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SAFETY DATA SHEET OB-1/1, Vrijedi Od 4.1.2021. Str. 1/10 SECTION 1

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SAFETY DATA SHEET OB-1/1, Vrijedi Od 4.1.2021. Str. 1/10 SECTION 1 SAFETY DATA SHEET Document number: 07-04-5-0008/0002 Urea Revision No: 0 According to Regulation (EC) No 1907/2006 Date: 10/3/2021 Izradio: Pregledao: Odobrio: I. Kufrin M. Pukec I. Vidalin I. Losso SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product trade name Product code Product description Inorganic straight primary nutrient fertiliser. UREA N 46 2602832 Nitrogenous fertiliser. UREA 46 % N (technical grade) 2602840 Urea technical grade. Micro grade Urea 2608498 Urea technical grade, fraction <1 mm. Substance name: Urea EC No: 200-315-5 CAS No: 57-13-6 REACH Registration No: 01-2119463277-33-0041 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: As fertilizer in the nutrition of agricultural and forestry crops, foliar fertilization of plants, nutrition via irrigation systems. For waste water and gas treatment. Intermediate in the chemical industry (production of aqueous solutions of urea, ureaformaldehyde, synthetic resins, pharmaceuticals, inks, coatings). Raw material in the cement, steel and glass industry. In the cleaning and maintenance industry. Used in mining and quarrying. Anti-freezing agent, pH regulator. Additive in the food industry. Uses advised against: Not known. 1.3. Details of the supplier of the safety data sheet Manufacturer/Supplier: Petrokemija, Plc. Fertilizer Company Address: Aleja Vukovar 4, 44320 Kutina, Croatia Internet page: http://petrokemija.hr/ Telephone number: +385 44 647 212 E-mail address of responsible person for SDS: [email protected] 1.4. Emergency telephone number European emergency call number: 112 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [CLP] This product does not meet the criteria for classification in any hazard class according to Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures. 2.2. Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP] Hazard pictograms: Not applicable. Signal word: Not applicable. Hazard statements: Not applicable. Precautionary statements: Not applicable. Supplemental Hazard information: Not applicable. OB-1/1, vrijedi od 4.1.2021. str. 1/10 SAFETY DATA SHEET Document number: 07-04-5-0008/0002 Urea Revision No: 0 According to Regulation (EC) No 1907/2006 Date: 10/3/2021 2.3. Other hazards None. SECTION 3: Composition/information on ingredients 3.1. Substances Weight % Substance name Index number in CLP Annex VI content Urea Not applicable. ≥ 98 SECTION 4: First aid measures 4.1. Description of first aid measures General notes: Before providing first aid to injured people first protect yourself. Show this safety data sheet or label from the packaging to the doctor in attendance. Following inhalation: Remove from source of exposure to fresh air. Following skin contact: Wash exposed parts with soap and water. Following eye contact: Flush eyes with running water keeping eyelids open. Following ingestion: Not applicable. Self-protection of the first aider: See Section 8.2. 4.2. Most important symptoms and effects, both acute and delayed Following inhalation: Coughing. Following skin contact: Slight redness and itching. Following eye contact: Slight redness and excessive tearing. Following ingestion: Not applicable. 4.3. Indication of any immediate medical attention and special treatment needed None. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Non flammable. Select fire fighting measures according to the surrounding conditions. Unsuitable extinguishing media: Not applicable. 5.2. Special hazards arising from the substance or mixture Hazardous combustion products: Thermal decomposition of urea fertilizers takes place at temperatures above melting point (134 °C), releasing toxic ammonia gas. Accidental mixing of urea with nitric acid during fire might result with urea nitrate formation which has explosive properties. Molten urea formed during fire can cause thermal burns of the skin. 5.3. Advice for firefighters Fire fighting Use water sprays to disperse or suppress (knock down) eventualy released ammonia gas. Special protective equipment for firefighters Wear EN 137 Type 2 Self contained breathing apparatus (SCBA) with EN 136 full face mask. Properties of protective clothing to wear in case of fire are defined in EN 469. OB-2/1, vrijedi od 4.1.2021. str. 2/10 SAFETY DATA SHEET Document number: 07-04-5-0008/0002 Urea Revision No: 0 According to Regulation (EC) No 1907/2006 Date: 10/3/2021 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid inhalation of dust. Use personal protection equipment where excessive levels of dust are present (see Section 8.2.). 