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Thermal Behaviour and Excess Entropy of Bioactive Glasses and Zn-Doped Glasses
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by HAL-Rennes 1 Thermal behaviour and excess entropy of bioactive glasses and Zn-doped glasses. Eric Wers, Hassane Oudadesse To cite this version: Eric Wers, Hassane Oudadesse. Thermal behaviour and excess entropy of bioactive glasses and Zn-doped glasses.. Journal of Thermal Analysis and Calorimetry, Springer Verlag (Germany), 2013, pp.1-8. <10.1007/s10973-013-3280-3>. <hal-00914284> HAL Id: hal-00914284 https://hal.archives-ouvertes.fr/hal-00914284 Submitted on 5 Dec 2013 HAL is a multi-disciplinary open access L'archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destin´eeau d´ep^otet `ala diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publi´esou non, lished or not. The documents may come from ´emanant des ´etablissements d'enseignement et de teaching and research institutions in France or recherche fran¸caisou ´etrangers,des laboratoires abroad, or from public or private research centers. publics ou priv´es. J Therm Anal Calorim (2013) p: 1–8 DOI 10.1007/s10973-013-3280-3 Thermal behaviour and excess entropy of bioactive glasses and Zn-doped glasses E. Wers, H. Oudadesse ( ✉) Received: 22 March 2013 / Accepted: 4 June 2013 E. Wers, H. Oudadesse ( ✉) SCR, UMR CNRS 6226, University of Rennes 1, 263 av. du Général Leclerc, 35042 Rennes Cedex, France Abstract Bioactive glasses prepared in SiO 2–CaO–Na 2O and P 2O5 system are used as biomaterials in orthopaedic and maxillofacial surgery. -
The World of SCHOTT 3
The World of SCHOTT 3 SCHOTT is a leading international technology group in the areas of specialty glass and glass-ceramics. With more than 130 years of outstanding development, materials and technology expertise we offer a broad portfolio of high-quality products and intelligent solutions that contribute to our customers’ success. Our true passion for glass is sparked by imagination and fueled by expertise. Whatever you envision, we will find a way to realize it. We reinvent glass in all its numerous properties. We can bend it, roll it up and off, combine it with metal, light it up, make it round, turn it into glass powder or make it ultra-thin. SCHOTT creates solutions that bring unique products and novel applications to life – “glass made of ideas”. The memorial next to the Atocha station in Madrid, Spain: An elliptical cylinder that is made solely of highly transparent and temperature- resistant borosilicate glass blocks from SCHOTT conveys the idea of preserving an intangible moment and creates a translucent space for reflection. 4 5 The SCHOTT Group A team of experts providing innovations you can rely on. The chemistry was right in every sense when glass chemist Otto Schott teamed up with physicist Ernst Abbe and mechanic Carl Zeiss. In 1884, Otto Schott was the first to develop and apply scientifically-based methods to glass making, a revolutionary concept that enabled him to develop completely new optical and technical glasses. He achieved matchless quality levels in glass manufacturing and enhanced the design of new glasses, such as the now well- known borosilicate glass, for groundbreaking solutions. -
Quarterly Journal of the All India Glass Manufacturers' Federation
Vol. 3 | No. 4 | January - March 2016 Quarterly Journal of The All India Glass Manufacturers’ Federation Bi-lingual www.aigmf.com Technical Articles Prof. (Dr.) A. K. Bandyopadhyay Prof. (Dr.) A Sustainable 50 for postage postage for 50 ` ASS ASS www.aigmf.com Building and Packaging material An Publication - GlASS Gl Gl 500 (within India) + + India) (within 500 ` ` Kanch | Vol. 3 | No. 4 | January-March 2016 2 Overseas: US$ 60 (including postage and bank charges) bank and postage (including 60 US$ Overseas: Order Print Copies: Print Order Price: Price: www.aigmf.com President SANJAY GANJOO Sr. Vice President ARUN KUMAR DUKKIPATI Vice President RAJ KUMAR MITTAL Hon. General Secretary BHARAT SOMANY Hon. Treasurer SANJAY AGARWAL Member Editorial Board A K Bandyopadhyay Quarterly Journal of THE ALL INDIA GLASS MANUFACTURERS’ FEDERATION Former Principal, Govt. College of Engineering & Ceramic Technology-GCECT, Kolkata