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Adsorption of Analcime and Zsm-5 on Metals
1 Wang Yuxian ADSORPTION OF ANALCIME AND ZSM-5 ON METALS Thesis CENTRAL OSTROBOTHNIA UNIVERSITY OF APPLIED SCIENCES Degree Programme in Chemistry and Technology December 2011 2 ABSTRACT CENTRAL OSTROBOTHNIA Date Author UNIVERSITY OF APPLIED SCIENCES Technology and Business December 2011 Yuxian Wang Degree programme Chemistry and Technology Name of thesis ADSORPTION OF ANALCIME AND ZSM-5 ON METALS Instructor Pages Laura Rahikka 44 + Appendices (2) Supervisor Laura Rahikka and Maija Rukajärvi-Saarela Natural zeolite with the basic cell structure of AlO4 and SiO4 tetrahedron has the ability of sewage purification. The way to adsorb in sewage is similar to activated carbon, and the zeolite has a good capacity of adsorption on cations. After modification, the activated zeolite acquires a better capacity of adsorption, cation-exchange and ion-exchange. After surfactant modification, zeolite can absorb the anions and organic compounds. In this way, zeolite can adsorb many kinds of ions in sewage. The aims of the thesis were: study the properties of natural zeolites; the adsorption capacity of analcime and ZSM-5 on metals and the theory of modification. In the experiment, the aim was to check out the adsorption capacity of Cu2+ and Ni2+ by using analcime and ZSM-5 and make a compare of the adsorption capacity between the cations in the same zeolite and between the zeolites in the same cations to find out which zeolite is better and in the same zeolite which cation was better adsorbed. The results of the experiment were that the Cu2+ cation was adsorbed better than Ni2+ in both analcime and ZSM-5. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
List of New Mineral Names: with an Index of Authors
415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis. -
Studies of the Zeolites Composition of Zeolites of the Natrolite Group and Compositional Relations Among Thomsonites Gonnardites, and Natrolites
r-'1 ~ Q I ~ c lt') ~ r-'1 'JJ ~ Q.) < ~ ~ ......-~ ..,.;;j ~ <z 0 0 Q.) 1-4 rJ:J rJ:J N r-'1 ~ Q.) 0 ~ ..c ~ ~ ~ I r-'1 ~ > ~ 0 I ~ rJ:J 'JJ ..,.;;j Q.) < .....-~ 0 . 1-4 ~ C"-' 0 ~ ..,.;;j ~ 0 r-'1 00 C"-' Foster-STUDIES•. OF THE ZEOLITES-Geological Survey Professional Paper 504-D, E Studies of the Zeolites Composition of Zeolites of the Natrolite Group and Compositional Relations among Thomsonites Gonnardites, and Natrolites By MARGARET D. FOSTER SHORTER CONTRIBUTIONS TO GENERAL GEOLOGY GEOLOGICAL SURVEY PROFESSIONAL PAPER 504-D, E UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON 1965 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretory GEOLOGICAL SURVEY Thomas B. Nolan, Director The U.S. Geological Survey Library has cataloged this publication as follows: Foster, Margaret Dorothy, 1895- Studies of the zeolites. D. Composition of zeolites of the natrolite group. E. Compositional relations among thom sonites, gonnardites, and natrolites. Washington, U.S. Govt. Print. Off., 1965. v, 7; iii, 10 p. diagrs., tables. 30 em. (U.S. Geological Survey. Professional paper 504-D, E) Shorter contributions to general geology. Each part also has separate title page. Includes bibliographies. (Continued on next card) Foster, Margaret Dorothy, 1895- Studies of the zeolites. 1965. (Card 2) 1. Zeolites. I. Title. II. Title: Composition of zeolites of the natro lite group. III. Title: Compositional relations among thomsonites, gonnardites, and natrolites. (Series) For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 - Price 25 cents (paper cover) Studies of the Zeolites Composition of Zeolites of the N atrolite Group By MARGARET D. -
Lii Foi - Ifil Rhkl = ---'--'---'---'--'-' = 0.15
