingestion may cause health problems, including stomach pain and sting, nausea and vomiting. Acute effects: contact with skin may cause irritation, erythema, edema, dryness and chapped skin. Inhalation of vapors may cause moderate irritation of the upper respiratory tract. Ingestion may cause health problems, including stomach pain and sting, nausea and vomiting.

DISODIUM CARBONATE, COMPOUND WITH HYDROGEN PEROXIDE (2: 3) LD50 (Oral). 1034 mg / kg LC50 (Inhalation). 1200 mg / m3 disodium carbonate, compound with hydrogen peroxide (2: 3) :: c) serious eye damage / eye irritation: severe eye irritation, rabbit. e) Germ cell mutagenicity: No mutagenic effect f) carcinogenicity; IARC: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by the IARC

SODIUM CARBONATE LD50 (Oral). 4090 mg / kg Rat LD50 (Dermal). 117 mg / kg Mouse LC50 (Inhalation). 2.3 mg / l / 2h Rat Sodium carbonate: Acute effects: contact with eyes causes irritation; Symptoms may include: redness, swelling, pain and tearing. Inhalation of dust can cause moderate irritation of the upper respiratory tract; contact with the skin may cause slight irritation. Ingestion may cause health problems, including stomach pain and sting, nausea and vomiting. Oral LD50 2800 mg / kg Wistar rats, male / female. No guidelines. Test conditions: Groups of 5 male and 5 female Wistar rats were treated with a 20% solution of sodium carbonate in water by intubation, in concentrations of 1300, 1800, 2600, 3600, and 5000 mg / kg body weight. The LD50 was calculated in relation to such conditions of administration. Oral LD50 4090 mg / kg Rat Reference: Toxicological Data, compiled by the National Institute of Health (NIH), USA, selected and distributed by Technical Database Services (TDS), New York, 2009

DISHWASHING POWDER Flacer - page 5 of 10 Dermal LD50> 2000 mg / kg New Zealand White Rabbits EPA 16 CFR 1500.40 LC50 Inhalation 2300 mg / m³ Wistar rats and Sprague-Dawley male. No guidelines. Test conditions: Deviations from OECD guidelines 403: 2 hours of exposure in place of 4 hours of exposure, only the males used; reporting less elaborate and complete. Effects of irritation and corrosivity: Effects of corrosion / skin irritation: Result: Not irritating. Average value for erythema: 0. Average value for edema: 0. Species: Rabbits New Zealand White. Method: OECD Guideline 404. Effects of eye irritation: Result: Irritating. Total value of eye irritation - Draize score (average): 105 Species: Rabbits New Zealand White. Method: EPA 16 CFR 1500.42. Mutagenicity: Mutagenicity - Genotoxicity in vitro test: negative. Cytotoxicity: 1100 microg / ml PQ37 (uvrB-). No guidelines. Species: Escherichia coli. Method: Chromotest. Carcinogenicity: IARC: This substance has not been identified as a known or anticipated carcinogen by IARC. Reproductive toxicity: Developmental toxicity / teratogenicity: NOAEL (maternal toxicity) ≥ 245 mg / kg bw / day. NOAEL (teratogenicity) ≥ 245 mg / kg bw / day Species: Wistar rats. Method: No guidelines.

SODIUM METASILICATE PENTAHYDRATE LD50 (Oral). 847 mg / kg Rat a) acute toxicity; causes chemical burns. All symptoms of toxicity are caused by high basicity. b) skin corrosion / irritation; Corrosive to the skin c) serious eye damage / eye irritation; Corrosive to eyes d) respiratory or skin sensitization; Non-sensitizing e) germ cell mutagenicity; there is no evidence of genotoxicity f) carcinogenicity; no alarming g) reproductive toxicity; Information not available h) Specific target organ toxicity (STOT) - single exposure; Irritating to respiratory system i) Specific target organ toxicity (STOT) - repeated exposure; Not classified NOAEL oral (rat) 227 mg / kg body weight / day j) in case of danger aspirazione.Non classified

SECTION 12. Ecological information.

