NEW TECHNOLOGY BATTERIES GUIDE NIJ Guide 200-98 ABOUT the LAW ENFORCEMENT and CORRECTIONS STANDARDS and TESTING PROGRAM
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Material - Safety - Data Sheet (MSDS) No.16 for Ansmann Zinc Carbon (Mercury Free Heavy Duty) Batteries Single Cells and Multi-Cell Battery Packs 1/6
Material - Safety - Data Sheet (MSDS) No.16 for Ansmann Zinc Carbon (Mercury Free Heavy Duty) Batteries single cells and multi-cell battery packs 1/6 Date of issue: 2015 - 02 - 23 The information contained within is provided as a service to our customers and Revision no: 1 for their information only. The information and recommendations set forth herein Revision date: 2016 - 10 - 07 are made in good faith and are believed to be accurate at the date of preparation. Editor: Ansmann AG ANSMANN AG makes no warranty expressed or implied. 1. Product and Supplier Identification Product name: ANSMANN (Super) Heavy Duty Battery Designation: Zinc Manganese Dioxide Battery Models / types: R3 (AAA); R6 (AA); R14 (C); R20 (D); 6F22 (9V E-Block); 3R12; 4R25 Electrochemical system: MnO2 (Manganese Dioxide) (positive electrode) Zn (negative electrode) NH4Cl, ZnCl2 (electrolyte) Supplier: Germany ANSMANN AG Address: Industriestraße 10; 97959 Assamstadt; Germany Phone / Fax: + 49 (0) 6294 42040 / + 49 (0) 6294 420444 Home / email: ansmann.de / [email protected] USA ANSMANN USA Corporation Address: 1001 Lower Landing Rd. Ste 101; Blackwood, NJ08012; USA Phone / Facsimile: +1 973 4395244 1012 / +1 973 2062006 email: [email protected] United Kingdom ANSMANN UK LTD. Address: Units 11-12, RO24, Harlow Business Park, Harlow, Essex. CM19 5QB. UK Phone / Facsimile: +44 (0) 870 609 2233 / +44 (0) 870609 2234 email: [email protected] Hong Kong ANSMANN Energy Int. LTD. Address: Unit 3117-18, 31/F; Tower 1; Millenium City 1; No. 388 Kwun Tong Road; Kwun Tong, kowloon; Hong-Kong -
PSDS Zinc Air Batteries MF
Primary Zinc-Air-Battery: Button Type Hearing Aid Batteries Product Safety Data Sheet This "Safety information" is provide as a service to our customers Disclaimer: (EU) These batteries are no "substances" nor "preparations"according to Regulation (EC) No 1907/2006 EC. Instead they have to be regarded as "articles", no substances are intended to be released during handling. Therefore there is no obligation to supply a MSDS according to Regulation (EC) 190'7/2006, Article 31. This PSDS is intended to be unsolicited information without any further legal commitment. The details presented are in accordance with our present knowledge and experiences. They are no contractual assurances of product attributes. (U.S.A.) Material Safety Data Sheets (MSDS) are a sub-requirement of the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR Subpart 1910.1200. This Hazard Communication Standard does not apply to various subcategories including anything defined by OSHA as an "article". OSHA has defined "article" as a manufactured item other than a fluid or particle; (i) which is formed to a specific shape or design during manufacture; ii) which has end use function(s) dependent in whole or in part upon its shape or design during end use; and (iii) which under normal conditions of use does not release more than very small quantities, e.g. minute or trace amounts of a hazardous chemical, and does not pose a physical hazard or health risk to employees. This sheet is provided as technical information only. The information contained in this Product Safety Data Sheet has been established to the best of RENATA SA's knowledge and belief. -
Electrochemical Cells
Electrochemical cells = electronic conductor If two different + surrounding electrolytes are used: electrolyte electrode compartment Galvanic cell: electrochemical cell in which electricity is produced as a result of a spontaneous reaction (e.g., batteries, fuel cells, electric fish!) Electrolytic cell: electrochemical cell in which a non-spontaneous reaction is driven by an external source of current Nils Walter: Chem 260 Reactions at electrodes: Half-reactions Redox reactions: Reactions in which electrons are transferred from one species to another +II -II 00+IV -II → E.g., CuS(s) + O2(g) Cu(s) + SO2(g) reduced oxidized Any redox