6.2. Environmental precautions Contain spillage from direct entering to the environment or drains. Inform appropriate authority (see Section 1.4.) in case of accidental contamination of watercourses or soil. 6.3. Methods and material for containment and cleaning up For containment Collect immediately or isolate and cover with PE foil to protect spilled product and dust from spreading. For cleaning up Large spill: Collect dry by mechanical means. Put collected material into clean container. Avoid generation of dust. Do not wash into water-courses or drains. Re-use or dispose according to national regulations. Small spill: Collect and put into clean container. Clean up affected area and wash down with water. 6.4. Reference to other sections For protective equipment see Section 8. For waste tretament see Section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures: Avoid dust formation. Provide adequate ventilation. Avoid heating of the product. Keep away from incompatible materials, heat, moisture and direct sunlight. Avoid damaging the bags during handling. Damaged bags should be removed from the stack in order to secure stack stability and prevent further spillage. Measures to prevent fire: Forbid smoking, open fires, electrical heaters with exposed radiant coils/filaments and naked flames (except when authorised for maintenance). Measures to protect the environment: Do not allow to enter directly into the environment or sewage drainage system. Measures to prevent contact with incompatible substances: Clean the storage area before putting fertilizers into the storage and when switching from one product to another. Advice on general occupational hygiene: Wash hands with soap and water before eating, drinking and smoking. Do not eat, drink or smoke in the working and storage area. 7.2. Conditions for safe storage, including any incompatibilities Technical measures and storage conditions Store in well ventilated, preferably covered storage area or storage building with adequate ventilation. Keep away from incompatible materials, heat, moisture and direct sunlight. The recommended storage temperature is below 50 C to maintain product quality. Urea should not be stored in the same building with ammonium nitrate based fertilizers. If this is unavoidable, conditions should be such that neither fertilizer can affect the other in any circumstances, in particular in the case of a fire. Packaging materials: Polyethylene (PE) and polypropylene/polyethylene (PP/PE) bags. OB-2/1, vrijedi od 4.1.2021. str. 3/10 SAFETY DATA SHEET Document number: 07-04-5-0008/0002 Urea Revision No: 0 According to Regulation (EC) No 1907/2006 Date: 10/3/2021 Further information on storage conditions Storage in bulk: Store bulk product in closed, dry and ventilated storing premises, with storage floor and heap covered with PE or PP/PE foil. When storing different fertilizer products and non-fertilizer materials in the same building they should be well separated to prevent cross-contamination. Outside storage: Outside storage is generally suitable for packaged products. Bulk fertilizers should only be stored outside in closed bins, hoppers or silos. Stacking recommendations: • bags with unit weights of up to 50 kg: vertical stack up to 2m, • loaded pallets stacking: 2 pallets in a vertical stack max., • big-bags with unit weights of up to 500 kg: 3 bags in a vertical stack max., • big-bags with unit weights of up to 1000 kg: 2 bags in a vertical stack max. The maximum height of the stack should take into account stack stability, bag strength and safe handling when loading and unloading. Limit the size of stacks in accordance with national regulations, if any. 7.3. Specific end use(s) Recommendations: None. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure limit values The product does not contain substances for which workplace exposure limits are proscribed. Supervise the concentration of total dust in the workplace. Exposure limit value for dust is 10 mg/m3. Substance name Urea EC No. 200-315-5 CAS No. 57-13-6 DNEL Workers Route of Acute effects Chronic effects Chronic effects Acute effect local exposure systemic local systemic Oral Not known Not known Not known Not known Inhalation Not known Not known Not known 292 mg/m³ 580 mg/kg body Dermal Not known Not known Not known weight/day DNEL Consumers Route of Acute effects Chronic effects Chronic effects Acute effect local exposure systemic local systemic 42 mg/kg body Oral Not known Not known Not known weight/day Inhalation Not known Not known Not known 125 mg/m³ 580 mg/kg body Dermal Not known Not known Not known weight/day PNEC Environmental protection target PNEC values Fresh water 0.047 mg/L (Assessment factor 1000) Freshwater sediments Not known Marine water 0.047 mg/L (Assessment factor 1000) Marine sediments Not known Food chain Not known Microorganisms in sewage treatment Not known OB-2/1, vrijedi od 4.1.2021. str. 4/10 SAFETY DATA SHEET Document number: 07-04-5-0008/0002 Urea Revision No: 0 According to Regulation (EC) No 1907/2006 Date: 10/3/2021 Soil (agricultural) Not known Air Not known 8.2. Exposure controls 8.2.1 Appropriate engineering controls Technical measures to prevent exposure: Provide adequate ventilation in work and storage areas.
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