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1982 Post Accident Procedures for Chemicals and Propell.Pdf ^ / c V // AFRPL-TR-82-032 F04611-80-C-0046 POST ACCIDENT PROCEDURES FOR CHEMICALS AND PROPELLANTS Authors: Deborah K. Shaver Robert L. Berkowitz SYSTEMS TECHNOLOGY LABORATORY, INC, 2045 North 15th Street Arlington, Virginia 22201 September 1982 Interim Report for the Period April 1981 through January(1982 Approved for Public Release; Distribution Unlimited The AFRPL Technical Services Office has reviewed this report and it is releasable to the.National Technical Information Service, where it is releasable to the general public including foreign nationals. Prepared for AIR FORCE ROCKET PROPULSION LABORATORY U.S. DEPARTMENT OF TRANSPORTATION DIRECTOR OF LABORATORIES FEDERAL RAILROAD ADMINISTRATION AIR FORCE SYSTEMS COMMAND OFFICE OF RESEARCH AND DEVELOPMENT EDWARDS AIR FORCE BASE, CALIFORNIA 93523 WASHINGTON, D.C. 20590 \ 4 - Hazmat I FOREWARD This report was prepared by Systems Technology Laboratory, Inc., 2045 North 15th Street, Arlington, Virginia 22201 under contract F046II-80-C-0046 with the Air Force Rocket Propulsion Laboratory (AFRPL), Edwards Air Force Base, California 93523. Mr. John Marshall was COTR for AFRPL. The project was also jointly sponsored through the Federal Railroad Administration (FRA), Office of Rail Safety Research. This technical report has been reviewed and is approved for publication in accordance with the distribution statement on the cover and on the DD Form 1473. DAVID DANCER Federal Railroad Administration )HN W. MARSHALL FORREST S. FORBES (■oject Manager Chief, Propellant Systems Section Air Force Rocket Propulsion Laboratory Air Force Rocket Propulsion Laboratory FOR THE DIRECTOR n EUGENE G. HAB^RMAN Chief, Liquid Rodket Division Air/Force Rocket Propulsion Laboratory No warranty, guarantee or representation, expressed or implied, is made by or on behalf of the U.S. Government as to the absolute correctness or sufficiency of any representation contained in this document, and the U.S. Government assOmes no responsibility in connection therewith, nor can it be assumed that all acceptable safety measures are contained in this or associated documents, or that, other or additional measures may not be required under particular or exceptional conditions or circumstances, READ INSTRUCTIONS REPORT DOCUMENTATION PAGE BEFORE COMPLETING FORM t. REPORT NUMBER 2. GOVT ACCESSION NO. 3. RECIPIENT’S CATALOG NUMBER AFRPL-TR-82-032 4. TITLE (and Subtitle) 5. TYPE OF REPORT & PERIOD COVERED POST ACCIDENT PROCEDURES FOR CHEMICALS AND Interim PROPELLANTS April 1981-January 1982 6. PERFORMING O^G. REPORT NUMBER FQ4611-80-C-0046 ____________ 7. AU THORf e) 8. CONTRACT OR GRANT NUMBERfsJ Deborah K. Shaver F04611-80-C-0046 Robert L. Berkowitz 10. PROGRAM ELEMENT, PROJECT, TASK 9. PERFORMING ORGANIZATION NAME AND ADDRESS AREA & WORK UNIT NUMBERS SYSTEMS TECHNOLOGY LABORATORY, INC. 2045 North 15th Street Arlington, Virginia 22201 11. CONTROLLING OFFICE NAME AND ADDRESS 12. REPORT DATE U.S. DEPARTMENT OF TRANSPORTATION September 1982 Federal Railroad Administration 13. NUMBER OF PAGES Office of Rsch § D ev.. Washington DC 20590 298__________________________ 14. MONITORING AGENCY NAME & ADDRESSfi/ different from Controlling Office) 15. SECURITY CLASS, (of this report) A ir Force Rocket Propulsion Laboratory/LKCP UNCLASSIFIED Edwards AFB, C alifo rn ia 93523 15a. DECLASSI FI CATION/DOWN GRADING SCHEDULE 16. DISTRIBUTION STATEMENT (of this Report) APPROVED FOR PUBLIC RELEASE: DISTRIBUTION UNLIMITED Document is available to the public through the National Technical Information Service, S prin gfield, V irg in ia 22151. 17. DISTRIBUTION STATEMENT (of the abstract entered in Block 20, if different from Report) 18. SUPPLEMENTARY NOTES Refer to AFRPL-TR-82-031 which provides database fo r additional 12 hazardous materials and to AFRPL-TR-82-075 which is the two volume guidelines manual. 19. KEY WORDS (Continue on reverse side if necessary and identify by block number) hazardous materials vapor dispersion production hazards assessment transportation hazards mitigation accident assessment wreckage removal emergency response cleanup/disposal 20. ABSTRACT (Continue on reverse side if necessary and identify by block number) This report presents production volumes, storage capacities, shipment quantities, containers used for highway and r a il shipments, general commodity flow patterns and disposal sites and capabilities for 16 hazardous materials; an overview of emergency response guidelines and resources available to selected industry groups and state and local agencies; key findings based on STL's accident assess­ m ent; assessment of methods fo r implementing c ris is management techniques used by police, fire chiefs, and other disaster response officers; and criteria for interactive feedback c ris is management system. DD 1 F0RMJAN 73 •XATi1473 EDITION OF I NOV 65 IS OBSOLETE SECURITY CLASSIFICATION OF THIS PAGE (When Dele Entered) SECURITY CLASSIFICATION O Tute PAGE (When Data Entered) TABLE OF CONTENTS ■LIST OF ACRONYM S . ............................ ............................................................................................................................................................................... i 1 . EXECUTIVE SUMMARY ... ......................................... ......................................................................................................................1 - 1 2 . BACKGROUND . i . ...............................................................................................................................................................................................2 - 1 3 . CHEMICALS AND PROPELLANTS PRODUCTION AND TRANSPORTATION D A T A . .....................................................................................................................................................................................................................................3 - 1 3 .1 D a t a S o u r c e s .................................... 3 - 1 3 . 2 Physical/Chemical Data ....................... ’..............................................................................................................................3 - 2 3 .3 Production Quantities . ................................................................................................... 3 - 2 3 . 3 .1 A c e t o n e ..............................................................................................................................................................................3 - 2 3 . 3 . 2 A c e t o n e C y a n o h y d r i n ......................................... 3 - 6 3 . 3 .3 A c r y l o n i t r i l e ...................................................... 3 - 6 3 . 3 . 4 A e r o z i n e - 5 0 . ........................................................................................................ 3 - 9 3 . 3 .5 E t h y l A c r y l a t e ................................................................................................................................... .3 - 9 3 . 3 .6 H y d r o c y a n ic A c i d .................................................. 3 - 9 3 . 3 . 7 . I s o b u t a n e ................................ ............................................................................. ................................ 3 - 1 2 3 . 3 .8 Methanol . ............................... 3 - 1 2 3 . 3 .9 M e t h y l B r o m i d e ......................................................................................................................................... 3 —16 3 . 3 . 1 0 Monomethylamine Nitrate ........................... 3 - 1 6 3 . 3 .1 1 P r o p y l e n e ............................................................... 3 - 1 6 3 . 3 . 1 2 . Sodium Hydrosulfide Solution ................................................ 3 - 1 6 3 . 3 .1 3 Sodium Hydroxide Solution ............................................................................. 3 - 2 3 3 . 3 . 1 4 Styrene Monomer ............................................ 3 - 2 3 3 . 3 . 1 5 T o l u e n e ...................................................... ....................................................................................... 3 - 2 3 3 . 3 . 1 6 . V i n y l A c e t a t e ......................................................................................................................................... 3 - 3 3 3 .4 S h ip m e n t Q u a n t i t i e s .......................................................................................,.......................................................................3 - 3 3 3 .5 C o n t a in e r s R e q u ir e d f o r S h ip p in g .................................................. 3 - 3 3 3 . 5 .1 A c e t o n e ......................................... 3 - 3 8 3 . 5 .2 A c e t o n e C y a n o h y d r i n ................................................................ 3 - 3 8 3 . 5 .3 A c r y l o n i t r i l e .......................................................... 3 - 3 8 3 . 5 . 4 . Aerozine - 5 0 . ................................................................ 3 - 4 4 3 . 5 .5 Ethyl Acrylate ................................................................... 3 - 4 4 3 . 5 .6 Hydrocyanic Acid ..........................................................................................................................................3 - 4 4 3 . 5 .7 I s o b u t a n e ...................................................................................................................................... 3 - 4 4 3 . 5 .8 M e t h a n o l ................................................................................
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