reactions can be expressed as the difference between two reduction half-reactions in which e- are taken up Reduction of Cu2+: Cu2+(aq) + 2e- → Cu(s) Reduction of Zn2+: Zn2+(aq) + 2e- → Zn(s) Difference: Cu2+(aq) + Zn(s) → Cu(s) + Zn2+(aq) - + - → 2+ More complex: MnO4 (aq) + 8H + 5e Mn (aq) + 4H2O(l) Half-reactions are only a formal way of writing a redox reaction Nils Walter: Chem 260 Carrying the concept further Reduction of Cu2+: Cu2+(aq) + 2e- → Cu(s) In general: redox couple Ox/Red, half-reaction Ox + νe- → Red Any reaction can be expressed in redox half-reactions: + - → 2 H (aq) + 2e H2(g, pf) + - → 2 H (aq) + 2e H2(g, pi) → Expansion of gas: H2(g, pi) H2(g, pf) AgCl(s) + e- → Ag(s) + Cl-(aq) Ag+(aq) + e- → Ag(s) Dissolution of a sparingly soluble salt: AgCl(s) → Ag+(aq) + Cl-(aq) − 1 1 Reaction quotients: Q = a − ≈ [Cl ] Q = ≈ Cl + a + [Ag ] Ag Nils Walter: Chem 260 Reactions at electrodes Galvanic cell: -
Hydrogel Leclanché Cell: Construction and Characterization
energies Article Hydrogel Leclanché Cell: Construction and Characterization Greg Jenson 1,2,* , Gurjap Singh 2,3 , Jay K. Bhama 2,4,5 and Albert Ratner 2,3 1 Department of Surgery, University of Iowa Hospitals and Clinics, Iowa City, IA 52242, USA 2 Bhama-Ratner Artificial Heart & MCS Advancement Lab, University of Iowa Department of Mechanical Engineering, 3131 Seamans Ctr, Iowa City, IA 52242, USA; [email protected] (G.S.); [email protected] (J.K.B.); [email protected] (A.R.) 3 Department of Mechanical Engineering, University of Iowa, Iowa City, IA 52242, USA 4 Baptist Health Medical Center, Little Rock, AR 72205, USA 5 Division of Cardiovascular Surgery, University of Arkansas for Medical Sciences, University of Arkansas for Medical Sciences, 4301 W Markham, Little Rock, AR 72205, USA * Correspondence: [email protected] Received: 10 December 2019; Accepted: 21 January 2020; Published: 28 January 2020 Abstract: A liquid-to-gel based Leclanché cell has been designed, constructed and characterized for use in implantable medical devices and other applications where battery access is limited. This well-established chemistry will provide reliable electrochemical potential over a wide range of applications and the novel construction provides a solution for the re-charging of electrodes in hard to access areas such as an internal pacemaker. The traditional Leclanché cell, comprised of zinc (anode) and manganese dioxide (cathode), conductive carbon powder (acetylene black or graphite), and aqueous electrolyte (NH4Cl and ZnCl2), has been suspended in an agar hydrogel to simplify construction while maintaining electrochemical performance. Agar hydrogel, saturated with electrolyte, serves as the cell support and separator allowing for the discharged battery suspension to be easily replaced once exhausted. -
On the Electrochemical Stability of Nanocrystalline La0.9Ba0.1F2.9 Against Metal Electrodes
nanomaterials Article Fluoride-Ion Batteries: On the Electrochemical Stability of Nanocrystalline La0.9Ba0.1F2.9 against Metal Electrodes Maria Gombotz 1,* , Veronika Pregartner 1, Ilie Hanzu 1,2,* and H. Martin R. Wilkening 1,2 1 Institute for Chemistry and Technology of Materials, Technical Universtiy of Graz, Graz 8010, Austria; [email protected] (V.P.); [email protected] (H.M.R.W.) 2 ALISTORE—European Research Institute, CNRS FR3104, Hub de l’Energie, Rue Baudelocque, 80039 Amiens, France * Correspondence: [email protected] (M.G.); [email protected] (I.H.) Received: 27 September 2019; Accepted: 23 October 2019; Published: 25 October 2019 Abstract: Over the past years, ceramic fluorine ion conductors with high ionic conductivity have stepped into the limelight of materials research, as they may act as solid-state electrolytes in fluorine-ion batteries (FIBs). A factor of utmost importance, which has been left aside so far, is the electrochemical stability of these conductors with respect to both the voltage window and the active materials used. The compatibility with different current collector materials is important as well. In the course of this study, tysonite-type La0.9Ba0.1F2.9, which is one of the most important electrolyte in first-generation FIBs, was chosen as model substance to study its electrochemical stability against a series of metal electrodes viz. Pt, Au, Ni, Cu and Ag. To test anodic or cathodic degradation processes we carried out cyclic voltammetry (CV) measurements using a two-electrode set-up. We covered a voltage window ranging from −1 to 4 V, which is typical for FIBs, and investigated the change of the response of the CVs as a function of scan rate (2 mV/s to 0.1 V/s). -
