Petroleum Coke Refueling—An Economic Alternative for Existing
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Update on Lignite Firing
Update on lignite firing Qian Zhu CCC/201 ISBN 978-92-9029-521-1 June 2012 copyright © IEA Clean Coal Centre Abstract Low rank coals have gained increasing importance in recent years and the long-term future of coal -derived energy supplies will have to include the greater use of low rank coal. However, the relatively low economic value due to the high moisture content and low calorific value, and other undesirable properties of lignite coals limited their use mainly to power generation at, or, close to, the mining site. Another important issue regarding the use of lignite is its environmental impact. A range of advanced combustion technologies has been developed to improve the efficiency of lignite-fired power generation. With modern technologies it is now possible to produce electricity economically from lignite while addressing environmental concerns. This report reviews the advanced technologies used in modern lignite-fired power plants with a focus on pulverised lignite combustion technologies. CFBC combustion processes are also reviewed in brief and they are compared with pulverised lignite combustion technologies. Acronyms and abbreviations CFB circulating fluidised bed CFBC circulating fluidised bed combustion CFD computational fluid dynamics CV calorific value EHE external heat exchanger GRE Great River Energy GWe gigawatts electric kJ/kg kilojoules per kilogram kWh kilowatts hour Gt billion tonnes FBC fluidised bed combustion FBHE fluidised bed heat exchanger FEGT furnace exit gas temperature FGD flue gas desulphurisation GJ -
'Retrofitting CCS to Coal: Enhancing Australia's Energy
RETROFITTING CCS TO COAL: ENHANCING AUSTRALIA’S ENERGY SECURITY RETROFITTING CCS TO COAL: ENHANCING AUSTRALIA’S ENERGY SECURITY any representation about the content and suitability Disclaimer of this information for any particular purpose. The document is not intended to comprise advice, and is This report was completed on 2 March 2017 and provided “as is” without express or implied therefore the Report does not take into account warranty. Readers should form their own conclusion events or circumstances arising after that time. The as to its applicability and suitability. The authors Report’s authors take no responsibility to update the reserve the right to alter or amend this document Report. without prior notice. The Report’s modelling considers only a single set of Authors: Geoff Bongers, Gamma Energy Technology input assumptions which should not be considered Stephanie Byrom, Gamma Energy Technology entirely exhaustive. Modelling inherently requires Tania Constable, CO2CRC Limited assumptions about future behaviours and market interactions, which may result in forecasts that deviate from actual events. There will usually be About CO2CRC Limited: differences between estimated and actual results, CO2CRC Limited is Australia’s leading CCS research because events and circumstances frequently do not organisation, having invested $100m in CCS research occur as expected, and those differences may be over the past decade. CO2CRC is the first organisation material. The authors of the Report take no in Australia to have demonstrated CCS end-to-end, responsibility for the modelling presented to be and has successfully stored more than 80,000 tonnes considered as a definitive account. of CO2 at its renowned Otway Research Facility in The authors of the Report highlight that the Report, Victoria. -
Solutions for Energy Crisis in Pakistan I
Solutions for Energy Crisis in Pakistan i ii Solutions for Energy Crisis in Pakistan Solutions for Energy Crisis in Pakistan iii ACKNOWLEDGEMENTS This volume is based on papers presented at the two-day national conference on the topical and vital theme of Solutions for Energy Crisis in Pakistan held on May 15-16, 2013 at Islamabad Hotel, Islamabad. The Conference was jointly organised by the Islamabad Policy Research Institute (IPRI) and the Hanns Seidel Foundation, (HSF) Islamabad. The organisers of the Conference are especially thankful to Mr. Kristof W. Duwaerts, Country Representative, HSF, Islamabad, for his co-operation and sharing the financial expense of the Conference. For the papers presented in this volume, we are grateful to all participants, as well as the chairpersons of the different sessions, who took time out from their busy schedules to preside over the proceedings. We are also thankful to the scholars, students and professionals who accepted our invitation to participate in the Conference. All members of IPRI staff — Amjad Saleem, Shazad Ahmad, Noreen Hameed, Shazia Khurshid, and Muhammad Iqbal — worked as a team to make this Conference a success. Saira Rehman, Assistant Editor, IPRI did well as stage secretary. All efforts were made to make the Conference as productive and result oriented as possible. However, if there were areas left wanting in some respect the Conference management owns responsibility for that. iv Solutions for Energy Crisis in Pakistan ACRONYMS ADB Asian Development Bank Bcf Billion Cubic Feet BCMA -
Petroleum Coke
