Isoamyl Acetate Hazard Summary Identification

Total Page:16

File Type:pdf, Size:1020Kb

Isoamyl Acetate Hazard Summary Identification Common Name: ISOAMYL ACETATE CAS Number: 123-92-2 DOT Number: UN 1104 RTK Substance number: 1038 DOT Hazard Class: 3 (Flammable Liquid) Date: May 1998 Revision: July 2005 ------------------------------------------------------------------------- ------------------------------------------------------------------------- HAZARD SUMMARY * Isoamyl Acetate can affect you when breathed in. * If you think you are experiencing any work-related health * Contact can irritate the skin and eyes. problems, see a doctor trained to recognize occupational * Breathing Isoamyl Acetate can irritate the nose, throat diseases. Take this Fact Sheet with you. and lungs. * ODOR THRESHOLD = 0.22 ppm. * Exposure to high concentrations of Isoamyl Acetate can * The range of accepted odor threshold values is quite cause headache, drowsiness, dizziness, lightheadedness, broad. Caution should be used in relying on odor alone as fatigue, and may cause you to pass out. a warning of potentially hazardous exposures. * Prolonged or repeated contact can cause drying and cracking of the skin. WORKPLACE EXPOSURE LIMITS * Isoamyl Acetate is a FLAMMABLE LIQUID and a FIRE OSHA: The legal airborne permissible exposure limit HAZARD. (PEL) is 100 ppm averaged over an 8-hour workshift. IDENTIFICATION Isoamyl Acetate is a clear, colorless liquid with a banana-like NIOSH: The recommended airborne exposure limit is odor. It is used as a solvent, in perfumes, and in artificial fruit 100 ppm averaged over a 10-hour workshift. flavorings. ACGIH: The recommended airborne exposure limit is REASON FOR CITATION 50 ppm averaged over an 8-hour workshift and * Isoamyl Acetate is on the Hazardous Substance List 100 ppm as a STEL (short term exposure limit). because it is regulated by OSHA and cited by ACGIH, DOT, NIOSH and NFPA. WAYS OF REDUCING EXPOSURE * This chemical is on the Special Health Hazard Substance * Where possible, enclose operations and use local exhaust List because it is FLAMMABLE. ventilation at the site of chemical release. If local exhaust * Definitions are provided on page 5. ventilation or enclosure is not used, respirators should be worn. HOW TO DETERMINE IF YOU ARE BEING * Wear protective work clothing. * Wash thoroughly immediately after exposure to Isoamyl EXPOSED Acetate and at the end of the workshift. The New Jersey Right to Know Act requires most employers * Post hazard and warning information in the work area. In to label chemicals in the workplace and requires public addition, as part of an ongoing education and training employers to provide their employees with information and effort, communicate all information on the health and training concerning chemical hazards and controls. The safety hazards of Isoamyl Acetate to potentially exposed federal OSHA Hazard Communication Standard, 1910.1200, requires private employers to provide similar training and workers. information to their employees. * Exposure to hazardous substances should be routinely evaluated. This may include collecting personal and area air samples. You can obtain copies of sampling results from your employer. You have a legal right to this information under OSHA 1910.1020. ISOAMYL ACETATE page 2 of 6 This Fact Sheet is a summary source of information of all WORKPLACE CONTROLS AND PRACTICES potential and most severe health hazards that may result from exposure. Duration of exposure, concentration of the substance Unless a less toxic chemical can be substituted for a hazardous and other factors will affect your susceptibility to any of the substance, ENGINEERING CONTROLS are the most potential effects described below. effective way of reducing exposure. The best protection is to --------------------------------------------------------------------------- enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also HEALTH HAZARD INFORMATION reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is Acute Health Effects sometimes necessary. The following acute (short-term) health effects may occur immediately or shortly after exposure to Isoamyl Acetate: In evaluating the controls present in your workplace, consider: (1) how hazardous the substance is, (2) how much of the * Contact can irritate the skin and eyes. substance is released into the workplace and (3) whether * Breathing Isoamyl Acetate can irritate the nose and throat. harmful skin or eye contact could