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Report of the Advisory Group to Recommend Priorities for the IARC Monographs During 2020–2024
IARC Monographs on the Identification of Carcinogenic Hazards to Humans Report of the Advisory Group to Recommend Priorities for the IARC Monographs during 2020–2024 Report of the Advisory Group to Recommend Priorities for the IARC Monographs during 2020–2024 CONTENTS Introduction ................................................................................................................................... 1 Acetaldehyde (CAS No. 75-07-0) ................................................................................................. 3 Acrolein (CAS No. 107-02-8) ....................................................................................................... 4 Acrylamide (CAS No. 79-06-1) .................................................................................................... 5 Acrylonitrile (CAS No. 107-13-1) ................................................................................................ 6 Aflatoxins (CAS No. 1402-68-2) .................................................................................................. 8 Air pollutants and underlying mechanisms for breast cancer ....................................................... 9 Airborne gram-negative bacterial endotoxins ............................................................................. 10 Alachlor (chloroacetanilide herbicide) (CAS No. 15972-60-8) .................................................. 10 Aluminium (CAS No. 7429-90-5) .............................................................................................. 11 -
New Nickel Complexes for Trifluoromethylation Studies
NEW NICKEL COMPLEXES FOR TRIFLUOROMETHYLATION STUDIES A THESIS SUBMITTED TO THE GRADUATE DIVISION OF THE UNIVERSITY OF HAWAIʻI AT MĀNOA IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE IN CHEMISTRY DECEMBER 2012 BY Hiromi Ichioka Thesis Committee: David Vicic, Chairperson Marcus A. Tius Philip Williams i NEW NICKEL COMPLEXES FOR TRIFLUOROMETHYLATION STUDIES A THESIS SUBMITTED TO THE GRADUATE DIVISION OF THE UNIVERSITY OF HAWAIʻI AT MĀNOA IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE IN CHEMISTRY DECEMBER 2012 BY Hiromi Ichioka Thesis Committee: David Vicic, Chairperson Marcus A. Tius Philip Williams ii Acknowledgements I would like to thank the members of my thesis committee for spending their time to modify my thesis. I would like to appreciate Professor Vicic for overall advice. I would like to thank help and support from many individuals in the Chemistry Department, from faculty and staff. I would like to thank University of Hawaii for financial support in the form of teaching assistant. I would like to thank Professor Yamaguchi working together to synthesize bis-perfluoroalkyl nickel complexes. I would also like to appreciate Professor Shimada to experimentally help me and make good advice. iii Abstract We decided to prepare bis-perfluoroalkyl nickel complexes bearing a bipyridine ligand for investigation of the fundamental nickel perfluoroalkyl chemistry and reductive elimination of perfluoroethylene. Moreover, we envisioned a new precursor for investigation of Ar-CF3 reductive elimination. We have successfully demonstrated the syntheses of [(dtbpy)Ni(CF3)2] and [(dtbpy)Ni(CF2CF3)2] in moderate yields. The key intermediate nickel complex, [(tmeda)Ni(CF3)Br] allowed for the preparation of new complexes in good yields. -
Effect of Enzymes on Strawberry Volatiles During Storage, at Different Ripeness