Report No. 72 PETROLEUM COKE by SAMUEL C. SPENCER October 1971 A private report by the 0 PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA I * CONTENTS 1 INTRODUCTION, . 1 2 SUMMARY . * . , . Economic Aspects ...................... 6 Technical Aspects ..................... 10 3 INDUSTRY STATUS . , . , , . 17 Trends . .................... 17 Applications . , . .................... 29 Fuel . .................... 31 Aluminum (anodes) .................... 32 MetallurgicalCoke .................... 36 Chemicals . .................... 37 Formed Shapes . .................... 38 Other Uses . , .................... 39 4 DEVELOPMENTOF COKING PROCESSES . , , , , . , . 41 5 CHEMISTRY ......................... 47 Composition ........................ 47 Basic Chemistry ...................... 52 6 DELAYED COKING. ...................... 59 Review of Process ..................... 59 Process Description .................... 68 Materials of COnStrUctiOn ................. 83 Process Discussion ..................... 84 Process Variations and Innovations ............. 93 Cost Estimates ....................... 95 Capital Costs ...................... 96 Production Costs ..................... 100 Needle Coke Economics ................... 112 V CONTENTS 7 FLUID COKING ........................ 119 Review of Process ..................... 119 Process Description .................... 129 Materials of Construction ................. 133 Process Discussion ..................... 140 Process Variations and Innovations ............. 144 Cost Estimates -
Screening-Level Hazard Characterization of Petroleum Coke
U.S. Environmental Protection Agency June 2011 Hazard Characterization Document SCREENING-LEVEL HAZARD CHARACTERIZATION Petroleum Coke Category SPONSORED CHEMICALS Petroleum coke, green CASRN 64741-79-3 Petroleum coke, calcined CASRN 64743-05-1 The High Production Volume (HPV) Challenge Program1was conceived as a voluntary initiative aimed at developing and making publicly available screening-level health and environmental effects information on chemicals manufactured in or imported into the United States in quantities greater than one million pounds per year. In the Challenge Program, producers and importers of HPV chemicals voluntarily sponsored chemicals; sponsorship entailed the identification and initial assessment of the adequacy of existing toxicity data/information, conducting new testing if adequate data did not exist, and making both new and existing data and information available to the public. Each complete data submission contains data on 18 internationally agreed to “SIDS” (Screening Information Data Set1,2) endpoints that are screening-level indicators of potential hazards (toxicity) for humans or the environment. The Environmental Protection Agency’s Office of Pollution Prevention and Toxics (OPPT) is evaluating the data submitted in the HPV Challenge Program on approximately 1400 sponsored chemicals by developing hazard characterizations (HCs). These HCs consist of an evaluation of the quality and completeness of the data set provided in the Challenge Program submissions. They are not intended to be definitive statements regarding the possibility of unreasonable risk of injury to health or the environment. The evaluation is performed according to established EPA guidance2,3 and is based primarily on hazard data provided by sponsors; however, in preparing the hazard characterization, EPA considered its own comments and public comments on the original submission as well as the sponsor’s responses to comments and revisions made to the submission. -
Carbon Footprint for Mercury Capture from Coal-Fired Boiler Flue Gas
energies Article Carbon Footprint for Mercury Capture from Coal-Fired Boiler Flue Gas Magdalena Gazda-Grzywacz 1,* , Łukasz Winconek 2 and Piotr Burmistrz 1 1 Faculty of Energy & Fuels, AGH University of Science and Technology, Mickiewicz Avenue 30, 30-059 Krakow, Poland; [email protected] 2 Grand Activated Sp. z o.o., Białostocka 1, 17-200 Hajnówka, Poland; [email protected] * Correspondence: [email protected] Abstract: Power production from coal combustion is one of two major anthropogenic sources of mercury emission to the atmosphere. The aim of this study is the analysis of the carbon footprint of mercury removal technologies through sorbents injection related to the removal of 1 kg of mercury from flue gases. Two sorbents, i.e., powdered activated carbon and the coke dust, were analysed. The assessment included both direct and indirect emissions related to various energy and material needs life cycle including coal mining and transport, sorbents production, transport of sorbents to the power plants, and injection into flue gases. The results show that at the average mercury concentration in processed flue gasses accounting to 28.0 µg Hg/Nm3, removal of 1 kg of mercury from flue gases required 14.925 Mg of powdered activated carbon and 33.594 Mg of coke dust, respec- tively. However, the whole life cycle carbon footprint for powdered activated carbon amounted to −1 89.548 Mg CO2-e·kg Hg, whereas for coke dust this value was around three times lower and −1 amounted to 24.452 Mg CO2-e·kg Hg. Considering the relatively low price of coke dust and its lower impact on GHG emissions, it can be found as a promising alternative to commercial powdered Citation: Gazda-Grzywacz, M.; activated carbon. -
Why the Bay Area Should Say “No” to Coal and Petroleum Coke Exports