Adopt good working practices, avoiding littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation.

12.1. Toxicity. Sodium carbonate: Parameter Test Result Species LC50 (fish, 96h) 300 mg / l Lepomis macrochirus No guidelines. Static method. LC50 (fish, 96h) 740 mg / l Mosquitofish Recommendations of Committee on Research Were Followed (Doudoroff et al., 1951) EC50 (invertebrates, 48 h) 200-227 mg / l Ceriodaphnia sp. NSW Environment Protection Authority (Warne & Julli, 1999) EC50 (invertebrates, 48 h) 265 mg / l Daphnia magna Anderson et al. (1948) Inhibition of growth (algae): Data not available. SODIUM CARBONATE LC50 (96h): 300 mg / l Lepomis macrochirus, static method. EC50 (48h): 265 mg / l Daphnia magna

Sodium percarbonate: aquatic toxicity Specification: EC50 (sodium percarbonate; Nr. CAS: 15630-89-4) Paramettro: Daphnia Daphnia pulex Value = 4.9 mg / l To. of the test: 48 h Specification: EC50 (sodium percarbonate; Nr. CAS: 15630-89-4) Paramettro: Algae anabaena Value = 8 mg / l To. of the test: 140 h Specification: LC50 (sodium percarbonate; Nr. CAS: 15630-89-4) Paramettro: Fish fathead minnows Value = 70.7 mg / l To. of the test: 96 h Specification: NOEC (sodium percarbonate; Nr. CAS: 15630-89-4) Paramettro: Fish fathead minnows Value = 7.4 mg / l To. of the test: 96 h Specification: NOEC (sodium percarbonate; Nr. CAS: 15630-89-4) Paramettro: Daphnia Daphnia pulex Value = 2 mg / l To. of the test: 48 h

DISHWASHING POWDER Flacer - page 6 of 10 12.2. Persistence and degradability. The surfactants contained in this preparation comply with the biodegradability criteria established by Regulation (EC) No. 648/2004 on detergents. Information on the surfactant Persistence / Biodegradability Test method: OECD 301 Rating: readily biodegradable Soluble in water.

12.3. Bioaccumulation potential. Sodium carbonate: Not bioaccumulative.

12.4. Mobility in soil. It is not expected that the product represents a significant risk to the environment.

12.5. Results of PBT and vPvB. Based on the available data, the product does not contain PBT or vPvB percentage greater than 0.1%. PBT: no VPvB Substances: None.

12.6. Other adverse effects. no one.

SECTION 13. Disposal considerations.

13.1. Methods of waste treatment. Reuse, when possible. Product residues are considered hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorized waste management, in compliance with national and local regulations. Avoid release of the product in the soil, sewers and waterways. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

Recover if possible. To dispose of the product or containers uncleaned / reclaimed rivolgersdi companies expressly autotizzate waste management (recovery or disposal of hazardous waste). The containers cleaned / decontaminated should be disposed of / recovered as rifiiuti special. Never discharge the product into surface water or groundwater. Where applicable, refer to the following standards: 91/156 / EEC, 91/689 / EEC, 94/62 / EC and subsequent adjustment.

SECTION 14. Transport information.

The product is not classified as dangerous under current provisions governing the transport of dangerous goods by road (ADR) and by Rail (RID), by sea (IMDG Code) and by air (IATA).

SECTION 15. Regulatory information.

15.1. Standards and legislation on health, safety and environment specific for the substance or mixture. Seveso category. No.

Restrictions relating to the product or contained substances pursuant to Annex XVII to Regulation (EC) 1907/2006. No.

Substances in Candidate List (Art. 59 REACH). No.

Substances subject to authorization (Annex XIV REACH). No.

Substances subject to export notification Reg. (EC) 649/2012: No.

Substances subject to the Rotterdam Convention: No.

Substances subject to the Stockholm Convention: No.

Healthcare controls.

Workers exposed to this chemical agent to health must undergo health checks carried out in accordance with art. 41 of Legislative Decree no. 81 dated 9 April 2008 unless the risk to the safety and health of the worker has been evaluated irrelevant, according to art. 224 paragraph 2.

