GaziUniversityJournalofScience GUJSci 23(2):211226(2010) www.gujs.org

Damage Assessment and Mortar Identification in

FuatARAS 1♠

1AnadoluUniversity,FacultyofEngineering,CivilEngineeringDepartment,Eskiehir, Received:04.07.2009Revised:02.10.2009Accepted:03.11.2009

ABSTRACT ThehistoricalbuildingstockandseismicriskofAnatoliadrawsconsiderableattentionoftheengineersforstudying theconstructiontechniquesandtheearthquakeperformanceofthesestructures.Thisstudyisdealingwiththe145 yearsoldBeylerbeyipalace.Withinthestudyarchitecturalfeaturesandtheconstructiontechniqueofthepalaceare introducedandtheexistingconditionofthestructureisinvestigated.Theobserveddamagesareclassifiedandthe possible sources of these damages are discussed. The final stage is the chemical analyses, performed over the mortar of the structure. Thin section analyses, Scanning Electro microscope analyses, Energy Dispersive X Ray AnalysesandXRayDiffractionAnalyseshavebeenappliedoverruinsofBeylerbeyiPalace.Theresultsofthe analyseshavebeenusedtodeterminetheoriginofthemortar.

Key Words :Historicalstructures,Damageevaluation,Horasanmortar,Mortarinvestigation.

1. INTRODUCTION Withitspermanentoccupancy,Anatoliaisthecradleof immediate restoration work and prevention of the civilization. There are many historical buildings and propagation of the damages. Secondly mortar monuments spread over every corner. Every city in identification is essential for several reasons, such as, Turkey has many historical structures, built especially determination of origin of the material, mechanical in Seljuk, Byzantine and Ottoman times. With their properties of the material, and determination of magnificencemanystructuresaredefyingthecenturies. appropriate restoration materials. Before starting to For the modern engineers and architects construction elaborate the damage and structural system of techniques of the old structures are always in Beylerbeyi Palace it would be valuable to summarize importancewithrespecttoboththelessonstakenfrom the history and general architectural features of the them and conservation work to make them stronger structure. againstagingandearthquakeeffects. 2. HISTORY AND ARCHITECTURE OF THE Thisstudyisgrownupastheinitialstepofabroader STRUCTURE one which aims to investigate the earthquake performanceofBeylerbeyipalace.Inthispaperexisting Beylerbeyi Palace is the largest and the most elegant conditionofthepalacewithrespecttodamageandthe OttomanpalaceontheAsianshoreofthe.It historical mortar investigation are explained. was constructed between 1861 and 1865. The palace Identification of the existing damages would be very wasgenerallyreservedforsummerusebythesultansor helpful for the assessment the necessity of the to accommodate foreign heads of state visiting the Ottomancapital.ThepalaceisshowninFigure1. 212 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

Figure1.BeylerbeyiPalace. Thepalaceconsistsoftwomainfloorsandabasement The load bearing system is mainly made of masonry containingkitchensandstoragerooms.Inthebasement walls and timber slabs. The basement floor of the floor storey heights vary between 1.5 m. and 2.2 m. Harem part enables to identify the masonry which is whereas in regular floors, storey heights change composedoflimemortar,brickandstones.Thesewalls between6–9m.Ithasthreeentrances,sixstaterooms are also forming the foundation system of the palace. and24smallerrooms.Thebuildinghasa72mlength Thetimberfloorisalsovisible.Itisdeterminedthatthe alongtheshore48mintheperpendiculardirection[1]. slabofthestructureismainlycomposedoftwotypesof It is divided to two parts as Mabeyn and Harem. timber crosssections. 20*20 cm 2 beams (supporting Mabeyn is the name of the official part on which the beam)werelocatedonthemasonrywallsand8*40cm2 imperialworkswerecarriedoutwhileistheprivatepart beams(slabbeam)with40cmspacingliebetweentwo on which sultans live with their families. These two wallsperpendiculartowalldirection.Oak wasusedfor partshavedifferententrances. the supporting beam while slab beams were produced fromfir.Figure2showsthedetailsfromthatfloor[1].