DEVENDRA KUMAR Prof. & HOD, Dept. of Ceramic, Indian Institute of Technology (Banaras Hindu University) Vol. 3 | No. 4 | January-March 2016 K K SHARMA President, NIGMA and Plant Head, HNG Neemrana, Rajasthan MEMBER ASSOCIatIONS EASTERN INDIA GLASS MANUFACTURERS’ ASSOCIATION (EIGMA) Contents c/o La Opala RG Ltd. Chitrakoot, 10th Floor, 230 A, A.J.C. Bose Road From President's Desk 5 Kolkata - 700 020 President - Sushil Jhunjhunwala Glass as Vital Building Material for Smart / Solar Cities NORTHERN INDIA GLASS MANUFACTURERS’ ASSOCIATION (NIGMA) & c/o Hindustan National Glass & Industries Limited 6 Post Office - Bahadurgarh, Jhajjar, Haryana-124 507 Book Launch: “Glass - A Sustainable Building and Packaging President - KK Sharma Material” Vice President - Jimmy Tyagi Honorary General Secretary - NN Goyal Glass News 13 Secretary & Treasurer - JB Bhardwaj SOUTH INDIA GLASS MANUFACTURERS’ ASSOCIATION (SIGMA) Smart City and Glasses for Flat-Screen Products – Part II 21 c/o AGI Glasspac (An SBU of HSIL Ltd.) Glass Factory Road, Off. -
Journal of Orthodontics and Craniofacial Research
Journal of Orthodontics and Craniofacial Research Masood H. J Orthod Craniofac Res 2: 109. Research Article DOI: 10.29011/JOCR-109.100109 The Effect of Bioactive Glasses in Air Abrasion Procedures Masood H, Gillam D*, Hill RG Oral Bioengineering, Institute of Dentistry, Barts and the London School of Medicine and Dentistry, Queen Mary University, London, UK *Corresponding author: David Gillam, Oral Bioengineering, Institute of Dentistry, Bart’s and the London School of Medicine and Dentistry, Queen Mary University, London, UK Citation: Masood H, Gillam D, Hill RG. (2020) The Effect of Bioactive Glasses in Air Abrasion Procedures. J Orthod Craniofac Res 2: 109. DOI: 10.29011/JOCR-109.100109 Received Date: 14 July 2020; Accepted Date: 24 July 2020; Published Date: 31 July 2020 Abstract Objective: To analyse the effect of particle size and shape of a new bioactive glass BioMinF on air abrasion compared to an air polishing powder (Sylc) using an enamel substitute material (Macor®). Method: The materials used in the study were: 1) Macor, (Precision Ceramics UK) 2) BioMinF: 500gm of glass frit (Cera Dynamics Ltd, UK) and 3) Sylc: Sylc 45S5 glass (Velopex International, UK). An AquaCare Air Abrasion & Polishing System (Velopex) with a hand piece with a 0.8 mm diameter tip was used with a 2mm thick Macor sheet with a feed rate of 1 and an air pressure of 2 bar. The BioMinF glass was milled for 45 seconds in five batches each containing 100 gm of BioMinF frit using a milling machine (Gy-Ro Mill, Glen Creston, and London). The angular particles produced were separated using different sieves to produce <38 micron, 38-63 microns, 63-80 microns, 80-125 microns and 125-250 microns particle size(s) respectively. -
Glass Ionomer Bone Cements Based on Magnesium-Containing Bioactive
Biomed. Glasses 2019; 5:1–12 Research Article Roland Wetzel, Leena Hupa, and Delia S. Brauer* Glass ionomer bone cements based on magnesium-containing bioactive glasses https://doi.org/10.1515/bglass-2019-0001 Received Sep 25, 2018; revised Dec 16, 2018; accepted Jan 14, 2019 1 Introduction Abstract: Glass ionomer cements (GIC) are used in restora- Cements for prosthetic stabilisation or spinal corrective tive dentistry and their properties (low heat during setting, surgeries (vertebroplasty, kyphoplasty) typically consist adhesion to mineralised tissue and surgical metals) make of polymethylmethacrylate [1, 2]. They exhibit a number them of great interest for bone applications. However, den- of drawbacks which include high curing temperatures tal GIC are based on aluminium-containing glasses, and or the presence of unreacted and toxic methacrylic acid the resulting release of aluminium ions from the cements monomers. They also do not bind to bone and are held in needs to be avoided for applications as bone cements. Re- place by mechanical interlocking only [2–6]. As a result, placing aluminium ions in glasses for use in glass ionomer there is a demand for alternative non-toxic cements with cements is challenging, as aluminium ions play a critical bone bonding capability. role in the required glass degradation by acid attack as Glass ionomer cements (GIC) have been used in well as in GIC mechanical stability. Magnesium ions have restorative dentistry as filler or luting materials for been used as an alternative for aluminium in the glass decades [7, 8]. They are formed by an acid-base reaction component, but so far no systematic study has looked into between a polymeric acid and an acid-degradable fluoro- the actual role of magnesium ions. -
