Calculation Exercises with Answers and Solutions
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Development Team
Paper No: 16 Environmental Chemistry Module: 01 Environmental Concentration Units Development Team Prof. R.K. Kohli Principal Investigator & Prof. V.K. Garg & Prof. Ashok Dhawan Co- Principal Investigator Central University of Punjab, Bathinda Prof. K.S. Gupta Paper Coordinator University of Rajasthan, Jaipur Prof. K.S. Gupta Content Writer University of Rajasthan, Jaipur Content Reviewer Dr. V.K. Garg Central University of Punjab, Bathinda Anchor Institute Central University of Punjab 1 Environmental Chemistry Environmental Environmental Concentration Units Sciences Description of Module Subject Name Environmental Sciences Paper Name Environmental Chemistry Module Name/Title Environmental Concentration Units Module Id EVS/EC-XVI/01 Pre-requisites A basic knowledge of concentration units 1. To define exponents, prefixes and symbols based on SI units 2. To define molarity and molality 3. To define number density and mixing ratio 4. To define parts –per notation by volume Objectives 5. To define parts-per notation by mass by mass 6. To define mass by volume unit for trace gases in air 7. To define mass by volume unit for aqueous media 8. To convert one unit into another Keywords Environmental concentrations, parts- per notations, ppm, ppb, ppt, partial pressure 2 Environmental Chemistry Environmental Environmental Concentration Units Sciences Module 1: Environmental Concentration Units Contents 1. Introduction 2. Exponents 3. Environmental Concentration Units 4. Molarity, mol/L 5. Molality, mol/kg 6. Number Density (n) 7. Mixing Ratio 8. Parts-Per Notation by Volume 9. ppmv, ppbv and pptv 10. Parts-Per Notation by Mass by Mass. 11. Mass by Volume Unit for Trace Gases in Air: Microgram per Cubic Meter, µg/m3 12. -
Air Pressure
Name ____________________________________ Date __________ Class ___________________ SECTION 15-3 SECTION SUMMARY Air Pressure Guide for ir consists of atoms and molecules that have mass. Therefore, air has Reading A mass. Because air has mass, it also has other properties, includ- ing density and pressure. The amount of mass per unit volume of a N What are some of substance is called the density of the substance. The force per unit area the properties of air? is called pressure. Air pressure is the result of the weight of a column of N What instruments air pushing down on an area. The molecules in air push in all directions. are used to mea- This is why air pressure doesn’t crush objects. sure air pressure? Falling air pressure usually indicates that a storm is approaching. Rising N How does increas- air pressure usually means that the weather is clearing. A ing altitude affect barometer is an instrument that measures changes in air pressure. There air pressure and are two kinds of barometers: mercury barometers and aneroid density? barometers. A mercury barometer consists of a glass tube open at the bottom end and partially filled with mercury. The open end of the tube rests in a dish of mercury, and the space above the mercury in the tube contains no air. The air pressure pushing down on the surface of the mer- cury in the dish is equal to the weight of the column of mercury in the tube. At sea level, the mercury column is about 76 centimeters high, on average. An aneroid barometer has an airtight metal chamber that is sen- sitive to changes in air pressure. -
Supplement Of
Supplement of Effects of Liquid–Liquid Phase Separation and Relative Humidity on the Heterogeneous OH Oxidation of Inorganic-Organic Aerosols: Insights from Methylglutaric Acid/Ammonium Sulfate Particles Hoi Ki Lam1, Rongshuang Xu1, Jack Choczynski2, James F. Davies2, Dongwan Ham3, Mijung Song3, Andreas Zuend4, Wentao Li5, Ying-Lung Steve Tse5, Man Nin Chan 1,6 1Earth System Science Programme, Faculty of Science, The Chinese University of Hong Kong, Hong Kong, China 2Department of Chemistry, University of California Riverside, Riverside, CA, USA 3Department of Earth and Environmental Sciences, Jeonbuk National University, Jeollabuk-do, Republic of Korea 4Department of Atmospheric and Oceanic Sciences, McGill University, Montreal, Québec, Canada 