List of Products &Quantity : ( Existing & Additional) : A. Technicals

List of Products &Quantity : ( Existing & Additional) : A. Technicals:

Sr. Product Description Existing Qty. per Additional Qty. Total Qty. Per No. Month ( MT ) Per Month ( MT ) Month ( MT )

1. d-trans Allethrin Tech 2.5 MT 2.5 MT 5.00 MT

2. Allethrin Tech. 1 MT 1.0 MT 2.00 MT

3. Prallethrin Tech. 1 MT 5.0 MT 6.00 MT

4. Transfluthrin Tech. 1.2 MT 4.8 MT 6.00 MT

5. Deltamethrin Tech 0 2.0 MT 2.00 MT

6. Imidacloprid Tech 0 5.0 MT 5.00 MT

7. Bifenthrin Tech. 0 1.5 MT 1.50 MT

8. Fipronil Tech. 0 2.5 MT 2.50 MT

9. Cypermethrin Tech. 0 4.5 MT 4.50 MT

10. Permethrin Tech. 0 1.5 MT 1.50 MT

11. DEET Tech. 0 1.5 MT 1.50 MT

12. Renofluthrin Tech. 0 4.0 MT 4.00 MT

13. Dimefluthrin Tech. 0 3.0 MT 3.00 MT TOTAL QUANTITY PER MONTH - 5.7 MT 38.8 MT 44.5 MT ( A )

B. List of Intermediates & Quantity : ( Existing & Additional) :

Sr. Product Description Existing Qty. Per Additional Qty. Total Quantity No. Month ( MT ) Per Month ( MT Per Month ( MT )

1. Chrysanthemic Acid Chloride 2.25 MT 0.0 2.25 MT

2. Allethlone Alcohol 10.0 MT 0.0 ( Production 0.0 MT( will be Production will discontinued ) be discontinued )

3. Prallethrolone Alcohol 10.0 MT 0.0( Production 0.0 MT( will be Production will discontinued ) be discontinued )

4. R-Cypermethric Acid Chloride 0.0 4.0 MT 4.0 MT

5. Cypermethric Acid Chloride 0.0 6.0 MT 6.0 MT TOTAL QUANTITY PER MONTH - ( B ) 22.25 MT 10.0 MT 12.25 MT

GRAND TOTAL OF QUANTITY 27.95 MT 48.8 MT 56.75 MT ( A + B )

C. List of By Products & Quantity : ( Existing & Additional) :

Sr. Product Description Existing Qty. Per Additional Qty. Total Quantity No. Month ( MT ) Per Month ( MT Per Month ( MT )

1. Hydrochloric Acid 0.0 1.9 MT 1.9 MT

2. Sodium Sulphate 0.0 4.9 MT 4.9 MT

3. S-Cypermethric Acid 0.0 7.0 MT 7.0 MT TOTAL QUANTITY PER MONTH – 0.0 13.8 MT 13.8 MT ( C )

D. List of Formulations & Quantity : ( Existing & Additional) :

Sr. Product Description Existing Additional Qty. Per Total Quantity No. Quantity per Month Per Month Month

1. LV with 0.88% Transfluthrin 0 9. 0 MT 9.0 MT ( 35 ML & 45 ML ) (200,000 bottles) (200,000 bottles)

2. LV with 1.6% Transfluthrin 0 9. 0 MT 9. 0 MT ( 35 ML & 45 ML ) (200,000 bottles) (200,000 bottles)

3. Imidacloprid 2.15% Gel 0 1.25 MT 1.25 MT (50,000 tubes) (50,000 tubes) 1.25 MT 1.25 MT 4. Imidacloprid 17.8% SL 0 (50,000 tubes) (50,000 tubes) 1.25 MT 1.25 MT 5. Imidacloprid 30.5% SC 0 (50,000 tubes) (50,000 tubes) 1.25 MT 1.25 MT 6. Fipronil 5% Gel 0 (50,000 tubes) (50,000 tubes)

7. Transfluthrin 1% FU 0 3.0 MT 3.0 MT (75000 sachets) (75000 sachets)

8. Renofluthrin 5% MUP 0 30.0 MT 30.0 MT

9. Solvent Mix 0 3.0 MT 3.0 MT

10. DEP with Perfume 0 3.0 MT 3.0 MT

11. Renofluthrin 0.025% Coil 0 5.0 MT 5.0 MT

12. Renofluthrin 0.03% Coil 0 5.0 MT 5.0 MT

13. Transfluthrin12% AE 0 10.0 MT 10.0 MT (100,000 Cans) (100,000 Cans) 14. Renofluthrin 0.17% Insence Sticks ( Agarbatti ) 0 4.2 MT 4.2 MT 15. Renofluthrin 0.20% Insence Sticks ( Agarbatti ) 0 4.2 MT 4.2 MT 16. Renofluthrin 0.125% Insence Sticks ( Agarbatti ) 0 4.2 MT 4.2 MT

17. Renofluthrin 0.75% Liquid 0 9.0 MT 9.0 MT Vaporiser (200,000 Bottles) (200,000 Bottles) 18. Transfluthtin 0.06% + Cypermethrin 0.11% AE 0 10.0 MT 10.0 MT (100,000 Cans) (100,000 Cans) GRAND TOTAL OF QUANTITY ( D ) 0 MT 113.6 MT 113.6 MT

E. Heater Machines :

Sr. Product Description Existing Additional Qty. Per Total Quantity No. Quantity per Month Per Month Month

01. Heater Machines 0 25,000 Nos. 25,000 Nos.

ANNEXURE – 4

3.1 Project description with process detail. The process details and material balance for d-trans Allethrin Technical is given in following table. Manufacturing process of other products is given in Annexure-1.

PRODUCT NAME :d-trans Allethrin Technical

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.192 5 12 60 Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 1.0 Allethlone Alcohol 0.103 Reactant 1.0 Organic Layer 0.782 Chry. Acid Pyridine 2.0 Chloride 0.126 Reactant 2.0 Hydrochloride 0.095 3.0 Sodium Hydroxide 0.004 Washing 3.0 Effluent 0.062 4.0 Pyridine 0.072 Solvent 5.0 HCL 0.044 Washing 6.0 Toluene 0.590 Solvent Total 0.939 0.939

Distillation Recovered 1.00 Organic layer 0.782 1.00 Solvent 0.531 Residue 2.00 (Product) 0.192 3.00 Solvent Loss 0.059 Total 0.782 0.782 Distillation ( Recovery of Pyridine ) Pyridine 2.0 Hydrochloride 0.095 1.00 Pyridine 0.081 2.00 Effluent 0.014 Total 0.095 0.095 CHEMICAL FORMULAE : CH CH 3 3 O OH CH 3CH 3 Cl CH CH + 3 2 CH CH3 2 3CH O O 3CH CH3 3CH HCl O + Alletholone Alcohol Chrysanthemic Acid Chloride M. F :C H O 9 12 2 M. F : C H ClO 10 15 O Hydrochloric acid F. W : 152.19 F. W : 186.67 d-Trans Allethrin F. W.: 36.46 M. F : C 19 H26 O3 F. W : 302.40

CHEMICAL EQUATION:

C9H12 O2+ C 10 H15 ClO C 19 H26 O3+ HCl 1.0000 0.9952 0.9294

BRIEF PROCESS DESCRIPTION :