Celebrating 100 Years
AMERICANa CERAMICting SOCIETY ars Celebr 100 ye bullemerginge ceramicstin & glass technology SEPTEMBER 2021 Laser-driven chemical vapor deposition for high-performance fibers and powders New issue inside: SEPTEMBER 2021 • VOLUME 2 • ISSUE 3 www.ceramics.org/ceramicandglassmanufacturing THE VALUE OF COLLABORATION: PARTNERSHIPS ARE A PATH TO SUCCESS ABET ENSURES QUALITY IN UNIVERSITY ENGINEERING EDUCATION ACerS Awards of 2021 | Coe College glass research | Big science in aerospace When it Comes to Heat, We Sweat the Details! Your firing needs are unique. Our laboratory can run tests to So why use an “off the shelf” help identify your process kiln in your process? boundaries. Through our toll firing facility, we can At Harrop, we get it. help to further define That’s why, for over a the equipment/ century, we’ve been processing putting in the hard work combination that to design and service works best for your custom kilns. Is it harder material. And if you to do things this way? are not ready for a Yes. Is the extra effort new kiln, we can toll worth it? You bet! fire your material to help meet your At Harrop, we don’t production needs. stop there. If you aren’t sure what you Does your current need, we can help. kiln company sweat the details? www.harropusa.com 1.614.231.3621 Harrop Ad Sweat the Details ACerS Full Size w 100 logo.indd 1 5/21/20 9:33 AM contents September 2021 • Vol. 100 No.7 feature articles department Announcing ACerS Awards of 2021 News & Trends . 3 29 The Society will honor members and corporations at the Spotlight . -
The Beneficial Mechanical and Biological Outcomes of Thin Copper-Gallium Doped Silica-Rich Bio-Active Glass Implant-Type Coatings
coatings Article The Beneficial Mechanical and Biological Outcomes of Thin Copper-Gallium Doped Silica-Rich Bio-Active Glass Implant-Type Coatings George E. Stan 1,* , Teddy Tite 1, Adrian-Claudiu Popa 1, Iuliana Maria Chirica 1, Catalin C. Negrila 1, Cristina Besleaga 1 , Irina Zgura 1, Any Cristina Sergentu 1, Gianina Popescu-Pelin 2 , Daniel Cristea 3, Lucia E. Ionescu 4, Marius Necsulescu 4 , Hugo R. Fernandes 5 and José M. F. Ferreira 5 1 National Institute for Materials Physics, RO-077125 Magurele, Romania; teddy.tite@infim.ro (T.T.); [email protected] (A.-C.P.); iuliana.bogdan@infim.ro (I.M.C.); catalin.negrila@infim.ro (C.C.N.); cristina.besleaga@infim.ro (C.B.); irina.zgura@infim.ro (I.Z.); [email protected] (A.C.S.) 2 National Institute for Lasers, Plasma and Radiation Physics, RO-077125 Magurele, Romania; gianina.popescu@inflpr.ro 3 Faculty of Materials Science and Engineering, Transilvania University of Brasov, 500068 Brasov, Romania; [email protected] 4 Army Centre for Medical Research, RO-020012 Bucharest, Romania; [email protected] (L.E.I.); [email protected] (M.N.) 5 Department of Materials and Ceramics Engineering, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal; [email protected] (H.R.F.); [email protected] (J.M.F.F.) * Correspondence: george_stan@infim.ro; Tel.: +40-21-241-8128 Received: 12 October 2020; Accepted: 18 November 2020; Published: 20 November 2020 Abstract: Silica-based bioactive glasses (SBG) hold great promise as bio-functional coatings of metallic endo-osseous implants, due to their osteoproductive potential, and, in the case of designed formulations, suitable mechanical properties and antibacterial efficacy. -
The Effects of Copper Addition on the Structure and Antibacterial