Mineral. Soc. Amer. Spec. Pap. 2, 111-115 (1969). JOESMITHITE: A NOVEL AMPHIBOLE CRYSTAL CHEMISTRY PAUL B. MOORE Department oj the Geophysical Sciences, University oj Chicago, Chicago, Illinois 60637 ABSTRACT Joesmithite, a 9.885 (15), b 17.875 (18), c 5.227 (5) A, B 105.67 (17)0, P2/a, is a beryllo-silicate clinoamphibole 3 with composition (Ca,Pb)Ca2(Mg,Fe'+,Fe +),[Si,Be20,,] (OH)2, Z = 2. One out of four tetrahedra in the asymmetric unit is occupied by beryllium, at the cross-linking site in one of the pyroxene chain sub-units. The A site is not centered but displaced 0.6 A along the two-fold rotor and toward the beryllate tetrahedron. It is suggested that a coupled relationship exists between A' (the off-centered A site) and Be, a condition ensuring reasonable charge balance around their mutual anions. The A' and Be atomic species lower the symmetry of the crystal: though joesmithite is topologically akin to the C-centered c1inoamphiboles, its chemical contents are somewhat different. The lower symmetry induced by these atomic species probably accounts for the unequal octahedral cation distribution, which was assessed by least-squares analysis of three-dimensional single-crystal X-ray data. INTRODUCTION TABLE 1. JOESMITHITE. CRYSTAL CELL Joesmithite, a new mineral discovered by the author three years ago, proved to be related to the clinoamphibole a 9.885(15) A b mineral group. This mineral has been previously reported 17.875(18) 5.227(5) in two papers, one which describes the species for the first (3 105. -
The Challenges of Li Determination in Minerals: a Comparison of Stoichiometrically Determined Li by EPMA with Direct Measurement by LA-ICP-MS and Handheld LIBS
The challenges of Li determination in minerals: A comparison of stoichiometrically determined Li by EPMA with direct measurement by LA-ICP-MS and handheld LIBS Robin Armstrong (NHM) THE TEAM & ACKNOWLEDGEMENTS • This work was carried out as part of the WP2 of the FAME project • The “analysts”: John Spratt & Yannick Buret (NHM) and Andrew Somers (SciAps) • The “mineralogists”: Fernando Noronha &Violeta Ramos (UP), Mario Machado Leite (LNEG), Jens Anderson, Beth Simmons & Gavyn Rollinson (CSM), Chris Stanley, Alla Dolgopolova, Reimar Seltmann & Mike Rumsey* (NHM) • Literature mineral data is taken from Mindat, Webmineral and DHZ • Robin Armstrong ([email protected]) INTRODUCTION • The analytical problems of Li • Whole Rock analysis (WR) • Examples and is it safe to make mineralogical assumptions on the base of WR • Li Mineral analysis • Li-minerals overview • Li-minerals examined • EPMA • LA-ICP-MS • LIBS • Summary and thoughts for the future LITHIUM ORES ARE POTENTIALLY COMPLEX 50mm • Li-bearing phases identified: • Lepidolite, Amblygonite-Montebrasite Li = 1.17 wt% group, Lithiophosphate(tr) and Petalite WHOLE ROCK ANALYSIS (Li ASSAYS) • Li is not that straight forward to analyse in whole rock • Its low mass means that there are low fluorescence yields and long wave-length characteristic radiation rule out lab-based XRF and pXRF • We cannot use conventional fluxes as these are generally Li- based • We can use “older” non Li fluxes such as Na2O2 but then there maybe contamination issues in the instruments • We can use multi-acid digests (HF+HNO3+HClO4 digestion with HCl-leach) (FAME used the ALS ME-MS61) however there may still be contamination issues and potentially incomplete digestion. -
Gonnardite Na2caal4si6o20 ² 7H2O C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Tetragonal
Gonnardite Na2CaAl4Si6O20 ² 7H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Tetragonal. Point Group: 42m: Fibrous crystals, at the centers of radiating spherulites, to 3 cm; massive. Physical Properties: Hardness = 5 D(meas.) = 2.25{2.36 D(calc.) = 2.33 Optical Properties: Translucent. Color: White, yellowish to salmon-red. Luster: Silky. Optical Class: Biaxial (+) or ({); commonly zoned. Orientation: X = c. ® = 1.497{1.508 ¯ = 1.498{1.510 ° = 1.499{1.513 2V(meas.) = 50± Cell Data: Space Group: I42d: a = 13.21(1) c = 6.622(4) Z = 2 X-ray Powder Pattern: Chaux de Bergonne, France; may be confused with natrolite and tetranatrolite. 