Charge Allethlone Alcohol, Pyridine and Tolune in room temperature. Add Chry. Acid Chloride slowly by maintaining temperature to 25°C under string. On completion, wash the unreacted content with HCL and make neutral by NaOH SOLUTION. Then transfer the mass to distillation. Distilled out solvent and get the product.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty Allethlone Alcohol 0.103 Organic Layer 0.782

Chry. Acid Reaction& Pyridine Chloride 0.126 Washing Hydrochloride 0.095 Toluene 0.590 Effluent 0.062

Sod. Hydroxide 0.004

Pyridine 0.072 HCL 0.044 Total 0.939 Distillation Total 0.939

Organic Recovered Layer 0.782 Solvent 0.531 Residue (Product) 0.192 Solvent Loss 0.059 Total 0.782 Total 0.782

Distillation Recovery of : Pyridine Pyridine Hydrochloride 0.095 Pyridine 0.081 Effluent 0.014 Total 0.095 0.095

Total outlet Byproduct Type Qty /Day Remark 0 0 Total

Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 4.58 Re-used for packing

PRODUCT NAME :d- Allethrin Technical

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.076 2 12 24 Insecticide

RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day Allethlone 1.0 Alcohol 0.041 Reactant 1.0 Organic Layer 0.309 Chry. Acid Pyridine 2.0 Chloride 0.050 Reactant 2.0 Hydrochloride 0.039 Sodium 3.0 Hydroxide 0.002 Washing 3.0 Effluent 0.024 4.0 Pyridine 0.029 Solvent 5.0 HCL 0.017 Washing 6.0 Toluene 0.233 Solvent Total 0.372 0.372

Distillation Recovered 1.00 Organic layer 0.309 1.00 Solvent 0.210 Residue 2.00 (Product) 0.076 3.00 Solvent Loss 0.023 Total 0.309 0.309

Distillation : Pyridine Recovery 2.00 Pyridine Hydrochloride 0.039 2.00 Pyridine 0.033 3.00 Effluent 0.006 Total 0.039 0.039

CHEMICAL FORMULAE : CH3 CH 3 O OH CH 3CH 3 Cl CH3 CH2 + CH3 CH2 3CH O O 3CH CH3 3CH HCl O + Alletholone Alcohol Chrysanthemic Acid Chloride M. F :C H O d-Allethrin Hydrochloric acid 9 12 2 M. F : C H ClO 10 15 M. F : C H O O F.W. 36.46 F. W : 152.19 F. W : 186.67 19 26 3 F. W::302.40

CHEMICAL EQUATION:

C9H12 O2+ C 10 H15 ClO C 19 H26 O3+ HCl 1.0000 0.9952 0.9294

BRIEF PROCESS DESCRIPTION :

Charge Allethlone Alcohol, Pyridine and Tolune in room temperature. Add Chry. Acid Chloride slowly by maintaining temperature to 25°C under string. On completion, wash the unreacted content with HCL and make neutral by NaOHsolution. Then transfer the mass to distillation. Distilled out solvent and get the product. FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty AllethloneAl cohol 0.041 Organic Layer 0.309

Chry. Acid Reaction& Pyridine Chloride 0.050 Washing Hydrochloride 0.039 Toluene 0.233 Effluent 0.024

Sod. Hydroxide 0.002 Pyridine 0.029 HCL 0.017 Total 0.372 Total 0.372

Organic Distillation Recovered Layer 0.309 Solvent 0.210 Residue (Product) 0.076 Solvent Loss 0.023

Total 0.309 Total 0.309 Distillation : Recovery of Pyridine

Pyridine Hydrochloide 0.039 Pyridine 0.033 Effluent 0.006 Total 0.039 0.039

Total outlet Byproduct Type Qty /Day Remark 0 0 Total Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 1.82 Re-used for packing

PRODUCT NAME :Prallethrin Technical

PRODUCT DETAILS :

For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.230 6 12 72 Insecticide

RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day Prallethlone 1.0 Alcohol 0.139 Reactant 1.0 Organic Layer 1.147 Chry. Acid Pyridine 2.0 Chloride 0.176 Reactant 2.0 Hydrochloride 0.131 3.0 Pyridine 0.097 Solvent 3.0 Sludge 0.060 4.0 Toluene 0.917 Solvent 4.0 Effluent 0.146 5.0 HCL 0.059 Washing Potassium 6.0 Carbonate 0.036 Washing 7.0 Activated Clay 0.060 Decolor Total 1.484 1.484

Distillation Recovered 1.00 Organic layer 1.147 1.00 Solvent 0.825 Residue 2.00 (Product) 0.230 3.00 Solvent Loss 0.092 Total 1.147 1.147 Distillation : Recovery of Pyridine Pyridine Hydrochloride 0.131 1.0 Pyridine 0.112 2.0 Effluent 0.019 Total 0.131 0.131

CHEMICAL FORMULAE : CH3 O 3CH CH3 CH O O 3 CH CH + Cl 3CH

OH CH3 + HCl CH3 Pralletholone Alcohol 3CH 3CH CH3 O M F : C 9H10 O2 F. W : 150.18 Chrysanthemic Acid Chloride O Prallethrin Hydrochloric acid M. F : C 10 H15 ClO M. F : C 19 H24 O3 F.W. 36.46 F. W: 186.67 F. W: 300.39

CHEMICAL EQUATION:

C9H10O2+ C 10 H15 ClO C 19 H24O3+HCl 1.0000 1.0189 0.8269

BRIEF PROCESS DESCRIPTION :

Charge Prallethlone Alcohol, Pyridine and Tolune in room temperature. Add Chry. Acid Chloride slowly by maintaining temperature to 25°C under string. On completion, wash the unreacted content with HCL and make neutral by NaOHsolution. Then transfer the mass to distillation. Distilled out solvent and get the product.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty Prallethlone Alcohol 0.139 Organic Layer 1.147

Chry. Acid Reaction& Pyridine Chloride 0.176 Washing Hydrochloride 0.131 Pyridine 0.097 Sludge 0.060 Toluene 0.917 Effluent 0.146

HCL 0.059 Potassium Carbonate 0.036 Activated Clay 0.060 Distillation Total 1.484 Total 1.484

Organic Recovered Layer 1.147 Solvent 0.825 Residue (Product) 0.230 Solvent Loss 0.092 Total 1.147 1.147 Total outlet Byproduct Type Qty /Day Remark 0 0 Total Solid Waste ( Sludge) 0.060 CHWTSDF 0.060 Empty Containers,Nos 6.3 Re-used for packing

PRODUCT NAME :Transfluthrin Technical

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.230 6 12 72 Insecticide

RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 2,3,5,6 TrtraFluro 1.0 Benzyl Alcohol 0.119 Reactant 1.0 Organic Layer 0.862 R-Cypermethric 2.0 Acid Chloride 0.156 Reactant 2.0 Sludge 0.012 3.0 Toluene 0.632 Solvent 3.0 Effluent 0.084 Sodium 4.0 Hydroxide 0.035 Washing 5.0 HCL 0.004 Washing Activated 6.0 Charcoal 0.012 Decolor Total 0.958 0.958

