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MINERAIOGY 0F POI.ËUCIIE AND BERTL FRCI,Í fi{E ÎANCO PEGMATIIE AT BERNIC IAffi, }ÍANITOBA A Thesis Subnttted to .tthe Faculty of &aduate Studies Universlty of Þfanitoba In Partial frrlfill¡ent of the Requirenents for the Degree Master of SeLence by Frederick Simpson L97b THE t'4INERALOGY OF PNLLUCITE AND BERYL FR.OM THE TANCO PEGI,IATITT AT BERNIC LAKE, MANiTOBA b-v Frederick Simpson' A dissertation submitted to the Faculty of Graduate Studies of the University of Manitoba in partial fulfill¡nent of the requirements of the degree of ¡4ASTER OF SCIENCE @ t974 Pern¡ission has been grantctl to the LTBRARy oF Tfru uNlvDR- slrY oF MANTToBA t. tcntr or sert copies of trris dissertrtion, to the NATtoNAL LTtsRAIì,y oF- cANADA to'ricrorirm this dissertation and to lend or sell copies of the filnr, and uNrvËRstry MlcRoFrtMS to publish an abstract of trris dissertation. The author reserves other publicati,' rights, and neithcr ttre dissertation nor extensive cxtracts f'rum it rnay be printed or t¡ttrer- wise reproduced without ttrc uurilror's written ¡re*rrissiorr -ti- ry CHAPlEB PA@ ABSTBACT vli AEKIT{IEDEEI{ENTS in Ï. IN1RODTICÎICAI (a) Ggncral fntroduction . .. .. .... .... .. .. .. t (u) IÍtstory ....................... .............. e..... ? (e) Gþncral Gcologr . .... .... .. .... o. .. .. .... .. ... I (a) Frevlous lrlork e... .. .... ...... ... u (e) Prcsgnt Study ............................. e....... L5 (r) Erperinental Mcthodg . ...... .... ... ... L5 Befractive Lndcor .. .. ... ... ...... ..... L5 lample eeparation . .. .. .... .... .. .. L6 ÐCne5.ty ..... ò e oo o.......... o.oo............... L6 UnLü cgll di-ngnsions . .. o. ... o......... .. ..... t7 Chenistly . .............. .......... o.. ..... .. o n Thin geetion9 ........ ) .. .. ..... ....... .. .. 18 l-ray diffractlon of aXteration products ...... 18 IT. POIJIrcITE (a) Introductlon ....... ..... .... e .... ,.. ........ .... L9 (u) CeneraL Study d @4 e s Fhyslcal, and optlcal propcrtíeg ' ............... 2L PartlaL chc¡ntcal analysls- . .... .... .. o. .. ... 27 (c) hrt t Müieralogical Study ...... .. .... ............. 29 Ðeneity and rgfþactlvg index .......... ... ).. o. 29 Unft egll. di.ngrælons .. ..... ......,. .. ......... 32 Dlscrepaneles ln the full chcmical analyscs ... 32 (0) sccondary cegign-analcines ................ )....... 32 (g) ALtæation Productg ...... ................ ... .. 35 III. BERTT (a) Inürodr¡ctlon ...................................... 37 (u) Genera!, Study Plyoical and optical, propertiee ...,. .......... 37 Partlal chcntcaL ånalygis- . ............. ., .,. .. 46 (c) Fux.t lftngralogical study . ......... ... ... ...... 5L Denclty and rcfÞactLvc lndax ....... ,. ..... a. 5L Urd.t cgll dinensLong . e ...... o............ .. o.. 53 t\¡1,1 chentcal analysis . .... ...... ... ..... ... .. 53 (A) Scconda¡T Ceglan BeryLs ................. o......... 60 rV. PETAOTPGICAI CONCIT'SIO{S (a) PoX.luctte a a a a a aaa aa a a a a a a.a a o a a a aaaaaaa a a a a a a a a a a a 64 -lii- CHAP1ER PACE (u) SgcondarT Ceslan AnaLei.ug o . .. .. .. ... .......... 65 (c) Beryl .... Ò a...... a....... e......... a aa a a. a. a aa..aa.. 65 (a) Secondary Ggstan Bgryl . .. ... .... ... .. o .. 