Green Quaternions, Tenacious Symmetry, and Octahedral Zome
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Symmetry of Fulleroids Stanislav Jendrol’, František Kardoš
Symmetry of Fulleroids Stanislav Jendrol’, František Kardoš To cite this version: Stanislav Jendrol’, František Kardoš. Symmetry of Fulleroids. Klaus D. Sattler. Handbook of Nanophysics: Clusters and Fullerenes, CRC Press, pp.28-1 - 28-13, 2010, 9781420075557. hal- 00966781 HAL Id: hal-00966781 https://hal.archives-ouvertes.fr/hal-00966781 Submitted on 27 Mar 2014 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Symmetry of Fulleroids Stanislav Jendrol’ and Frantiˇsek Kardoˇs Institute of Mathematics, Faculty of Science, P. J. Saf´arikˇ University, Koˇsice Jesenn´a5, 041 54 Koˇsice, Slovakia +421 908 175 621; +421 904 321 185 [email protected]; [email protected] Contents 1 Symmetry of Fulleroids 2 1.1 Convexpolyhedraandplanargraphs . .... 3 1.2 Polyhedral symmetries and graph automorphisms . ........ 4 1.3 Pointsymmetrygroups. 5 1.4 Localrestrictions ............................... .. 10 1.5 Symmetryoffullerenes . .. 11 1.6 Icosahedralfulleroids . .... 12 1.7 Subgroups of Ih ................................. 15 1.8 Fulleroids with multi-pentagonal faces . ......... 16 1.9 Fulleroids with octahedral, prismatic, or pyramidal symmetry ........ 19 1.10 (5, 7)-fulleroids .................................. 20 1 Chapter 1 Symmetry of Fulleroids One of the important features of the structure of molecules is the presence of symmetry elements. -
Origin of Icosahedral Symmetry in Viruses
Origin of icosahedral symmetry in viruses Roya Zandi†‡, David Reguera†, Robijn F. Bruinsma§, William M. Gelbart†, and Joseph Rudnick§ Departments of †Chemistry and Biochemistry and §Physics and Astronomy, University of California, Los Angeles, CA 90095-1569 Communicated by Howard Reiss, University of California, Los Angeles, CA, August 11, 2004 (received for review February 2, 2004) With few exceptions, the shells (capsids) of sphere-like viruses (11). This problem is in turn related to one posed much earlier have the symmetry of an icosahedron and are composed of coat by Thomson (12), involving the optimal distribution of N proteins (subunits) assembled in special motifs, the T-number mutually repelling points on the surface of a sphere, and to the structures. Although the synthesis of artificial protein cages is a subsequently posed ‘‘covering’’ problem, where one deter- rapidly developing area of materials science, the design criteria for mines the arrangement of N overlapping disks of minimum self-assembled shells that can reproduce the remarkable properties diameter that allow complete coverage of the sphere surface of viral capsids are only beginning to be understood. We present (13). In a similar spirit, a self-assembly phase diagram has been here a minimal model for equilibrium capsid structure, introducing formulated for adhering hard disks (14). These models, which an explicit interaction between protein multimers (capsomers). all deal with identical capsomers, regularly produced capsid Using Monte Carlo simulation we show that the model reproduces symmetries lower than icosahedral. On the other hand, theo- the main structures of viruses in vivo (T-number icosahedra) and retical studies of viral assembly that assume icosahedral sym- important nonicosahedral structures (with octahedral and cubic metry are able to reproduce the CK motifs (15), and, most symmetry) observed in vitro. -
The Cubic Groups
