Evaluation of the Performance of the Intermittent Cycle Extended Aeration System in Detergent Removal from Bathroom Greywater
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Journal of Applied Research in Water and Wastewater 11(2019) 51-55 Original paper Evaluation of the performance of the intermittent cycle extended aeration system in detergent removal from bathroom greywater Vahab Ghaleh Khondabi1, Alireza Fazlali1,*, Mojtaba Zolfaghari2 1Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak, Iran. 2Department of Mechanical Engineering, Faculty of Engineering, Arak University, Arak, Iran. ARTICLE INFO ABSTRACT Article history: On average, 67 % of household wastewater is made up of greywater, which Received 26 February 2019 includes wastewater produced in household other than toilets. There are different Revised 29 March 2019 biological treatment processes for greywater treatment. One of these systems is Accepted 25 April 2019 the sequencing batch reactor (SBR), which has proven to be an effective way of treating wastewater. One of the amendments to the SBR process is the intermittent cycle extended aeration system (ICEAS). The purpose of this study was to Keywords: Activated sludge system investigate the performance of an advanced-SBR in the bathroom greywater Bathroom greywater (BGW) treatment. For this purpose, a rectangular SBR reactor (402020 cm) Intermittent cycle extended aeration with a working volume of 12 liters was developed and utilized. The primary system microorganisms of this reactor were prepared from the active sludge return to the Linear alkyl benzene sulfonates aeration pond of the Arak municipal wastewater treatment plant. The reactor was Sequencing batch reactor fed with the effluent from the initial settling ponds of the same treatment plant. After the system was set up and sufficient microorganisms were grown, the exploitation phase began with synthetic greywater. The experiments were carried out in three cycles of 4, 6 and 8 hours. The concentrations of linear alkyl benzene sulfonates (LAS), chemical oxygen demand (COD) and biochemical oxygen demand (BOD5) at the inlet were 6.8 mg/L, 385 mg/L and 170 mg/L, and in the outlet, 0.95 mg/L, 19.25 mg/L and 8.5 mg/L, in a 8-hour cycle. Therefore, the removal efficiency of the system in 8 h cycle was 86 %, 93 % and 95 %, respectively. ©2019 Razi University-All rights reserved. 1. Introduction to biological degradation resistance. ABS has been replaced by carboxylic acids and linear alkyl benzene sulfonates (LAS) since 1967, Household wastewater is recognized as one of the largest which by 97-99 % degradation was identified as a biodegradable demands on water supply, thus its recycling and reuse will significantly surfactant (Scott and Jones. 2002). LAS values in domestic wastewater reduce the amount of water consumed by households (Shamabadi et were estimated to be about 3-21 mg/L and based on samples taken al. 2015; Moslemi Zadeh. 2013; Boyjoo et al. 2013). Household from municipal wastewater treatment plants, LAS values in effluent wastewater is divided into two categories: the first group is black water, samples are about 0.071-0.71 mg/L (Torben. 2001). In general, the which is defined as toilet waste, and the second is greywater, which amount of LAS removal in wastewater treatment plants involves includes other household wastewater sources such as laundry, bath, activated sludge system (ASS) about 85 % have been reported shower, kitchen and dishwasher (Al-Jayyousi. 2003). Greywater, as a (Redisher. 1990). diluted form of wastewater, contains an average of 67 % of wastewater One of the modifications on ASS is a sequencing batch reactor (Chankya and Khuntia. 2014). Studies have shown that reuse of (SBR), which has proven to be an effective way on wastewater greywater can reduce the demand for fresh water by about 30-70 % treatment. Between 1914 and 1920, several fill and empty systems, (Wiltshire. 2005). In order to study the characteristics of greywater, it is similar to SBR, were used. But the interest in SBR system re-emerged important to consider their source. In the definition, greywater is divided from the late 1950s and early 1960s with the development of new into two groups of dark and light. Light greywater comes from technologies (USEPA. 1999). The idea of utilization of this system was bathroom/lavatory basins (sinks), showers, tubs and clothes washing offered by Robert L. Irvine (USA, 1970s) (Metcaf and Eddy. 2003). The machines, generally contain significantly less dissolved organic carbon, most important modifications on SBR system are biofilmic SBR, nitrogen and phosphorus than dark greywater. Dark greywater sources anaerobic SBR, and anaerobic-aerobic SBR. Intermittent cycle are non-laundry utility sinks and the kitchen, including sinks and extended aeration system (ICEAS) is a superior technology than SBR dishwashers, typically contain more pathogens, chemicals, fats, oil and process in, which the wastewater flows continuously into the basin. This grease (Tsoumachidou et al. 2016; Katukiza et al. 2014; Penn et al. means that the flow of input is not interrupted during the phases of the 2013). cycle. This system has three phases of aeration, settling and decanting The first synthetic detergent was made in 1916 in Germany and in in each cycle (Folke and Landner. 