2.92 (100), 5.93 (80), 6.70 (60), 4.44 (60), 4.74 (50), 3.23 (50), 3.12 (40) Chemistry: (1) (2) (3) SiO2 43.45 43.20 44.58 Al2O3 27.91 27.90 25.22 CaO 6.95 3.61 6.94 Na2O 8.69 13.16 7.66 H2O [13.00] 11.74 15.60 Total [100.00] 99.61 100.00 (1) Chaux de Bergonne, France; by electron microprobe, H2O by di®erence; corresponding to Na2:22Ca0:98Al4:32Si5:71O20 ² 5:70H2O: (2) Aci Trezza, Sicily, Italy; corresponds to Na3:5Ca0:5Al4:5 Si5:9O20:8 ² 5:35H2O: (3) Na2CaAl4Si6O20 ² 7H2O: Mineral Group: Zeolite group. Occurrence: In cavities in basalt, leucite tephrite, and altered skarn. Association: Zeolites, calcite. Distribution: Well characterized material from: in France, at Chaux de Bergonne, Gignat, Puy de D^ome. In Italy, from Capo di Bove, near Rome, Lazio; and at Aci Castello, Aci Trezza, Osilo, and other places on Sardinia. -
Mineral Collecting Sites in North Carolina by W
.'.' .., Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie RUTILE GUMMITE IN GARNET RUBY CORUNDUM GOLD TORBERNITE GARNET IN MICA ANATASE RUTILE AJTUNITE AND TORBERNITE THULITE AND PYRITE MONAZITE EMERALD CUPRITE SMOKY QUARTZ ZIRCON TORBERNITE ~/ UBRAR'l USE ONLV ,~O NOT REMOVE. fROM LIBRARY N. C. GEOLOGICAL SUHVEY Information Circular 24 Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie Raleigh 1978 Second Printing 1980. Additional copies of this publication may be obtained from: North CarOlina Department of Natural Resources and Community Development Geological Survey Section P. O. Box 27687 ~ Raleigh. N. C. 27611 1823 --~- GEOLOGICAL SURVEY SECTION The Geological Survey Section shall, by law"...make such exami nation, survey, and mapping of the geology, mineralogy, and topo graphy of the state, including their industrial and economic utilization as it may consider necessary." In carrying out its duties under this law, the section promotes the wise conservation and use of mineral resources by industry, commerce, agriculture, and other governmental agencies for the general welfare of the citizens of North Carolina. The Section conducts a number of basic and applied research projects in environmental resource planning, mineral resource explora tion, mineral statistics, and systematic geologic mapping. Services constitute a major portion ofthe Sections's activities and include identi fying rock and mineral samples submitted by the citizens of the state and providing consulting services and specially prepared reports to other agencies that require geological information. The Geological Survey Section publishes results of research in a series of Bulletins, Economic Papers, Information Circulars, Educa tional Series, Geologic Maps, and Special Publications. -
Minerals of the Eudialyte Group from the Sagasen Larvikite Quarry, Porsgrunn, Norway
= Minerals of the eudialyte group from the Sagasen larvikite quarry, Porsgrunn, Norway Alf Olav Larsen, Arne Asheim and Robert A. Gault Introduction Eudialyte, aNa-rich zirconosilicate with varying amounts of Ca, Fe, Mn, REE, Nb, K, Y, Ti, CI and F, was first described from the llimaussaq alkaline complex, South Greenland by Stromeyer (1819), Since then, the mineral has been described from many other alkaline deposits, and is a characteristic mineral in agpaitic nepheline syenites and their associated pegmatites. In recent years, eudialyte (sensa lata) has been the subject of extensive studies. The broad compositional variations and new insight into the crystal chemistry of the mineral group resulted in the definition of several new species by the Eudialyte Nomenclature Subcommittee under the Commission on New Minerals and Mineral Names of the International Mineralogical Association (Johnsen et al. 2003b). Brown eudialyte (s. I.) is a common constituent of the agpaitic pegmatites in the Langesundsfjord district in the western part of the Larvik plutonic complex (Br0gger 1890). Recent chemical analyses of the mineral have shown that some localities contain ferrokentbrooksite (Johnsen et al. 2003a). Other localities hold eudialyte (sensa stricto). Ferrokentbrooksite is the ferrous-iron-dominant analogue of kentbrooksite with Fe as the predominant element replacing Mn. Kentbrooksite is the Mn-REE-Nb-F end member in a solid solution series between eudialyte (s. s.) and ferrokentbrooksite, with an extension to oneillite (Johnsen et al. 1998, Johnsen et al. 1999, Johnsen et al. 2003a), as well as to carbokentbrooksite and zirsilite-(Ce) (Khomyakov et al. 2003). Carbokentbrooksite has a significant content of carbonate and Na > REE for the N4 site, while zirsilite-(Ce) has REE > Na (with Ce predominant) for the N4 site. -
