SDS, Eye Contact, Inhalation, Ingestion

SAFET Y DATA SHEET : STRIP-IT PROTM ISSUE DATE 15-September-2020 ◆ REVISION DATE 15-September-2020 ◆ REV. 2 1. IDENTIFICATION 4. FIRST AID MEASURES 6. ACCIDENTAL RELEASE MEASURES PRODUCT IDENTIFIER GENERAL ADVICE: Immediate medical attention is required: The LEAK & SPILL PROCEDURE: Stop leak & ventilate area. Wear PRODUCT TRADE NAME: STRIP-ITTM effect of Hydrofluoric Acid (HF), i.e. the onset of pain, particularly protective gear sufficient to stop body contact of spilled material. RECOMMENDED USE: Sunblock coating remover in dilute solutions, may not be felt for up to Cover spill with chalk (Calcium carbonate) and allow to 24 hours. It is important that workers have immediate neutralize. Beware of fumes. Pick up neutralized material and RESTRICTIONS ON USE: Industrial and Institutional use only access to the antidote (calcium gluconate) both on and place into a disposable container. Wash down floor. SUPPLIER: off the worksite in order to apply it as soon as possible. WASTE DISPOSAL PROCEDURE: Only dispose of Pace Solutions Corp. INHALATION: Remove to fresh air. Call a physician or poison according to local municipal regulations. control center immediately. If not breathing, give artificial 1597 Derwent Way, Delta B.C., V3M 6K8 CANADA 7. HANDLING AND STORAGE Phone (800) 799-6211 | www.pacechem.com EMERGENCY respiration. If breathing is difficult, give oxygen. Remove the subject from the contaminated area as soon as possible. HANDLING PROCEDURE & EQUIPMENT: Use good industrial PHONE NUMBER/ 24-HOUR NUMBER: Canada: Canutec Transport subject lying down, with the head higher than the hygiene. Do not get in eyes. Avoid contact with skin and clothing. 613-996-6666 body, to a quiet, uncontaminated and well-ventilated location. Avoid breathing sprays or mists. Store in a cool, dry place away 2. HAZARD IDENTIFICATION Administer oxygen (2.5% calcium gluconate if available, can be from incompatibles. Handle with great care. Read label. oxygen nebulized with trained personnel) or cardiopulmonary PHYSICAL HAZARDS: NONE KNOWN resuscitation if necessary and as soon as possible. If patient STORAGE REQUIREMENTS: Keep closed when not in use. Store locked up. Keep only in original container. Store in corrosive HEALTH HAZARDS: ACUTE TOXICITY – ORAL – Category 3 is unconscious, give artificial respiration. Note: Mouth to mouth resuscitation is not recommended. Keep warm resistant container with a resistant inner liner. Incompatible with ACUTE TOXICITY – DERMAL – Category 1 (blanket). Consult physician in all cases. Take to a hospital. strong acids, bases, oxidizing agents, metals. ACUTE TOXICITY – INHALATION – Category 3 SKIN CONTACT: Immediate medical attention is required. Wash 8. EXPOSURE CONTROLS/PERSONAL PROTECTION SKIN CORROSION/ off immediately with soap and plenty of water while removing all EXPOSURE LIMITS: IRRITATION – Category 1 contaminated clothes and shoes. Immediately apply calcium OSHA (PEL): Sulfuric Acid: TWA 1 mg/m3, (vacated) TWA : 1mg/m3 gluconate gel 2.5% and massage into the affected area using CARCINOGENICITY Ammonium Bifluoride : TWA 2.5 mg/m3 F, (vacated) TWA : 1mg/m3 rubber gloves; continue to massage while repeatedly applying Hydrofluoric Acid : TWA 3 mg/m3, (vacated) TWA : 2.5mg/m3 – Category 1 gel until 15 minutes after pain is relieved. Alternately, immerse LABEL ELEMENTS the burned area in a solution of 0.2% iced aqueous Hyamine 1622 ACGIH TLV: Sulfuric Acid: TWA 0.2 mg/m3 thoracic fraction Ammonium Bifluoride : TWA 2.5 mg/m3 F HAZARD STATEMENT: or 0.13% iced aqueous Zephiran Chloride. If finger/ fingernails are touched, even if there is no pain, dip them in a bath of 5% Hydrofluoric Acid : TWA 2.5 mg/m3 F, ceiling : 2ppm F H301 Toxic if swallowed calcium gluconate for 15 to 20 minutes. Consult a physician OTHER EXPOSURE LIMIT: NIOSH IDLH H310 Fatal in contact with skin immediately in all cases of skin contact no matter how minor. Immediately Dangerous to Life or Health H331 Toxic if inhaled EYE CONTACT: Keep eye wide open while rinsing. Immediate APPROPRIATE ENGINEERING CONTROLS: Showers, H314 Causes severe skin burns and eye damage medical attention is required. Rinse immediately with plenty eyewash stations and ventilation systems. H350 May cause cancer of water, also under the eyelids, for at least 15 minutes. Do not rub affected area. Rinse the eyes with a calcium INDIVIDUAL PROTECTION MEASURES / PRECAUTIONARY STATEMENTS gluconate 1% solution for 10 minutes. In the case of difficulty PERSONAL