The Cubic Groups Baccalaureate Thesis in Electrical Engineering Author: Supervisor: Sana Zunic Dr. Wolfgang Herfort 0627758 Vienna University of Technology May 13, 2010 Contents 1 Concepts from Algebra 4 1.1 Groups . 4 1.2 Subgroups . 4 1.3 Actions . 5 2 Concepts from Crystallography 6 2.1 Space Groups and their Classification . 6 2.2 Motions in R3 ............................. 8 2.3 Cubic Lattices . 9 2.4 Space Groups with a Cubic Lattice . 10 3 The Octahedral Symmetry Groups 11 3.1 The Elements of O and Oh ..................... 11 3.2 A Presentation of Oh ......................... 14 3.3 The Subgroups of Oh ......................... 14 2 Abstract After introducing basics from (mathematical) crystallography we turn to the description of the octahedral symmetry groups { the symmetry group(s) of a cube. Preface The intention of this account is to provide a description of the octahedral sym- metry groups { symmetry group(s) of the cube. We first give the basic idea (without proofs) of mathematical crystallography, namely that the 219 space groups correspond to the 7 crystal systems. After this we come to describing cubic lattices { such ones that are built from \cubic cells". Finally, among the cubic lattices, we discuss briefly the ones on which O and Oh act. After this we provide lists of the elements and the subgroups of Oh. A presentation of Oh in terms of generators and relations { using the Dynkin diagram B3 is also given. It is our hope that this account is accessible to both { the mathematician and the engineer. The picture on the title page reflects Ha¨uy'sidea of crystal structure [4]. -
Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of F Orbitals
molecules Article Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals R. Bruce King Department of Chemistry, University of Georgia, Athens, GA 30602, USA; [email protected] Academic Editor: Vito Lippolis Received: 4 June 2020; Accepted: 29 June 2020; Published: 8 July 2020 Abstract: The combination of atomic orbitals to form hybrid orbitals of special symmetries can be related to the individual orbital polynomials. Using this approach, 8-orbital cubic hybridization can be shown to be sp3d3f requiring an f orbital, and 12-orbital hexagonal prismatic hybridization can be shown to be sp3d5f2g requiring a g orbital. The twists to convert a cube to a square antiprism and a hexagonal prism to a hexagonal antiprism eliminate the need for the highest nodality orbitals in the resulting hybrids. A trigonal twist of an Oh octahedron into a D3h trigonal prism can involve a gradual change of the pair of d orbitals in the corresponding sp3d2 hybrids. A similar trigonal twist of an Oh cuboctahedron into a D3h anticuboctahedron can likewise involve a gradual change in the three f orbitals in the corresponding sp3d5f3 hybrids. Keywords: coordination polyhedra; hybridization; atomic orbitals; f-block elements 1. Introduction In a series of papers in the 1990s, the author focused on the most favorable coordination polyhedra for sp3dn hybrids, such as those found in transition metal complexes. Such studies included an investigation of distortions from ideal symmetries in relatively symmetrical systems with molecular orbital degeneracies [1] In the ensuing quarter century, interest in actinide chemistry has generated an increasing interest in the involvement of f orbitals in coordination chemistry [2–7]. -
Can Every Face of a Polyhedron Have Many Sides ?
Can Every Face of a Polyhedron Have Many Sides ? Branko Grünbaum Dedicated to Joe Malkevitch, an old friend and colleague, who was always partial to polyhedra Abstract. The simple question of the title has many different answers, depending on the kinds of faces we are willing to consider, on the types of polyhedra we admit, and on the symmetries we require. Known results and open problems about this topic are presented. The main classes of objects considered here are the following, listed in increasing generality: Faces: convex n-gons, starshaped n-gons, simple n-gons –– for n ≥ 3. Polyhedra (in Euclidean 3-dimensional space): convex polyhedra, starshaped polyhedra, acoptic polyhedra, polyhedra with selfintersections. Symmetry properties of polyhedra P: Isohedron –– all faces of P in one orbit under the group of symmetries of P; monohedron –– all faces of P are mutually congru- ent; ekahedron –– all faces have of P the same number of sides (eka –– Sanskrit for "one"). If the number of sides is k, we shall use (k)-isohedron, (k)-monohedron, and (k)- ekahedron, as appropriate. We shall first describe the results that either can be found in the literature, or ob- tained by slight modifications of these. Then we shall show how two systematic ap- proaches can be used to obtain results that are better –– although in some cases less visu- ally attractive than the old ones. There are many possible combinations of these classes of faces, polyhedra and symmetries, but considerable reductions in their number are possible; we start with one of these, which is well known even if it is hard to give specific references for precisely the assertion of Theorem 1. -