5Departemnt of Chemistry, The Chinese University of Hong Kong, Hong Kong, China’ 6The Institute of Environment, Energy and Sustainability, The Chinese University of Hong Kong, Hong Kong, China Corresponding author: [email protected] Table S1. Composition, viscosity, diffusion coefficient and mixing time scale of aqueous droplets containing 3-MGA and ammonium sulfate (AS) in an organic- to-inorganic dry mass ratio (OIR) = 1 at different RH predicted by the AIOMFAC-LLE. RH (%) 55 60 65 70 75 80 85 88 Salt-rich phase (Phase α) Mass fraction of 3-MGA 0.00132 0.00372 0.00904 0.0202 / / Mass fraction of AS 0.658 0.616 0.569 0.514 / / Mass fraction of H2O 0.341 0.380 0.422 0.466 / / Organic-rich phase (Phase β) Mass fraction of 3-MGA 0.612 0.596 0.574 0.546 / / Mass fraction of AS 0.218 0.209 0.199 0.190 -
Colloidal Suspensions
Chapter 9 Colloidal suspensions 9.1 Introduction So far we have discussed the motion of one single Brownian particle in a surrounding fluid and eventually in an extaernal potential. There are many practical applications of colloidal suspensions where several interacting Brownian particles are dissolved in a fluid. Colloid science has a long history startying with the observations by Robert Brown in 1828. The colloidal state was identified by Thomas Graham in 1861. In the first decade of last century studies of colloids played a central role in the development of statistical physics. The experiments of Perrin 1910, combined with Einstein's theory of Brownian motion from 1905, not only provided a determination of Avogadro's number but also laid to rest remaining doubts about the molecular composition of matter. An important event in the development of a quantitative description of colloidal systems was the derivation of effective pair potentials of charged colloidal particles. Much subsequent work, largely in the domain of chemistry, dealt with the stability of charged colloids and their aggregation under the influence of van der Waals attractions when the Coulombic repulsion is screened strongly by the addition of electrolyte. Synthetic colloidal spheres were first made in the 1940's. In the last twenty years the availability of several such reasonably well characterised "model" colloidal systems has attracted physicists to the field once more. The study, both theoretical and experimental, of the structure and dynamics of colloidal suspensions is now a vigorous and growing subject which spans chemistry, chemical engineering and physics. A colloidal dispersion is a heterogeneous system in which particles of solid or droplets of liquid are dispersed in a liquid medium. -
The Vertical Distribution of Soluble Gases in the Troposphere
UC Irvine UC Irvine Previously Published Works Title The vertical distribution of soluble gases in the troposphere Permalink https://escholarship.org/uc/item/7gc9g430 Journal Geophysical Research Letters, 2(8) ISSN 0094-8276 Authors Stedman, DH Chameides, WL Cicerone, RJ Publication Date 1975 DOI 10.1029/GL002i008p00333 License https://creativecommons.org/licenses/by/4.0/ 4.0 Peer reviewed eScholarship.org Powered by the California Digital Library University of California Vol. 2 No. 8 GEOPHYSICAL RESEARCHLETTERS August 1975 THE VERTICAL DISTRIBUTION OF SOLUBLE GASES IN THE TROPOSPHERE D. H. Stedman, W. L. Chameides, and R. J. Cicerone Space Physics Research Laboratory Department of Atmospheric and Oceanic Science The University of Michigan, Ann Arbor, Michigan 48105 Abstrg.ct. The thermodynamic properties of sev- Their arg:uments were based on the existence of an eral water-soluble gases are reviewed to determine HC1-H20 d•mer, but we consider the conclusions in- the likely effect of the atmospheric water cycle dependeht of the existence of dimers. For in- on their vertical profiles. We find that gaseous stance, Chameides[1975] has argued that HNO3 HC1, HN03, and HBr are sufficiently soluble in should follow the water-vapor mixing ratio gradi- water to suggest that their vertical profiles in ent, based on the high solubility of the gas in the troposphere have a similar shape to that of liquid water. In this work, we generalize the water va•or. Thuswe predict that HC1,HN03, and moredetailed argumentsof Chameides[1975] and HBr exhibit a steep negative gradient with alti- suggest which species should exhibit this nega- tude roughly equal to the altitude gradient of tive gradient and which should not. -
