Leclanché Stationary Storage Solutions Credentials
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Hydrogel Leclanché Cell: Construction and Characterization
energies Article Hydrogel Leclanché Cell: Construction and Characterization Greg Jenson 1,2,* , Gurjap Singh 2,3 , Jay K. Bhama 2,4,5 and Albert Ratner 2,3 1 Department of Surgery, University of Iowa Hospitals and Clinics, Iowa City, IA 52242, USA 2 Bhama-Ratner Artificial Heart & MCS Advancement Lab, University of Iowa Department of Mechanical Engineering, 3131 Seamans Ctr, Iowa City, IA 52242, USA; [email protected] (G.S.); [email protected] (J.K.B.); [email protected] (A.R.) 3 Department of Mechanical Engineering, University of Iowa, Iowa City, IA 52242, USA 4 Baptist Health Medical Center, Little Rock, AR 72205, USA 5 Division of Cardiovascular Surgery, University of Arkansas for Medical Sciences, University of Arkansas for Medical Sciences, 4301 W Markham, Little Rock, AR 72205, USA * Correspondence: [email protected] Received: 10 December 2019; Accepted: 21 January 2020; Published: 28 January 2020 Abstract: A liquid-to-gel based Leclanché cell has been designed, constructed and characterized for use in implantable medical devices and other applications where battery access is limited. This well-established chemistry will provide reliable electrochemical potential over a wide range of applications and the novel construction provides a solution for the re-charging of electrodes in hard to access areas such as an internal pacemaker. The traditional Leclanché cell, comprised of zinc (anode) and manganese dioxide (cathode), conductive carbon powder (acetylene black or graphite), and aqueous electrolyte (NH4Cl and ZnCl2), has been suspended in an agar hydrogel to simplify construction while maintaining electrochemical performance. Agar hydrogel, saturated with electrolyte, serves as the cell support and separator allowing for the discharged battery suspension to be easily replaced once exhausted. -
247. the Leclanche Cell Copy
Notes from the Oesper Collections The Leclanché Cell William B. Jensen Department of Chemistry, University of Cincinnati Cincinnati, OH 45221-0172 The previous three issues of Museum Notes have described the Edison nickel-iron alkaline storage cell (1), the Daniel gravity cell (2), and the Grove and Bun- sen cells (3) respectively. This issue will deal with yet a fifth cell of historical importance found among the collection of voltaic cells donated to the Oesper Col- lections some years ago by the Chemistry Department of Oberlin College – the primary Leclanché cell. First described by the French scientist, Georges Leclanché, (figure 1) in 1868 (4, 5), this cell is based on the net cell reaction: Zn(s) + 2MnO2(s) + 2(NH4)Cl(aq) + 2H2O(l) → ZnCl2(aq) + 2Mn(OH)3 + 2NH3(aq) + ΔEel in which Zn(0) is oxidized to Zn(II) at the anode, Mn(IV) is reduced to Mn(III) at the cathode, and the resulting net cell potential is roughly 1.4 V. Figure 1. A portrait medallion commemorating Georges Like the Edison cell described earlier, the Leclan- Leclanché (1838-1882). ché cell was a single-fluid system that employed a saturated aqueous solution of ammonium chloride [(NH4)Cl] as the electrolyte. As originally conceived, the MnO2(s) and an inert rectangular carbon cathode came sealed in a large porous ceramic spacer (figures 2-3) and the Zn anode as a separate rod. Both of these were placed in a large rectangular glass battery jar and the jar half-filled with the (NH4)Cl(aq) electrolyte. To increase the conductivity of the MnO2(s), it was in- termixed with an equal quantity of powdered carbon. -
On Manganese (IV) Oxide (Mno2) in a Leclanche Dry Cell
Available online a t www.pelagiaresearchlibrary.com Pelagia Research Library Der Chemica Sinica, 2012, 3(1):182-191 ISSN: 0976-8505 CODEN (USA) CSHIA5 2+ Adsorption of zinc ion (Zn ) on manganese (IV) oxide (MnO 2) in a leclanche dry cell Adejoh Adu Zakariah* and Aloko Duncan Folorunsho Department of Chemical Engineering, University of Abuja, Nigeria _____________________________________________________________________________________________ ABSTRACT This work was carried out to study the adsorption of zinc nitrate (Zn(NO 3)2) on manganese (IV) oxide (MnO 2) in a leclanche dry cell. The aim of the study is to optimize the process for the adsorption of zinc ion on MnO 2 in a leclanche dry cell using a second order factorial method. Potentiometric titration method was the adsorption method used. Considering the temperature effect on electric surface charge, pH respond during titration, concentration effect on adsorption and surface charge and the nature of cation, results obtain show that adsorption is inversely proportional to temperature, in other words, as temperature of cation increases, the adsorption capacity on MnO 2 decreases at a given concentration. Also at a given temperature adsorption capacity increases as the concentration of the adsorbent increases. The highest adsorption capacity was observed at 0.1M for Zn 2+ at 28 oC . Key words : Adsorption, zinc nitrate (Zn(NO 3)2), manganese (IV) oxide, potentiometric, concentration, adsorbent. _____________________________________________________________________________________________ INTRODUCTION An electrochemical cell is a device designed to produce electrical energy as the primary output product with the cell itself undergoing a chemical transformation (reaction). Conversely, in cell some chemical reaction can be made to occur through ionic mechanism by passing electric energy into the cell (as a form of secondary input). -