On Polyhedra with Transitivity Properties
Discrete Comput Geom 1:195-199 (1986) iSCrete & Computathm~ ~) 1986 Springer-V©rlagometrvNew York Inc. IF On Polyhedra with Transitivity Properties J. M. Wills Mathematics Institute, University of Siegen, Hoelderlinstrasse 3, D-5900 Siegen, FRG Abstract. In a remarkable paper [4] Griinbaum and Shephard stated that there is no polyhedron of genus g > 0, such that its symmetry group acts transitively on its faces. If this condition is slightly weakened, one obtains" some interesting polyhedra with face-transitivity (resp. vertex-transitivity). In recent years several attempts have been/made to find polyhedral analogues for the Platonic solids in the Euclidean 3-space E 3 (cf. [1, 4, 5, 7-14]). By a polyhedron P we mean the union of a finite number of plane polygons in E 3 which form a 2-manifold without boundary and without self-intersections, where, as usual, a plane polygon is a plane set bounded by finitely many line segments. If the plane polygons are disjoint except for their edges, they are called the faces of P. We require adjacent faces to be non-coplanar. The vertices and edges of P are the vertices and edges of the faces of P. The genus of the underlying 2-manifold is the genus of P. A flag of P is a triplet consisting of one vertex, one edge incident with this vertex, and one face containing this edge. If, for given p- 3, q >- 3 all faces of P are p-gons and all vertices q-valent, we say that P is equivelar, i.e., has equal flags (cf. -
Maximal Subgroups of the Coxeter Group W(H4) and Quaternions
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Elsevier - Publisher Connector Linear Algebra and its Applications 412 (2006) 441–452 www.elsevier.com/locate/laa Maximal subgroups of the Coxeter group W(H4) and quaternions Mehmet Koca a, Ramazan Koç b,∗, Muataz Al-Barwani a, Shadia Al-Farsi a aDepartment of Physics, College of Science, Sultan Qaboos University, P.O. Box 36, Al-Khod 123, Muscat, Oman bDepartment of Physics, Faculty of Engineering, Gaziantep University, 27310 Gaziantep, Turkey Received 9 October 2004; accepted 17 July 2005 Available online 12 September 2005 Submitted by H. Schneider Abstract The largest finite subgroup of O(4) is the non-crystallographic Coxeter group W(H4) of order 14,400. Its derived subgroup is the largest finite subgroup W(H4)/Z2 of SO(4) of order 7200. Moreover, up to conjugacy, it has five non-normal maximal subgroups of orders 144, two 240, 400 and 576. Two groups [W(H2) × W(H2)]Z4 and W(H3) × Z2 possess non- crystallographic structures with orders 400 and 240 respectively. The groups of orders 144, 240 and 576 are the extensions of the Weyl groups of the root systems of SU(3) × SU(3), SU(5) and SO(8) respectively. We represent the maximal subgroups of W(H4) with sets of quaternion pairs acting on the quaternionic root systems. © 2005 Elsevier Inc. All rights reserved. AMS classification: 20G20; 20F05; 20E34 Keywords: Structure of groups; Quaternions; Coxeter groups; Subgroup structure ∗ Corresponding author. Tel.: +90 342 360 1200; fax: +90 342 360 1013. -
Platonic Solids Generate Their Four-Dimensional Analogues