Effect of Tropospheric Air Density and Dew Point Temperature on Radio (Electromagnetic) Waves and Air Radio Wave Refractivity
International Journal of Scientific & Engineering Research, Volume 7, Issue 6, June-2016 356 ISSN 2229-5518 Effect of Tropospheric Air density and dew point temperature on Radio (Electromagnetic) waves and Air radio wave refractivity <Joseph Amajama> University of Calabar, Department of Physics, Electronics and Computer Technology Unit Etta-agbor, Calabar, Nigeria [email protected] Abstract: Signal strengths measurements were obtained half hourly for some hours and simultaneously, the atmospheric components: atmospheric temperature, atmospheric pressure, relative humidity and wind direction and speed were registered to erect the effects of air density and dew point temperature on radio signals (electromagnetic waves) as they travel through the atmosphere and air radio wave refractivity. The signal strength from Cross River State Broadcasting Co-operation Television (CRBC-TV), (4057'54.7''N, 8019'43.7''E) transmitted at 35mdB and 519.25 MHz (UHF) were measured using a Cable TV analyzer in a residence along Ettaabgor, Calabar, Nigeria (4057'31.7''N, 8020'49.7''E) using the digital Community – Access (Cable) Television (CATV) analyzer with 24 channels, spectrum 46 – 870 MHz, connected to a domestic receiver antenna of height 4.23 m. Results show that: on the condition that the wind speed and direction are the same or (0 mph NA), the radio signal strength is near negligibly directly proportional to the air density, mathematically Ss / ∂a1.3029 = K, where Ss is Signal Strength in dB, ∂a is Density of air Kg/m3 and K is constant; radio -
Package 'Marelac'
Package ‘marelac’ February 20, 2020 Version 2.1.10 Title Tools for Aquatic Sciences Author Karline Soetaert [aut, cre], Thomas Petzoldt [aut], Filip Meysman [cph], Lorenz Meire [cph] Maintainer Karline Soetaert <[email protected]> Depends R (>= 3.2), shape Imports stats, seacarb Description Datasets, constants, conversion factors, and utilities for 'MArine', 'Riverine', 'Estuarine', 'LAcustrine' and 'Coastal' science. The package contains among others: (1) chemical and physical constants and datasets, e.g. atomic weights, gas constants, the earths bathymetry; (2) conversion factors (e.g. gram to mol to liter, barometric units, temperature, salinity); (3) physical functions, e.g. to estimate concentrations of conservative substances, gas transfer and diffusion coefficients, the Coriolis force and gravity; (4) thermophysical properties of the seawater, as from the UNESCO polynomial or from the more recent derivation based on a Gibbs function. License GPL (>= 2) LazyData yes Repository CRAN Repository/R-Forge/Project marelac Repository/R-Forge/Revision 205 Repository/R-Forge/DateTimeStamp 2020-02-11 22:10:45 Date/Publication 2020-02-20 18:50:04 UTC NeedsCompilation yes 1 2 R topics documented: R topics documented: marelac-package . .3 air_density . .5 air_spechum . .6 atmComp . .7 AtomicWeight . .8 Bathymetry . .9 Constants . 10 convert_p . 11 convert_RtoS . 11 convert_salinity . 13 convert_StoCl . 15 convert_StoR . 16 convert_T . 17 coriolis . 18 diffcoeff . 19 earth_surf . 21 gas_O2sat . 23 gas_satconc . 25 gas_schmidt . 27 gas_solubility . 28 gas_transfer . 31 gravity . 33 molvol . 34 molweight . 36 Oceans . 37 redfield . 38 ssd2rad . 39 sw_adtgrad . 40 sw_alpha . 41 sw_beta . 42 sw_comp . 43 sw_conserv . 44 sw_cp . 45 sw_dens . 47 sw_depth . 49 sw_enthalpy . 50 sw_entropy . 51 sw_gibbs . 52 sw_kappa . -
Air Infiltration Glossary (English Edition)