occur. Special controls * Exposure to high concentrations of Isoamyl Acetate can should be in place for highly toxic chemicals or when cause headache, drowsiness, dizziness, lightheadedness, significant skin, eye, or breathing exposures are possible. fatigue, and may cause you to pass out. In addition, the following controls are recommended: Chronic Health Effects * Where possible, automatically pump liquid Isoamyl The following chronic (long-term) health effects can occur at Acetate from drums or other storage containers to process some time after exposure to Isoamyl Acetate and can last for containers. months or years: * Before entering a confined space where Isoamyl Acetate Cancer Hazard may be present, check to make sure that an explosive concentration does not exist. * According to the information presently available to the New Jersey Department of Health and Senior Services, Isoamyl Good WORK PRACTICES can help to reduce hazardous Acetate has not been tested for its ability to cause cancer in exposures. The following work practices are recommended: animals. Reproductive Hazard * Workers whose clothing has been contaminated by Isoamyl Acetate should change into clean clothing promptly. * According to the information presently available to the New * Contaminated work clothes should be laundered by Jersey Department of Health and Senior Services, Isoamyl individuals who have been informed of the hazards of Acetate has not been tested for its ability to affect exposure to Isoamyl Acetate. reproduction. * Eye wash fountains should be provided in the immediate work area for emergency use. Other Long-Term Effects * If there is the possibility of skin exposure, emergency * Breathing Isoamyl Acetate can irritate the lungs causing shower facilities should be provided. coughing and/or shortness of breath. * On skin contact with Isoamyl Acetate, immediately wash * Prolonged or repeated contact can cause drying and or shower to remove the chemical. At the end of the cracking of the skin. workshift, wash any areas of the body that may have contacted Isoamyl Acetate, whether or not known skin MEDICAL contact has occurred. * Do not eat, smoke, or drink where Isoamyl Acetate is Medical Testing handled, processed, or stored, since the chemical can be There is no special test for this chemical. However, if illness swallowed. Wash hands carefully before eating, drinking, occurs or overexposure is suspected, medical attention is smoking, or using the toilet. recommended. PERSONAL PROTECTIVE EQUIPMENT Any evaluation should include a careful history of past and present symptoms with an exam. Medical tests that look for WORKPLACE CONTROLS ARE BETTER THAN damage already done are not a substitute for controlling PERSONAL PROTECTIVE EQUIPMENT. However, for exposure. some jobs (such as outside work, confined space entry, jobs done only once in a while, or jobs done while workplace Request copies of your medical testing. You have a legal right controls are being installed), personal protective equipment to this information under OSHA 1910.1020. may be appropriate. ISOAMYL ACETATE page 3 of 6 OSHA 1910.132 requires employers to determine the * Exposure to 1,000 ppm is immediately dangerous to life appropriate personal protective equipment for each hazard and and health. If the possibility of exposure above 1,000 ppm to train employees on how and when to use protective exists, use a NIOSH approved self-contained breathing equipment. apparatus with a full facepiece operated in a pressure- demand or other positive-pressure mode equipped with an The following recommendations are only guidelines and may emergency escape air cylinder. not apply to every situation. HANDLING AND STORAGE Clothing * Avoid skin contact with Isoamyl Acetate. Wear solvent- * Prior to working with Isoamyl Acetate you should be resistant gloves and clothing. Safety equipment suppliers/ trained on its proper handling and storage. manufacturers can provide recommendations on the most * Isoamyl Acetate is not compatible with METALS; protective glove/clothing material for your operation. OXIDIZING AGENTS (such as PERCHLORATES, * Safety equipment manufacturers recommend Polyvinyl PEROXIDES, PERMANGANATES, CHLORATES, Alcohol and Nitrile as protective materials. NITRATES, CHLORINE, BROMINE and FLUORINE); * All protective clothing (suits, gloves, footwear, headgear) STRONG ACIDS (such as HYDROCHLORIC, should be clean, available each day, and put on before SULFURIC and NITRIC); and STRONG BASES (such as work. SODIUM HYDROXIDE and POTASSIUM HYDROXIDE). Eye Protection * Store in tightly closed containers in a cool, well-ventilated * Wear indirect-vent, impact and splash resistant goggles area away from COMBUSTIBLES. when working with liquids. * Sources of ignition, such as smoking and open flames, are * Wear a face shield along with goggles when working with prohibited where Isoamyl Acetate is used, handled, or corrosive, highly irritating or toxic substances. stored. * Metal containers involving the transfer of Isoamyl Acetate Respiratory Protection should be grounded and