66 V. MONOITTC COI{SIDENATIONS (a ) Pollucltg . .. .. 67 (U) Beryl ............................................... 68 nErmElpEs 69 -iv- TAru PA@ I. PhyslcaL and Oryetatlographieat Oharacteristics of FoX,lucite .......................... .................. 2 rr. Physical and Ctystatlographlcal Characterlstico of Beryl ..... a...... a... a.............. r.. a.............. 2 IIï. Rcfþactive IndLces and Footage in Feet of PoLLucite Sanple8 ......... ).....Ç... o............... ò o o o o....... 20 fV. Honogencity ?est on FolX-ucltc by Befractive Index ..... 2j V. Partfal Chenr cal AnaþcJ.a for PolLucite . .... .. .... 28 vI. t\rlt chgùnical Analysås for poLt-ucLte .............. .... 30 VfI. Chentaal Oonpoeition and PhyefcaL Pr.orperties of 0 gsian AnaLci.nc ........ .. .. .. ............ .. 33 VIII. Rcfraetlve Indiees for Be,r1y!- Saryles .................. 38 ï¡(. Partlal. ChemÍ¡cal Anal,yoes andr.¡,' for Berl¡l- Saryles ..... w J(. FulL GhenlcaL Anaþses for Berryl fÞon the Taneo Fegmatlte and Oùhgr Pcgmat,ltes ........................ 49 XI. GaLeulatlon of Oatl,on 0ontents of BerSrX. BaEed on 36 Qrygeng per Untt Ccll .............................. 54 XI[. OaLculatl.on of Cation Contenüs Bascd on Sl ............ 57 NfïI. Unl-t Cell Oontent and Site PopuLqtlon of lanco Ber'¡rl-s .. 58 XfV. Correätioar of Cation Gontent for Beryl- #3 tor Quartz ConùamlnatLon . 59 Xlf. FhysicaL Propcutlcg of Cegian Berfl. ...........o....... 62 IJST OF FTGT'RF FTGTTRE PAS 1. ProJection on (OOt) of thc ah¡minosil-:lcaùe ftanøwork and cg and tltO positions in pox.tuelte ................... 3 2. ProJectlon on (OOl) of the Cs aüons and H20 nolecu,[ee of polluclte shorring forrr eglX.s . .. .......... .. .. ..... 5 3. ProJection on (OOX.) of the Na atons in pollucite ........ 5 4. Structt¡¡lg of beryX. ...... ... .. ..... )........ .. 6 5. CreologleaX nap of the Bird lake - Bernlc trake - tfinr'Épeg River Area ... ... .. .. ..... ... ......... .. ... I 6a. Ptan of ùhe Tanco mine shorrl-ng thc poof.tion of Cro8S-Section A-A r . .. r . x0 b. A !û-S (l-lt) gection of the Tanco pegmqtLte ...........e. 11 7. Plan of ühe Tanco nlne chorring the eastern poll-ucitc n¡lp body ...... a... a... a. a o...... o.. a a. a. a....... ..... a a a a a.. pocket 8. hofl-lca of R vB. depth for polLuoite saryX.ee eollectcd fþon drill- co¡re¡ V39, BLz, ItI5r'and 834 fron the easüern poll.ucite bory and corês U and C fron the mstcDn igoLsted pods of polX.ucite . ... .. ... ... 22 9. Illstogran shorfng the variatLon of n in 135 poLLueitc sanpl,eo .. ... ......... .. .. .. ... o ...... .. ... o . 24 10. Itldlght ¡leroenüagc of 0eo0 vs. E for poX.lucite fron thg Tanco pegnatfte , ..7........ ........ ... ... ... ....... 26 11. Deneity yg. ! in Èhc analclne-poLluclte aeries .......... 3L 12. Paragesretf.o sequanccg of secondary nf-nerals ln ff.vo hydrothcmal asscnbLageo fron the upper lnte¡nedlate zonc (5) of ühe Tanco pegnqtltc )............r........... 34 13. The Tanco nf.ne chorlng the locatio4 of beryl saryler naP collected rrnderground fbon zone (6) (east) .............. pocket l4a. Hf.stogran ehoring the varlatl-on of ,^.r !n 43 ber-yl sanplea fÞom zone (4), zone (z) (pt¡*), zone (2) (eray), and zong (X.) . .. .... o...... .. .. ....... .... ...... .. ..... 