AIRGLOSS: Air Infiltration Glossary (English Edition) Carolyn Allen ~)Copyrlght Oscar Faber Partnership 1981. All property rights, Including copyright ere vested In the Operating Agent (The Oscar Faber Partnership) on behalf of the International Energy Agency. In particular, no part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without the prior written permluion of the operat- ing agent. Contents (i) Preface (iii) Introduction (v) Umr's Guide (v) Glossary Appendix 1 - References 87 Appendix 2 - Tracer Gases 93 Appendix 3 - Abbreviations 99 Appendix 4 - Units 103 (i) (il) Preface International Energy Agency In order to strengthen cooperation In the vital area of energy policy, an Agreement on an International Energy Program was formulated among a number of industrialised countries In November 1974. The International Energy Agency (lEA) was established as an autonomous body within the Organisation for Economic Cooperation and Development (OECD) to administer that agreement. Twenty-one countries are currently members of the lEA, with the Commission of the European Communities participating under a special arrangement. As one element of the International Energy Program, the Participants undertake cooperative activities in energy research, development, and demonstration. A number of new and improved energy technologies which have the potential of making significant contributions to our energy needs were identified for collaborative efforts. The lEA Committee on Energy Research and Development (CRD), assisted by a small Secretariat staff, coordinates the energy research, development, and demonstration programme. Energy Conservation in Buildings and Community Systems The International Energy Agency sponsors research and development in a number of areas related to energy. -
CE-087 Calculation of Gas Density and Viscosity
CE‐087 Calculation of Gas Density and Viscosity Instructor: Harlan Bengtson, PhD, P.E. Course ID: CE‐087 PDH Hours: 2 PDH PDH Star | T / F: (833) PDH‐STAR (734‐7827) | E: [email protected] Calculation of Gas Density and Viscosity Harlan H. Bengtson, PhD, P.E. COURSE CONTENT 1. Introduction The density and/or viscosity of a gas is often needed for some other calculation, such as pipe flow or heat exchanger calculations. This course contains discussion of, and example calculation of, the density and viscosity of a specified gas at a given temperature and pressure. If the gas temperature is high relative to its critical temperature and the gas pressure is low relative to its critical pressure, then it can be treated as an ideal gas and its density can be calculated at a specified temperature and pressure using the ideal gas law. If the density of a gas is needed at a temperature and pressure at which it cannot be treated as an ideal gas law, however, then the compressibility factor of the gas must be calculated and used in calculating its density. In this course, the Redlich Kwong equation will be used for calculation of the compressibility factor of a gas. The Sutherland formula can be used to calculate the viscosity of a gas at a specified temperature and pressure if the Sutherland constants are available for the gas. It will be discussed and used in example calculations. Another method for calculating the viscosity of air at a specified temperature and pressure will also be presented and discussed. -
Lecture 3. the Basic Properties of the Natural Atmosphere 1. Composition
Lecture 3. The basic properties of the natural atmosphere Objectives: 1. Composition of air. 2. Pressure. 3. Temperature. 4. Density. 5. Concentration. Mole. Mixing ratio. 6. Gas laws. 7. Dry air and moist air. Readings: Turco: p.11-27, 38-43, 366-367, 490-492; Brimblecombe: p. 1-5 1. Composition of air. The word atmosphere derives from the Greek atmo (vapor) and spherios (sphere). The Earth’s atmosphere is a mixture of gases that we call air. Air usually contains a number of small particles (atmospheric aerosols), clouds of condensed water, and ice cloud. NOTE : The atmosphere is a thin veil of gases; if our planet were the size of an apple, its atmosphere would be thick as the apple peel. Some 80% of the mass of the atmosphere is within 10 km of the surface of the Earth, which has a diameter of about 12,742 km. The Earth’s atmosphere as a mixture of gases is characterized by pressure, temperature, and density which vary with altitude (will be discussed in Lecture 4). The atmosphere below about 100 km is called Homosphere. This part of the atmosphere consists of uniform mixtures of gases as illustrated in Table 3.1. 