Recommended publications
  • Effect of Enzymes on Strawberry Volatiles During Storage, at Different Ripeness
    Effect of Enzymes on Strawberry Volatiles During Storage, at Different Ripeness Level, in Different Cultivars and During Eating Thesis Presented in Partial Fulfillment of the Requirements for the Degree Master of Science in the Graduate School of The Ohio State University By Gulsah Ozcan Graduate Program in Food Science and Technology The Ohio State University 2010 Thesis Committee: Sheryl Ann Barringer, Adviser W. James Harper John Litchfield 1 Copyright by Gülşah Özcan 2010 ii ABSTRACT Strawberry samples with enzyme activity and without enzyme activity (stannous chloride added) were measured for real time formation of lipoxygenase (LOX) derived aroma compounds after 5 min pureeing using selected ion flow tube mass spectrometry (SIFT-MS). The concentration of (Z)-3-hexenal and (E)-2-hexenal increased immediately after blending and gradually decreased over time while hexanal concentration increased for at least 5 min in ground strawberries. The formation of hexanal was slower than the formation of (Z)-3-hexenal and (E)-2-hexenal in the headspace of pureed strawberries. The concentration of LOX aldehydes and esters significantly increased during refrigerated storage. Damaging strawberries increased the concentration of LOX aldehydes but did not significantly affect the concentration of esters. The concentrations of many of the esters were strongly correlated to their corresponded acids and/or aldehydes. The concentration of LOX generated aldehydes decreased during ripening, while fruity esters increased. Different varieties had different aroma profiles and esters were the greatest percentage of the volatiles. The aroma release of some of the LOX derived aldehydes in the mouthspace in whole strawberries compared to chopped strawberries showed that these volatiles are formed in the mouth during chewing.
    [Show full text]
  • Isoamyl Acetate
    SUMMARY OF DATA FOR CHEMICAL SELECTION Isoamyl Acetate CAS No. 123-92-2 Prepared for NTP by Technical Resources International, Inc Prepared on 11/94 Under NCI Contract No. N01-CP-56019 Table of Contents I. Chemical Identification II. Exposure Information Table 1. Levels of isoamyl acetate reported in foods III. Evidence for Possible Carcinogenic Activity Appendix A: Structural Analogs of Isoamyl Acetate IV. References SUMMARY OF DATA FOR CHEMICAL SELECTION CHEMICAL IDENTIFICATION CAS Registry No.: 123-92-2 Chem. Abstr. Name: 1-Butanol, 3-methyl-, acetate Synonyms: Acetic acid 3-methylbutyl ester; acetic acid, isopentyl ester; AI3-00576; banana oil; isoamyl ethanoate; isopentyl acetate; isopentyl alcohol, acetate; pear oil; 3-methyl-1-butanol acetate; 3-methyl-1-butyl acetate; 3-methylbutyl acetate; 3-methylbutyl ethanoate; i-amyl acetate Structure: Molecular Formula and Molecular Weight: C7H14O2 Mol. Wt.: 130.18 Chemical and Physical Properties: Description: Colorless, flammable liquid with a banana-like odor (ACGIH, 1993). Boiling Point: 142°C (Lide, 1993) Melting Point: -78.5°C (Mark, et al, 1984; Lide, 1993) Solubility: Soluble in water (2000 mg/L at 25°C) (Howard, 1990); soluble in ethanol, diethyl ether, and acetone (Lide, 1993). Vapor 4.5 mm Hg at 20°C (Howard, 1990) Pressure: Refractive 1.4003 (Lide, 1993) Index: Flash Point: closed cup, 33°C; open cup, 38°:C (Budavari, 1989) Density: 0.876 (Lewis, 1993) Reactivity: Thermal decomposition of isoamyl acetate may produce acrid fumes. Contact with strong oxidizing agents, strong acids, and alkaline materials should be avoided (Haarmann & Reimer Corp., 1994). Hazardous decomposition products of isoamyl acetate include CO and CO2 (AESAR/Alfa, 1994) Log 2.13 (Howard, 1990) P(octanol/water partition coefficient): Technical Isoamyl acetate is commercially available as both a natural and synthetic product with a purity Products and range of 95-99+%.
