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Shear Deformation in Polymer Gels and Dense Colloidal Suspensions
SHEAR DEFORMATION IN POLYMER GELS AND DENSE COLLOIDAL SUSPENSIONS Anindita Basu A DISSERTATION in Physics and Astronomy Presented to the Faculties of the University of Pennsylvania in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy 2012 Arjun G. Yodh, James M. Skinner Professor of Science, Professor of Physics Supervisor of Dissertation Alan T. Charlie Johnson, Jr., Professor of Physics Graduate Group Chairperson Dissertation Committee Paul A. Janmey, Professor of Physiology Tom Lubensky, Professor of Physics Douglas Durian, Professor of Physics Gary Bernstein, Professor of Physics Dedication To my mother. ii Acknowledgements I am deeply indebted to the following individuals for my education and the work presented in this thesis. I am infinitely grateful to my advisor, Dr. Arjun Yodh for his unfailing guidance and support, not to mention his patience in my endeavours. I acknowledge his constant efforts in teaching me to think critically and interact effectively. I also thank my thesis committee members- Drs. Gary Bernstein, Douglas Durian, Paul Janmey, and Tom Lubensky. I thank my dear husband and best friend, Soumyadip Ghosh, for his unwavering support- he took upon himself a 130-mile commute, shine or snow during my PhD. I thank my mother and father, who provided me with every opportunity. I am also grateful to my colleagues and group mates, past and present- Ahmed Alsayed, Kevin Aptowicz, David Busch, Dan Chen, Ke Chen, Piotr Habdas, Yilong Han, Larry Hough, Matt Gratale, Matt Lohr, Xiaoming Mao, Saurav Pathak, Matt Pelc, Tim Still, Qi Wen, Ye Xu, Peter Yunker, and Zexin Zhang. Not only were they instrumental in much that I have learned during my PhD, but they made every moment enjoyable. -
March 2010 Booklet
DPOLYMarch 2010 Meeting Program including Soft-Matter Physics sessions TM 2010 APS March Meeting • March 15–19 • Portland, Oregon DPOLY Short Course Polymers for Energy Generation and Storage March 13, 1:00 - 5:30 and March 14, 8:30 – 5:30 Oregon Convention Center Course Description Polymers hold much promise as active layers in inexpensive, lightweight energy generating and storing devices. Although the solid state physics and electrochemistry of such devices have been the subject of intense research, it has more recently become clear that an understanding of the polymer physics will lead to both an ability to control nanoscale morphology and optimize transport across the material. The purpose of this short course is to provide a background in the basic device physics of both organic photovoltaics and batteries to an audience primarily consisting of graduate students, postdoctoral researchers, and early career scientists already knowledgeable in polymer physics. It is hoped that this forum will both provide a basic foundation of knowledge as well as a deeper discussion of outstanding problems and avenues of research in energy relevant polymers. Each half of the course will begin by covering the basic underlying physics of charge/ion transport as well as device operation. Then our current understanding of the thermodynamics, morphology, self-assembly, and mechanisms of charge transport within these systems will be outlined with significant time reserved for discussion of gaps in current understanding and promising areas of future research. The course schedule allows for talks from each of the below speakers with ample time for discussion and interaction. This is roughly the schedule that has been followed by recent DPOLY short courses. -
2007 APS March Meeting Denver, Colorado
2007 APS March Meeting Denver, Colorado http://www.aps.org/meetings/march i Monday, March 5, 2007 8:00AM - 11:12AM — Session A29 DFD: Focus Session: Colloids I Colorado Convention Center 303 8:00AM A29.00001 How confinement modifies the colloidal glass transition1 ERIC R. WEEKS, Emory University — We study concentrated colloidal suspensions, a model system which has a glass transition. These are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the particles are roughly analogous to individual molecules in a traditional glass. We view the motion of these colloidal particles in three dimensions by using an optical confocal microscope. This allows us to directly study the microscopic behavior responsible for the macroscopic viscosity divergence of glasses. In particular, we study how confinement changes the particle dynamics. We confine a colloidal suspension between two parallel walls, and find that in thin sample chambers the particle motion is greatly slowed. This suggests that confinement causes the onset of the glass transition to happen “sooner,” at particle concentrations which are not normally glassy. 1Supported by the National Science Foundation under Grant No. DMR-0239109. 8:36AM A29.00002 Periodic Stresses and Shear Thickening in an Attractive Colloidal Gel1 , CHINEDUM OSUJI, DAVID WEITZ, Applied Physics, Harvard University — We report on the observation of periodic stresses in a colloidal gel at rest and under minute shear deformation. Dilute suspensions of carbon black colloidal particles in hydrocarbon oil with an attractive Van der Waals interaction are found to shear thicken in two distinct regimes. The first, low shear rate regime is ascribed to network elongation and the high shear regime to hydrodynamic clustering, akin to that observed in concentrated hard sphere systems. -