247. the Leclanche Cell Copy
Notes from the Oesper Collections The Leclanché Cell William B. Jensen Department of Chemistry, University of Cincinnati Cincinnati, OH 45221-0172 The previous three issues of Museum Notes have described the Edison nickel-iron alkaline storage cell (1), the Daniel gravity cell (2), and the Grove and Bun- sen cells (3) respectively. This issue will deal with yet a fifth cell of historical importance found among the collection of voltaic cells donated to the Oesper Col- lections some years ago by the Chemistry Department of Oberlin College – the primary Leclanché cell. First described by the French scientist, Georges Leclanché, (figure 1) in 1868 (4, 5), this cell is based on the net cell reaction: Zn(s) + 2MnO2(s) + 2(NH4)Cl(aq) + 2H2O(l) → ZnCl2(aq) + 2Mn(OH)3 + 2NH3(aq) + ΔEel in which Zn(0) is oxidized to Zn(II) at the anode, Mn(IV) is reduced to Mn(III) at the cathode, and the resulting net cell potential is roughly 1.4 V. Figure 1. A portrait medallion commemorating Georges Like the Edison cell described earlier, the Leclan- Leclanché (1838-1882). ché cell was a single-fluid system that employed a saturated aqueous solution of ammonium chloride [(NH4)Cl] as the electrolyte. As originally conceived, the MnO2(s) and an inert rectangular carbon cathode came sealed in a large porous ceramic spacer (figures 2-3) and the Zn anode as a separate rod. Both of these were placed in a large rectangular glass battery jar and the jar half-filled with the (NH4)Cl(aq) electrolyte. To increase the conductivity of the MnO2(s), it was in- termixed with an equal quantity of powdered carbon. -
Batteries Information Received from EU, Canada, Japan, Indonesia, USA and Other Stakeholders (BAJ, IPEN, NRDC, ZMWG)
Batteries Information received from EU, Canada, Japan, Indonesia, USA and other stakeholders (BAJ, IPEN, NRDC, ZMWG) 1. Category of mercury-added product Batteries 2. Further description of the product Mercury-containing button cells 3. Information on the use of the Currently, there are three types of button cell batteries that contain mercury: zinc air, silver oxide and alkaline. product These batteries contain mercury in small amounts (typically 0.1-2%) and the purpose of mercury in the cell is to prevent the build-up of hydrogen gas. The mercury acts as a barrier to the production of hydrogen and as such prevents the cell swelling and becoming damaged. Figure 1 – Cross Section of Zinc Anode Button Cell and Zinc Air Button Cell (European Commission, 2014) Range of mercury content/consumption per unit product - 0.1 – 2 weight-% (button cells with intentionally added mercury) - 0.0005 weight-% (button cells without intentionally added mercury) Button batteries are used for powering high drain devices such as watches, calculators, and hearing aids. 4. Information on the availability of EU mercury-free (or less-mercury) Main alternatives: Mercury-free zinc air batteries alternatives Mercury free versions are commercially available for all applications of the main types of button cells (lithium, silver, oxide, alkaline and zinc air). The most frequently used types make use of zinc air technology (European Commission, 2014). Since October 2015, mercury-containing button cell batteries have been prohibited in the EU following the expiry of the exemption granted under the Batteries Directive. 1 Canada Alternatives: mercury-free silver oxide batteries, mercury-free zinc air batteries, lithium batteries Mercury-free alternatives have been available from major battery manufacturers since the late 1990s and early 2000s (e.g. -
Galvanic Cell Notation • Half-Cell Notation • Types of Electrodes • Cell