PROTECTIVE EQUIPMENT: PREVENTION: P201 Obtain special instructions before use . opening the lids, administer an analgesic eyewash. Do GLOVES: Non-permeable gloves (rubber, nitrile) recommended. P202 Do not handle until all safety precautions not use oily drops, ointment, or HF skin burn treatments. Consult an ophthalmologist or eye specialist and physician immediately MASKS/GOGGLES: Tight sealing safety have been read and understood. in all cases. Take to hospital immediately. goggles. Face protection shield. P280 Wear protective gloves/ protective RESPIRATOR: Good general ventilation or local exhaust clothing/ eye protection/ face protection. INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. ventilation for spraying and misting in confined areas. NIOSH/ P264 Wash hands and affected area thoroughly after handling. Immediately medical attention is required. Remove from MSHA approved respiratory protection should be worn if P270 Do not eat, drink or smoke when using this product. exposure, lie down. Clean mouth with water and drink afterwards exposure limits are exceeded or irritation is experienced. P262 Do not get in eyes, on skin, or on clothing. plenty of water. Call a physician or poison control center APRON: Rubber apron recommended. immediately. When directed by physician, give orally either 1% P271 Use only outdoors or in a well-ventilated area. aqueous calcium gluconate solution, milk or calcium/ BOOTS: Rubber boots recommended. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. magnesium containing anti-acid. Such solution can be beneficial OTHER PROTECTIVE EQUIPMENT: Eye wash, but also may be problematic if they induce vomiting. RESPONSES: P321 Specific treatment is urgent (see safety shower and full protective clothing supplemental first aid information on this label). SELF-PROTECTION OF THE FIRST AIDER: Use personal recommended in the immediate work area. protective equipment as required. Avoid contact with skin, eyes 9. PHYSICAL AND CHEMICAL PROPERTIES P305 + P351 + P338 IF IN EYES: Rinse cautiously with or clothing: Mouth to mouth resuscitation is not recommended. water for several minutes. Remove contact lenses, APPEARANCE: Clear, amber color liquid. if present and easy to do. Continue rinsing. NOTE TO PHYSICIANS: Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation ODOR: Acidic. P310 Immediately call a POISON CENTER/ doctor/ physician. of stomach or esophagus should be investigated. Do not give ODOR THRESHOLD: N/A chemical antidotes. Asphyxia from glottal edema may occur. P303+P361+P353 IF ON SKIN (or hair): Remove/ pH: <2 Take off immediately all contaminated clothing. Marked decrease in blood pressure may occur with moist rales, Rinse skin with water/shower. frothy sputum, and high pulse pressure. Treat symptomatically. MELTING POINT/FREEZING POINT: N/A 5. FIRE-FIGHTING MEASURES INITIAL BOILING POINT AND BOILING P301 + P330 + P331 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. EXTINGUISHING MEDIA: Use extinguishing RANGE: 100°C approximate. Rinse mouth. Do NOT induce vomiting. measures that are appropriate to local circumstances FLASH POINT: None. and the surrounding environment. P304 + P340 IF INHALED: Remove person to fresh EVAPORATION RATE (WATER=1): <1 FLAMMABILITY: Not flammable. air and keep comfortable for breathing. FLAMMABILITY: Not flammable. FLASH POINT: Not flammable. STORAGE: P403 + P233 Store in a well-ventilated UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: None. place. Keep container tightly closed. SPECIAL FIREFIGHTING PROCEDURES: Directing a solid stream of water into a hot burning liquid can cause frothing and spread VAPOR PRESSURE: N/A P405 Store locked up. the fire. Wear NIOSH/MSHA approved, self-contained breathing VAPOR DENSITY: N/A DISPOSAL: P501 Dispose of contents/ container apparatus for firefighting situation. RELATIVE DENSITY/SPECIFIC GRAVITY (WATER = 1): 1.16 to an approved waste disposal plant. Use water spray to cool all nearby fire exposed surfaces. Do not allow runoff to get into the sewage system. SOLUBILITY(IES): Soluble in water 3. COMPOSITION/INFORMATION ON INGREDIENTS UNUSUAL FIRE / EXPLOSION HAZARDS: Risk of explosion PARTITION COEFFICIENT: N-OCTANOL/WATER: N/A Approx. CAS in contact with potassium, sodium, cyanogen fluoride, potassium AUTO-IGNITION TEMPERATURE: Not flammable Ingredient Wt.% Number permanganate, metals (produce flammable hydrogen gas), methanesulfonic acid, nitric acid + glycerin. DECOMPOSITION TEMPERATURE: N/A Sulfuric Acid 10-30 7664-93-9 HAZARDOUS DECOMPOSITION PRODUCTS: The VISCOSITY: Water thin. Ammonium Bifluoride 5-10 1341-49-7 product causes burns of eyes, skin and mucous Hydrofluoric Acid 1-5 7664-39-3 membranes. Thermal decomposition can lead to release Linear Dodecyl Benzene Sulphonic Acid 1-5 27176-87-0 of irritating and toxic gases and vapors. In the event of fire and/ or explosion, do not breathe fumes. *The exact percentage (concentration) of composition has been withheld as a trade secret TM SAFET Y DATA SHEET: STRIP-IT PRO