Distillation Recovered 1.00 Organic layer 0.862 1.00 Solvent 0.569 Residue 2.00 (Product) 0.230 3.00 Solvent Loss 0.063 Total 0.862 0.862

CHEMICAL FORMULAE :

OH F O O F

F Cl Cl F Cl O + + HCl Cl Cl F F 3CH CH3 3CH CH3 F F Cypermethric Acid Chloride Transfluthrin Hydrochloric acid Tetraflurobenzyl Alcohol M. F : C H Cl F O M. F : C 8H9Cl 3O 15 12 2 4 2 F.W. 36.46 M. F : C H F O 17 4 4 F. W : 227.52 F. W : 371.15 F. W : 180.09

CHEMICAL EQUATION:

C17 H4F4O+ C 8H9Cl 3O C 15H12 Cl 2F4O2+HCl 1.0000 1.0408 0.9391

BRIEF PROCESS DESCRIPTION :

Charge TertaFluoro Benzyl Alcohol with catalyst and Tolune in room temperature. Add R-Cypermethric Acid Chloride slowly and sodium hydroxide simultaneously by maintaining temperature to 16°C under string. On completion, wash the unreacted content with NaoH and water and make it neutral . Filter through activated charcoal and then transfer the mass to distillation. Distilled out solvent and get the product.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty 2,3,5,6 TrtraFluro Benzyl Alcohol 0.119 Organic Layer 0.862

R-Cypermethric Reaction& Acid Chloride 0.156 Washing Sludge 0.012 Toluene 0.632 Effluent 0.084 Sodium Hydroxide 0.035

HCL 0.004 Activated Charcoal 0.012 Total 0.958 Total 0.958 Distillation Recovered Organic Layer 0.862 Solvent 0.569 Residue (Product) 0.230 Solvent Loss 0.063 Total 0.862 0.862

Total outlet

Byproduct Type Qty /Day Remark 0 0 Total Solid Waste ( Sludge) 0.012 CHWTSDF 0.012 Empty Containers,Nos 5.5 Re-used for packing

PRODUCT NAME :Deltamethrin Technical

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.076 2 12 24 Insecticide

RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day M- PhenoxyBenzal 1.0 dehyde 0.042 Reactant 1.0 Organic Layer 0.286 Becisthemic 2.0 Acid Chloride 0.067 Reactant 2.0 Effluent 0.087 3.0 Toluene 0.210 Solvent 3.0 Sodium 4.0 Hypochloride 0.042 Washing 5.0 Sodium Cyanide 0.012 Reactant Total 0.373 0.373

Distillation Recovered 1.00 Organic layer 0.286 1.00 Solvent 0.189 Residue 2.00 (Product) 0.076 3.00 Solvent Loss 0.021 Total 0.286 0.286

CHEMICAL FORMULAE : 3CH CH3 Br

NaCN + O O Br O + Sodium Cyanide Cl meta-phenoxybenzaldehyde M. F: NaCN Becisthemic Acid Chloride F.W: 49.00 M. F: C H Br ClO Molecular Formula: C H O 8 9 2 13 10 2 F. W: 316.42 Formula Weight: 198.22

O N Br O + NaCl 3CH O CH3 Sodium chloride H F.W. 58.44

Deltamethrin

M. F: C 22 H19 Br 2NO 3 F. W: 505.20

CHEMICAL EQUATION:

C13 H10O2+ NaCN + C8H9Br 2ClO C 22 H19 Br 2NO3+ NaCl 1.0000 1.1838 1.0212 0.7161

BRIEF PROCESS DESCRIPTION :

Prepare solution of Sodium cyanide. Then add TBAC and dissolved in water. Charged m- phenoxybenzaldehyde and stir the mass. Start addition of DV Acid chloride and m-Phenoxybenzaldehyde simultaneously at 33°C .remove sample to check the reactant. Then transfer for work-up. After work up do the distillation to remove solvent.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty M- PhenoxyBenz

aldehyde 0.042 Reaction& Organic Layer 0.286 Becisthemic Washing Acid Chloride 0.067 Effluent 0.087 Toluene 0.210

Sodium Hypochloride 0.042 Sodium Cyanide 0.012 Total 0.373 Total 0.373 Distillation Recovered Organic Layer 0.286 Solvent 0.189 Residue (Product) 0.076 Solvent Loss 0.021 Total 0.286 Total 0.286

Total outlet

Byproduct Type Qty /Day Remark 0 0 Total

Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 0.54 Re-used for packing

PRODUCT NAME :Imidacloprid Technical

PRODUCT DETAILS :

For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.192 5 12 60 Insecticide

RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 2-Chloro 5 - Chloromethyl 1.0 Pyridine 0.146 Reactant 1.0 Organic Layer 1.012 NitroiminoImid 2.0 azolidene 0.129 Reactant 2.0 Effluent 0.133 Sodium 3.0 Hydroxide 0.038 Washing Dimethyl 4.0 Formamide 0.820 Solvent 5.0 HCl 0.012 Washing Total 1.145 1.145

Distillation & Filtration 1.00 Organic layer 1.012 1.00 Solvent 0.738 2.00 Product 0.192 3.00 Solvent Loss 0.082 Total 1.012 0.125

CHEMICAL FORMULAE : - O O Cl + + N O N N - N O + N NH NH + HCl Cl N NH Cl N 2-chloro-5-(chloromethyl)pyridine N -nitroimidazolidin-2-imine Imidacloprid Hydrochloric acid M. F: C 6H5Cl 2N M. F: C 3H6N4O2 F.W: 162.01 M. F: C 9H10 ClN 5O2 F .W. :36.46 F. W: 130.11 F. W: 255.66

CHEMICAL EQUATION:

C6H5Cl 2N+ C3H6N4O2C9H10 ClN5O2 + HCl 1.0000 0.9116 0.7564

BRIEF PROCESS DESCRIPTION :

Charge DMF and CCMP in adding tank. Add mixture of DMF and CCMP in a reactor and charge Nitroguanidine and DMF in the same reactor at temperature 65°C. Add NaOH . Filter the mass and send Nacl to ETP. Remove DMF AT 80°C. Again filter and get dry Imidacloprid.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty 2-Chloro 5 - Chloromethyl

Pyridine 0.146 Reaction& Organic Layer 1.012 NitroiminoImi Washing dazolidene 0.129 Effluent 0.133

Sodium Hydroxide 0.038 Dimethyl Formamide 0.820 HCl 0.012

Total 1.145 Distillation & Total 1.145 Filtration Organic Layer 1.012 Solvent 0.738 Product 0.192

Solvent Loss 0.082 Total 1.012 1.012

Total outlet

Byproduct Type Qty /Day Remark 0 0 Total

Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 1.37 Re-used for packing

PRODUCT NAME :Bifenthrin Technical

PRODUCT DETAILS :

For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.057 1.5 12 18 Insecticide

RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 2-Methyl -3- Biphenyl 1.0 Methanol 0.026 Reactant 1.0 Organic Layer 0.125 Cyhalothric 2.0 Acid Chloride 0.036 Reactant 2.0 Effluent 0.017 3.0 n-Hexane 0.068 Solvent Sodium 4.0 Bicarbonate 0.012 Washing Total 0.142 0.142

Distillation Recovered 1.00 Organic layer 0.125 1.00 Solvent 0.058 Residue 2.00 (Product) 0.057 3.00 Solvent Loss 0.010 Total 0.125 0.125