Galvanic Cell Notation ¾Inactive (inert) electrodes – not involved in the electrode half-reaction (inert solid conductors; • Half-cell notation serve as a contact between the – Different phases are separated by vertical lines solution and the external el. circuit) 3+ 2+ – Species in the same phase are separated by Example: Pt electrode in Fe /Fe soln. commas Fe3+ + e- → Fe2+ (as reduction) • Types of electrodes Notation: Fe3+, Fe2+Pt(s) ¾Active electrodes – involved in the electrode ¾Electrodes involving metals and their half-reaction (most metal electrodes) slightly soluble salts Example: Zn2+/Zn metal electrode Example: Ag/AgCl electrode Zn(s) → Zn2+ + 2e- (as oxidation) AgCl(s) + e- → Ag(s) + Cl- (as reduction) Notation: Zn(s)Zn2+ Notation: Cl-AgCl(s)Ag(s) ¾Electrodes involving gases – a gas is bubbled Example: A combination of the Zn(s)Zn2+ and over an inert electrode Fe3+, Fe2+Pt(s) half-cells leads to: Example: H2 gas over Pt electrode + - H2(g) → 2H + 2e (as oxidation) + Notation: Pt(s)H2(g)H • Cell notation – The anode half-cell is written on the left of the cathode half-cell Zn(s) → Zn2+ + 2e- (anode, oxidation) + – The electrodes appear on the far left (anode) and Fe3+ + e- → Fe2+ (×2) (cathode, reduction) far right (cathode) of the notation Zn(s) + 2Fe3+ → Zn2+ + 2Fe2+ – Salt bridges are represented by double vertical lines ⇒ Zn(s)Zn2+ || Fe3+, Fe2+Pt(s) 1 + Example: A combination of the Pt(s)H2(g)H Example: Write the cell reaction and the cell and Cl-AgCl(s)Ag(s) half-cells leads to: notation for a cell consisting of a graphite cathode - 2+ Note: The immersed in an acidic solution of MnO4 and Mn 4+ reactants in the and a graphite anode immersed in a solution of Sn 2+ overall reaction are and Sn . -
On Manganese (IV) Oxide (Mno2) in a Leclanche Dry Cell
Available online a t www.pelagiaresearchlibrary.com Pelagia Research Library Der Chemica Sinica, 2012, 3(1):182-191 ISSN: 0976-8505 CODEN (USA) CSHIA5 2+ Adsorption of zinc ion (Zn ) on manganese (IV) oxide (MnO 2) in a leclanche dry cell Adejoh Adu Zakariah* and Aloko Duncan Folorunsho Department of Chemical Engineering, University of Abuja, Nigeria _____________________________________________________________________________________________ ABSTRACT This work was carried out to study the adsorption of zinc nitrate (Zn(NO 3)2) on manganese (IV) oxide (MnO 2) in a leclanche dry cell. The aim of the study is to optimize the process for the adsorption of zinc ion on MnO 2 in a leclanche dry cell using a second order factorial method. Potentiometric titration method was the adsorption method used. Considering the temperature effect on electric surface charge, pH respond during titration, concentration effect on adsorption and surface charge and the nature of cation, results obtain show that adsorption is inversely proportional to temperature, in other words, as temperature of cation increases, the adsorption capacity on MnO 2 decreases at a given concentration. Also at a given temperature adsorption capacity increases as the concentration of the adsorbent increases. The highest adsorption capacity was observed at 0.1M for Zn 2+ at 28 oC . Key words : Adsorption, zinc nitrate (Zn(NO 3)2), manganese (IV) oxide, potentiometric, concentration, adsorbent. _____________________________________________________________________________________________ INTRODUCTION An electrochemical cell is a device designed to produce electrical energy as the primary output product with the cell itself undergoing a chemical transformation (reaction). Conversely, in cell some chemical reaction can be made to occur through ionic mechanism by passing electric energy into the cell (as a form of secondary input). -
Energizer Non-Rechargeable Batteries: Frequently Asked Questions