10. STABILITY AND REACTIVITY 14. TRANSPORT INFORMATION REACTIVITY: N/A CANADIAN TDG CHEMICAL STABILITY: Stable under normal storage conditions. Inner Packaging Not Over 1.0 L: LTD QTY (LTDY) POSSIBILITY OF HAZARDOUS REACTIONS: Polymerization with cyanogen fluoride. None under normal processing. Hazard Class: 8 CONDITIONS TO AVOID: Temperatures above 30°C (86°F) and Packing Group: II below 5°C (41°F). Exposure to air or moisture over prolonged ID Number: UN1760 periods. Extremes of temperature and direct sunlight. Hazard Label: 8 INCOMPATIBILITY: Alkalies, strong oxidizing agents, Proper Shipping Name: UN1760, CORROSIVE LIQUID, N.O.S, arsenic trioxide, phosphorus pentoxide, ammonia, calcium (SULFURIC ACID, AMMONIUM BIFLUORIDE), 8, II (HM-AS2F) oxide, sodium hydroxide, sulfuric acid, vinyl acetate, ethylenediamine, acetic anhydride, organic materials, most common metals (will react to produce flammable Hydrogen gas), rubber, leather, carbonates, sulfides, cyanides, oxides of silicon (especially glass), concrete, silica, fluorine. Will AIR TRANSPORT: (IATA/ICAO) also react with steam or water to produce toxic fumes. 5 x 0.1 L Per Package: LTD QTY (LTDY) HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen fluoride, hydrogen chloride, oxides of nitrogen, For packages greater than 5 x 0.1 L refer to IATA shipping ammonia, oxides of carbon, hydrocarbons. guidelines and above hazard class information. 11. TOXICOLOGICAL INFORMATION 15. REGULATORY INFORMATION LIKELY ROUTES OF EXPOSURE: Skin contact, skin absorption, All pertinent hazard information has been provided in this SDS, eye contact, inhalation, ingestion. per the requirements of the U.S. Federal Occupational Safety and SYMPTOMS: SKIN CONTACT: May cause deep chemical burns Health Administration Standard (29 CFR 1910.1200), U.S. State and permanent scarring. Effect on skin may be delayed and equivalent Standards, and the Canadian Workplace Hazardous damage may occur without the onset of pain. The fluoride ion Materials Identification System Standards (CPR 4). readily penetrates the skin causing destruction of deep tissue layers and even bone. Fatal if absorbed through skin. 16. OTHER INFORMATION EYE CONTACT: May cause burns and permanent eye damage. ACRONYM LIST: INHALATION: Irritant Vapour. Mists may cause permanent damage to respiratory tract. May cause sore throat, coughing, ACGIH American Conference of Governmental labored breathing and lung damage. Industrial Hygienists INGESTION: May cause permanent damage to the digestive system. May cause kidney damage. Toxic if swallowed FR Code of Federal Regulations ACUTE TOXICITY ESTIMATES: 2.87% of the mixture HMIS Hazardous Materials Identification System consists of ingredient(s) of unknown toxicity. IARC International Agency for Research on Cancer CARCINOGENICITY: MSHA Mine Safety and Health Administration Sulfuric Acid – A2 (ACGIH) – Group 1 (IARC) – Known (NTP) N/A Not Available Ammonium Bifluoride – Group 3 (IARC) NIOSH The National Institute for Occupational Safety A2 (ACGIH) – suspected human carcinogen and Health Group 1 (IARC) – Carcinogenic to humans NTP National Toxicology Program Group 3 (IARC) – not classifiable as a human carcinogen OSHA Occupational Safety and Health Administration Known (NTP) – known carcinogen EL Permissible Exposure Limit 12. ECOLOGICAL INFORMATION TDG Transportation of Dangerous Goods Threshold Not required. LV Limit Value 13. DISPOSAL CONSIDERATIONS N United Nations Only dispose of according to local municipal WHMIS Workplace Hazardous Materials Information System regulations. Do not reuse container. The information supplied in this data sheet is derived from sources believed to be reliable, however PACE SOLUTION CORP. offers no warranty, written or implied, as to the accuracy of its contents. We advise recipients to confirm in advance of need that the information is current, suitable and applicable to their requirements.

PREPARED BY: Technical Service PREPARATION DATE: 3-June-2019 PRODUCT NUMBER: STRIPIT