Significance Patterns of Organic Chemistry in Real World
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INFORMATION to USERS the Most Advanced Technology Has Been
INFORMATION TO USERS The most advanced technology has been used to photo graph and reproduce this manuscript from the microfilm master. UMI films the original text directly from the copy submitted. Thus, some dissertation copies are in typewriter face, while others may be from a computer printer. In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyrighted material had to be removed, a note will indicate the deletion. Oversize materials (e.g., maps, drawings, charts) are re produced by sectioning the original, beginning at the upper left-hand comer and continuing from left to right in equal sections with small overlaps. Each oversize page is available as one exposure on a standard 35 mm slide or as a 17" x 23" black and white photographic print for an additional charge. Photographs included in the original manuscript have been reproduced xerographically in this copy. 35 mm slides or 6" x 9" black and white photographic prints are available for any photographs or illustrations appearing in this copy for an additional charge. Contact UMI directly to order. Accessing the World'sUMI Information since 1938 300 North Zeeb Road, Ann Arbor, Ml 48106-1346 USA Order Number 8820378 Stereochemical studies in anaerobic metabolism Zydowsky, Lynne Douthit, Ph.D. The Ohio State University, 1988 UMI 300 N. Zeeb Rd. Ann Aibor, M I 48106 PLEASE NOTE: In all cases this material has been filmed in the best possible way from the available copy. Problems encountered with this document have been identified here with a check mark V . -
Process for Producing Sulfonic Acids Or Salts Thereof
Europäisches Patentamt *EP001036788B1* (19) European Patent Office Office européen des brevets (11) EP 1 036 788 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.7: C07C 303/14, C07C 303/06, of the grant of the patent: C07C 309/25 04.06.2003 Bulletin 2003/23 (21) Application number: 00104958.4 (22) Date of filing: 08.03.2000 (54) Process for producing sulfonic acids or salts thereof Verfahren zur Herstellung von Sulfonsäuren oder deren Salzen Procédé pour la préparation d’acides sulfoniques ou leurs sels (84) Designated Contracting States: • Nakano, Tatsuya DE FR GB Hyogo 670-0094 (JP) (30) Priority: 09.03.1999 JP 6244399 (74) Representative: Grünecker, Kinkeldey, Stockmair & Schwanhäusser Anwaltssozietät (43) Date of publication of application: Maximilianstrasse 58 20.09.2000 Bulletin 2000/38 80538 München (DE) (73) Proprietor: Daicel Chemical Industries, Ltd. (56) References cited: Osaka 590-8501 (JP) EP-A- 0 824 962 US-A- 3 454 481 (72) Inventors: • Ishi, Yasutaka Osaka 569-1112 (JP) Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). EP 1 036 788 B1 Printed by Jouve, 75001 PARIS (FR) EP 1 036 788 B1 Description BACKGROUND OF THE INVENTION 5 1. Field of the Invention [0001] The present invention relates to a process for producing organic sulfur acids or salts thereof which are useful as, for example, materials for pharmaceuticals, agrochemicals and dyestuffs, or as detergents. -
Inhaltsstoffe Ingredients Ingredientes
BeyuLogo_black.pdf 1 24.02.12 13:58 C M Y Nägel · Nails · Unas · Ongles · Ногти CM · · · · MY CY CMY K 605 IN SEC1 EXPRESS DRY TOP COAT ETHYL ACETATE, ACETATE, ALCOHOL BUTYL DENAT., ACETATE, BUTYL NITROCELLULOSE, ACETATE, CELLULOSE ADIPIC ACETATE ACID/NEOPENTYL BUTYRATE, ACRYLA- TESGLYCOL/TRIMELLITIC COPOLYMER, TRIMETHYL ANHYDRIDE PENTANYL COPOLYMER, DIISOBUTYRATE, ACETYL SUCROSE TRIBUTYL BENZOATE, CITRATE, TRIPHENYL ISO- PROPYLPHOSPHATE, ALCOHOL, NITROCELLULOSE, HEPTANE, ETOCRYLENE, BENZOPHENONE-3, ISOPROPYL ALCOHOL, TRIMETHYLPENTANEDIYL BENZOPHENONE-1, DIME DI- BENZOATE,THICONE, CI 60725 POLYVINYL (VIOLET 2) BUTYRAL, CI 60725 (VIOLET 2) Art.No. M13050 Art. No. 30815 ANGEL60SEC SPEED BEAUTY DRY NAIL NAIL POLISH LACQUER (INCI 139) (INCI 73) BUTYLETHYL ACETATE, ACETATE, ETHYL BUTYL ACETATE, ACETATE, NITROCELLULOSE, NITROCELLULOSE, ADIPIC ACID/NEOPENTYL ACETYL TRIBUTYL GLYCOL/TRIMEL CITRA- LITICTE, ISOPROPYL