Figure2.Foundationofthepalace. Thefirstandsecondstoreyofthestructureismadeof structurewascoveredby “küfeki”stone whileinterior masonry walls, consists of lime mortar and brick, faces were veneered with stucco and lime plaster and marble and wood columns and timber slabs. The timbercover. thicknessofthewallsinthefirststoreyisgenerally80 cm while it is 60 cm in the second floor. Cast iron Theroofofthepalaceverifiestheslabconfigurationin clampswereusedwithinthewallstoincreasetheoutof the basement. On the other hand the first story slab planestabilityofthestructure.Theexteriorfaceofthe configuration could not be examined. Figure 3 illustratestheinteriorsideoftheroofofthepalace. GUJSci ,23(2):211226(2010)/FuatARAS 1♠ 213

Figure3.Structuralwallandtimberslabintheroofofthestructure. 3. DAMAGE ASSESSMENT the construction technique of the structure is clearly understood. Thicknesses of the walls are changing Adetaileddamagesurveywascarriedoutinthepalace. between2mand1manditisoften1.4monthatfloor. Itshouldbeemphasizedthatthestructureisunderthe High humidity existence is monitored on that part protection of the state establishment, Regional although it has several ventilation openings. Figure 4 Directorate of National Palaces. The directorate has illustrates one of the ventilation openings on the great effort and spends valuable time to save the foundationwhilehighhumidity isshowninFigure5. structure against aging and atmospheric conditions. In The high level of humidity affected both the timbers, that respect many minor restoration works have been forming the slab system by causing decay and the carried out for both interior and exterior sides of the masonrywallsbycausingcracking.Figure6showsthe structure. chipped timber members in order to prevent the Thebasementfloorofthestructureisdividedintotwo propagationofthedecay.Itisobviousthatventilation parts with different entrances. This floor is used as openings in Beylerbeyi Palace are not adequate to officers’roomandstoragepurposesinthemabeynpart prevent high humidity. Recent studies have revealed while in the harem a small portion of the basement is that ventilation by using the appropriate machinery usedasonlystoragepurposesandotherbiggerportion equipment can be used as a solution against high isfunctionless.Damagesurveyofthebasementflooris humidity[2]. especially gathered on that functionless part on which

Figure4.Ventilationopeninginthefoundationfloor. 214 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

Figure5.Highhumidityoverstonesanditseffects.

Figure6.Chippedtimberbeamsduetodecayonthefoundationfloor. On the first and second floors of the structure several stemfromthedamageoccurredonthewallbeneaththe crackswereobserved.Sincenorestorationprocesshas covering,specialcaremustbetaken.Otherwisethese been carried out in the mabeyn part of the palace, cracksareharmlessandtheyonlydisturbthebeautyof everythingisoriginal.Ontheotherhandintheharem therooms.ThroughFigures7–9,theobservedcracks partofthepalacerepairworkswereperformedtocover are shown. The cracks can be classified into three thecracks.Forthisreasonmostofthedetectedcracks categoriesasfollows: areinthemabeynpartonthestuccoplaster.Sincethe reproductionofstuccoplasterisimpossiblenowadays, • Thehorizontalcracks, authorities do not touch the cracks to repair them. • Verticalcracksonthesideofthewindows, Similarlythetimbercoveringsoftheroomsinmabeyn part have very wide cracks which make it hard to • Inclinedcracksonthecornersoftheopenings. interprettheireffectoverstructuralsafety.Ifthecracks GUJSci ,23(2):211226(2010)/FuatARAS 1♠ 215

Figure7.HorizontalcrackintheMabeynpart.

Figure8.VerticalcrackinMabeynpart. 216 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