    [Show full text]
  • Butyl Acetate Safety Data Sheet Sipchem Chemicals Company
    Butyl Acetate Safety Data Sheet Sipchem Chemicals Company SCC Sipchem Chemicals Company Safety Data Sheet According to Regulation (EC) No. 1272/2008, Regulation (EC) 1907/2006 1. Identification of the substance/mixture and of the responsible company 1.1. Product Identifier: Butyl Acetate (C6H12O2) BUTYL ACETATE; BUTYL ETHANOATE; 1-BUTYL ACETATE; ACETIC ACID N-BUTYL ESTER; ACETIC ACID, BUTYL ESTER; 1-ACETOXYBUTANE; UN 1123; C6H12O2 1.2. Relevant identified uses of the substance or mixture and uses advised against: Identified uses: Industrial solvent, solvent for coatings, films, perfumes and synthetic flavoring agents, extraction solvent for various products and laboratory procedures. 1.3. Details of the supplier of the safety data sheet: Sipchem Chemicals Company (SCC) PO Box 12021 Post Coe 31961 Jubail Industrial City Kingdom of Saudi Arabia Website: www.sipchem.com/en/affiliates.htm 1.4. Emergency telephone number: 00966-359 9985 (24 hours) 2. Hazards Identification Butyl Acetate CAS 123-86-4 Purity: >99.0% Trace Impurities: Butanol 2.1. Classification of the substance or mixture: Classification of Labeling in accordance with the CLP Regulations: Classification Labeling N International Hazard Class and Hazard statement Pictogram Hazard Suppl. Hazard Specific o Index No Chemical EC No CAS No Category Code(s) Code(s) Signal Statement statement Conc. Limits, t Identification Word Code(s) Code(s) M-factors e Code(s) s 607-025- R:10-66-67 GHS02 H225 123-86-4 Flam. Liq. 3 00-1 Butyl Acetate 204-658-1 GHS07 H319 #EUH066 100 STOT SE 3 H336 Classification according to Regulation 1272/2008/EC (CLP) Basis for Classification This substance is classified based on Directive 1272/2008/EC and its amendments (CLP Regulation,GHS) BUTYL ACETATE (123-86-4) SAFETY DATA SHEET according to Regulation (EC) No.
    [Show full text]
  • Dc349fr3501 A3 1/12
    DC349FR3501_A3 Safety Data Sheet DEVTHANE 349 LOW HAP ARMAG WHITE PTA Bulk Sales Reference No.: DC349FR3501 SDS Revision Date: 02/11/2019 SDS Revision Number: A3-7 1. Identification of the preparation and company 1.1. Product identifier Product Identity DEVTHANE 349 LOW HAP ARMAG WHITE PTA Bulk Sales Reference No. DC349FR3501 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. 1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC Manufacturer: Akzo Nobel Coatings International Paint 6001 Antoine Drive Houston, Texas 77091 Emergency CHEMTREC (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481 2. Hazard identification of the product 2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Skin Sens. 1;H317 May cause an allergic skin reaction. Aquatic Chronic 3;H412 Harmful to aquatic life with long lasting effects. 2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows. Warning. H226 Flammable liquid and vapor. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P235 Keep cool. P240 Ground / bond container and receiving equipment. 1/12 DC349FR3501_A3 P241 Use explosion-proof electrical / ventilating / light / equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust / fume / gas / mist / vapors / spray.