ANHYDRIDE COPOLYMER,ALCOHOL, POLYESTER-23,ACETYL TRIBUTYL ACRYLATESCITRATE, ISOPROPYL COPOLYMER, ALCOHOL, MICA, POLYPRO STE- INCI PYLENE,ARALKONIUM SILICA, STEARALKONIUM BENTONITE, HYDRATED BENTONITE, CALCIUMSILICA, ALUMINUMSYNTHETIC BOROSILICATE, FLUORPHLOGOPITE, ACRYLATES DIACETONECOPOLYMER, STYRENE/ACRYLATESALCOHOL, CALCIUM COPOLYMER, ALUMINUM BENZOPHENONE-1, BOROSILICATE, DIACETONE BARIUM SULFATE,ALCOHOL, DIPROPYLENETRIMETHYLPENTANEDIYL GLYCOL DIBENZOATE, DIBENZOATE, PHOSPHORIC PENTAERYTHRITYL ACID, [+/- (MAY CONTAIN) TETRAISOSTEARATE, MICA, TIN OXIDE, ALUMINUMCI 15850 (RED 6 HYDROXIDE, LAKE), CI 15880 TRIETHOXYCAPRYLYLSILANE, (RED -
Co Co Co 2C,H5 + O<Zgfi>
View Article Online / Journal Homepage / Table of Contents for this issue 2194 MILLS AND MILLS: THE SYNTHETICAL PRODUCI’ION Ok’ CCXXX.-The Synthetical Production of Devivatives of Dinapht han t hracene. By WILLIAMHOBSON MILLS and MILDREDMILLS. THE knowledge hitherto possessed of /3/3/3’/3’-dinaphthanthracene(I) or of its derivatives is exceedingly scanty: co co co (1.1 (11.1 Russig (J. pr. Chem., 1900, [ii], 63, 30) obtained a dinaphth- anthratriquinone (11) by the action of concentrated sulphuric acid on 1: 4-dihydroxy-2-naphthoic acid, and this is apparently the only compound hitherto described which can be regarded definitely as a representative of this group.* In view of the interest which /3B/3’/3’-dinaphthanthracenepossesses as a higher member of the series of hydrocarbons, naphthalene, anthracene, naphthacene-composed of benzene nuclei condensed in straight alinernenb-we have endeavoured to obtain some more extended knowledge of this hydrocarbon and its derivatives in the hope that it might be possible thereby to gain further insight into the constitution of condensed nuclei of this type. With this end in view we have attempted to bring about by means of aluminium chloride a reaction between benzene and pyro- Published on 01 January 1912. Downloaded by Gazi Universitesi 13/11/2017 13:20:15. mellitic anhydride analogous to the well known condensation of benzene with phthalic anhydride, which results in the formation of benzoylbenzoic acid. In this manner we have obtained two isomeric dibenzoylbenzenedicarboxylic acids, as shown by the following equations : (111.) C,H5*CO/\CO*C6€15 2C,H5 + o<zgfi>. -
Carbon Compounds and Cells Are Very Large and Complex
7/21/2009 How are the ingredients for life put together? • Most molecules that make up living things Carbon Compounds and Cells are very large and complex. • Now let’s learn abou t their s tru ctur e an d All living organisms are composed function. of cells, from just one to many trillions. Carbon compounds Carbon is unique among the elements. • Life as we know it is carbon based. • A carbon atom can • This means that most of the compounds form chemical bonds with other carbon you are made of contain the element atoms in long chains carbon. or rings. • Some carbon compounds contain several thousand carbon atoms. You use carbon compounds every day. The carbon compounds in living things are classified into four groups: • Carbon compounds are not only found in living things. 1. carbohydrates, • Plastic, rubber, and gasoline are carbon compounds. 2. lipids, • In fact, there are over 12 3. proteins, and million known carbon 4. nucleic acids. compounds! 1 7/21/2009 Compounds in a Person CARBOHYDRATES Is water a carbon compound? Plants and animals use carbohydrates. Carbohydrates are energy-rich compounds made from carbon, • Cells use carbohydrates to get and hyygdrogen, and oxyg en. store energy. • Plants conta in ce llu lose, a carbohydrate, which gives them a rigid structure. Glucose Carbohydrates are classified as sugars and starches. • Glucose is a simple sugar made of 6 • Sugars are simple carbon, 12 hydrogen, molecules which are and 6 oxygen atoms. smaller than starches. 2 7/21/2009 The sugar you use to sweeten food is called sucrose. -
United States Patent (19) 11 4,301,046 Schlossman 45} Nov