DISHWASHING POWDER Flacer - page 7 of 10 15.2. Chemical safety assessment. Was not processed a chemical safety assessment for the mixture.

SECTION 16. Other information.

Text of hazard (H) indications mentioned in section 2-3 of the sheet: Ox. Sol. 3 Oxidising solid, category 3 Acute Tox. 4 Acute toxicity, category 4 Skin Corr. 1B Skin corrosion, category 1B Eye Dam. 1 Serious eye damage, category 1 Eye Irrit. 2 Eye irritation, category 2 Skin Irrit. 2 Skin irritation, category 2 STOT SE 3 Specific target organ toxicity - single exposure, category 3 H272 May intensify fire; oxidizing. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H319 Causes serious eye irritation. H315 Causes skin irritation. H335 May cause respiratory irritation.

Text of risk (R) phrases mentioned in section 2-3 of the sheet:

R 8 MAY CAUSE combustible material. R22 HARMFUL IF SWALLOWED. R34 CAUSES BURNS. R36 Irritating to eyes. R37 IRRITATING TO RESPIRATORY SYSTEM. R41 RISK OF SERIOUS DAMAGE TO EYES.

LEGEND: - ADR: European Agreement concerning the transport of dangerous goods by road - CAS NUMBER: Number of the Chemical Abstract Service - EC50: Concentration that gives effect to 50% of the population subject to testing - EC NUMBER: ID number in ESIS (European archive of existing substances) - CLP: Regulation EC 1272/2008 - DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonised System for the classification and labeling of chemicals - IATA DGR: Regulation for the transport of dangerous goods by the International Air Transport Association - IC50: Concentration of immobilization of 50% of the population subject to testing - IMDG: International Maritime Code for Dangerous Goods - IMO: International Maritime Organization - INDEX NUMBER: Identification number nell`Annesso VI of the CLP - LC50: Lethal concentration, 50% - LD50: Lethal dose, 50% - OEL: Occupational Exposure Level - PBT: Persistent, bioaccumulative and toxic according to REACH - PEC: Predicted Environmental Concentration - PEL: predictable level of exposure - PNEC: Predicted No Effect Concentration - REACH Regulation EC 1907/2006 - RID: Regulations concerning the international carriage of dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration which should not be exceeded during any time EXPOSURE work. - TWA STEL: Short Term Exposure Limit - TWA: Exposure Limit weighted mean - VOC: Volatile Organic Compound - VPvB: Very persistent and very bioaccumulative according to REACH - WGK: Water hazard class (Germany).

GENERAL BIBLIOGRAPHY 1. Directive 1999/45 / EC as amended 2. Directive 67/548 / EEC and subsequent amendments 3. Regulation (EC) 1907/2006 of the European Parliament (REACH) 4. Regulation (EC) 1272/2008 of the European Parliament (CLP) 5. Regulation (EC) 790/2009 of the European Parliament (I Atp. CLP) 6. Regulation (EC) 453/2010 of the European Parliament 7. Regulation (EC) 286/2011 of the European Parliament (II Atp. CLP) 8. Regulation (EC) 618/2012 of the European Parliament (III Atp. CLP) 9. The Merck Index. Ed. 10 10. Handling Chemical Safety 11. Niosh - Registry of Toxic Effects of Chemical Substances 12. INRS - Fiche Toxicologique 13. Patty - Industrial Hygiene and Toxicology 14. N.I. Sax - Dangerous properties of Industrial Materials-7 Ed., 1989 15. Web Site Agency ECHA

DISHWASHING POWDER Flacer - page 8 of 10 Note: USER: The information in this sheet are based on knowledge available at the date of the last version. Users must verify the suitability and completeness of information in relation to the specific use of the product. It should not be construed as a guarantee on any specific product property. The use of this product is not subject to our direct control, users must, under their own responsibility, laws and regulations on hygiene and safety. Do not assume responsibility for improper use. Provide adequate training to staff all`utilizzo chemicals.

Changes to previous review. Changes were made to the following sections: 01/02/08/11/12.