Effect of Enzymes on Strawberry Volatiles During Storage, at Different Ripeness Level, in Different Cultivars and During Eating Thesis Presented in Partial Fulfillment of the Requirements for the Degree Master of Science in the Graduate School of The Ohio State University By Gulsah Ozcan Graduate Program in Food Science and Technology The Ohio State University 2010 Thesis Committee: Sheryl Ann Barringer, Adviser W. James Harper John Litchfield 1 Copyright by Gülşah Özcan 2010 ii ABSTRACT Strawberry samples with enzyme activity and without enzyme activity (stannous chloride added) were measured for real time formation of lipoxygenase (LOX) derived aroma compounds after 5 min pureeing using selected ion flow tube mass spectrometry (SIFT-MS). The concentration of (Z)-3-hexenal and (E)-2-hexenal increased immediately after blending and gradually decreased over time while hexanal concentration increased for at least 5 min in ground strawberries. The formation of hexanal was slower than the formation of (Z)-3-hexenal and (E)-2-hexenal in the headspace of pureed strawberries. The concentration of LOX aldehydes and esters significantly increased during refrigerated storage. Damaging strawberries increased the concentration of LOX aldehydes but did not significantly affect the concentration of esters. The concentrations of many of the esters were strongly correlated to their corresponded acids and/or aldehydes. The concentration of LOX generated aldehydes decreased during ripening, while fruity esters increased. Different varieties had different aroma profiles and esters were the greatest percentage of the volatiles. The aroma release of some of the LOX derived aldehydes in the mouthspace in whole strawberries compared to chopped strawberries showed that these volatiles are formed in the mouth during chewing. -
Evolution of Ethyl Carbamate During Madeira Wine Ageing by GC-MS a New Methodology MASTER DISSERTATION
DM Evolution of Ethyl Carbamate During Madeira Wine Ageing by GC-MS A new methodology MASTER DISSERTATION João Micael da Silva Leça MASTER IN APPLIED BIOCHEMISTRY November | 2014 Evolution of Ethyl Carbamate During Madeira Wine Ageing by GC-MS A new methodology MASTER DISSERTATION João Micael da Silva Leça MASTER IN APPLIED BIOCHEMISTRY SUPERVISOR José Carlos Antunes Marques CO-SUPERVISOR Vanda Nulita Gomes Pereira Evolution of ethyl carbamate during Madeira wine ageing by GC-MS: a new methodology AGRADECIMENTOS Quero começar por agradecer à minha família e em especial à minha mãe, Teresa Silva, à minha avó, Teresa Teixeira, ao meu avô, Quirino Teixeira, à minha tia, Ana Teixeira, à minha madrinha, Sandra Nunes, à minha madrinha, Maria Nunes e aos meus primos Ludgero Gomes e Lília Gomes, por todo o amor e apoio que sempre me deram. Um obrigado à Fátima Spínola pelo seu amor. Um especial obrigado por toda a compreensão, pelo apoio e por todos os momentos bons que já partilhamos. Certamente seria uma pessoa muito diferente se nunca nos tivéssemos conhecido. Obrigado por tudo. Um enorme obrigado à Anabela Moura, à Manuela Godinho e ao Dr. António Godinho por toda a dedicação e apoio. O meu agradecimento torna-se difícil de expressar por palavras. E porque a vida não tem valor sem ser partilhada, um grande obrigado aos meus amigos mais próximos: Vítor Correia, Victor Andrade, Catarina Lume, João Mendes, Igor Nunes, Pedro Leme, Marco Franco, João Silva, Nuno Pestana, Válter Mendes, Julie Campbell, Luís Freitas, Igor Afonso, Roberto Aguiar, Marisa Faria, Dina Maciel, Neide Cardoso, Joaquim Lopes, Miguel Nunes, Paulo Silva, Dinarte Jesus, Hugo Câmara, Núria Fernandes, Vânia Silva, Rodolfo Silva e Ricardo Mendonça. -
12E4968079.Pdf
Fluorocarbon compatibilized gold-silica nanocomposites for recyclable regioselective hydroamination of alkynes in a fluorous biphasic system Item Type Conference Paper Authors Merican, Zulkifli; Vu, Bao Khanh; Solovyeva, Vera; Rodionov, Valentin; Khe, Cheng Seong; Rajalingam, Sokkalingam; Vasant, Pandian Citation Merican Z, Vu BK, Solovyeva VA, Rodionov VO, Khe CS, et al. (2016) Fluorocarbon compatibilized gold-silica nanocomposites for recyclable regioselective hydroamination of alkynes in a fluorous biphasic system. Available: http:// dx.doi.org/10.1063/1.4968079. Eprint version Publisher's Version/PDF DOI 10.1063/1.4968079 Publisher AIP