Figure9.Inclinedcracksonthecornersofthedoor. Not only is the existence of thedamage but also their addressedasCtype,BtypeandAtypesoilinNEHRP reasons are in importance. The existing damages may classification. It is guessed that the weaker soil was stem from the horizontal earthquake loads, ground removedattheconstructionphaseandthestructurewas settlements, or aging and atmospheric conditions. The builtonstrongersoilwhichisclassifiedasBtype[3]. palace experienced two strong earthquakes (1894 and Constructionofthepalaceonsuchastrongsoilreduces 1999) since it was built. As mentioned the palace has thechanceofgroundsettlementasapossiblesourceof timber floor system which is not adequate to supply observeddamages. rigid diaphragm action on the floor levels. In this condition the horizontal cracks can be induced by the Anothertypeofdamageiscausedbythemetalclamps out of plane movement of the walls whereas the placedwithinthemasonrywalls.Theoxidationofcast inclined cracks at the corner of the openings like iron clamps used within the masonry caused swelling windowsanddoorsarethesignofinplaneactionunder andfinallycrackingofthewallinaroomandstaircase in harem part. This damage ended up with the horizontalloads.Inthisrespectitcanbeconcludedthat 2 these cracks are probably induced by the horizontal separationofabout50*50cm wallpartintheroomas earthquake load. On the other hand stress analysis by seen in Figure 10. The same fact has repeated the using an efficient computer package program is damage in the staircase of harem part. This crack essentialforacertainconclusion. formation is shown in Figure 11. Together with the damages observed of foundation floor, the damages Thesiteonwhichthepalaceissittinghasadetailedsite inducedbytheoxidationofmetalclampscanbenamed investigation report prepared in 2005. The report as damages caused by aging and atmospheric identifies three different layers of the soil at the conditions. inspected site. From top to bottom layers were

Figure10.Damageinducedbytheoxidationofmetalclampsbeforeandaftertheseparationofwallpartintheroom. GUJSci ,23(2):211226(2010)/FuatARAS 1♠ 217

Figure11.DamageinducedbyoxidationofthemetalclampsinthestaircaseofHarempart. 4. MORTAR IDENTIFICATION impregnated sections. With a scanning electro microscope,equippedwithanEnergyDispersiveXRay Thedamages,inducedbytheoxidationofmetalclamps (EDX)detector,valuableinformationcanbeobtained used within the masonry enabled to determine the onthemineralphasecomposition[4]. masonryconfigurationandhaveruinsfromtheoriginal mortarofthestructure.Bothmortarandplasterparticles For these reasons chemical and mineralogical were taken to analyze the origin of the mortar. The composition of mortar from Beylerbeyi Palace was average mortar thickness is about 18 mm and brick determinedbyThinSectionanalysis,ScanningElectron heightwasmeasuredas65mm. MicroscopeEnergy Dispersive XRay (SEMEDX) analysisandXRayDiffraction(XRD)analysis. More recently developed mortar characterization schemes have optical microscopy as the first step in 4.1. Thin Sections, Under Polarizing Microscope identifyingtheaggregates,ofvariousmineraladditions, binder type, and binderrelated particles and in For the characterization of mortar, the study of thin describingtheporestructure.Opticalmicroscopyisalso sections under the polarizing microscope is a very a valuable aid for damage diagnosis of degraded efficientanalyticaltechnique.Athinsectionismadeby historicmortarsandforthestudyoftheinterfacialzone, grindingdownasliceofrockwhichhasbeengluedtoa the bonding and possible reaction rims between glassslideuntilitreachesathicknessofabout0.03mm aggregates,brickorstoneandthemortar[4]. (30 microns). At this thickness most minerals become moreorlesstransparentandcanthereforebestudiedby A Scanning Electro Microscopy (SEM) analysis amicroscopeusingtransmittedlight.Inthisstudyfive togetherwithanXRayDiffraction(XRD)analysisis thinsectionswerepreparedandinvestigated.Figure12 the most valuable second step in the characterization shows three enlarged views of the prepared thin process of historic mortars. SEM analysis can be sectionsandFigure13showsthephotographofathin performed on mortar fragments or on polished epoxy section,takenunderpetrographymicroscope.

Figure12.Thinsections. 218 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

Thinsection analysis showed that, about 60% of the mineralparticles,quartsparticlesandclearlyidentified mortar is binding material and remaining part is the brick powder particles. Table 1 summarizes the grains.Thegeneralgrainsizeisabout500mandless. identifiedingredientsofthethinsections. It occasionally reaches to 1 mm. These grains contain

Figure13.Photographofthinsectionundermicroscope. Although the brick powder can be recognized in thin since the quarts particles may come from the brick section analysis, it is hard to say that the determined grains.BrickaggregatesalsocontainCalcite[5]. ratios are the initial proportion of the brick powder Table1.Mortaringredientsaccordingtothinsectionanalysis.