bioRxiv preprint doi: https://doi.org/10.1101/2020.01.24.918524; this version posted January 25, 2020. The copyright holder for this preprint (which was not certified by peer review) is the author/funder, who has granted bioRxiv a license to display the preprint in perpetuity. It is made available under aCC-BY 4.0 International license. The Effects of Copper Addition on The Structure and Antibacterial Properties of Biomedical Glasses Leyla Mojtabavi1, Amir Razavi1* 1University of Tehran, Department of Engineering Science, Enghelab Ave, Tehran, Iran 111554563 Address for Correspondence: Department of Engineering Science, University of Tehran, Enghelab Ave, Tehran, Iran 111554563 Tel: +989147560142 Email: [email protected] This study was conducted to determine the effects that copper (Cu) has on the glass structure and antibacterial efficacy of a SiO2- CaO-Na2O-P2O5 bioactive glass composition. Copper is known to be an antibacterial agent, which could potentially be a safer alternative to doping materials with antibiotics. Additionally, the structural effects of copper in the glass were studied, as the glass structure plays an important role in its bioactivity in the physiological solutions. This leads to the possibility of achieving antibacterial glass that can serve as a bioactive glass for skeletal tissue. bioRxiv preprint doi: https://doi.org/10.1101/2020.01.24.918524; this version posted January 25, 2020. The copyright holder for this preprint (which was not certified by peer review) is the author/funder, who has granted bioRxiv a license to display the preprint in perpetuity. It is made available under aCC-BY 4.0 International license. -
Bioactive Glasses: from Parent 45S5 Composition to Scaffold-Assisted Tissue-Healing Therapies
Journal of Functional Biomaterials Review Bioactive Glasses: From Parent 45S5 Composition to Scaffold-Assisted Tissue-Healing Therapies Elisa Fiume, Jacopo Barberi, Enrica Verné * and Francesco Baino * ID Institute of Materials Physics and Engineering, Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy; elisa.fi[email protected] (E.F.); [email protected] (J.B.) * Correspondence: [email protected] (E.V.); [email protected] (F.B.); Tel.: +39-011-090-4717 (E.V.); +39-011-090-4668 (F.B.) Received: 19 February 2018; Accepted: 13 March 2018; Published: 16 March 2018 Abstract: Nowadays, bioactive glasses (BGs) are mainly used to improve and support the healing process of osseous defects deriving from traumatic events, tumor removal, congenital pathologies, implant revisions, or infections. In the past, several approaches have been proposed in the replacement of extensive bone defects, each one with its own advantages and drawbacks. As a result, the need for synthetic bone grafts is still a remarkable clinical challenge since more than 1 million bone-graft surgical operations are annually performed worldwide. Moreover, recent studies show the effectiveness of BGs in the regeneration of soft tissues, too. Often, surgical criteria do not match the engineering ones and, thus, a compromise is required for getting closer to an ideal outcome in terms of good regeneration, mechanical support, and biocompatibility in contact with living tissues. The aim of the present review is providing a general overview of BGs, with particular reference to their use in clinics over the last decades and the latest synthesis/processing methods. -
Lecture #16 Glass-Ceramics: Nature, Properties and Processing Edgar Dutra Zanotto Federal University of São Carlos, Brazil [email protected] Spring 2015
Glass Processing Lecture #16 Glass-ceramics: Nature, properties and processing Edgar Dutra Zanotto Federal University of São Carlos, Brazil [email protected] Spring 2015 Lectures available at: www.lehigh.edu/imi Sponsored by US National Science Foundation (DMR-0844014) 1 Glass-ceramics: nature, applications and processing (2.5 h) 1- High temperature reactions, melting, homogeneization and fining 2- Glass forming: previous lectures 3- Glass-ceramics: definition & applications (March 19) Today, March 24: 4- Composition and properties - examples 5- Thermal treatments – Sintering (of glass powder compactd) or -Controlled nucleation and growth in the glass bulk 6- Micro and nano structure development April 16 7- Sophisticated processing techniques 8- GC types and applications 9- Concluding remmarks 2 Review of Lecture 15 Glass-ceramics -Definition -History -Nature, main characteristics -Statistics on papers / patents - Properties, thermal treatments micro/ nanostructure design 3 Reading assignments E. D. Zanotto – Am. Ceram. Soc. Bull., October 2010 Zanotto 4 The discovery of GC Natural glass-ceramics, such as some types of obsidian “always” existed. René F. Réaumur – 1739 “porcelain” experiments… In 1953, Stanley D. Stookey, then a young researcher at Corning Glass Works, USA, made a serendipitous discovery ...… 5 <rms> 1nm Zanotto 6 Transparent GC for domestic uses Zanotto 7 Company Products Crystal type Applications Photosensitive and etched patterned Foturan® Lithium-silicate materials SCHOTT, Zerodur® β-quartz ss Telescope mirrors Germany -
