Komatiitic Flows of the Pioneer Ultramafic Complex of the 3.3Ga
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Louisiana State University LSU Digital Commons LSU Master's Theses Graduate School 2008 Komatiitic flows of the pioneer ultramafic complex of the 3.3Ga Weltevreden Formation, Barberton Greenstone Belt, South Africa: stratigraphy, petrology, and geochemistry Marc Romain Cooper Louisiana State University and Agricultural and Mechanical College, [email protected] Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_theses Part of the Earth Sciences Commons Recommended Citation Cooper, Marc Romain, "Komatiitic flows of the pioneer ultramafic ompc lex of the 3.3Ga Weltevreden Formation, Barberton Greenstone Belt, South Africa: stratigraphy, petrology, and geochemistry" (2008). LSU Master's Theses. 1599. https://digitalcommons.lsu.edu/gradschool_theses/1599 This Thesis is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Master's Theses by an authorized graduate school editor of LSU Digital Commons. For more information, please contact [email protected]. KOMATIITIC FLOWS OF THE PIONEER ULTRAMAFIC COMPLEX OF THE 3.3GA WELTEVREDEN FORMATION, BARBERTON GREENSTONE BELT, SOUTH AFRICA: STRATIGRAPHY, PETROLOGY, AND GEOCHEMISTRY A Thesis Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College In partial fulfillment of the requirements for the degree of Master of Science in The Department of Geology and Geophysics by Marc Romain Cooper B.S., Louisiana State University, 2003 August, 2008 ACKNOWLEDGEMENTS The author wishes to thank Dr. Gary Byerly, the author’s major advisor, for his guidance, support, and patience throughout the project, for the opportunity to carry out the field study and guidance therein, and for his unparalleled support in many other endeavors at LSU and beyond. The author also wishes to thank Dr. Darrell Henry and Dr. Huiming Bao of the Department of Geology and Geophysics at Louisiana State University for serving on his thesis committee and offering sound valuable advice and guidance. In particular, the author would also like to thank Dr. Xiaogang Xie of the microanalysis lab at LSU for technical assistance, conversation, and the opportunity to visit China on a field geology trip and Dr. Barb Dutrow for providing generous guidance, opportunities, and support throughout his time at LSU. Dr. Don Lowe and PhD candidate Melanie Thompson at Stanford University and Dr. Maud Walsh and MS graduate Judith Stoute at LSU provided memorable camaraderie during the field study in South Africa and valuable discussions on the field interpretations subsequently. The work of Dr. Gary Byerly, Dr. Don Lowe, Dr. Keena Kareem (PhD, LSU, 2005), and Melanie Thompson was integral to this study. This research was funded by an NSF Grant to Dr. Gary Byerly and the author also received scholarships from the Shreveport and Houston Geological Societies. The author wishes to commend several of his fellow graduate students for the examples they provided during his time as a graduate student at LSU. Lawrence Febo, Julie Hill, Jason Holloman, Jeff Agnew, and Jennifer Whittington made an immense impression upon the author through their contributions to the department as leaders, organizers, and community builders. Maria Pacheco, Katie Howell, Anna Belanger, Russell Willis, Matthew Hackworth, Rebecca Tedford, Mike Blevins, and Issaku Kohl were models of enthusiasm for the science and made it cool to be a geologist. The author also wishes to express gratitude to others in the Department of Geology at LSU who provided assistance: Rick Young in the rock lab, Wanda Leblanc in the ii geochemistry labs, and all the office staff whose dedication and enthusiasm did not go unnoticed. Among his friends and family, the author would like to thank Elizabeth Belton, Lisette Cooper, Grant Cooper, Kris Pottharst, Michelle Klein, Johnny Sanders, and Luke Sanders for their support. Finally, the author is grateful to the faculty of the Department of Geology at LSU with whom he had positive experiences as a student, teaching assistant, and member of the department community. The contributions of these individuals are too numerous to list. iii TABLE OF CONTENTS ACKNOWLEDGEMENTS ............................................................................................................ ii ABSTRACT ................................................................................................................................... vi 1. INTRODUCTION ...................................................................................................................... 1 2. GEOLOGICAL BACKGROUND.............................................................................................. 3 BARBERTON GREENSTONE BELT ...................................................................................... 3 WELTEVREDEN FORMATION ULTRAMAFIC COMPLEXES .......................................... 8 KOMATIITES ............................................................................................................................ 9 3. FIELD OBSERVATIONS ........................................................................................................ 15 MAPPING AND STRATIGRAPHY ....................................................................................... 15 LITHOLOGIC OBSERVATIONS ........................................................................................... 20 4. METHODS ............................................................................................................................... 26 EMPA ANALYTICAL METHODS ........................................................................................ 26 XRF AND ICP-MS ANALYTICAL METHODS .................................................................... 27 MELTS MODELING PROCEDURES .................................................................................... 28 5. RESULTS ................................................................................................................................. 30 PETROGRAPHY AND ELECTRON MICROGRAPHY ....................................................... 30 Massive Cumulate Komatiites .............................................................................................. 30 Dunitic Cumulate Komatiites ............................................................................................... 38 Peridotitic Cumulate Komatiites ........................................................................................... 38 Pyroxenitic Spinifex Komatiites ........................................................................................... 41 Pyroxene Spinifex Komatiitic Basalts .................................................................................. 42 MINERAL CHEMISTRY ........................................................................................................ 42 Olivine................................................................................................................................... 43 Chromite ............................................................................................................................... 46 Pyroxene ............................................................................................................................... 49 ROCK CHEMISTRY ............................................................................................................... 57 Major Elements ..................................................................................................................... 57 Trace Elements ...................................................................................................................... 63 6. DISCUSSION ........................................................................................................................... 66 EXTRUSIVE ORIGIN AND VOLCANOLOGY .................................................................... 66 CRYSTALLIZATION MODEL .............................................................................................. 69 INTERFLOW GEOCHEMICAL VARIATIONS .................................................................... 74 PARTITION COEFFICIENTS ................................................................................................. 76 HIGH PRESSURE FRACTIONATION .................................................................................. 80 ALTERNATE PETROGENETIC MODELS ........................................................................... 83 COMPARISON TO OTHER BGB KOMATIITES ................................................................. 85 7. CONCLUSIONS....................................................................................................................... 88 iv REFERENCES ............................................................................................................................. 90 APPENDIX A: EMPA UNCERTAINTY AND RESULTS ........................................................ 95 EMPA STANDARDS .............................................................................................................. 95 EMPA UNCERTAINTY .......................................................................................................... 96 EMPA RESULTS ..................................................................................................................... 97 APPENDIX B: XRF UNCERTAINTY AND RESULTS .......................................................... 133 XRF UNCERTAINTY ..........................................................................................................