CHEMICAL FORMULAE :

F F CH3 F CH3 F

F F CH3 Cl + Cl O CH Cl 3

O OH CH 3 O HCl 3-(chloromethyl)-2-methylbiphenyl Z + 3-[(1 )-2-chloro-3,3,3-trifluoroprop-1-e CH3 M. F: C 14 H13 Cl n-1-yl]-2,2-dimethylcyclopropanecarb F. W: 216.71 oxylic acid Bifenthriin M. F: C H ClF O Hydrochloric acid 9 10 3 2 M. F: C 23 H22 ClF 3O2 F. W: 242.62 F. W: 422.87 F. W.:36.46

CHEMICAL EQUATION:

C14H13Cl+ C9H10 ClF3O2C23H22 ClF3O2 + HCl 1.0000 1.2570 1.1215

BRIEF PROCESS DESCRIPTION :

Charge Cyhalothric Acid Chloride in adding vessel . Take 2-Methyl Biphenyl Methanol in reactor alongwith n-Hexane. Start addition of Acid chloride from adding vessel. Stir for 3 hrs. Separate aqual layer and organic layer. Transfer organic layer for distillation. Distill the mass and remove n-haxane and send it for isomerization. Do work up and washing with 0.1 N HCL and water. Distill the product.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty 2-Methyl -3- Biphenyl

Methanol 0.026 Reaction& Organic Layer 0.125 Cyhalothric Washing Acid Chloride 0.036 Effluent 0.017 n-Hexane 0.068

Sodium Bicarbonate 0.012 Total 0.142 Total 0.142

Recovered Organic Layer 0.125 Distillation Solvent 0.058 Residue (Product) 0.057 Solvent Loss 0.010 Total 0.125 0.125

Total outlet Byproduct Type Qty /Day Remark 0 0 Total Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 0.31 Re-used for packing

PRODUCT NAME :Fipronil Technical

PRODUCT DETAILS :

For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.096 2.5 12 30 Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day Thiopyrazol 1.0 Alcohol 0.095 Reactant 1.0 Organic Layer 0.197 Trichloro Acetic 2.0 Acid 0.237 Reactant 2.0 Effluent 0.255 Mono Chloro 3.0 Benzene 0.101 Solvent 3.0 Hydrogen 4.0 Peroxide 0.018 Catalyst 5.0 Boric Acid 0.001 Washing Total 0.452 0.452

Filtration & Distillation Recovered 1.00 Organic layer 0.197 1.00 Solvent 0.091 Residue 2.00 (Product) 0.096 3.00 Solvent Loss 0.010 Total 0.197 0.197

CHEMICAL FORMULAE :

Cl N Cl N F N F N F N H F N O + + 2OH F S F S O Cl 2NH Cl 2NH F F F H O F F F 5-amino-1-[2,6-dichloro-4-(trifluorom Fipronil ethyl)phenyl]-4-[(trifluoromethyl)sulf Hydrogen Peroxide M. F: H O Water anyl]-4,5-dihydro-1 H-pyrazole-3-car 2 2 M. F: C 12 H4Cl 2F6N4OS bonitrile F. W : 34.01 F. W: 437.15 F.W:18.01

M. F: C 12 H4Cl 2F6N4S F. W: 421.15

CHEMICAL EQUATION:

C12 H4Cl 2F6N4S+ H2O2C12 H4Cl 2F6N4OS+ H 2O 1.0000 0.9952 0.9294

BRIEF PROCESS DESCRIPTION :

ChargeThiopyrazole in reactor with MCB. Then add TCAA and H2O2 and H3BO3 in intervals. Stir the .mass for 3 hours. Draw the sample and analyse and then send it for work up by adding water. Filter the mass by using ANF and get it in cake form. Send it for purification by MCB and Sod. Bicarbonate. Again filter by ANF. And do the steam distillation. Dry the mass in drier. Will get the dry Fipronil.. FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty Thiopyrazol Alcohol 0.095 Organic Layer 0.197

Reaction, Trichloro Washing & Acetic Acid 0.237 Effluent 0.255 Filtration Mono Chloro Benzene 0.101

Hydrogen Peroxide 0.018 Boric Acid 0.001 Total 0.452 Total 0.452

Organic Distillation Recovered Layer 0.197 Solvent 0.091 Residue (Product) 0.096 Solvent Loss 0.010 Total 0.197 Total 0.197

Total outlet

Byproduct Type Qty /Day Remark 0 0

Total

Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 2.16 Re-used for packing

PRODUCT NAME :Cypermethrin Technical

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.173 4.5 12 54 Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day M- PhenoxyBenzal 1.0 dehyde 0.086 Reactant 1.0 Organic Layer 0.341 Cypermethric 2.0 Acid Chloride 0.101 Reactant 2.0 Effluent 0.049 3.0 N-Hexane 0.168 Solvent 3.0 4.0 Sodium Cynide 0.025 Catalyst Sodium 5.0 Hydroxide 0.010 Washing Total 0.390 0.390

Distillation Recovered 1.00 Organic layer 0.341 1.00 Solvent 0.143 Residue 2.00 (Product) 0.173 3.00 Solvent Loss 0.025 Total 0.341 0.341

CHEMICAL FORMULAE : O CH3 N O Cl 3CH

Cl Cl + NaCN O O + O Cl Cl CH CH O Meta Phenoxy Benzaldehyde Sodium Cyanide 3 3 F. W : 49.00 Cypermethric Acid Chloride M. F : C 13 H10 O2 M. F :C H Cl O Cypermethrin F.W : 198.22 8 9 3 F. W : 227.52 M. F : C 22 H19 Cl 2NO 3 F. W : 416.30 + NaCl Sodium Chloride F. W .:58.44

CHEMICAL EQUATION:

C13 H10O2+ NaCN + C8H9Cl 3O C 22 H19 Cl2NO3+ NaCl 1.0000 1.2053 1.0310 0.9619

BRIEF PROCESS DESCRIPTION :

Raw Materials Qty Product Qty

M- PhenoxyBenz

aldehyde 0.086 Reaction& Organic Layer 0.341 Cypermethric Washing Acid Chloride 0.101 Effluent 0.049 N-Hexane 0.168 Sodium Cynide 0.025

Sodium Hydroxide 0.010 Total 0.390 Total 0.390

Distillation Recovered Organic Layer 0.341 Solvent 0.143 Residue (Product) 0.173 Solvent Loss 0.025 Total 0.341 Total 0.341

Total outlet

Byproduct Type Qty /Day Remark 0 0 Total

Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 1 Re-used for packing

PRODUCT NAME :Permethrin Technical

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.057 1.5 12 18 Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 2-Methyl -3- Biphenyl 1.0 Methanol 0.030 Reactant 1.0 Organic Layer 0.104 Cypermethric 2.0 Acid Chloride 0.034 Reactant 2.0 Effluent 0.007 3.0 n-Hexane 0.047 Solvent 3.0 Total 0.111 0.111

Distillation Recovered 1.00 Organic layer 0.104 1.00 Solvent 0.040 Residue 2.00 (Product) 0.057 3.00 Solvent Loss 0.007 Total 0.104 0.104

CHEMICAL FORMULAE :