41 ì b. Histogran shoving the varlation of r¡,rln 81 beryl sarylee ftom zoae (6) (east), sone (6) (ucst) ana zgng (9) ....e.............o............................. l+L -\n - FIq'RE PA6E C. llistogran of the nrünber of sanplee vo.l-¡J for al.L the 120 bcryL sappLes coLl-ceted fron thc Tanco pegmatlte ..... o... ... o. ..... .......... a. ........ l+2 L5,.ree,ig. Sketchco of bcryl crystals studled for zonlng shorvlng thc changc of r-r"' through the cryetal over A mQagEfGd digüanCe ..... ..... .. .... ...... ....... 4l+ t6. Refractlvc lndq (w) vs. SRAO for berXrl ............ 46 yl. DensLty v!t. t for beryl . ..... ........ .. ..... .. o.. o 52 18. Denaf.ty vs. 8q0 fsr the threc beryl sanpleg chctntcaXly analyged in full . .. ...... .. .... ..... 61 -vti- +ry PoX,Lucite and beryl are two of the cconomicatly anO petro- logically Ínportant nineraLs ln the lanco pegoat'it,c, Bernic lake, Manitobq. One hundred and thirüy sfx polluciùe sanples were coLX.ected fron the eastern poLlucite body and the Lsolated pods of pol.lucite 1n ühe western portLon of the pegnatite. The refractive fndex (gr) uaa measured on aLL sanpLes. SanpX.es were scLected for partial or ftrLL chentcal analysis on the baels of g and location. three sanpl-es uero chemf.cal,þ analysed in fuLl- and theLr density and untt cell denet-rsions were deterntned. lhe polluelte from the lanco peg- natitc uas found to fit the previously establlshed positlve correlatLons beüwecn g, dcnslty and rÊ.1 CsAO. Iü was noted that the sanp!.es from the western isolsted pods of poLlueite had, in general¡ a highen g than those fron the eastern pollucite body indicating they are richer ln Cor0. Alteration products of pollucite occur as thln velns and spherlcaL nassec, and aonsist of spodunene, nica and clay nineraLs. Ona hrrndred and thlrteen beryl saryLes were collected from thc wall zone, lower internedíate uone, ccntral inüernedlate sone and ühe Lepidolite zonc of the pegmatfto. The refþactive index (u,¡) of eaah sample nac measured, and on the basis of rr¡ and locatlon eanples were gelected for fuX.l or partial chenlcal anal¡rsis. DeneLtles and unlt aeLl dinensions were moqaured for the ühree oaryLes vhlch uere ehemicaLly analyaed in fulX.. Beryls fron the lanco pcgmatite appoar to ftt the esüablished positlve correLations between density and ã R 0. Zordng in the beryl crystals ruas checkcd by syetcnatically meqcuring rrr from the center to the outcrmost edge of thc cr'¡rsüal. '-''-.-.-.'....-. - ïLIJ - In nany caaos the crystalc were found to be iratensel¡r zoned. Zoning of bcryL with respect to znzo and r^.r was ax.so noted in the pcgnqtlte and lt appeqrs, ln general, that the aR20 q¡{ ur increaae tonards the ccnter of thc peBmatite. -j¡c- ACKNCffI..EÐGÐ.ÍENTS The auühor is very gratefi¡l to Dr. P. Ce¡n\y, Aasoclate Profcssor of lrflncnaXogy, aü the Unl-verslty of l{ani.toba for suggesting thla proJect and contl.nued guidance throughout the rescareh. The author ls also gratefrrl to Dr. R. B. Ferguoon, Professor of llllnenalogyt Univereity of Manitoba and lüQ. B. Bannatyne of, the lfanitoba lfinee Branch .for rcadlng the