This is a repository copy of Platonic solids generate their four-dimensional analogues. White Rose Research Online URL for this paper: https://eprints.whiterose.ac.uk/85590/ Version: Accepted Version Article: Dechant, Pierre-Philippe orcid.org/0000-0002-4694-4010 (2013) Platonic solids generate their four-dimensional analogues. Acta Crystallographica Section A : Foundations of Crystallography. pp. 592-602. ISSN 1600-5724 https://doi.org/10.1107/S0108767313021442 Reuse Items deposited in White Rose Research Online are protected by copyright, with all rights reserved unless indicated otherwise. They may be downloaded and/or printed for private study, or other acts as permitted by national copyright laws. The publisher or other rights holders may allow further reproduction and re-use of the full text version. This is indicated by the licence information on the White Rose Research Online record for the item. Takedown If you consider content in White Rose Research Online to be in breach of UK law, please notify us by emailing [email protected] including the URL of the record and the reason for the withdrawal request. [email protected] https://eprints.whiterose.ac.uk/ 1 Platonic solids generate their four-dimensional analogues PIERRE-PHILIPPE DECHANT a,b,c* aInstitute for Particle Physics Phenomenology, Ogden Centre for Fundamental Physics, Department of Physics, University of Durham, South Road, Durham, DH1 3LE, United Kingdom, bPhysics Department, Arizona State University, Tempe, AZ 85287-1604, United States, and cMathematics Department, University of York, Heslington, York, YO10 5GG, United Kingdom. E-mail: [email protected] Polytopes; Platonic Solids; 4-dimensional geometry; Clifford algebras; Spinors; Coxeter groups; Root systems; Quaternions; Representations; Symmetries; Trinities; McKay correspondence Abstract In this paper, we show how regular convex 4-polytopes – the analogues of the Platonic solids in four dimensions – can be constructed from three-dimensional considerations concerning the Platonic solids alone. -
Remarks on the Cohomology of Finite Fundamental Groups of 3–Manifolds
Geometry & Topology Monographs 14 (2008) 519–556 519 arXiv version: fonts, pagination and layout may vary from GTM published version Remarks on the cohomology of finite fundamental groups of 3–manifolds SATOSHI TOMODA PETER ZVENGROWSKI Computations based on explicit 4–periodic resolutions are given for the cohomology of the finite groups G known to act freely on S3 , as well as the cohomology rings of the associated 3–manifolds (spherical space forms) M = S3=G. Chain approximations to the diagonal are constructed, and explicit contracting homotopies also constructed for the cases G is a generalized quaternion group, the binary tetrahedral group, or the binary octahedral group. Some applications are briefly discussed. 57M05, 57M60; 20J06 1 Introduction The structure of the cohomology rings of 3–manifolds is an area to which Heiner Zieschang devoted much work and energy, especially from 1993 onwards. This could be considered as part of a larger area of his interest, the degrees of maps between oriented 3– manifolds, especially the existence of degree one maps, which in turn have applications in unexpected areas such as relativity theory (cf Shastri, Williams and Zvengrowski [41] and Shastri and Zvengrowski [42]). References [1,6,7, 18, 19, 20, 21, 22, 23] in this paper, all involving work of Zieschang, his students Aaslepp, Drawe, Sczesny, and various colleagues, attest to his enthusiasm for these topics and the remarkable energy he expended studying them. Much of this work involved Seifert manifolds, in particular, references [1, 6, 7, 18, 20, 23]. Of these, [6, 7, 23] (together with [8, 9]) successfully completed the programme of computing the ring structure H∗(M) for any orientable Seifert manifold M with 1 2 3 3 G := π1(M) infinite. -
Chapter 3: Transformations Groups, Orbits, and Spaces of Orbits