Why the Bay Area should say “No” to Coal and Petroleum Coke Exports Big coal and oil companies are looking for ways to ship their dirty commodities abroad from U.S. ports. As Northwest communities push back against proposed export terminals in Washington and Oregon, the companies have turned to their next target: the Bay Area. If coal and petroleum coke-carrying trains come to our area, coal dust from open rail cars will threaten community health by polluting our air, land and water. Thousands of people on the West Coast are leading a grassroots movement against coal exports. It’s time to let big coal and oil know that their exports aren’t welcome in California. Where is the coal coming from? To reach Bay Area ports, coal trains from mines in the Powder River Basin (PRB) or the Utah and Colorado region travel through many communities including Sacramento, Richmond, Stockton, Pittsburg, Bakersfield, Fresno, Merced and Modesto. And these trains are already on the move.1 Where is petcoke coming from, and what is it? • Petroleum coke, or petcoke, is a solid carbon byproduct that results from oil refining processes. When petcoke is burnt, it emits 5 to 10 percent more carbon dioxide 2) per (C0 unit of energy than coal. On average, one ton of petcoke yields 53.6 percent more CO2 than a ton of coal.2 Petcoke also emits toxic residues, from heavy metals to sulfur. • Petcoke is so dirty that the U.S. Environmental Protection Agency bans it from being burned in our country. Yet, the EPA still allows it to be exported abroad, pushing the pollution offshore. -
Appendix A: Calculation of Flue Gas Composition
Appendix A: Calculation of Flue Gas Composition Consider 100 kg of biomass (pine wood) with an Ultimate Analysis on a dry ash free basis given in Table A.1. This calculation assumes that all the carbon is burned i.e. there is no carbon in the ash or carbon monoxide formed. If there is the unburned carbon has to be sub- tracted from the value of carbon in the above table. Also that the S, N and Cl are negligible and there is no ingress of N2 in the flue or sampling system. Moisture content given in the Proximate Analysis has to be allowed for in the calculation as well. Assume the combustion reactions are C + O2 = CO2 2H2 + O2 = 2H2O Oxygen required for stoichiometric combustion = 4.33 + 1.6 − 1.3 = 4.63kg-mol Air requirement = [4.63 × 100 × 22.41 ]/[ 21]=494.1 m3 at NTP Composition of the dry flue gas from the stoichiometric combustion of 1 kg of biomass: 3 N2 from theoretical air 4.94 0.79 3.90 m . = × = 3 N2 from biomass 0.001 0.224 0.0002 m . = × = 3 CO2 from biomass 4.33 0.224 0.97 m . Total amount of dry= flue gas× per 1 kg= wood 4.872 m3. = If the concentration in the wet flue gas is required then the water content has to be included in the above calculation. © The Author(s) 2014 105 J.M. Jones et al., Pollutants Generated by the Combustion of Solid Biomass Fuels, SpringerBriefs in Applied Sciences and Technology, DOI 10.1007/978-1-4471-6437-1 106 Appendix A: Calculation of Flue Gas Composition Table A.1 Calculation of Element Molecular weight Mols O2 required flue gas composition C, 52.00 12 4.33 H, 6.20 2 1.6 O, 41.60 32 1.3 − N, 0.2 28 Therefore % CO 0.97/4.872 19.91 assuming stoichiometric combustion (0 % 2 = = O2). -
COAL CONFERENCE University of Pittsburgh · Swanson School of Engineering ABSTRACTS BOOKLET
Thirty-Fifth Annual INTERNATIONAL PITTSBURGH COAL CONFERENCE University of Pittsburgh · Swanson School of Engineering ABSTRACTS BOOKLET Clean Coal-based Energy/Fuels and the Environment October 15-18, 2018 New Century Grand Hotel Xuzhou Hosted by: The conference acknowledges the support of Co-hosted by: K. C. Wong Education Foundation, Hong Kong A NOTE TO THE READER This Abstracts Booklet is prepared solely as a convenient reference for the Conference participants. Abstracts are arranged in a numerical order of the oral and poster sessions as published in the Final Conference Program. In order to facilitate the task for the reader to locate a specific abstract in a given session, each paper is given two numbers: the first designates the session number and the second represents the paper number in that session. For example, Paper No. 25.1 is the first paper to be presented in the Oral Session #25. Similarly, Paper No. P3.1 is the first paper to appear in the Poster Session #3. It should be cautioned that this Abstracts Booklet is prepared based on the original abstracts that were submitted, unless the author noted an abstract change. The contents of the Booklet do not reflect late changes made by the authors for their presentations at the Conference. The reader should consult the Final Conference Program for any such changes. Furthermore, updated and detailed full manuscripts, published in the Conference Proceedings, will be sent to all registered participants following the Conference. On behalf of the Thirty-Fifth Annual International Pittsburgh Coal Conference, we wish to express our sincere appreciation and gratitude to Ms. -
Identification and Selection of Major Carbon Dioxide Stream Compositions