    [Show full text]
  • Analysis of Strawberry Volatiles in Different Hydrocolloids and Different
    Analysis of strawberry volatiles in different hydrocolloids and different conditions using Selected Ion Flow Tube – Mass Spectrometry THESIS Presented in Partial Fulfillment of the Requirements for the Degree Master of Science in the Graduate School of the Ohio State University By Yachen Zhang Graduate Program in Food Science and Technology The Ohio State University 2016 Master's Examination Committee: Dr. Sheryl Barringer, Advisor Dr. Dennis Heldman Dr. Christopher Simons © Copyright by Yachen Zhang 2016 i ABSTRACT Hydrocolloids and additives in gummy candies bind flavors, thus it is important to know how these additives affect flavor release. Selected Ion Flow Tube- Mass Spectrometry (SIFT-MS) was used to perform static headspace and mouthspace tests. The release of strawberry flavor in different hydrocolloids (gelatin, pectin, and starch) and conditions were analyzed. The factors that were considered were the type of hydrocolloid (gelatin, pectin, and starch), the concentration of the pectin (0, 2, 3, 5 g), sugar content (0, 55, 64, 74g), and acidity (pH 3.86, 3.65, 3.55, 3.47). Volatile release into the headspace of the samples containing no hydrocolloids was significantly higher than samples that contained hydrocolloids. The type of hydrocolloid significantly affected volatile compound concentration released into the headspace. Volatile levels in pectin and starch were lower than when no hydrocolloid was present, but they were not significant different with each other. Gelatin had the lowest volatile concentrations released into the headspace for most compounds. Increasing pectin decreased volatiles release compared to no hydrocolloids present. When the pectin content was further increased from 2g to 5g, most of volatiles had no significant difference.
    [Show full text]
  • BLUE BOOK 1 Methyl Acetate CIR EXPERT PANEL MEETING
    BLUE BOOK 1 Methyl Acetate CIR EXPERT PANEL MEETING AUGUST 30-31, 2010 Memorandum To: CIR Expert Panel Members and Liaisons From: Bart Heldreth Ph.D., Chemist Date: July 30, 2010 Subject: Draft Final Report of Methyl Acetate, Simple Alkyl Acetate Esters, Acetic Acid and its Salts as used in Cosmetics . This review includes Methyl Acetate and the following acetate esters, relevant metabolites and acetate salts: Propyl Acetate, Isopropyl Acetate, t-Butyl Acetate, Isobutyl Acetate, Butoxyethyl Acetate, Nonyl Acetate, Myristyl Acetate, Cetyl Acetate, Stearyl Acetate, Isostearyl Acetate, Acetic Acid, Sodium Acetate, Potassium Acetate, Magnesium Acetate, Calcium Acetate, Zinc Acetate, Propyl Alcohol, and Isopropyl Alcohol. At the June 2010 meeting, the Panel reviewed information submitted in response to an insufficient data announcement for HRIPT data for Cetyl Acetate at the highest concentration of use (lipstick). On reviewing the data in the report, evaluating the newly available unpublished studies and assessing the newly added ingredients, the Panel determined that the data are now sufficient, and issued a Tentative Report, with a safe as used conclusion. Included in this report are Research Institute for Fragrance Materials (RIFM) sponsored toxicity studies on Methyl Acetate and Propyl Acetate, which were provided in “wave 2” at the June Panel Meeting but are now incorporated in full. The Tentative Report was issued for a 60 day comment period (60 days as of the August panel meeting start date). The Panel should now review the Draft Final Report, confirm the conclusion of safe, and issue a Final Report. All of the materials are in the Panel book as well as in the URL for this meeting's web page http://www.cir- safety.org/aug10.shtml.