INGREDIENTS SHEET - DESCALER

COMPONENT IUPAC INCI NAME CAS Pharmacopea name % SODIUM sodium carbonate 497-19-8 natrii carbonas > 10 CARBONATE PENTASODIUM pentasodium triphosphate 7758-29-4 n.d. > 10 TRIPHOSPHATE SODIUM sodium sulphate 7757-82-6 natrii sulfas > 10 SULFATE SODIUM sodium chloride 7647-14-5 natrii chloridum > 10 CHLORIDE SODIUM disodium carbonate, compound > = 1% CARBONATE 15630-89-4 n.d. with hydrogen peroxide (2:3) < 10% PEROXIDE SODIUM natrii > = 1% sodium hydrogen carbonate 144-55-8 BICARBONATE hydrogenocarbonas < 10% > = 1% zeolites ZEOLITE 1318-02-1 n.d. < 10% > = 1% sodium metasilicate pentahydrate N.D. 10213-79-3 n.d. < 10% tetrasodium (1-hydroxyethane TETRASODIUM > = 0,1% 3794-83-0 n.d. -1,1-diyl)bis(phosphonate) ETIDRONATE < 1% > = 0,1% long chain alcohol, alkoxylated N.D. N.A. n.d. < 1% 2- propenoic acid sodium salt SODIUM > = 0,1% 9003-04-7 n.d. (polyacrilic acid) POLYACRYLATE < 1% HYDRATED > = 0,1% hydrated amorphous silica 112926-00-8 n.d. SILICA < 1% PROPYLENE > = 0,1% propane-1,2-diol 57-55-6 propylenglycolum GLYCOL < 1% Subtilisin SUBTILISIN 9014-01-1 n.d. < 0,1% Active enzyme protein of Amylase, N.D. 9000-90-2 n.d. < 0,1% a- 1H-benzotriazole BENZOTRIAZOLE 95-14-7 n.d. < 0,1%

Perfume N.D. N.A. n.d. < 0,01%

DISHWASHING POWDER Flacer - page 9 of 10 Emergency telephone numbers For urgent safety information call the Anti-Poison Center of your country:

COUNTRY CUSTOMER SERVICE NR. ANTI-POISON CENTER NR.

AUSTRIA (0043) 050 6700 200 (0043) 01 406 43 43 BELGIUM 0032 (0)2 263 33 33 (0032) 070 245 245 CZECK REP. (00420) 840 111 313 (00420) 224 91 54 02 DENEMARK (0045) 44880280 (0045) 82121212 FINLAND (09) 61336 235 (09) 471977 FRANCE (0033) 0892 700 150 (0033) 01 40 05 48 48 GERMAN (0049) 0711 93533655 (0049) 0761 19240 GREECE (0030) 2109946400 (0030) 2107793777 HOLLAND 0031 (0)76 530 6400 (0031) 030 274 8888 HUNGARY (0036) 06 40 109 109 (0036) 80 20 11 99 IRELAND (00353) 0844 815 8989 (00353) 1 8092566 ITALY (0039) 199 580 480 (0039) 02 66101029 NORWAY (0047) 22782500 (0047) 22 59 13 00 POLAND (0048) 801 900 666 Warszawa: (0048) 22 619 66 54 Gdańsk: (0048) 58 682 04 04 Poznań: (0048) 61 847 69 46 Kraków: (0048) 12 411 99 99 PORTUGAL (00351) 707 203 204 (00351) 808 250143 ROMANIAN (0040) 0372 117 745 RUSSIA 007 (495)745 57 31 SLOVAKIA (00421) 0850 003 007 (00421) 2 54774166 SPAIN (0034) 902 203 204 (0034) 915 620 420 SWEDEN (0046) 0771 751570 (0046) 08 331231 SWISS (0041) 0848 801 005 (0041) 145 UK (0044) 0844 815 8989 (0044) 0845 46 47 (0044) 020 7188 0600 UCRAIN (00380) 0 800 501 150

DISHWASHING POWDER Flacer - page 10 of 10