PNNL-20493 Prepared for the U.S. Department of Energy under Contract DE-AC05-76RL01830 Identification and Selection of Major Carbon Dioxide Stream Compositions GV Last MT Schmick June 2011 PNNL-20493 Identification and Selection of Major Carbon Dioxide Stream Compositions GV Last MT Schmick June 2011 Prepared for the U.S. Department of Energy under Contract DE-AC05-76RL01830 Pacific Northwest National Laboratory Richland, Washington 99352 Abstract A critical component in the assessment of long-term risk from geologic sequestration of carbon dioxide (CO2) is the ability to predict mineralogical and geochemical changes within storage reservoirs as a result of rock-brine-CO2 reactions. Impurities and/or other constituents in CO2 source streams selected for sequestration can affect both the chemical and physical (e.g., density, viscosity, interfacial tension) properties of CO2 in the deep subsurface. The nature and concentrations of these impurities are a function of both the industrial source(s) of CO2, as well as the carbon capture technology used to extract the CO2 and produce a concentrated stream for subsurface injection and geologic sequestration. This report summarizes the relative concentrations of CO2 and other constituents in exhaust gases from major non-energy-related industrial sources of CO2. Assuming that carbon capture technology would remove most of the incondensable gases N2, O2, and Ar, leaving SO2 and NOx as the main impurities, the authors of this report selected four test fluid compositions for use in geochemical experiments. These included the following: 1) a pure CO2 stream representative of food-grade CO2 used in most enhanced oil recovery projects; 2) a test fluid composition containing low concentrations (0.5 mole %) SO2 and NOx (representative of that generated from cement production); 3) a test fluid composition with higher concentrations (2.5 mole %) of SO2; and 4) test fluid composition containing 3 mole % H2S. -
Experience from Post-Combustion Capture Pilot Plant Operations in Australia
1st Post Combustion Capture Conference Experience from post-combustion capture pilot plant operations in Australia A. Cottrella*, P.H.M. Ferona aCoal Technology Portfolio, CSIRO Energy Technology, Newcastle, Australia Australia is highly dependent on coal for power generation and also for income and job creation through its significant exports. With this it is essential that Australia has an active program for investigating the implementation of coal combustion CO2 reduction technologies. CSIRO is a national, government funded research organization that has been tasked with challenge of addressing the issues associated with the reduction of CO2 emissions through application of post- combustion capture technologies for coal fired power stations. PCC program at CSIRO investigates many aspects of the technology and part of that has been through construction and operation of three PCC pilot plants located at Australian power station sites treating real flue gas. This paper will discuss learnings that have come from the operation of the plants. Australia is highly dependent on coal for power generation and also income and job creation through its significant exports. With this it is essential that Australia has an active program for investigating the implementation of CO2 reduction technologies as a result of the combustion of coal. CSIRO is a national, government funded research organization that has been tasked with challenge of addressing the issues associated with the reduction of CO2 emissions through application of post-combustion capture technologies for coal fired power stations. PCC program at CSIRO investigates many aspects of the technology and part of that has been through construction and operation of three PCC pilot plants located at Australian power station sites treating real flue gas. -
Tutorial: Delayed Coking Fundamentals
Tutorial: Delayed Coking Fundamentals Paul J. Ellis Christopher A. Paul Great Lakes Carbon Corporation Port Arthur, TX Prepared for presentation at the AIChE 1998 Spring National Meeting New Orleans, LA March 8-12, 1998 Topical Conference on Refinery Processing Tutorial Session: Delayed Coking Paper 29a Copyright 1998 Great Lakes Carbon Corporation UNPUBLISHED March 9, 1998 1 ABSTRACT Great Lakes Carbon Corporation has worked closely with refineries producing delayed coke in all forms, fuel grade (shot or sponge), anode grade (sponge), and electrode grade (needle) since start-up of the company's first calcining operation in 1937. With on-going research in the area of delayed coking since 1942, Great Lakes Carbon (GLC) has operated delayed coking pilot units including an excellent large-scale pilot unit with a coke drum 0.3 meter (1 ft) diameter by 2.1 meters (7 ft) long and has developed physical models which explain coke formation in coke drums. Knowledge of commercial delayed coking units as well as that of the GLC Pilot Delayed Coker is used in this tutorial paper to describe the formation and uses of the three types of structures of delayed petroleum coke: needle, sponge, and shot. Troubleshooting tips are included on many aspects of the delayed coking drum cycle including: steam stripping, water quenching, coke cutting, drum warm-up, and drum switching technique. Suggestions and descriptions of delayed coking unit hardware are included. The objective of this tutorial paper is to acquaint the non-refinery technologist and further the knowledge of refinery personnel with the delayed coking operation, delayed coking unit hardware, types of coke that can be produced, coke formation models, and the uses of petroleum coke.