Publishing Rights This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. The following article appeared in Merican, Z., Vu, B.K., Solovyeva, V.A., Rodionov, V.O., Khe, C.S., Rajalingam, S. and Vasant, P., 2016, November. Fluorocarbon compatibilized gold-silica nanocomposites for recyclable regioselective hydroamination of alkynes in a fluorous biphasic system. In 4TH INTERNATIONAL CONFERENCE ON FUNDAMENTAL AND APPLIED SCIENCES (ICFAS2016) (Vol. 1787, No. 1, p. 030014). AIP Publishing and may be found at http://aip.scitation.org/doi/abs/10.1063/1.4968079. Download date 27/09/2021 23:14:23 Link to Item http://hdl.handle.net/10754/622088 Fluorocarbon compatibilized gold-silica nanocomposites for recyclable regioselective hydroamination of alkynes in a fluorous biphasic system Zulkifli Merican, Bao Khanh Vu, Vera A. Solovyeva, Valentin O. Rodionov, Cheng Seong Khe, Sokkalingam Rajalingam, and Pandian Vasant Citation: 1787, 030014 (2016); doi: 10.1063/1.4968079 View online: http://dx.doi.org/10.1063/1.4968079 View Table of Contents: http://aip.scitation.org/toc/apc/1787/1 Published by the American Institute of Physics Fluorocarbon Compatibilized Gold-Silica Nanocomposites For Recyclable Regioselective Hydroamination of Alkynes In A Fluorous Biphasic System Zulkifli Merican1, a Bao Khanh Vu2, Vera A. -
Isoamyl Acetate
SUMMARY OF DATA FOR CHEMICAL SELECTION Isoamyl Acetate CAS No. 123-92-2 Prepared for NTP by Technical Resources International, Inc Prepared on 11/94 Under NCI Contract No. N01-CP-56019 Table of Contents I. Chemical Identification II. Exposure Information Table 1. Levels of isoamyl acetate reported in foods III. Evidence for Possible Carcinogenic Activity Appendix A: Structural Analogs of Isoamyl Acetate IV. References SUMMARY OF DATA FOR CHEMICAL SELECTION CHEMICAL IDENTIFICATION CAS Registry No.: 123-92-2 Chem. Abstr. Name: 1-Butanol, 3-methyl-, acetate Synonyms: Acetic acid 3-methylbutyl ester; acetic acid, isopentyl ester; AI3-00576; banana oil; isoamyl ethanoate; isopentyl acetate; isopentyl alcohol, acetate; pear oil; 3-methyl-1-butanol acetate; 3-methyl-1-butyl acetate; 3-methylbutyl acetate; 3-methylbutyl ethanoate; i-amyl acetate Structure: Molecular Formula and Molecular Weight: C7H14O2 Mol. Wt.: 130.18 Chemical and Physical Properties: Description: Colorless, flammable liquid with a banana-like odor (ACGIH, 1993). Boiling Point: 142°C (Lide, 1993) Melting Point: -78.5°C (Mark, et al, 1984; Lide, 1993) Solubility: Soluble in water (2000 mg/L at 25°C) (Howard, 1990); soluble in ethanol, diethyl ether, and acetone (Lide, 1993). Vapor 4.5 mm Hg at 20°C (Howard, 1990) Pressure: Refractive 1.4003 (Lide, 1993) Index: Flash Point: closed cup, 33°C; open cup, 38°:C (Budavari, 1989) Density: 0.876 (Lewis, 1993) Reactivity: Thermal decomposition of isoamyl acetate may produce acrid fumes. Contact with strong oxidizing agents, strong acids, and alkaline materials should be avoided (Haarmann & Reimer Corp., 1994). Hazardous decomposition products of isoamyl acetate include CO and CO2 (AESAR/Alfa, 1994) Log 2.13 (Howard, 1990) P(octanol/water partition coefficient): Technical Isoamyl acetate is commercially available as both a natural and synthetic product with a purity Products and range of 95-99+%. -
Compound Formula Tin (II) Nitride Silver Oxide Lithium Sulfide Magnesium Sulfide
Ionic Bonding Drill Write the correct formula for the following compounds Compound Formula tin (II) nitride silver oxide lithium sulfide magnesium sulfide copper (I) nitride AgCl boron iodide potassium fluoride copper (I) chloride is CuCl iron (II) oxide is FeO tin (IV) fluoride is SnF4 nickel (II) fluoride is NiF2 lead (IV) oxide is PbO2 silver chloride is calcium iodide is CaI2 potassium bromide sodium phosphide iron (II) chloride copper (I) bromide lead (II) sulfide lead (IV) nitride beryllium nitride potassium bromide is KBr sodium phosphide is Na3P iron (II) chloride is FeCl2 copper (I) bromide is CuBr lead (II) sulfide is PbS lead (IV) nitride is Pb3N4 beryllium nitride is Be3N2 copper (I) chloride iron (II) oxide tin (IV) fluoride nickel (II) fluoride lead (IV) oxide Ag2O silver chloride calcium iodide Answers copper (I) nitride is Cu3N boron iodide is BI3 potassium fluoride is KF silver oxide is lithium sulfide is Li2S magnesium sulfide is MgS tin (II) nitride is Sn3N2 Ionic Bonding Drill Write the correct formula for the following compounds Compound Formula lithium bromide sodium sulfide lead (II) chloride nickel (II) oxide AlBr3 copper (II) oxide AlI3 iron (II) fluoride tin (II) oxide iron (II) oxide is FeO lead (II) oxide is PbO aluminum bromide is potassium oxide is K2O potassium oxide is K2O aluminum iodide is lead (II) nitride is Pb3N2 tin (IV) sulfide iron (III) sulfide lead (II) nitride copper (II) oxide silver fluoride AgF sodium chloride magnesium bromide tin (IV) sulfide is SnS2 iron (III) sulfide is Fe2S3 lead (II) -
Butyl Acetate Safety Data Sheet Sipchem Chemicals Company
Butyl Acetate Safety Data Sheet Sipchem Chemicals Company SCC Sipchem Chemicals Company Safety Data Sheet According to Regulation (EC) No. 1272/2008, Regulation (EC) 1907/2006 1. Identification of the substance/mixture and of the responsible company 1.1. Product Identifier: Butyl Acetate (C6H12O2) BUTYL ACETATE; BUTYL ETHANOATE; 1-BUTYL ACETATE; ACETIC ACID N-BUTYL ESTER; ACETIC ACID, BUTYL ESTER; 1-ACETOXYBUTANE; UN 1123; C6H12O2 1.2. Relevant identified uses of the substance or mixture and uses advised against: Identified uses: Industrial solvent, solvent for coatings, films, perfumes and synthetic flavoring agents, extraction solvent for various products and laboratory procedures. 1.3. Details of the supplier of the safety data sheet: Sipchem Chemicals Company (SCC) PO Box 12021 Post Coe 31961 Jubail Industrial City Kingdom of Saudi Arabia Website: www.sipchem.com/en/affiliates.htm 1.4. Emergency telephone number: 00966-359 9985 (24 hours) 2. Hazards Identification Butyl Acetate CAS 123-86-4 Purity: >99.0% Trace Impurities: Butanol 2.1. Classification of the substance or mixture: Classification of Labeling in accordance with the CLP Regulations: Classification Labeling N International Hazard Class and Hazard statement Pictogram Hazard Suppl. Hazard Specific o Index No Chemical EC No CAS No Category Code(s) Code(s) Signal Statement statement Conc. Limits, t Identification Word Code(s) Code(s) M-factors e Code(s) s 607-025- R:10-66-67 GHS02 H225 123-86-4 Flam. Liq. 3 00-1 Butyl Acetate 204-658-1 GHS07 H319 #EUH066 100 STOT SE 3 H336 Classification according to Regulation 1272/2008/EC (CLP) Basis for Classification This substance is classified based on Directive 1272/2008/EC and its amendments (CLP Regulation,GHS) BUTYL ACETATE (123-86-4) SAFETY DATA SHEET according to Regulation (EC) No. -
Dc349fr3501 A3 1/12
DC349FR3501_A3 Safety Data Sheet DEVTHANE 349 LOW HAP ARMAG WHITE PTA Bulk Sales Reference No.: DC349FR3501 SDS Revision Date: 02/11/2019 SDS Revision Number: A3-7 1. Identification of the preparation and company 1.1. Product identifier Product Identity DEVTHANE 349 LOW HAP ARMAG WHITE PTA Bulk Sales Reference No. DC349FR3501 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. 1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC Manufacturer: Akzo Nobel Coatings International Paint 6001 Antoine Drive Houston, Texas 77091 Emergency CHEMTREC (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481 2. Hazard identification of the product 2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Skin Sens. 1;H317 May cause an allergic skin reaction. Aquatic Chronic 3;H412 Harmful to aquatic life with long lasting effects. 2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows. Warning. H226 Flammable liquid and vapor. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P235 Keep cool. P240 Ground / bond container and receiving equipment. 1/12 DC349FR3501_A3 P241 Use explosion-proof electrical / ventilating / light / equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust / fume / gas / mist / vapors / spray. -