2000). the United States in 1946. The discovery of detergents was actually in Shin et al. (1998) examined the performance of a SBR system in order to meet the need for non-soap cleaners, which, unlike soap, don’t removing organic compounds and nitrogen from greywater. They combine with mineral salts of water don’t create insoluble compounds. considered the influent of 2 m3/d and designed an equalization tank to In 1960, the most surfactant reported in detergents was the alkyl store 2.5 m3. They maintained dissolved oxygen (DO) and pH of 3.5 benzene sulfonates (ABS) which increased wastewater problems due and 7.2 mg/L respectively. SBR performance was satisfactory in * Corresponding author Email: [email protected] P a g e Please cite this article as: V. Ghaleh Khondabi, A.R. Fazlali, M. Zolfaghari, Evaluation of the performance of the intermittent cycle extended aeration system | in detergent removal from bathroom greywater, Journal of Applied Research in Water and Wastewater, 6 (1), 2019, 51-55. 51 Ghaleh Khondabi et al. / J. App. Res. Wat. Wast. 11(2019) 51-55 greywater purification, as the effluent was 20 mg/L, 5 mg/L and 0.5 removed, only a small amount at the top of clear liquid, was removed at mg/L of COD, BOD5 and NH3, respectively. In a study on removal the discharge stage. In addition, mixed liquor suspended solid (MLSS) efficiency of BOD5, COD and detergents, Ehrampoush et al. (2007) and mixed liquor volatile suspended solid (MLVSS) increased from low concluded that artificial subsurface constructed wetland system has concentrations to 2714 mg/L and 2047 mg/L, respectively. lower removal efficiency compared to the SBR system. Ghahfarrokhi et al. (2010) conducted a study on removal of detergents from hospital wastewaters using SBR method and indicated removal efficiencies of 94.54 %, 92.97 % and 84.99 % for BOD5, COD and detergents, respectively. In a study by Pirsaheb et al. (2013) the average of LAS removal in an extended aeration process in winter and summer were 94.06 % and 99.23 %, respectively. In a study by Duarte et al. (2015) degradation of LAS in anaerobic SBR (ASBR) was evaluated. Degradation of the surfactant at the end of the operation was 87% and the removal of COD was 86 %. Eslami et al. (2015) conducted a study to evaluate the performance of an advanced-SBR in a treatment plant to remove organic materials and detergents. They achieved an efficiency of 92.92 %, 90.06 % and 81.6 % for BOD5, COD and LAS, respectively. The purpose of this study was to investigate the possibility of removing detergents and lowering the COD and BOD5 from BGW by advanced-SBR (ICEAS) and determining the required time for each of (a) the phases of the cycle in a specified flow rate. 2. Materials and methods 2.1. Experimental setup The Schematic diagram of the ICEAS bioreactor is shown in Fig. 1. Experiments were carried out in a Plexiglas cube reactor with length, width and height of 402020 cm and a working volume of 12 l (Fig. 2a). Raw wastewater in a 60 l feeding tank, continuously introduced to the reactor by a peristaltic pump. In order to provide sufficient air to microorganisms, an aeration pump with aeration rate of 5 l/m was used as well as 12 diffusers that placed at the bottom of the reactor. To ensure uniform distribution of air, especially at the low rate of aeration and in order to prevent sludge settlement without aeration, two mixers with 20 cm heights at 80 rpm were utilized (one near the bottom and the other at a height of 5 cm). It is to be noted that time of any phase and inflow level was set by an automatic the time control system. Each of the aeration, settling and decanting phases are shown in Fig. 2b, c and d, respectively. (b) Fig. 1. Schematic diagram of the SBR system. 2.2. Synthetic bathroom greywater characteristics A synthetic feed solution was adapted from previous literature (McAdam et al. 2005) in order to produce an analogue greywater (Table 1). At all stages of loading, Na2co3 was used as the only source of (c) carbon, urea and NH4Cl as nitrogen sources and K2HPO4 as the phosphate source. The characteristics of the wastewater and the concentration range of the compounds contained therein are shown in Table 2. The apparent characteristic of wastewater before and after treatment is shown in Fig. 3. This can clearly be seen in Fig. 3 which show a photograph of treated wastewater (Fig. 3a) which has a very low turbidity compared to the raw wastewater (Fig. 3b). 2.3. Reactor start up and sludge specification In order to start up SBR, the return activated sludge seed (sludge volume index (SVI): 280 mg/L, settled sludge volume (SSV); 760 mL/L) to aeration pond of the municipal wastewater treatment plant with an approximately volume of 4 L for a reactor containing 8 L of wastewater.