Arxiv:1610.10013V2 [Cond-Mat.Soft] 30 Jan 2017 to Understand Some of the Issues, It Is Relevant to Be X
Experimental soft-matter science Sidney R. Nagel The James Franck and Enrico Fermi Institutes and the Department of Physics The University of Chicago, Chicago, IL 60637 (Dated: January 31, 2017) Soft materials consist of basic units that are significantly larger than an atom but much smaller than the overall dimensions of the sample. The label \soft condensed matter" emphasizes that the large basic building blocks of these materials produce low elastic moduli that govern a material's ability to withstand deformations. Aside from softness, there are many other properties that are also caused by the large size of the constituent building blocks. Soft matter is dissipative, disordered, far-from-equilibrium, non-linear, thermal and entropic, slow, observable, gravity-affected, patterned, non-local, interfa- cially elastic, memory-forming and active. This is only a partial list of how matter created from large component particles is distinct from \hard matter" composed of constituents at an atomic scale. Issues inherent in soft matter raise problems that are broadly important in diverse areas of science and require multiple modes of attack. For example, far-from-equilibrium be- havior is confronted in biology, chemistry, geophysics, astrophysics and nuclear physics. Similarly, issues dealing with disorder appear broadly throughout many branches of inquiry wherever rugged landscapes are invoked. This article reviews the discussions that occurred during a workshop held on January 30-31, 2016 in which opportunities in soft-matter experiment were surveyed. Soft matter has had an exciting history of discovery and continues to be a fertile ground for future research. PACS numbers: 47.57.-s, 47.54.-r, 82.35.-x, 05.70.Ln, 46.65.+g, 83., 47. -
APS March Meeting 2010 Portland, Oregon
APS March Meeting 2010 Portland, Oregon http://www.aps.org/meetings/march/index.cfm i Monday, March 15, 2010 8:00AM - 11:00AM — Session A12 DFD: Microfluidics I: Electrokinesis and Transport B110-B111 8:00AM A12.00001 Flow Regimes and Parametric Competitions in Nanochannel Flows CHONG LIU, ZHIGANG LI, Department of Mechanical Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong — Nanoscale fluid flow systems involve both micro- and macroscopic parameters, which compete with each another and lead to different flow regimes. In this work, we investigate the competitions of four fundamental parameters, including the fluid-fluid, fluid-wall binding energies, temperature of the system, and driving force. By illustrating the fluid flux as a function of a dimensionless number, which represents the effective surface effect on the fluid, we show that the fluid motion in nanochannels falls into different regimes. For small fluid-fluid self-binding energy, there are three flow regimes; as the dimensionless number increases, the flux undergoes a transition from fluid-wall binding energy independent to temperature independent. If the fluid-wall binding energy is of the order of room temperature, there is a critical value for the dimensionless number, which divides the flow into weak and strong fluid-wall interaction regimes. Each of these regimes is associated with a distinct mechanism which reveals the competitions of the parameters. 8:12AM A12.00002 Microfluidic Chemical Concentration Switching at Taylor’s Limit1 , EBERHARD BODENSCHATZ, ALBERT BAE, LASSP, Cornell University, Ithaca and MPI for Dynamics and Selforganization, Goettingen, CARSTEN BETA, Institute for Physics and Astronomy, University of Potsdam and MPI for Dynamics and Selforganization, Goettingen — In this talk, we will discuss the time for switching chemical concentrations in microfluidic devices. -
2008 APS March Meeting New Orleans, Louisiana
2008 APS March Meeting New Orleans, Louisiana http://www.aps.org/meetings/march/index.cfm i Monday, March 10, 2008 8:00AM - 11:00AM — Session A8 DFD: Colloidal Self-Assembly I Morial Convention Center RO6 8:00AM A8.00001 Directed Self-Assembly of Spherical Particles NATALIE ARKUS, GUANGNAN MENG, VINOTHAN MANOHARAN, MICHAEL BRENNER, Harvard University — We examine the kinetics and energetics of self-assembly in systems containing a small number of spherical colloidal nanoparticles using a combination of theory, simulation, and experiment. We then explore how the addition of spherically symmetric binding specificity can be used to direct the self-assembly of a given structure. Using graph theoretic, numerical, and algebraic geometric techniques, we denumerate all possible packings for a system of n particles. We map out the energy landscape of these packings, which is determined not only by the value of the potential energy at these minima, but also by the vibrational normal modes of the structures. Experiments for a 6 particle system show that the likelihood of a given packing follows this expected equilibrium distribution. To explore the kinetics of packing formation, we simulate the self-assembly of these systems in the irreversible binding limit. For the 6 particle system, this reveals that the kinetics required to form one of the packings is highly unlikely, resulting in the other packing forming with 100% probability. With the addition of binding specificity however, we can cause the unlikely packing to form with 100% probability. We show how the addition of binding specificity effects the energetic landscape of these systems, and that it alone is sufficient to direct self-assembly.