Ethyl Carbamate Formation in Sub-Optimal Wine Storage Conditions and Influence of the Yeast Starter
03-larcher_05b-tomazic 26/03/13 18:21 Page65 ETHYL CARBAMATE FORMATION IN SUB-OPTIMAL WINE STORAGE CONDITIONS AND INFLUENCE OF THE YEAST STARTER Roberto LARCHER, Sergio MOSER, Ainhoa Usua MENOLLI, Loris TONIDANDEL and Giorgio NICOLINI* Unità Chimica Vitienologica e Agroalimentare, Centro Trasferimento Tecnologico - Fond. Edmund Mach, Via E. Mach 1, 38 010 San Michele all’Adige (TN), Italy Abstract Résumé Aim : To evaluate the potential risk of ethyl carbamate (EC) Objectif : Évaluer le risque potentiel de formation de carbamate formation in wine by studying its production kinetics at sub- d'éthyle (CE) dans le vin par l'étude de la cinétique de production à optimal storage temperatures. des températures de stockage sous-optimales. Methods and results : The kinetics of EC formation was Méthodes et résultats : La cinétique de formation de CE a été investigated in 60 white wines obtained from 6 varietal juices étudiée chez 60 vins blancs issus de six moûts variétaux fermentés fermented with 10 yeast strains. The wines were analysed for their avec 10 souches de levure. Les vins ont été analysés pour leur urea content at bottling, then EC formation was monitored during teneur en urée à la mise en bouteilles, puis la formation de CE a été in-bottle storage at < 12 °C for 150 days followed by 152 days at contrôlée au cours du stockage en bouteilles à < 12 °C pendant 40 °C. Storage at < 12 °C had no effect on EC formation, 150 jours, suivis par 152 jours à 40 °C. Le stockage à < 12 °C n'a regardless of initial urea content ; however, at 40 °C we found a eu aucun effet sur la formation de CE, quelle que soit la teneur en positive correlation between initial urea content and final EC urée initiale. -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK). -
Drmno Lignite Field (Kostolac Basin, Serbia): Origin and Palaeoenvironmental Implications from Petrological and Organic Geochemi
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Faculty of Chemistry Repository - Cherry J. Serb. Chem. Soc. 77 (8) 1109–1127 (2012) UDC 553.96.:550.86:547(497.11–92) JSCS–4338 Original scientific paper Drmno lignite field (Kostolac Basin, Serbia): origin and palaeoenvironmental implications from petrological and organic geochemical studies KSENIJA STOJANOVIĆ1*#, DRAGANA ŽIVOTIĆ2, ALEKSANDRA ŠAJNOVIĆ3, OLGA CVETKOVIĆ3#, HANS PETER NYTOFT4 and GEORG SCHEEDER5 1University of Belgrade, Faculty of Chemistry, Studentski trg 12–16, 11000 Belgrade, Serbia, 2University of Belgrade, Faculty of Mining and Geology, Djušina 7, 11000 Belgrade, Serbia, 3University of Belgrade, Centre of Chemistry, ICTM, Studentski trg 12–16, 11000 Belgrade; Serbia, 4Geological Survey of Denmark and Greenland, Øster Voldgade 10, DK-1350 Copenhagen, Denmark and 5Federal Institute for Geosciences and Natural Resources, Steveledge 2, 30655 Hanover, Germany (Received 26 November 2011, revised 17 February 2012) Abstract: The objective of the study was to determine the origin and to recon- struct the geological evolution of lignites from the Drmno field (Kostolac Ba- sin, Serbia). For this purpose, petrological and organic geochemical analyses were used. Coal from the Drmno field is typical humic coal. Peat-forming vegetation dominated by decay of resistant gymnosperm (coniferous) plants, followed by prokaryotic organisms and angiosperms. The coal forming plants belonged to the gymnosperm families Taxodiaceae, Podocarpaceae, Cupres- saceae, Araucariaceae, Phyllocladaceae and Pinaceae. Peatification was rea- lised in a neutral to slightly acidic, fresh water environment. Considering that the organic matter of the Drmno lignites was deposited at the same time, in a relatively constant climate, it could be supposed that climate probably had only a small impact on peatification.