3CH CH3 OH Cl Cl Cl O HCl + 3CH + O O CH3 O O Cl Cl Cypermethric Acid Chloride Meta Phenoxy Benzyl Alcohol Permethrin Hydrochloric acid M. F: C H Cl O 8 9 3 M. F: C 13 H12 O2 M F: C H Cl O F. W.: 36.46 F. W: 227.52 21 20 2 3 F. W: 200.23 F. W: 391.29

CHEMICAL EQUATION:

C13 H12O2+ C8H9Cl 3O C 21H20 Cl 2O3+ HCl 1.0000 1.0209 0.9854

BRIEF PROCESS DESCRIPTION :

Charge DV Acid Chloride in GLR and then add Metaphenoxybenzaldehyde and n-Hexane. Scrub the SO2 gases in scrubber. Separate out Aq. Layer and hexane layer. Send hexane layer for washing with water. Organic layer send for distillation. Remove solvent n-Hexane and get the product Permethrin.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty 2-Methyl -3- Biphenyl

Methanol 0.030 Reaction& Organic Layer 0.104 Cypermethric Washing Acid Chloride 0.034 Effluent 0.007 n-Hexane 0.047

Total 0.111 Total 0.111

Recovered Organic Layer 0.104 Solvent 0.040 Residue Distillation (Product) 0.057 Solvent Loss 0.007 Total 0.104 0.104

Total outlet

Byproduct Type Qty /Day Remark 0 0 Total

Solid Waste 0 CHWTSDF 0 Empty Containers ,Nos. 0.32 Re-used for packing

PRODUCT NAME : Diethyl Tolumide Technical ( DEET )

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.057 1.5 12 18 Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 3 Methyl 1.0 Benzoic Acid 0.047 Reactant 1.0 Organic Layer 0.068 2.0 Di-ethylamine 0.029 Reactant 2.0 Effluent 0.018 3.0 Toluene 0.002 Solvent Ortho 4.0 Phosphoric Acid 0.004 Catalyst Sodium 5.0 Hydroxide 0.004 Washing Total 0.086 0.086

Distillation 1.00 Organic layer 0.068 1.00 Solvent 0.009 2.00 Product 0.056 3.00 Solvent loss 0.003 Total 0.068 0.068

CHEMICAL FORMULAE : O O

OH 3CH NH CH3 N CH + 3

CH3 CH3 CH H O 3-methylbenzoic acid Di-ethylamine 3 + 2 Diethyl Tolumide M. F: C 8H8O2 M. F: C 4H11 N Water M. F: C 12 H17 NO F.W: 136.14 F. W 73.14 F. W: 18.01 F W: 191.27

CHEMICAL EQUATION:

C8H8O2+ C 4H11NC12H17 NO+ H2O 1.0000 1.1539 0.8631

BRIEF PROCESS DESCRIPTION :

Charge Meta Toluic Acid with di-ethyl Amine and Orthophosphoric acid and Toluene. Stir the mass . Take temperature to 100 – 110°C. Stir for 2 – 3 hrs and then cool the mass. Transfer organic layer to separator. Keep for settling for 2 – 3 hrs. Then distilled out at 120°C and get the product.. FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty 3 Methyl Benzoic

Acid 0.047 Reaction& Organic Layer 0.068 Di - Washing ethylamin e 0.029 Effluent/Water 0.018 Toluene 0.002

Ortho Phosphori c Acid 0.004 Sodium Hydroxide 0.004 Distillation Total 0.086 Total 0.086

Organic Layer 0.068 Solvent 0.009 Main Cut (Product) 0.056 Solvent loss 0.003 Total 0.068 0.068 Total outlet Byproduct Type Qty /Day Remark 0 0 Total Solid Waste 0 CHWTSDF 0 Empty Containers,Nos 0.15 Re-used for packing

PRODUCT NAME :Renofluthrin Technical

PRODUCT DETAILS :

For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.153 4 12 48 Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 1.0 W-52 Alcohol 0.085 Reactant 1.0 Organic Layer 0.605 Cypermethric 2.0 Acid Chloride 0.086 Reactant 2.0 Effluent 0.040 3.0 Toluene 0.452 Solvent Sodium 4.0 Hydroxide 0.019 Washing 5.0 HCL 0.003 Washing Total 0.645 0.645

Distillation Recovered 1.00 Organic layer 0.605 1.00 Solvent 0.407 Residue 2.00 (Product) 0.153 3.00 Solvent Loss 0.045 Total 0.605 0.605

CHEMICAL FORMULAE : CH3 O O O F

Cl Cl F F F Cl O

+ Cl Cl F CH CH ClH F F 3 3 + F O 3CH CH3 CH3 OH [2,3,5,6-tetrafluoro-4- Cypermethric acid (methoxymethyl)phen chloride Renofluthrin Hydrochloric acid yl]methanol F.W:36.46 M. F: C 17 H16 Cl 2F4O3 M. F: C H Cl O M. F:C 9H8F4O2 8 9 3 F. W: 415.21 F W: 227.52 F. W:224.15

CHEMICAL EQUATION:

C9H8F4O2+ C 8H9Cl 3O C 17H16Cl 2F4O3+HCl 1.0000 1.0000 0.9717

BRIEF PROCESS DESCRIPTION :

Charge W52 Alcohol with Toluene and Catalyst in a Reactor. Stir the mass. Charge Acid chloride in adding vessel and NaOH solution in another adding vessel. Start addition of DV Acid chloride and caustic solution simultaneously. maintain temperature at 17°C. on completion of reaction, send mass for washing and neutralization. Start distillation to remove solvent and receive product. FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty

W-52 Alcohol 0.085 Organic Layer 0.605

Cypermethric Reaction& Acid Chloride 0.086 Washing Effluent 0.040 Toluene 0.452

Sodium Hydroxide 0.019 HCL 0.003 Total 0.645 Total 0.645

Distillation Recovered Organic Layer 0.605 Solvent 0.407 Residue (Product) 0.153 Solvent Loss 0.045 Total 0.605 0.605

Total outlet

Byproduct Type Qty /Day Remark 0 0 Total Solid Waste 0 CHWTSDF 0 Empty Containers Nos 3.42 Re-used for packing

PRODUCT NAME :Dimefluthrin Technical

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Household Tech 0.115 3 12 36 Insecticide

RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Qty Sr. No. Name MT/Day Reaction Sr. No. outputs MT/Day 1.0 W-52 Alcohol 0.074 Reactant 1.0 Organic Layer 0.453 Chry. Acid Pyridine 2.0 Chloride 0.067 Reactant 2.0 Hydrochloride 0.064 3.0 Pyridine 0.051 Solvent 3.0 Effluent 0.069 4.0 Toluene 0.338 Solvent 5.0 HCL 0.031 Washing Potassium 6.0 Carbonate 0.025 Washing Total 0.586 0.586

Distillation

Recovered 1.00 Organic layer 0.453 1.00 Solvent 0.304 Residue 2.00 (Product) 0.115 3.00 Solvent Loss 0.034 Total 0.453 0.453 Distillation : Pyridine Recovery Pyridine Hydrochloride 0.064 Pyridine 0.055 Effluent 0.009 TOTAL 0.064 Total 0.064

CHEMICAL FORMULAE : CH3 O O O F CH 3 3CH F F F + Cl O CH3 CH F 3 CH CH ClH F F 3 3 + F O 3CH CH3 CH3 OH [2,3,5,6-tetrafluoro-4- Chrysanthamic (methoxymethyl)phen acid chloride Dimefluthrin Hydrochloric acid yl]methanol F.W:36.46 M. F: C 10 H15 ClO M. F: C H F O M. F:C H F O 19 22 4 3 9 8 4 2 F. W: 186.67 F. W: 374.36 F. W:224.15

CHEMICAL EQUATION:

C9H8F4O2+ C 10 H15 ClO C 19 H22F4O3+HCl 1.0000 1.00984 0.9340

BRIEF PROCESS DESCRIPTION :

Charge W52 Alcohol, Pyridine and Tolune in room temperature. Add Chry. Acid Chloride slowly by maintaining temperature to 25°C under string. On completion, wash the unreacted content with HCL and make neutral by NaOHsolution. Then transfer the mass to distillation. Distilled out solvent and get the product.

FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty W-52 Alcohol 0.074 Organic Layer 0.453

Chry. Acid Reaction& Pyridine Chloride 0.067 Washing Hydrochloride 0.064 Pyridine 0.051 Effluent 0.069

Toluene 0.338 HCL 0.031 Potassium Carbonate 0.025 Total 0.586 Total 0.586

Organic Distillation Recovered Layer 0.453 Solvent 0.304 Residue (Product) 0.115 Solvent Loss 0.034 Total 0.453 0.453

Total outlet

Byproduct Type Qty /Day Remark 0 0 Total Solid Waste 0 CHWTSDF 0 Empty Containers Nos 2.82 Re-used for packing

PRODUCT NAME :Chrysanthemic Acid Chloride

PRODUCT DETAILS :

For Grade MT/Day MT/Month Months MT/Year Application Tech 0.086 2.25 12 27 Household Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Sr. No. Name MT/Day Reaction Sr. No. outputs Qty MT/Day Chrysanthamic 1.0 Acid 0.078 Reactant 1.0 Organic Layer 0.145 2.0 N-Heptane 0.059 Solvent 2.0 HCl 0.020 3.0 Thionyl Chloride 0.060 Reactant Sod. Sulfite 0.032 Total 0.197 0.197

Distillation Recovered 1.00 Organic layer 0.145 1.0 Solvent 0.050 Residue 2.0 (Product) 0.086 3.0 Solvent Loss 0.009 Total 0.145 0.145 CHEMICAL FORMULAE : O O CH3 OH CH3 Cl 3CH 3CH + SOCl 2 + HCl Hydrochloric acid CH3 CH3 F. W.: 36.46 CH3 CH3 + Chrysanthemic Acid Chrysanthemic Acid Chloride Thionyl Chloride SO 2 M. F: C 10 H16 O2 M. F: C H ClO F. W: 118.98 10 15 Sulfur dioxide F.W: 168.23 F. W:186.67 F. W.: 64.08

CHEMICAL EQUATION:

C10 H16 O2+SOCl 2C10H15 Cl+HCl + SO 2 1.0000 1.1000 0.9914

BRIEF PROCESS DESCRIPTION :

Charge Chrysanthemic Acid in MSGLR. Add N-Heptane and stir the mass. Add slowly Thionyl Chloride under vacuum. Maintain temperature. Charge water in scrubber tank and NaOH solution in another scrubber tank for scrubbing off SO2 and HCL gases. Remove solvent by applying high vacuum and get the product, FLOW SHEET & MASS BALANCE :

Raw Materials Qty Product Qty Chrysantha mic Acid 0.078 Organic Layer 0.145

Reaction& N-Heptane 0.059 Washing HCl 0.020 Thionyl Chloride 0.060 Sod. Sulfite 0.032

Total 0.197 Total 0.197

Organic Recovered Layer 0.145 Solvent 0.050

Distillation Residue (Product) 0.086 Solvent Loss 0.009 Total 0.145 0.145

Total outlet

Byproduct Type Qty /Day Remark HCl Liq. 0.020 Sod. Sulphite Liquid 0.032 Total Solid Waste 0 CHWTSDF 0 Empty Containers Nos 1 Re-used for packing

PRODUCT NAME : R-Cypermethric Acid Chloride

PRODUCT DETAILS :

For Grade MT/Day MT/Month Months MT/Year Application Tech 0.153 4 12 48 Household Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Sr. No. Name MT/Day Reaction Sr. No. outputs Qty MT/Day Cypermethric 1.0 Acid 0.448 Reactant 1.0 Organic Layer 1.574 2.0 Ephidrine 0.344 Reactant 2.0 HCl 0.032 3.0 Caustic flakes 0.086 Sod. Sulfite 0.050 4.0 EDC 1.015 Effluent 0.680 5.0 MDC 0.418 SCMA 0.307 6.0 HCl 0.238 Thionyl 7.0 Chloride 0.094

Total 2.643 2.643

Filtration & Distillation 1.00 Organic layer 1.574 1.0 Filtrate EDC 0.862 Residue 2.0 (Product) 0.153 3.0 MDC 0.250 4.0 Solvent Loss 0.309 Total 1.574 1.574

CHEMICAL FORMULAE : O O Cl O OH Cl Cl + S Cl ClH Cl Cl Cl + 3CH CH3 H3C CH3 Thionyl Cypermethric Cypermethric Acid Hydrochloric acid Chloride Chloride Acid F.W :36.46 M.F : C 8H9Cl 3O M.F: C H Cl O M. F: Cl 2OS 8 10 2 2 F. W: 227.52 F. W: 209.08 F.W : 118.98 +

SO 2 Sulfur dioxide F .W :64.08

CHEMICAL EQUATION:

C8H10 Cl 2O2+SOCl 2C8H9Cl 3O+ HCl + SO 2 1.0000 0.3698 0.3136

BRIEF PROCESS DESCRIPTION :

Reaction, Crystalisation Raw & Filtration Materials Qty Product Qty Cypermethri c Acid 0.448 Organic Layer 1.574

Ephidrine 0.344 Distillation HCl 0.032 Caustic flakes 0.086 Sod. Sulphite 0.050 EDC 1.015 Effluent 0.680 MDC 0.418 SCMA 0.307 HCl 0.238 Thionyl Chloride 0.094 Total 2.643 Total 2.643

Organic Layer 1.574 Filtrate EDC 0.862 Residue (Product) 0.153 MDC 0.250 Solvent Loss 0.309 Total 1.574 1.574

Total outlet

Byproduct Type Qty /Day Remark HCl Liquid 0.032 Sod. Sulph. Liquid 0.050 SCMA Solid 0.307 Total Solid Waste 0 CHWTSDF 0 Empty Containers,Nos 9.87 Re-used for packing

PRODUCT NAME : Cypermethric Acid Chloride

PRODUCT DETAILS : For Grade MT/Day MT/Month Months MT/Year Application Tech 0.230 6 12 72 Household Insecticide RAW MATERIALS : Input output data per day. Reaction& Washing INPUTS OUTPUTS Role in Name of Sr. No. Name MT/Day Reaction Sr. No. outputs Qty MT/Day Cypermethric 1.0 Acid 0.211 Reactant 1.0 Organic Layer 0.231 2.0 Thionyl Chloride 0.132 Reactant 2.0 HCl 0.043 Sod. Sulphite 0.069 Total 0.343 0.343