    [Show full text]
  • Simultaneous Recovery of High-Purity Cu and Poly(Vinyl Chloride)
    www.nature.com/scientificreports OPEN Simultaneous recovery of high‑purity Cu and poly(vinyl chloride) from waste wire harness via swelling followed by ball milling Harendra Kumar, Shogo Kumagai*, Tomohito Kameda, Yuko Saito & Toshiaki Yoshioka Poly(vinyl chloride) (PVC) swelling coupled with ball milling was employed for the simultaneous recovery of high‑purity Cu and PVC from waste wire harness under ambient conditions. The experimentally determined performances of 15 organic solvents for PVC swelling and phthalate plasticiser extraction were compared with those predicted considering Hansen solubility parameters. As a result, n-butyl acetate and acetone were identifed as the two best solvents for adequate PVC swelling without PVC dissolution and almost complete plasticiser extraction within 60 min. The swelling was concluded to contribute to the control of phthalate plasticisers, the use of which in wire harness has recently been limited by the Restriction of Hazardous Substances (RoHS) directive. Cables swollen with n-butyl acetate or acetone were subjected to dry ball milling for ~ 60 min to completely separate PVC and Cu and achieve the quantitative recovery of these components from 20-cm-long cables. Thus, this work unveils the high potential of recycling the otherwise non‑recyclable long and non‑uniform waste wire harness cables and is expected to impact the related (e.g., automotive, electrical, and electronics) industries, contributing to the establishment of a more sustainable society. Electric cables are indispensable for electricity/information transmission and contain poly(vinyl chloride) (PVC) and Cu as major constituents accounting for almost 16 and 42%, respectively, of the total material consumption in cable production 1.
    [Show full text]
  • Glycidyl Methacrylate
    SOME INDUSTRIAL CHEMICAL INTERMEDIATES AND SOLVENTS VOLUME 125 This publication represents the views and expert opinions of an IARC Working Group on the Identification of Carcinogenic Hazards to Humans, which met in Lyon, 5–11 November 2019 LYON, FRANCE - 2020 IARC MONOGRAPHS ON THE IDENTIFICATION OF CARCINOGENIC HAZARDS TO HUMANS GLYCIDYL METHACRYLATE 1. Exposure Characterization 1.1.3 Chemical and physical properties of the pure substance 1.1 Identification of the agent Description: colourless, combustible liquid 1.1.1 Nomenclature substance with a sweetish or fruity odour, which tends to polymerize spontaneously Chem. Abstr. Serv. Reg. No.: 106-91-2 (HSDB, 2003) Chem. Abstr. Serv. name: 2,3-epoxypropyl- Boiling point: 189 °C (HSDB, 2003) methacrylate Melting point: −41.5 °C (HSDB, 2003) IUPAC systematic name: (oxiran-2-yl)methyl Density: 1.04–1.07 g/cm3 (20 °C) (ECHA, 2-methylprop-2-enoate 2019; IFA, 2019) Synonyms: glycidyl methacrylate; (RS)-2,3- Solubility: < 10–50 g/L (in water at 20–25 °C) epoxypropylmethacrylate; (±)-2,3-epoxypro- (ECHA, 2019; IFA, 2019), very soluble in pylmethacrylate; 2-((methacryloxy)methyl) benzene, ethyl ether, and ethyl alcohol oxirane; 2-oxiranylmethyl ester; methacrylic (HSDB, 2003) acid-2,3-epoxypropylester; 2-propenoic acid, Vapour pressure: 4.2 hPa (25 °C) (ECHA, 2-methyl-; 1-propanol, 2,3-epoxy-,methacryl- 2019) ate. Flash point: 76–84 °C at 101.3 kPa (ECHA, 2019) 1.1.2 Structural and molecular formula, and Auto-ignition temperature: 389 °C at 101.3 kPa relative molecular mass (ECHA, 2019) O Vapour density: 4.91 (air = 1) (IFA, 2019) Octanol/water partition coefficient (P): O log Kow = 0.96 (ILO, 2006) O Conversion factor: 1 ppm = 5.91 mg/m3 (at 20 °C and 101.3 kPa).