United States Patent (19) 11 4,301,046 Schlossman 45} Nov. 17, 1981 54 UNIVERSAL NAIL POLISH USING POLYESTER RESN FOREIGN PATENT DOCUMENTS 41-1 1000 6/1966 Japan ..................................... 424/61 75 Inventor: Mitchell L. Schlossman, Rockaway, N.J. Primary Examiner-Maurice J. Welsh Assistant Examiner-N. M. Nutter 73) Assignee: Tevco Inc. Attorney, Agent, or Firm-Toren, McGeady & Stanger 57 ABSTRACT 21 Appl. No.: 111,174 A nail polish is made from 92% to 96% ingredients including a film former, colorant, plasticizer and sol 22 Filed: Jan, 10, 1980 vent; and 4% to 8% polyester resin made from 2,2,4- trimethyl-1,3-pentanediol, isophthalic acid-85, and tri 51) Int. Cl. ................................................ C08L 1/10 mellitic anhydride, having an acid value of 75-85 and a 52) ... 260/16; 424/61 viscosity of 125-175 centipoise. In another example, the 58) Field of Search ............................. 260/16; 424/61 polyester is made from 50.932%. 2,2,4 trimethyl-1,3- pentanediol, 27.579% isophthalic acid-85, 0.186% dibu 56) References Cited tyl tin oxide catalyst and 21.303 trimellitic anhydride, U.S. PATENT DOCUMENTS having an acid value of 80 and a viscosity of 150 centi 2,215,898 9/1940 Anderson .............................. 424/61 poise, 3,849,547 11/1974 Kalopissis ....... ww. 424/61 4,022,724 5/1977 Kreuder et al. ... 260/16 29 Claims, No Drawings 4,301,046 2 tricresyl phosphate (24-255 C.), triphenyl phosphate UNIVERSAL NAL POLESH USENG EPOLYESTER and citrate piasticizers. RESN Colorants for nail enamel are usually confined to the non-bleeding in lacquer solvents. -
Macromolecules
Lesson Overview Carbon Compounds Lesson Overview 2.3 Carbon Compounds Lesson Overview Carbon Compounds THINK ABOUT IT In the early 1800s, many chemists called the compounds created by organisms “organic,” believing they were fundamentally different from compounds in nonliving things. We now understand that the principles governing the chemistry of living and nonliving things are the same, but the term “organic chemistry” is still around. Today, organic chemistry means the study of compounds that contain bonds between carbon atoms, while inorganic chemistry is the study of all other compounds. Lesson Overview Carbon Compounds The Chemistry of Carbon Carbon atoms have four valence electrons, allowing them to form strong covalent bonds with many other elements (including hydrogen, oxygen, phosphorus, sulfur, and nitrogen). Carbon atoms can also bond to each other (this gives carbon the ability to form millions of different large and complex structures). Living organisms are made up of molecules that consist of carbon and these other elements. Lesson Overview Carbon Compounds The Chemistry of Carbon Carbon-carbon bonds can be single , double , or triple covalent bonds. METHANE BUTADIENE ACETYLENE Lesson Overview Carbon Compounds The Chemistry of Carbon Chains of carbon atoms can be straight , branched , or even close up on themselves to form rings . BUTANE ISOOCTANE BENZENE Lesson Overview Carbon Compounds Macromolecules Many of the organic compounds in living cells are macromolecules. Macromolecule means “giant molecule” Macromolecules are made from thousands or even hundreds of thousands of smaller molecules. Lesson Overview Carbon Compounds Macromolecules Most macromolecules are formed by a process known as polymerization , in which large compounds are built by joining smaller ones together. -
Article Is Available Online Standing That Under the Correct Conditions, Microbes Can Pro- At
Biogeosciences, 15, 1733–1747, 2018 https://doi.org/10.5194/bg-15-1733-2018 © Author(s) 2018. This work is distributed under the Creative Commons Attribution 4.0 License. Molecular characterization of organic matter mobilized from Bangladeshi aquifer sediment: tracking carbon compositional change during microbial utilization Lara E. Pracht1, Malak M. Tfaily2, Robert J. Ardissono1, and Rebecca B. Neumann1 1Department of Civil and Environmental Engineering, University of Washington, Seattle, 98195, USA 2Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, 99354, USA Correspondence: Rebecca B. Neumann ([email protected]) Received: 29 June 2017 – Discussion started: 11 July 2017 Revised: 1 March 2018 – Accepted: 2 March 2018 – Published: 26 March 2018 Abstract. Bioavailable organic carbon in aquifer recharge In anaerobic environments, energy yields from redox reac- waters and sediments can fuel microbial reactions with im- tions are small and the amount of energy required to re- plications for groundwater quality. A previous incubation move electrons from highly reduced carbon substrates during experiment showed that sedimentary organic carbon (SOC) oxidation decreases the thermodynamic favorability of de- mobilized off sandy sediment collected from an arsenic- grading compounds with a low NOSC. While all compound contaminated and methanogenic aquifer in Bangladesh was types were eventually degraded during incubation, NOSC bioavailable; it was transformed into methane. We used and compound size controlled the rates of carbon transforma- high-resolution mass spectrometry to molecularly character- tion. Large, more thermodynamically favorable compounds ize this mobilized SOC, reference its composition against (e.g., aromatics with a high NOSC) were targeted first, while dissolved organic carbon (DOC) in surface recharge water, small, less thermodynamically favorable compounds (e.g., track compositional changes during incubation, and advance alkanes and olefinics with a low NOSC) were used last. -
United States Patent [191 [11] 4,233,220 Kvita Et A1
United States Patent [191 [11] 4,233,220 Kvita et a1. [45] Nov. 11, 1980 [54] IMIDYL-BENZENE-DICARBOXYLIC AND 3,465,002 9/ 1969 Bolhofer et a1. .............. .. 260/326.41 -'I“RICARBOXYLIC ACID DERIVATIVES 3,538,114 11/1976 l-limmele et a1. .. 260/326.5 FM 3,549,657 12/1970 Webster ......................... .. 260/326 A [75] Inventors: Vratislav Kvita, Muttenz; Roland 3,549,725 12/1970 Rose ........................ .. 260/326.5 FM Dar-ms, Therwil; Gerd Greber, 3,557,132 1/1971 Hermann et al. ........ .. 260/326.5 FM Binningen, all of Switzerland 3,660,408 5/1972 Ackerman ............... .. 260/326.5 FM 3,666,720 5/1972 Nield et a1. ................ .. 260/326 N [73] Assignee: Ciba-Geigy Corporation, Ardsley, ‘ 3,766,142 10/ 1973 Nield et a1. .............. .. 260/326.5 FM N.Y. 3,816,451 6/1974 Crovetti et a1. ......... .. 260/326.5 FM 3,878,224 4/1975 Matsui et a1. .................. .. 260/326 R [21] Appl. No.: 951,432 3,892,802 7/1975 Podesua et a1. .......... .. 260/326 A [22] Filed: Oct. 16, 1978 3,948,941 4/ 1976 Patton ............ .. .. 260/326.5 FM 3,979,393 9/1976 Kvita et a1. ................ .. 260/326 C Related US. Application Data 3,984,435 10/1976 Matsui et al. ...... .. .. 260/326.5 FM 4,043,986 8/1977 Gruffay et a1. ..... .. 260/47 UA [62] Division of Ser. No. 696,348, Jun. 15, 1976, Pat. No. 4,107,174 8/1978 Baumann et al. 260/326 N 4,132,716. , 4,126,619 11/1978 Darms et al. -
The Elements.Pdf
A Periodic Table of the Elements at Los Alamos National Laboratory Los Alamos National Laboratory's Chemistry Division Presents Periodic Table of the Elements A Resource for Elementary, Middle School, and High School Students Click an element for more information: Group** Period 1 18 IA VIIIA 1A 8A 1 2 13 14 15 16 17 2 1 H IIA IIIA IVA VA VIAVIIA He 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 2 Li Be B C N O F Ne 6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 3 Na Mg IIIB IVB VB VIB VIIB ------- VIII IB IIB Al Si P S Cl Ar 22.99 24.31 3B 4B 5B 6B 7B ------- 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95 ------- 8 ------- 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.47 58.69 63.55 65.39 69.72 72.59 74.92 78.96 79.90 83.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 5 Rb Sr Y Zr NbMo Tc Ru Rh PdAgCd In Sn Sb Te I Xe 85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 6 Cs Ba La* Hf Ta W Re Os Ir Pt AuHg Tl Pb Bi Po At Rn 132.9 137.3 138.9 178.5 180.9 183.9 186.2 190.2 190.2 195.1 197.0 200.5 204.4 207.2 209.0 (210) (210) (222) 87 88 89 104 105 106 107 108 109 110 111 112 114 116 118 7 Fr Ra Ac~RfDb Sg Bh Hs Mt --- --- --- --- --- --- (223) (226) (227) (257) (260) (263) (262) (265) (266) () () () () () () http://pearl1.lanl.gov/periodic/ (1 of 3) [5/17/2001 4:06:20 PM] A Periodic Table of the Elements at Los Alamos National Laboratory 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Lanthanide Series* Ce Pr NdPmSm Eu Gd TbDyHo Er TmYbLu 140.1 140.9 144.2 (147) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Actinide Series~ Th Pa U Np Pu AmCmBk Cf Es FmMdNo Lr 232.0 (231) (238) (237) (242) (243) (247) (247) (249) (254) (253) (256) (254) (257) ** Groups are noted by 3 notation conventions. -