Distillation 1.00 Organic layer 0.231 1.0 Excess TC 0.001 Residue 2.0 (Product) 0.230

Total 0.231 0.231 CHEMICAL FORMULAE : O O Cl O OH Cl Cl + S Cl ClH Cl Cl Cl + 3CH CH3 H3C CH3 Thionyl Cypermethric Cypermethric Acid Hydrochloric acid Chloride Chloride Acid F.W :36.46 M.F : C 8H9Cl 3O M.F: C H Cl O M. F: Cl 2OS 8 10 2 2 F. W: 227.52 F. W: 209.08 F.W : 118.98 +

SO 2 Sulfur dioxide F .W :64.08

CHEMICAL EQUATION:

C8H10 Cl 2O2+SOCl 2C8H9Cl 3O+ HCl + SO 2 1.0000 1.1000 1.0000

BRIEF PROCESS DESCRIPTION :

Raw Materials Qty Product Qty Cypermethri c Acid 0.211 Reaction& Organic Layer 0.231

Thionyl Washing Chloride 0.132 HCl 0.043 Sod. Sulphite 0.069

Total 0.343 Total 0.343

Organic 0.231 Distillation Excess TC 0.001

Layer Residue (Product) 0.230

Total 0.231 0.231

Total outlet

Byproduct Type Qty /Day Remark HCl Liquid 0.043 Sod. Sulphite Liquid 0.069 Total Solid Waste 0 CHWTSDF 0 Empty Containers,Nos 1.7 Re-used for packing

B.U.Area Calculations & Statement FORM-I S.NO. PARTICULARS OF BLDG. SIZE OF AREA HT. F.S.I BLDG.(M) (PLINTH) FACTOR CONSUMED A Area Statement Sq. Meters A BUILT UP AREA 1 PLANT-1 50.10 X 20.0 1002.00SQ.M. 2 2004.00 (FINISHED PRODUCTS) 1 AREA OF THE PLOT 106384.00 2 PERMISSIBLE F.S.I. 0.70 P C C COPING BARBED WIRES 2 STORAGE SHED 44.0 X 17.0 748.00SQ.M. 1.5 1122.00 M S ENT GATE 3 PERMISSIBLE B.U.AREA 74468.80 1.52M 3 COOLING TOWER 4.0 X 4.0 16.00SQ.M. 1 16.00 4 PERMISSIBLE B.U.AREA ON GROUND FLOOR 37234.40 4 PLANT-2 50.3 X 22.0 1106.60SQ.M. 2 2213.20 5 TOTAL PROPOSED BUILT UP AREA 9048.82 1.65M

900 DIA RCC HUME PIPE 0.12 5 FIRE HYD. PUMP RM 6.75 X 10 67.50SQ.M. 1.5 101.25 6 F.S.I. CONSUMED (w.r.t.permissible FSI) U C R 65384.59 SLOPE 7 BALANCE AREA OF THE PLOT ROAD 6 U.G.TANK 50.3 X 5.5 276.65SQ.M. 1 276.65 1:3: 6 P C C BED U C R 5880.28 RUBBLE SOILING 900 0 HUME PIPE 8 PROPOSED B.U.AREA ON GR. FLOOR RUBBLE MASONARY 7 PLANT-3 (INTERMEDIATE) 13.2.X 24.0 316.80SQ.M. 2 633.60 1:3: 6 P C C BED SECTION THRO. COMP. WALL(THREE SIDES) RUBBLE SOILING 8 O.H.TANK 3.0 M DIA 7.07SQ.M. 1 7.07 SCALE 1:50 SECTION OF C. WALL AT ENT. GATE 9 PLANT-4 10.0 X 20.1 201.00SQ.M. 1.5 301.50 SCALE 1:50 (UTILITY/BOILER ROOM) 10 BOILER CHIMNEY 5.0 X 3.0 15.00SQ.M. 1 15.00 11 PLANT-5 (COOLING TOWER ) 7.75 X 5.0 38.75SQ.M. 1.5 58.13 FORM-II 12 LAB(PLANT 6) 11.6 X 15.3 177.48SQ.M. 1.5 266.22 Contents of Sheet 3.55 X 15.3 54.32SQ.M. 1.5 81.48

13 R & D CENTRE (PLANT 7) 6.5 X 15.3 99.45SQ.M. 1.5 149.18 PROPOSED FACTORY LAYOUT

P C C COPING 14 W.STORAGE TANK 14.5 X 4.5 65.25SQ.M. 1 65.25 0.15M

R C C JALI 15 WATCHMAN CABIN/CHG. 3.0 X 4.0 28.00SQ.M. 1 28.00 100 MM THK PCC 1:2:4 ROOM 4.0 X 4.0 0.74M 230mm THK. EXT.BRICK WALL Stamp of Date Of Receipt of Plans 1.65M G.L 0.75M WITH U.C.R. FOUNDATION 16 TRANSFORMER 19.0 X 9.5 180.50SQ.M. 1 180.50 0.230 THK BK WALL 17 D.G.ROOM 9.5 X 6.5 61.75SQ.M. 1.5 92.63 0.61M G.L 900 DIA. HUME PIPE SECTION OF PLATFORM FOR TRANSFORMER scale 1:200 1.50M 8.0M 18 POWER HOUSE 9.50 X 4.0 38.00SQ.M. 1.5 57.00 (SIZE 19.00 X 9.5 M) RUBBLE FOUNDATION 19 EFFLUENT TREATMENT PLANT 25 X 40.0 1000.00SQ.M. 1 1000.00

P C C BED 20 TOI.BLOCK 6.1 X 2.1 12.81SQ.M. 1 12.81

SECTION THRO. COMP. WALL(ROAD SIDE) 9.50M 21 CANTEEN 7.0 X 4.0 28.00SQ.M. 1 28.00

SCALE 1:50 22 O.H.TANK 4.0 X 4.0 16.00SQ.M. 1 16.00 Stamp of Date Of Approval of Plans 23 TOI.(W.M.) 1.65 X 1.65 2.72SQ.M. 1 2.72

24 LOADING PLATFORM 42.75 X 7.5 320.63SQ.M. 1 320.63

25 BUILDING SHED AREA (PROP.) 35 X 20 700.00 SQ.M 1.5 1050.00

26 BUILDING SHED AREA (PROP.) 35 X 30 1050.00 SQ.M 1.5 1575.00

PLOT NO. D-17 (PEARL POLYMERS LTD.) 27 BUILDING SHED AREA (PROP.) 20 X 25 500.00 SQ.M 1.5 750.00 440.00M

TOTAL B.U.AREA 8130.28SQ.M. 12423.82SQ.M. NO. DATE REVISION DESCRIPTION G R E E N B E L T (PROPOSED) 10.00M 1 6.1.15 R1 8.0 M INT. ROAD NEAR STORAGE SHED & GREEN BELT