Glass Technology" Plansee Session Session "Laser Applications"
ftO "*S9<1 C8C) TIB/UB Hannover E 11th S Conference G together with 86 Annual Meeting of the DGG ICG Annual Meeting Glass Trend Seminar "Glass Technology" Plansee Session Session "Laser Applications" Maastricht, The Netherlands 3-6 June 2012 Abstracts National Committee German Society Netherlands' of Glass Glass Industry Technology CONTENTS 11th ESG Conference & 86. GLASTECHNISCHE TAGUNG ICG Annual Meeting, Glass Trend Seminar, Plansee Session, Session "Laser Applications" KEYNOTE LECTURE S. 26-27 L. L. Hench Emeritus Professor University of Florida, USA Bioactive Glasses: From Concept to Clinic, a 45th Year Celebration SESSION 1 S. 28 - 35 Batch, melting & sintering processes R. Conradt Institute of Mineral Engineering, Department of Glass and Ceramic Composites, RWTH Aachen University, Aachen, Germany How to overcome the chemical constraints of glass melting W. Jatmiko, R. Conrad Institute of Mineral Engineering, Department of Glass and Ceramic Composites, RWTH Aachen University, Aachen, Germany Experimental assessment of batch melting behavior M. Lindig Nikolaus Sorg GmbH & Co. KG, Lohr am Main, Germany Sorg Batch Handling Concept - updated report and future development R. Conradt Institute of Mineral Engineering, Department of Glass and Ceramic Composites, RWTH Aachen University, Aachen, Germany Assessment of batch melting behavior - trying to close the gap between lab and industrial scale C. Pust1, M. Rohmann1, S.-R. Kahl2 1Rheinkalk GmbH, Wulfrath, Germany 2Ardagh Glass Dongen B.V., Dongen, The Netherlands Decrepitation of Dolomite from batch blankets in glass furnaces 1 R. Clasen Chair of Powder Technology of Glass and Ceramics, Saarland University, Saarbriicken, Germany The preparation of glasses via a sintering route - state of the art and perspectives S. -
The Effect of Dentine Pre-Treatment Using Bioglass And/Or Polyacrylic
Journal of Dentistry 73 (2018) 32–39 Contents lists available at ScienceDirect Journal of Dentistry journal homepage: www.elsevier.com/locate/jdent The effect of dentine pre-treatment using bioglass and/or polyacrylic acid on T the interfacial characteristics of resin-modified glass ionomer cements ⁎ Salvatore Sauroa,b, , Timothy Watsonb, Agustin Pascual Moscardóc, Arlinda Luzia, Victor Pinheiro Feitosad, Avijit Banerjeeb,e a Dental Biomaterials, Preventive & Minimally Invasive Dentistry, Departamento de Odontologia, CEU Carndenal Herrera University, Valencia, Spain b Tissue Engineering and Biophotonics Research Division, King’s College London Dental Institute, King’s College London, United Kingdom c Departamento de Odontologia, Universitat de Valencia, Valencia, Spain d Paulo Picanço School of Dentistry, Fortaleza, Ceará, Brazil e Department of Conservative & MI Dentistry, King’s College London Dental Institute, King’s College London, United Kingdom ARTICLE INFO ABSTRACT Keywords: Objective: To evaluate the effect of load-cycle aging and/or 6 months artificial saliva (AS) storage on bond Air-abrasion durability and interfacial ultramorphology of resin-modified glass ionomer cement (RMGIC) applied onto den- Bioactive glass tine air-abraded using Bioglass 45S5 (BAG) with/without polyacrylic acid (PAA) conditioning. Bonding Methods: RMGIC (Ionolux, VOCO) was applied onto human dentine specimens prepared with silicon-carbide Dentine pre-treatment abrasive paper or air-abraded with BAG with or without the use of PAA conditioning. Half of bonded-teeth were Polyacrylic acid submitted to load cycling (150,000 cycles) and half immersed in deionised water for 24 h. They were cut into Resin-modified glass ionomer cements matchsticks and submitted immediately to microtensile bond strength (μTBS) testing or 6 months in AS im- mersion and subsequently μTBS tested.