Safety Data Sheet Organic Neroli Essential Oil (Citrus Aurantium Var
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Safety Data Sheet: Neroli Oil Organic Page 1 of 8 2 4 CHATH AM P LACE, BR IGH TON BN 1 3 TN ( U K) TE L. ( U K) 0 8 4 5 3 1 0 80 6 6 FAX. ( U K) 0 8 4 5 3 1 0 80 6 8 I n t e r n a t i o n a l T e l . + 4 4 1 2 7 3 7 4 6 5 0 5 I n t . F a x . + 4 4 1 2 7 3 2 0 2 7 2 9 EM A IL: i n fo@ n h r or gan i coi l s . com Web Site: www.nhrorganicoils.com Safety Data Sheet Organic Neroli Essential Oil (Citrus aurantium var. amara) 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING 1.1 Product Identifier Product Name Neroli Oil Organic Biological Definition The volatile oil obtained by steam distillation of the fragrant white blossoms of the bitter orange tree Citrus aurantium L. subsp. amara Engl. INCI Name Citrus Aurantium Flower Oil Synonyms & Trade Names - 8016-38-4 / CAS-No EC No. 277-143-2 EINECS No. 277-143-2 72968-50-4 1.2 Relative identified uses of the substance or mixture and uses advised against No additional data available. 1.3 Details of the supplier NHR Organic Oils, 24 CHATHAM PLACE, BRIGHTON, BN1 3TN, UK 1.4 Emergency Tel. No. 0845 310 8066 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture The Full Text for all Hazard Statements is Displayed in Section 16. Classification (EC 1272/2008) Physical and Chemical Hazards : not classified Human health Asp. : Tox. 1 – AH1 H304, Skin Irrit 2 – SCI2 H315, Skin Sens 1 – SS1 H317, Serous Eye Irrit 1 EDI1 – H318 Environment : Aquatic Chronic 2 – EHC2 H411 2.2 Label Elements Label in accordance with (EC) No 1272/2008 GHS08 GHS09 GHS07 GHS05 Signal Word Danger Contains Limonene, D-beta Pinene, Geraniol Hazard Statements Revision Date: 28/09/2015 Rev No/Repl SDS Generated 01 Safety Data Sheet: Neroli Oil Organic Page 2 of 8 H401 - Toxic to aquatic life H316 - Causes mild skin irritation H411 - Toxic to aquatic life with long lasting effects H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H303 - May be harmful if swallowed H315 - Causes skin irritation H304 - May be fatal if swallowed and enters airways H226 - Flammable liquid and vapour H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects H402 - Harmful to aquatic life H319 - Causes serious eye irritation H227 - Combustible liquid Precautionary Statements P280 Wear protective gloves/protective clothing/eye protection/face protection P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P331 Do NOT induce vomiting P302 + P352 IF ON SKIN: Wash with plenty of soap and water P333 + P313 If skin irritation or rash occurs: Get medical advice/attention P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P273 Avoid release to the environment Supplementary Precautionary Statements May be harmful if swallowed. Toxic to aquatic life. Combustible liquid 2.3 Other Hazards PBT or vPvB according to Annex XIII No additional data available. Adverse physio-chemical properties No additional data available. Adverse effects on human health No additional data available. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures 30 - 50% Linalool CAS-No.: 78-70-6 EC No.: 201-134-4 Classification (EC 1272/2008) Aquatic Acute 3 - H402, Eye Irrit. 1 - H319, Skin Irrit.2 - H315, Acute Tox. 5 - H303, Flam. Liq. 4 - H227 10 - 20 % Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5 Classification (EC 1272/2008) Aquatic Acute 1 - H400, Skin Sens. 1 - H317, Skin Irrit. 2 - H315, Asp. Tox. 1 - H304, Aquatic Chronic 1 - H410, Flam. Liq. 3 - H226 5 - 15% Beta Pinene CAS-No.: 127-91-3 EC No.: 204-872-5 Classification (EC 1272/2008) Skin Sens. 1 - H317, Skin Irrit. 2 - H315, Asp. Tox. 1 - H304, Flam. Liq. 3 - H226 1-5% Geraniol CAS-No.: 106-24-1 EC No.: 203-377-1 Classification (EC 1272/2008) Aquatic Acute 2 - H401, Skin Sens. 1 - H317, Eye Dam. 1 - H318, Skin Irrit. 2 - H315, Acute Tox. 5 - H303 1 - 5% Geranyl Acetate CAS-No.: 105-87-3 EC No.: 203-341-5 Safety Data Sheet: Neroli Oil Organic Page 3 of 8 Classification (EC 1272/2008) Aquatic Acute 2 - H401, Skin Irrit. 3 -H316, Aquatic Chronic 2 - H411 4. FIRST AID MEASURES 4.1 Description of first aid measures Inhalation Remove to fresh air for at least 15 minutes, in case of complaints seek medical attention. Ingestion DO NOT INDUCE VOMITING! Immediately rinse mouth and provide fresh air. Get medical attention immediately. Skin Contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues. Eye Contact Immediately flush with plenty of pure water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse. 4.2 Most important symptoms and effects, both acute and delayed None known. 