Preprint typeset in JHEP style - HYPER VERSION Chapter 3: Transformations Groups, Orbits, And Spaces Of Orbits Gregory W. Moore Abstract: This chapter focuses on of group actions on spaces, group orbits, and spaces of orbits. Then we discuss mathematical symmetric objects of various kinds. May 3, 2019 -TOC- Contents 1. Introduction 2 2. Definitions and the stabilizer-orbit theorem 2 2.0.1 The stabilizer-orbit theorem 6 2.1 First examples 7 2.1.1 The Case Of 1 + 1 Dimensions 11 3. Action of a topological group on a topological space 14 3.1 Left and right group actions of G on itself 19 4. Spaces of orbits 20 4.1 Simple examples 21 4.2 Fundamental domains 22 4.3 Algebras and double cosets 28 4.4 Orbifolds 28 4.5 Examples of quotients which are not manifolds 29 4.6 When is the quotient of a manifold by an equivalence relation another man- ifold? 33 5. Isometry groups 34 6. Symmetries of regular objects 36 6.1 Symmetries of polygons in the plane 39 3 6.2 Symmetry groups of some regular solids in R 42 6.3 The symmetry group of a baseball 43 7. The symmetries of the platonic solids 44 7.1 The cube (\hexahedron") and octahedron 45 7.2 Tetrahedron 47 7.3 The icosahedron 48 7.4 No more regular polyhedra 50 7.5 Remarks on the platonic solids 50 7.5.1 Mathematics 51 7.5.2 History of Physics 51 7.5.3 Molecular physics 51 7.5.4 Condensed Matter Physics 52 7.5.5 Mathematical Physics 52 7.5.6 Biology 52 7.5.7 Human culture: Architecture, art, music and sports 53 7.6 Regular polytopes in higher dimensions 53 { 1 { 8. -
New Perspectives on Polyhedral Molecules and Their Crystal Structures Santiago Alvarez, Jorge Echeverria
New Perspectives on Polyhedral Molecules and their Crystal Structures Santiago Alvarez, Jorge Echeverria To cite this version: Santiago Alvarez, Jorge Echeverria. New Perspectives on Polyhedral Molecules and their Crystal Structures. Journal of Physical Organic Chemistry, Wiley, 2010, 23 (11), pp.1080. 10.1002/poc.1735. hal-00589441 HAL Id: hal-00589441 https://hal.archives-ouvertes.fr/hal-00589441 Submitted on 29 Apr 2011 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Journal of Physical Organic Chemistry New Perspectives on Polyhedral Molecules and their Crystal Structures For Peer Review Journal: Journal of Physical Organic Chemistry Manuscript ID: POC-09-0305.R1 Wiley - Manuscript type: Research Article Date Submitted by the 06-Apr-2010 Author: Complete List of Authors: Alvarez, Santiago; Universitat de Barcelona, Departament de Quimica Inorganica Echeverria, Jorge; Universitat de Barcelona, Departament de Quimica Inorganica continuous shape measures, stereochemistry, shape maps, Keywords: polyhedranes http://mc.manuscriptcentral.com/poc Page 1 of 20 Journal of Physical Organic Chemistry 1 2 3 4 5 6 7 8 9 10 New Perspectives on Polyhedral Molecules and their Crystal Structures 11 12 Santiago Alvarez, Jorge Echeverría 13 14 15 Departament de Química Inorgànica and Institut de Química Teòrica i Computacional, 16 Universitat de Barcelona, Martí i Franquès 1-11, 08028 Barcelona (Spain). -
Half-Bps M2-Brane Orbifolds 3
HALF-BPS M2-BRANE ORBIFOLDS PAUL DE MEDEIROS AND JOSÉ FIGUEROA-O’FARRILL Abstract. Smooth Freund–Rubin backgrounds of eleven-dimensional supergravity of the form AdS X7 and preserving at least half of the supersymmetry have been recently clas- 4 × sified. Requiring that amount of supersymmetry forces X to be a spherical space form, whence isometric to the quotient of the round 7-sphere by a freely-acting finite subgroup of SO(8). The classification is given in terms of ADE subgroups of the quaternions embed- dedin SO(8) as the graph of an automorphism. In this paper we extend this classification by dropping the requirement that the background be smooth, so that X is now allowed to be an orbifold of the round 7-sphere. We find that if the background preserves more than half of the supersymmetry, then it is automatically smooth in accordance with the homo- geneity conjecture, but that there are many half-BPS orbifolds, most of them new. The classification is now given in terms of pairs of ADE subgroups of quaternions fibred over the same finite group. We classify such subgroups and then describe the resulting orbi- folds in terms of iterated quotients. In most cases the resulting orbifold can be described as a sequence of cyclic quotients. Contents List of Tables 2 1. Introduction 3 How to use this paper 5 2. Spherical orbifolds 7 2.1. Spin orbifolds 8 2.2. Statement of the problem 9 3. Finite subgroups of the quaternions 10 4. Goursat’s Lemma 12 arXiv:1007.4761v3 [hep-th] 25 Aug 2010 4.1.