1 Table 3.1. The composition of air. Gases Fraction of air Constant gases Nitrogen, N2 78.08% Oxygen, O2 20.95% Argon, Ar 0.93% Neon, Ne 0.0018% Helium, He 0.0005% Krypton, Kr 0.00011% Xenon, Xe 0.000009% Variable gases Water vapor, H2O 4.0% (maximum, in the tropics) 0.00001% (minimum, at the South Pole) Carbon dioxide, CO2 0.0365% (increasing ~0.4% per year) Methane, CH4 ~0.00018% (increases due to agriculture) Hydrogen, H2 ~0.00006% Nitrous oxide, N2O ~0.00003% Carbon monoxide, CO ~0.000009% Ozone, O3 ~0.000001% - 0.0004% Fluorocarbon 12, CF2Cl2 ~0.00000005% Other gases 1% Oxygen 21% Nitrogen 78% 2 • Some gases in Table 3.1 are called constant gases because the ratio of the number of molecules for each gas and the total number of molecules of air do not change substantially from time to time or place to place. -
Interactions Between Polymers and Nanoparticles : Formation of « Supermicellar » Hybrid Aggregates
1 Interactions between Polymers and Nanoparticles : Formation of « Supermicellar » Hybrid Aggregates J.-F. Berret@, K. Yokota* and M. Morvan, Complex Fluids Laboratory, UMR CNRS - Rhodia n°166, Cranbury Research Center Rhodia 259 Prospect Plains Road Cranbury NJ 08512 USA Abstract : When polyelectrolyte-neutral block copolymers are mixed in solutions to oppositely charged species (e.g. surfactant micelles, macromolecules, proteins etc…), there is the formation of stable “supermicellar” aggregates combining both components. The resulting colloidal complexes exhibit a core-shell structure and the mechanism yielding to their formation is electrostatic self-assembly. In this contribution, we report on the structural properties of “supermicellar” aggregates made from yttrium-based inorganic nanoparticles (radius 2 nm) and polyelectrolyte-neutral block copolymers in aqueous solutions. The yttrium hydroxyacetate particles were chosen as a model system for inorganic colloids, and also for their use in industrial applications as precursors for ceramic and opto-electronic materials. The copolymers placed under scrutiny are the water soluble and asymmetric poly(sodium acrylate)-b-poly(acrylamide) diblocks. Using static and dynamical light scattering experiments, we demonstrate the analogy between surfactant micelles and nanoparticles in the complexation phenomenon with oppositely charged polymers. We also determine the sizes and the aggregation numbers of the hybrid organic-inorganic 1 2 complexes. Several additional properties are discussed, such -
Use Nitrogen Safely
Safety Use Nitrogen Safely Paul Yanisko Understanding the potential hazards and Dennis Croll Air Products taking the proper precautions will allow you to reap such benefits as improved product quality and enhanced process safety. itrogen is valued both as a gas for its inert prop- Nitrogen does not support combustion, and at standard erties and as a liquid for cooling and freezing. conditions is a colorless, odorless, tasteless, nonirritating, NBecause of its unique properties, it is used in and inert gas. But, while seemingly harmless, there are haz- a wide range of applications and industries to improve ards associated with the use of nitrogen that require aware- yields, optimize performance, protect product quality, and ness, caution, and proper handling procedures. This article make operations safer (1). discusses those hazards and outlines the precautions that Nitrogen makes up 78% of the atmosphere, with the bal- must be taken to achieve the benefits of using nitrogen in the ance being primarily oxygen (roughly 21%). Most nitrogen safest possible manner. is produced by fractional distillation of liquid air in large plants called air separation units (ASUs). Pressure-swing Nitrogen applications adsorption (PSA) and membrane technologies are also used Many operations in chemical plants, petroleum refin- to produce nitrogen. Nitrogen can be liquefied at very low eries, and other industrial facilities use nitrogen gas to temperatures, and large volumes of liquid nitrogen can be purge equipment, tanks, and pipelines of vapors and gases. effectively transported and stored. Nitrogen gas is also used to maintain an inert and protective atmosphere in tanks storing flammable liquids or air-sensi- tive materials.