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. 05. FIRE-FIGHTING MEASURES 5.1 Extinguishing Media Extinguishing media: Carbon dioxide (CO2). Foam, dry Powder. 5.2 Special hazards arising from the product Thermal decomposition can lead to release of irritating and toxic gases and vapours. Hazardous combustion products - Irritating or toxic substances may be emitted upon burning, combustion, or decomposition. 5.3 Advice for firefighters Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions - Ensure adequate ventilation, especially in confined areas. For emergency responders - Use personal protection recommended in Section 8. 6.2 Environmental Precautions Do not discharge into drains. Keep away from surface and ground water. 6.3 Methods and material for containment and cleaning up. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 6.4 Reference to other sections See section 12. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Ensure adequate ventilation, especially in confined areas. Handle in accordance with good industrial hygiene and safety practice. Safety Data Sheet: Neroli Oil Organic Page 4 of 8 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) No additional data available. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Chemical Name European Union United Kingdom France Spain Germany LIMONENE, D- - - TWA: 1000 mg/m3 TWA: 5 ppm 5989-27-5 STEL: 1500 mg/m3 TWA: 28 mg/m3 Ceiling / Peak: 20 ppm Ceiling / Peak: 112 mg/m3 Skin BETA-PINENE - - TWA: 1000 mg/m3 TWA: 20 ppm 127-91-3 STEL: 1500 mg/m3 TWA: 113 mg/m3 Chemical Name Italy Portugal Netherlands Finland Denmark LIMONENE, D- - - - TWA: 25 ppm - 5989-27-5 TWA: 140 mg/m3 STEL: 50 ppm STEL: 280 mg/m3 BETA-PINENE - TWA: 20 ppm - - - 127-91-3 Chemical Name Austria Switzerland Poland Norway Ireland LIMONENE, D- - STEL: 14 ppm - TWA: 25 ppm - 5989-27-5 STEL: 80 mg/m3 - TWA: 140 mg/m3 TWA: 7 ppm - STEL: 37.5 ppm TWA: 40 mg/m3 - STEL: 175 mg/m3 BETA-PINENE - - - TWA: 25 ppm - 127-91-3 TWA: 140 mg/m3 STEL: 37.5 ppm STEL: 175 mg/m3 8.2 Exposure controls Protective Equipment Process Conditions No additional data available. Engineering Measures Provide adequate ventilation, especially in confined areas. Respiratory Equipment Provide adequate ventilation, especially in confined areas. Hand Protection Avoid contact with skin. War suitable gloves. Eye Protection Avid contact with eyes. Wear safety glasses with side shields. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene Measures Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Personal Protection Use personal protection according to Directive 89/686/EEC. Skin Protection Protective work clothing solvent resistant (should be checked regularly). Safety Data Sheet: Neroli Oil Organic Page 5 of 8 Environmental Exposure Avoid discharging into drainage water. Only remove via authorised companies. Controls 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Clear liquid Colour Pale yellow to amber yellow Odour Characteristic Relative Density 0.861 - 0.873 @ 20°C Flash Point (°C) 61 Refractive Index 1.468 - 1.474 @ 20°C Melting Point (°C) No additional data available. Boiling Point (°C) No additional data available. Vapour Pressure No additional data available. Solubility in Water @20°C No Auto-ignition No additional data available. temperature (°C) 9.2 Other information No additional data available. 10. STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal conditions of use. 10.2 Chemical stability Stable under normal conditions of use. 10.3 Possible hazardous reactions None if used according to storage and handling conditions and identified uses (see section 7). 10.4 Conditions to Avoid Avoid extreme heat and direct sunlight. 10.5 Incompatible materials No additional data available. 10.6 Hazardous Decomposition Products No under normal use conditions. 11. TOXOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute Toxicity Does not present an acute toxicity hazard according to information supplied. ATEmix (oral) 3,478.00 ATEmix (dermal) 6,960.00 29.2% of the mixture consists of ingredient(s) of unknown toxicity.