Components Sample Code Binding QuartsandCalcite Brick Material% Particles% Particles%

TS1 50 45 5 TS2 50 35 12 TS3 60 30 8 TS4 65 25 6 TS5 67 25 6 Average 58.4 32 7.4 4.2. Scanning Electron Microscope Views and Microscope and Energy Dispersive XRay device. Energy Dispersive X-ray Analysis Figure14showsthepolishedspecimens.Thefirsttwo specimens with bigger grain size belong to the mortar Scanning Electron Microscope is a widely used takenbetweenthebricksandthethirdoneistheplaster technique to study surface topography. The mortar mortar.Mineralogicalstructureoftheingredientsofthe specimens were searched under Philips XL30ESEM mortar were tried to be identified on enlarged views FEG&EDAX, Environmental Scanning Electron thankstoEDX. GUJSci ,23(2):211226(2010)/FuatARAS 1♠ 219

Figure14.Mortarspecimens,preparedforSEMandEDXanalysis. Good connection between particles and binding 17).Itisseenthatthegrainparticlesize,usedinmortar materialwasobservedthroughtheSEMviews.Nogap is grater than that used in plaster. According to SEM orcracksweredetermined.Particlesizedistributioncan views the maximum size is determined as about 1800 easily be determined from SEM views (Figures 15 – m. 220 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

Figure15.SEMviewsfromthemortarbetweenthebricks. GUJSci ,23(2):211226(2010)/FuatARAS 1♠ 221

Figure16.SEMviewsfromthemortarbetweenthebricks. 222 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

Figure17.SEMviewsfromtheplaster. TheEDXanalyseswereperformedsimultaneouslywith seen in SEM view as in grey colour. Wt % column the SEM. It was determined that the mineralogical showstheweightratiooftheeachelementandoxides. originoftheparticlesisquartz,SiO 2andderivedfrom Occasionally feldspar minerals were seen through the the aggregates containing sand and brick powder. EDXpatternsofaggregates(Figure19). Figure 18 represents the EDX analysis for a particle, GUJSci ,23(2):211226(2010)/FuatARAS 1♠ 223

Figure18.EDXanalysisofparticleinSEMview.

Figure19.Identifiedfeldsparelements,EDXanalysisofparticle. EDX analysis showed that the origin of the binding 20showstheEDXanalysis,appliedtothedarkerregion material between the particles is calcite minerals. (binding material) on the SEM view. Calcite is originated from carbonated lime [5]. Figure 224 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

Figure20.EDXanalysisofbindingmaterialinSEMview. 4.3. X-ray Diffraction Analysis analyzed and it is seen that each of them consists of quarts,calciteandfeldsparmineralswithvaryingratios. Xray Diffraction (XRD) clarifies the nature of the Table 2 summarizes identified component ratios for mineralogicalphasespresentinthesample[6,7,and8]. each specimen. These specimens were taken from the Pulverized mortar specimen were analyzed under two different room of the palace and all specimens Rigaku D/MaxUltima+/PC XRD device and belongtomortarbetweenbricks.Theaverageofratios diffractogramwereobtainedforeachspecimens.Figure indicates that, about 65% of the horasan mortar is 21 shows one of the XRD diffractograms. Mineral calcitederivedfromcarbonatedlime,30%ofthemortar ratios for each specimen were estimated by using line isquartz,derivedfromaggregates,and5%isfeldspar, magnitudesandareas.Theresultsverifiedtheexistence (Na,K,Ca),(Si Al)Oelements. of calcite and quarts elements. Six specimens were 3 GUJSci ,23(2):211226(2010)/FuatARAS 1♠ 225

Figure21.XRDdiffractogramofW02specimeninTable2. Table2.MineralogicalcomponentsofthespecimensaccordingtoXRDanalysis.