Energizer® Non-Rechargeable Batteries: Frequently Asked Questions Click on the question to view the answer: 1. Is it a good idea to store batteries in a refrigerator or freezer? 2. Why is mixing batteries of different chemistries, brands or age a potential problem? 3. What type of batteries can be recharged? 4. How long can I store batteries? 5. How can I test batteries to see if they’re still good? 6. What is the difference between carbon zinc and alkaline batteries? 7. Why doesn’t my flashlight work well in cold weather? 8. Are there potential dangers or safety issues carrying loose batteries in a purse or pocket? 9. How long will my batteries last in a device? 10.How is the rated capacity of a battery determined? 11.Does the capacity of a battery change with the drain rate? 12.Is there a guarantee on Energizer batteries? 13.What increases the possibility for alkaline battery leakage? 14.Are cylindrical alkaline batteries considered hazardous waste? 15.Where can I obtain information on the effects of swallowing a battery? 16.Are Energizer batteries RoHS and WEEE compliant? 17.Are Energizer batteries compliant to the EU Battery Directive (226/66/EC)? 18.Can I fly commercially with non-rechargeable Energizer primary lithium batteries? 19.Do Energizer batteries require an MSDS? 20.Can magnets affect battery performance Answers are designed to be generally informative ©2012 Energizer and do not constitute a warranty implied or otherwise. Version 6.2 Energizer® Non-Rechargeable Batteries: Frequently Asked Questions Click on blue arrow to return to questions: 1. -
Introduction to Batteries
Introduction to Batteries Course No: E03-002 Credit: 3 PDH A. Bhatia Continuing Education and Development, Inc. 22 Stonewall Court Woodcliff Lake, NJ 07677 P: (877) 322-5800 [email protected] CHAPTER 2 BATTERIES LEARNING OBJECTIVES Upon completing this chapter, you will be able to: 1. State the purpose of a cell. 2. State the purpose of the three parts of a cell. 3. State the difference between the two types of cells. 4. Explain the chemical process that takes place in the primary and secondary cells. 5. Recognize and define the terms electrochemical action, anode, cathode, and electrolyte. 6. State the causes of polarization and local action and describe methods of preventing these effects. 7. Identify the parts of a dry cell. 8. Identify the various dry cells in use today and some of their capabilities and limitations. 9. Identify the four basic secondary cells, their construction, capabilities, and limitations. 10. Define a battery, and identify the three ways of combining cells to form a battery. 11. Describe general maintenance procedures for batteries including the use of the hydrometer, battery capacity, and rating and battery charging. 12. Identify the five types of battery charges. 13. Observe the safety precautions for working with and around batteries. INTRODUCTION The purpose of this chapter is to introduce and explain the basic theory and characteristics of batteries. The batteries which are discussed and illustrated have been selected as representative of many models and types which are used in the Navy today. No attempt has been made to cover every type of battery in use, however, after completing this chapter you will have a good working knowledge of the batteries which are in general use. -
Evaluation of Rapid Electric Battery Charging Techniques
UNLV Theses, Dissertations, Professional Papers, and Capstones 2009 Evaluation of rapid electric battery charging techniques Ronald Baroody University of Nevada Las Vegas Follow this and additional works at: https://digitalscholarship.unlv.edu/thesesdissertations Part of the Power and Energy Commons Repository Citation Baroody, Ronald, "Evaluation of rapid electric battery charging techniques" (2009). UNLV Theses, Dissertations, Professional Papers, and Capstones. 156. http://dx.doi.org/10.34917/1392506 This Thesis is protected by copyright and/or related rights. It has been brought to you by Digital Scholarship@UNLV with permission from the rights-holder(s). You are free to use this Thesis in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s) directly, unless additional rights are indicated by a Creative Commons license in the record and/ or on the work itself. This Thesis has been accepted for inclusion in UNLV Theses, Dissertations, Professional Papers, and Capstones by an authorized administrator of Digital Scholarship@UNLV. For more information, please contact [email protected]. EVALUATION OF RAPID ELECTRIC BATTERY CHARGING TECHNIQUES By Ronald Baroody Bachelor of Science University of Nevada, Las Vegas 2005 A thesis submitted in partial fulfillment of the requirements for the Master of Science in Engineering Department of Electrical and Computer Engineering Howard R. Hughes College of Engineering Graduate