10.00M 2 9.1.15 R2 PROP. & EXTG. STRUCTURES INDICATED. B.U.A. REV. EXISTING CONSTRUCTION :- Certificate of Area PROPOSED CONSTRUCTION :- CERTIFIED THAT I HAVE SURVEYED THE PLOT UNDER REFERENCE ON 10.4.2010 AND THAT THE DIMENSIONS OF THE SIDES ETC. OF THE PLOT 900 MM DIA R .C.C. HUME PIPE HUME .C.C. R DIA MM 900 F U T U R E E X P A N S I O N STATED ON THE PLAN ARE AS MEASURED ON THE SITE AND THE AREA SO WORKED OUT IS 106384.00 SQ.M.(ONE LAC SIX THOUSAND THREE HUNDRED STATEMENT: AND EIGHTY FOUR SQ.MTS.)AND TALLIES WITH THE AREA STATED IN THE PARKING AREA DOCUMENT OF OWNERSHIP/TOWN STATED IN THE DOCUMENT OF PARKING AREA PROPOSED = 10638.40 SQ.M OWNERSHIP/TOWN PLANNING SCHEME RECORDS

GREEN BELT AREA = 18989.5 SQ.M G R E E N B E L T (PROPOSED) T L E B N E E R G PLANT 7 (EXTG.) PLANT 6 AR.G.R.KAMATH (CA/93/15699) (LAB) (R & D) PARKING AREA SIGNATURE OF THE ARCHITECT TOI.BLOCK (PROP.) (EXTG.) 21.65 X 15.30 M 6.1 X 2.1M PATH : MY DRAWINGS/SHOGUN_KURKUMBH/APPROVAL PLANS L A W N PARKING AREA PARKING AREA Description of Proposal & Property

GATE MAIN ENTRY 8.00 M W I D E INT. MAIN ACCESS ROAD M/S AMINEX CHEMICALS LTD. PROPOSED FACTORY BUILDING ON PLOT BEARING TO PLOT 264.50M 3.0M 4.0M TRUCK PARKING NO. D-18 AT M.I.D.C. KURKUMBH INDUSTRIAL AREA,

248.50M 4.0M 4.0M 9.0 M 9.0 M W.CABIN/ CHG. RM. (EXTG.) W.TANK (EXTG.) 9.0M

10.0M 9.0M PUNE 14.5 X 4.5 M 6.0M O.H.TANK 9.0M PLANT 2 (EXTG.) 6.50M 4.0 X 4.0 M 6.0M PROPOSED RAIN WATER PIT P L O T D - 17 11.10M (PROP.) BUILDING SHED 50.3 X 22.0 M 11.2M TOI. C.TOWER 440.00M 1.65 X 1.65M 7.75 X 5.0M (PROP.) CANTEEN 7 PLANT 4 (EXTG.) 7.0 X 4.0 M L A W N 50.3 X 5.5 M 10.0M Name of the Owner 25000 U G TANK 9.0 M (UTILITY/BOILER) (EXTG.) 20000 UNLOADING PLATFORM TRUCK PARKING FIRE HYD.PUMP 7.0M 6.75 X10.0 M 10.0 X 20.10 M F U T U R E E X P A N S I O N

(PROP.) 6.5M 25.0M M/S SHOGUN ORGANICS LTD 4.0M BOILER CHIMNEY (PROP.) 5.0 X 3.0M

M. I. D. C. R O A D A O R C. D. I. M. 8.00 M W I D E INT. ROAD

8.00M O.H.TANK (PROP.) P L O T D - 18 ALL DESIGN SPECIFICATIONS AND THEIR COPYRIGHT ARE THE PROPERTY OF M/S C.TOWER(PROP.) 3.0 M DIA.

4.0 X 4.0 M 19.10M GANESH KAMATH & ASSOCIATES & CANNOT BE USED WITHOUT THEIR 6.50M 106384.00 SQ.M. 6.25M (EXTG.) 30000 20000 (EXTG.) 4.20M PLANT 1(EXTG.) 7.0M EFFLUENT WRITTEN PERMISSION 9.50 M 264.50M 6 POWER 9.0 M TREATMENT 248.50M L A W N (FINISHED PRODUCT) 9.0M 9.0M 123.83M HOUSE

5 40.0M R O A D A O R PROPOSED PROPOSED 9.50 X 4.0 M 4.0 M PLANT 3 PLANT 35191 35191 50.1 X 20.0 M BUILDING SHED 10.2M (EXTG.) D.G. PROPOSED 9.50 X 6.50 M (INTERMEDIATE) Owner's Name & Signature BUILDING SHED 6.50 M 9.50 M 16.0 M 25.0 X 40.0M (EXTG.) 13.2 X 24.00 M

8.00 M W I D E INT. ROAD 8.00 M W I D E STORAGE SHED 44.0 X 17.0 M 6.00 M W I D E INT. ROAD GREEN BELT (30 M. WIDE) 8.00 M W I D E INT. ROAD 8.00 M WIDE INT. ROAD 8.00 M W I D E INT. ROAD (EXTG.) 8.00 M W I D E INT. ROAD PUNE SOLAPUR ROAD 9.50 M 410.00M GATE 30.00 M W I D E G R E E N B E L T (PROPOSED)

30.00M BLOCK PLAN scale 1:4000

19.0 M 30.00 M W I D E G R E E N B E L T (EXISTING)

FORMER DATE DRAWN BY TRANS- 19.00 X 9.5 M M/S FIBRE BOARD PVT. LTD. GANESH KAMATH & ASSOCIATES 14.8.14 R.V./G.K. 248.28M ARCHITECTS 410.00M NOTES & BRIEF SPECIFICATIONS : SCALE DEALT N FOUNDATION UP TO HARD STRATA ,R.C.C. FRAME STRUCTURE,0.23M & AS SHOWN G.K. TO P U N E P U N E --- S O L A P U R R O A D TO S O L A P U R THK. EXTERNAL WALL WITH SAND FACED PLASTER EXTERNALLY, INTERIOR DESIGNERS INTERNALLY SMOOTH PLASTER, TILE FLOORING,M.S.TRUSS FOR ROOFS DRG.NO. WITH P.V.C. SHEET ROOFING (SLOPING), B.B.C.,W.P. TREATMENT TO F-402,DHEERAJ DARSHAN CHS,OPP. KOKAN M1/R1/R2 HOSPITAL,NEAR MHADA COLONY,SHIVNERI TERRACE & TOI. & FLAT SLABS VASAHAT ROAD,JOGESHWARI(E),MUM-60 PROPOSED LAYOUT scale 1:1000 JOB NO. G.R.KAMATH ARCHITECT TEL:022 28321705(O),9320077970 CA/93/15699

FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT (ZERO LIQUID DISCHARGE) CH. OUT

Inlet Effluent From Plant 10 M2 Receiving C. OUT Tank Aeration RCC Tank 12KL 2KL 15M2 CH. IN VACUUM

C. IN Stainer Pump SS/FRP SS/FRP Steam SS Reactor RECEIVER RECEIVER Cooling Out 6KL 3 KL 1 KL

C. In TRAP

CHARCOL SAND BED BED WATER EFFLUENT Centrifuge

SLUDGE TANK FOR INCINARTION C. R. FILTER CLEAR WATER FILTRATE FILTRATE FOR REUSE TANK TANK TREATED 2.5 KL 2.5 KL CLEARED WATER SHOGUN ORGANICS LTD. TANK PLOT NO. D-18, MIDC, KURKUMBH, PUMP RCC TAL. DAUND, DISTT. - PUNE- 413802 12 KL