Root Exudation Rates Decrease with Increasing Latitude in Some Tree Species
Article Root Exudation Rates Decrease with Increasing Latitude in Some Tree Species Liu Yang 1 , Xiuwei Wang 1,* , Zijun Mao 2, Zhiyan Jiang 1, Yang Gao 2, Xiangwei Chen 1 and Doug P. Aubrey 3,4 1 Key Laboratory of Sustainable Forest Ecosystem Management-Ministry of Education, Northeast Forestry University, Harbin 150040, China; [email protected] (L.Y.); [email protected] (Z.J.); [email protected] (X.C.) 2 College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China; [email protected] (Z.M.); [email protected] (Y.G.) 3 Savannah River Ecology Laboratory, University of Georgia, PO Drawer E, Aiken, SC 29802, USA; [email protected] 4 Warnell School of Forestry and Natural Resources, University of Georgia, 180 E. Green St., Athens, GA 30602, USA * Correspondence: [email protected]; Tel.: +86-451-8219-1829 Received: 17 August 2020; Accepted: 27 September 2020; Published: 28 September 2020 Abstract: Research Highlights: Understanding of the spatial variation of root exudation on a regional scale can help understand the response of plant physiological activities to environmental changes. Background and Objectives: Although root exudation has become an important topic in belowground ecology, its relationship with root traits and environmental factors is poorly understood. Our objective was to explore how root traits and environmental factors influence root exudation. Materials and Methods: We used a multi-factorial design consisting of three tree species spanning across sites located at three latitudes to assess root exudation dynamics, which was measured using a syringe-basis incubation system. Results: The strongest and clearest effect observed in our study was a decrease in root exudation rates of Korean pine (Pinus koraiensis Sieb. -
Mercury Contamination in Man and His Environment
TECHNICAL REPORTS SERIES No. 137 Mercury Contamination in Man and his Environment A JOINT UNDERTAKING BY THE INTERNATIONAL LABOUR ORGANISATION. THE FOOD AND AGRICULTURE ORGANIZATION OF THE UNITED NATIONS. THE WORLD HEALTH ORGANIZATION AND THE INTERNATIONAL ATOMIC ENERGY AGENCY J WJ INTERNATIONAL ATOMIC ENERGY AGENCY, VIENNA, 1972 MERCURY CONTAMINATION IN MAN AND HIS ENVIRONMENT TECHNICAL REPORTS SERIES No. 137 MERCURY CONTAMINATION IN MAN AND HIS ENVIRONMENT A JOINT UNDERTAKING BY THE INTERNATIONAL LABOUR ORGANISATION, THE FOOD AND AGRICULTURE ORGANIZATION OF THE UNITED NATIONS, THE WORLD HEALTH ORGANIZATION AND THE INTERNATIONAL ATOMIC ENERGY AGENCY INTERNATIONAL ATOMIC ENERGY AGENCY VIENNA, 1972 MERCURY CONTAMINATION IN MAN AND HIS ENVIRONMENT IAEA, VIENNA, 1972 STI/DOC/lO/137 Printed by the IAEA in Austria July 1972 FOREWORD In May 1967, at a Symposium organized by the International Atomic Energy Agency in Amsterdam, the special problems of food and environ- mental contamination by mercury were discussed by world experts on the subject and by representatives of FAO, WHO and IAEA. One of the recom- mendations made by this meeting was that the international organizations of the United Nations family should assist in the collection and distribution of information on environmental mercury. Subsequently, the organizations concerned agreed that a handbook on mercury contamination would be es- pecially useful. This would deal with sources of mercury in relation to man and his environment; with physical and biological transfer processes that determine its distribution; with analytical methods for determining mercury and its compounds as environmental contaminants; with actual concentrations of mercury found in the environment, in living organisms and in man; and with its toxicology in animals and man.