    [Show full text]
  • EICG-Hot Spots
    State of California AIR RESOURCES BOARD PUBLIC HEARING TO CONSIDER AMENDMENTS TO THE EMISSION INVENTORY CRITERIA AND GUIDELINES REPORT FOR THE AIR TOXICS “HOT SPOTS” PROGRAM STAFF REPORT: INITIAL STATEMENT OF REASONS DATE OF RELEASE: September 29, 2020 SCHEDULED FOR CONSIDERATION: November 19, 2020 Location: Please see the Public Agenda which will be posted ten days before the November 19, 2020, Board Meeting for any appropriate direction regarding a possible remote-only Board Meeting. If the meeting is to be held in person, it will be held at the California Air Resources Board, Byron Sher Auditorium, 1001 I Street, Sacramento, California 95814. This report has been reviewed by the staff of the California Air Resources Board and approved for publication. Approval does not signify that the contents necessarily reflect the views and policies of the Air Resources Board, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. This Page Intentionally Left Blank TABLE OF CONTENTS EXECUTIVE SUMMARY .......................................................................................... 1 I. INTRODUCTION AND BACKGROUND ................................................................. 5 II. THE PROBLEM THAT THE PROPOSAL IS INTENDED TO ADDRESS .................... 6 III. BENEFITS ANTICIPATED FROM THE REGULATORY ACTION, INCLUDING THE BENEFITS OR GOALS PROVIDED IN THE AUTHORIZING STATUTE .................... 8 IV. AIR QUALITY ..........................................................................................................
    [Show full text]
  • Tert-Butyl Acetate: Non-HAP Solvent
    Tert-Butyl Acetate: Non-HAP Solvent Non-HAP Solvent for High-Solids Epoxy Formulations Charles Cooper, Paul Galick, Stephen Harris, Daniel Pourreau, and Carmen Rodriguez—Lyondell Chemical Company* Xylene is the traditional diluent solvent for formulating epoxy/ solvent suitable for both the epoxy resin and amine curative sides amine paints used in protective coatings and linings. Cur- of a two-component epoxy system. Molecular modeling predicts rently, it is under regulatory pressure because it is on the very low reactivity of the t-BAc ester functionality with amine hazardous air pollutant (HAP) list and it is also a volatile organic nucleophiles as a result of steric hindrance. Long-term aging compound (VOC). Ketones and acetate esters are powerful studies with amine curatives in t-BAc solutions confirm these solvents, but their use is limited by their reaction with the amine theoretical results. Kinetics of the reaction of amines with t-BAc curatives before paint application. Tert-butyl acetate (t-BAc) and its n-butyl acetate isomer support the view that steric proposed as a VOC-exempt solvent, is a nonreactive, non-HAP hindrance plays a major role in amine solution stability. INTRODUCTION amines and are also not used in these similar to nBuAc in its solvency power systems. and may be used as a diluent in epoxy The primary reason for reformulating a Previous work in our laboratories systems. To determine the range of ap- solvent system is to comply with haz- has demonstrated that tertiary butyl plicability of t-BAc as a solvent for the ardous air pollutant (HAP) and volatile acetate (t-BAc), unlike methyl acetate amine curative side of a 2K-epoxy sys- organic compound (VOC) content lim- and its isomer n-butyl acetate, is signifi- tem, we chose to evaluate high-solids, its.