Use of Local Minerals in the Treatment of Radioactive Waste
O = 0(0H) •=Si(AI) O = 0(0H) # = AI, Mg, Fe, etc. TECHNICAL REPORTS SERIES No. 136 Use of Local Minerals in the Treatment of Radioactive Waste INTERNATIONAL ATOMIC ENERGY AGENCY, VIENNA, 1972 USE OF LOCAL MINERALS IN THE TREATMENT OF RADIOACTIVE WASTE The following States are Members of the International Atomic Energy Agency: AFGHANISTAN GUATEMALA PAKISTAN ALBANIA HAITI PANAMA ALGERIA HOLY SEE PARAGUAY ARGENTINA HUNGARY PERU AUSTRALIA ICELAND PHILIPPINES AUSTRIA INDIA POLAND BELGIUM INDONESIA PORTUGAL BOLIVIA IRAN ROMANIA BRAZIL IRAQ SAUDI ARABIA BULGARIA IRELAND SENEGAL BURMA ISRAEL SIERRA LEONE BYELORUSSIAN SOVIET ITALY SINGAPORE SOCIALIST REPUBLIC IVORY COAST SOUTH AFRICA CAMEROON JAMAICA SPAIN CANADA JAPAN SUDAN CEYLON JORDAN SWEDEN CHILE KENYA SWITZERLAND CHINA KHMER REPUBLIC SYRIAN ARAB REPUBLIC COLOMBIA KOREA, REPUBLIC OF THAILAND COSTA RICA KUWAIT TUNISIA CUBA LEBANON TURKEY CYPRUS LIBERIA UGANDA CZECHOSLOVAK SOCIALIST LIBYAN ARAB REPUBLIC UKRAINIAN SOVIET SOCIALIST REPUBLIC LIECHTENSTEIN REPUBLIC DENMARK LUXEMBOURG UNION OF SOVIET SOCIALIST DOMINICAN REPUBLIC MADAGASCAR REPUBLICS ECUADOR MALAYSIA UNITED KINGDOM OF GREAT EGYPT, ARAB REPUBLIC OF MALI BRITAIN AND NORTHERN EL SALVADOR MEXICO IRELAND ETHIOPIA MONACO UNITED STATES OF AMERICA FINLAND MOROCCO URUGUAY FRANCE NETHERLANDS VENEZUELA GABON NEW ZEALAND VIET-NAM GERMANY, FEDERAL REPUBLIC OF NIGER YUGOSLAVIA GHANA NIGERIA ZAIRE, REPUBLIC OF GREECE NORWAY ZAMBIA The Agency's Statute was approved on 23 October 1956 by the Conference on the Statute of the IAEA held at United Nations Headquarters, New York; it entered into force on 29 July 1957, The Headquarters of the Agency are situated in Vienna. Its principal objective is "to accelerate and enlarge the contribution of atomic energy to peace, health and prosperity throughout the world". -
Mnfooi Trsy C the THERMAL DEHYDRATION of NATURAL ZEOLITES
MNfooi trSy C THE THERMAL DEHYDRATION OF NATURAL ZEOLITES BO L. P. VAN REEUWIJK MN0B201.587 L. P.VA N REEUWIJK THE THERMAL DEHYDRATION OF NATURAL ZEOLITES PROEFSCHRIFT TER VERKRIJGING VAN DE GRAAD VAN DOCTOR IN DE LANDBOUWWETENSCHAPPEN, OP GEZAG VAN DE RECTOR MAGNIFICUS, PROF. DR. IR. H. A. LENIGER, HOOGLERAAR IN DE TECHNOLOGIE, IN HET OPENBAAR TE VERDEDIGEN OP WOENSDAG 29 MEI 1974 DES NAMIDDAGS TE VIER UUR IN DE AULA VAN DE LANDBOUWHOGESCHOOL TE WAGENINGEN fBIBlIOTHEEK DER IANDBOUWHOGESCHOOL WAGENINGEN H.VEENMAN/& ZONEN B.V.- WAGENINGEN-1974 STELLINGEN Vanwegehu nuniek eeigenschappe n verdienen natuurlijke zeolietenmee r onder- zoek van huntoepassingsmogelijkhede n dan thans hetgeva lis . 2 Het bepalen van het z.g. H20- van zeolieten door het gewichtsverlies van monsters na verhitting tot 110°Ct e meten,zoal s voorgesteld door MARGARET FOSTER, is zinloos. FOSTER, M.D .(1965 ) U.S. Geol. Surv. Prof. Paper 504-D,E. 3 In tegenstelling tot de bewering van ZEN, hebben in zeolieten geadsorbeerde watermoleculen geen grotere entropie dandi e ind evloeibar e fase. ZEN, E-AN (1972) Amer. Miner. 57: 524. 4 Bij publicatie van differentieel thermische analyse (DTA) curves van reacties waarbij gassen zijn betrokken, dient van deze gassen de(partiele ) druk tewor - den vermeld, ook wanneer die gassen zijn samengesteld uit de lucht inhe t laboratorium end egasse n diebi jd ereacti e vrijkomen ofworde n opgenomen. MCADIE, H.G .(1967 ) Zeitschr. anal. Chem. 231: 35. 5 Bij hetgeve n vannieuw e namen aanminerale n dieslecht s in symmetric een weinig blijken af te wijken van eerder bekende mineralen, moet grote terug- houdendheid betracht worden.