Sample Mineralogical Component Code Calcite% Quartz% Feldspar%

W01 60 30 10

W02 30 65 5

W03 53 43 4

W04 85 10 5

T01 75 20 5

T02 90 5 5

Average 65.5 28.8 5.7 Thefindingsofthechemicalanalysesmaybecompared served as fibres [10]. Although no fibre was found in tosimilarsurveyformortarruinsofDolmabahçepalace the mortar of Beylerbeyi palace, the mineralogical which was built in the same period as Beylerbeyi componentsofthemortaroftwopalacesarethesame. palace. The analyses showed the ingredients of the mortar of Dolmabahce palace as lime, crushed brick, 5. CONCLUSION finesandmarblepowderandatypeoffibre(inavery Damage observations through Beylerbeyi Palace has small percentage) [9]. In Byzantine, Seljuk and showed the damages can be categorized into four Ottoman time the binding material of construction categories, namely, horizontal cracks, vertical cracks, mortar is carbonated lime while as aggregate, river inclined cracks and damages due to aging and sand,pebbles,brickpiecesandpowderhavebeenused atmospheric conditions. Although the first three together with hay, horse hair and rope which have categoriesarethesignofearthquakeorienteddamages, 226 GUJSci ,23(2):211226(2010)/FuatARAS 1♠

numerical analyses are required for certain a Cement and Concrete Research , 34: 1471– conclusion. 1475(2004). InordertocharacterizethemortarofBeylerbeyiPalace, [9] Yüzer, E., Görür, N., Gürdal, E., Vardar, M., builtbetween1861and1865,ThinSection,SEMEDX “Dolmabahçe Sarayında Kullanılan Taların andXRDanalyseshavebeenused.Whenthefindings KorunmulukDurumlarının,AyrımaNedenlerinin of the employed methods are assessed, it is seen that BelirlenmesiveKorumaveOnarımYöntemlerinin there is a good trustworthiness. These three methods Saptanması”, ITU Gelitirme Vakfı, Report No: gave the mineralogical ingredients of the mortar as 01103(2000). quartz,calciteandfeldspar.Thismineralogicalstructure and the construction period of the palace indicate the [10]Arioglu,N.,Acun,S.,“Aresearchaboutamethod mortaraslimemortar,knownasHorasanMortar. for restoration of traditional lime mortars and ACKNOWLEDGEMENT plasters: A staging system approach”, Building andEnvironment,41:1223–1230(2006). This work was developed within the FP6 research project, Protection of Historical Structures by ReversibleMixedTechnologies(PROHITECH). TheauthorsexpresssinceregratitudetoProf.Dr.Fahri Esenli and Orhan Yavuz (I.T.U. Mining Faculty), Yunus Aydın (Regional Directorate of National Palaces)andHarunYükselbrickfactory. Valuablecare,spentbythelaboratorystaffsofBoğaziçi UniversityandTechnicalUniversity,arekindly acknowledged. REFERENCES [1] Aras, F., “Earthquake protection of Beylerbeyi Palace by reversible mixed technologies”, Ph.D. Thesis, BoğaziçiUniversity ,Istanbul(2007). [2] Torres,M.I.M.,Freitas,V.S.,“TreatmentofRising Damp in Historical Buildings”, Building and Environment ,42:424435(2007). [3] Eren,R.H.,Oktay,F.Y.,Ilkisik,O.M.,“Beylerbeyi SarayıJeolojik/JeoteknikEtütRaporu”,TBMMof National Palaces, Report no. 05528, Istanbul, (2005). [4] Elsen, J., “Microscopy of Historic MortarsA Review”, Cement and Concrete Research , 36: 14161424(2006). [5] Böke, H., Akkurt, S., Ipekoglu, B., Ugurlu, E., “Characteristics of Brick Used as Aggregate in Historic BrickLime Mortars and Plasters”, Cement and Concrete Research , 36: 11151122 (2006). [6] Gülec, A., Tulun, T., “Physicochemical and petrographical studies of old mortars and plasters ofAnatolia”, CementandConcreteResearch ,27: 227–234(1997). [7] Antonelli, F., Cancelliere, S., Lazzarini, L., “Mineropetrographic characterization of historic bricks in the Arsenale, Venice”, Journal of CulturalHeritage ,3:59–64(2002). [8] Bianchini, G., Marrocchino, E., Vaccaro, C., “Chemical and mineralogical characterization of historic mortars in Ferrara (northeast Italy)”,