    [Show full text]
  • JACC No. 41 N-Butanol (CAS No
    n-Butanol (CAS No. 71-36-3) JACC No. 41 ISSN-0773-6339-41 Brussels, December 2003 n-Butanol (CAS No. 71-36-3) ECETOC JACC No. 41 © Copyright - ECETOC European Centre for Ecotoxicology and Toxicology of Chemicals 4 Avenue E. Van Nieuwenhuyse (Bte 6), B-1160 Brussels, Belgium. All rights reserved. No part of this publication may be reproduced, copied, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise without the prior written permission of the copyright holder. Applications to reproduce, store, copy or translate should be made to the Secretary General. ECETOC welcomes such applications. Reference to the document, its title and summary may be copied or abstracted in data retrieval systems without subsequent reference. The content of this document has been prepared and reviewed by experts on behalf of ECETOC with all possible care and from the available scientific information. It is provided for information only. ECETOC cannot accept any responsibility or liability and does not provide a warranty for any use or interpretation of the material contained in the publication. ECETOC JACC No. 41 n-Butanol (CAS No. 71-36-3) n-Butanol (CAS No. 71-36-3) CONTENTS EXECUTIVE SUMMARY 1 THE ECETOC SCHEME FOR THE JOINT ASSESSMENT OF COMMODITY CHEMICALS 2 1. SUMMARY AND CONCLUSIONS 3 2. IDENTTITY, PHYSICAL AND CHEMICAL PROPERTIES, ANALYTICAL METHODS 5 2.1 Identify 5 2.2 EU classification and labelling 5 2.3 Physical and chemical properties 6 2.4 Conversion factors 8 2.5 Analytical methods 9 2.5.1 In workplace air 9 2.5.2 In environmental media 9 2.5.3 In biological media 9 3.
    [Show full text]
  • SAFETY DATA SHEET Butyl Acetate, N- This SDS Is Valid for All Grades That Start with Catalog Number 304
    Product Information: 203.740.3471 Emergency Assistance (CHEMTREC): 1.800.424.9300 (USA) +1.703.527.3887 (INT) SAFETY DATA SHEET Butyl Acetate, n- This SDS is valid for all grades that start with catalog number 304 1. IDENTIFICATION OF SUBSTANCE / MIXTURE AND OF SUPPLIER Product Identifier: High Purity Chemicals Synonyms: 1-Butyl Acetate; Butyl Ethanoate; Acetic Acid, n-Butyl Ester Other means of identification: CAS No. 123-86-4 EINECS No. 204-658-1 Recommended use of the chemical and restrictions on use: Used in the production of lacquers. Supplier Details: Greenfield Global USA, Inc. Greenfield Global USA, Inc. 1101 Isaac Shelby Drive, Shelbyville, 58 Vale Road, Brookfield, KY 40065, USA. CT 06804, USA. Tel: 502.232.7600 Tel: 203.740.3471 Fax: 502.633.6100 Fax: 203.740.3481 CCN17213 CCN17213 Emergency Contact: CHEMTREC: 1.800.424.9300 (USA) / +1.703.527.3887 (International) 2. HAZARDS IDENTIFICATION OSHA Hazards: Flammable liquid, Target Organ Effect, Irritant Target Organs: Central nervous system SDS: 865 Revision Date: 06.29.17 Revision Number: 4.0 Initials: EF Page 1 of 10 Product Information: 203.740.3471 Emergency Assistance (CHEMTREC): 1.800.424.9300 (USA) NFPA +1.703.527.3887 (INT) GHS label elements, including precautionary statements Signal Word: WARNING! Hazard statement(s) H226 Flammable liquid and vapor H336 May cause drowsiness or dizziness. Precautionary statement(s) P210 Keep away from heat, sparks, open flames, and hot surfaces. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves and eye and face protection. P235 Keep cool. P261 Avoid breathing dust/fumes/gas/mist/vapors.
    [Show full text]