Hair Care Overview Brochure (Pdf)

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hair care — ingredients portfolio table of contents fixatives and styling polymers ...... 3–10 conditioning polymers ...... 11–13 rheology modifiers ...... 14 –15 conditioners ...... 16 –17 biofunctionals ...... 17–18 uv protectants ...... 19 preservatives ...... 19–24 aromatics with antimicrobial properties ...... 24 opacifiers/pearlizers ...... 24 emulsifiers ...... 25 emollients ...... 25–27 lubricants ...... 28–29 encapsulates ...... 30 –31

Hair Care Overview Guide / 2 fixatives and styling polymers

description/ trade name INCI name structure features and benefits applications use levels form

Vinyl Caprolactam/VP/ Advantage™ Dimethylaminoethyl LC-A polymer Methacrylate oostrong, durable hold Copolymer oostiff feel with good flexibility oosuperior high humidity curl retention at 37% solids in ooaerosol hairsprays low solids level 0 .5–4 .0% solids Vinyl Caprolactam/VP/ ethanol oonon-aerosol hairsprays Advantage ooexcellent shine Dimethylaminoethyl LC-E polymer oohigh propellant tolerance Methacrylate (Available in CH 3 oono neutralization required Copolymer (and) EU only) CH 2 CH CH 2 CH CH 2 C Lauryl Pyrrolidone N O N O C=O O

(CH 2) 2 x y oostrong, durable hold N oostiff feel with good flexibility Advantage CH 3 CH 3 ooexcellent high humidity curl retention at Powder oogels S polymer Vinyl Caprolactam/VP/ z low solids level oomousses Dimethylaminoethyl ooexcellent shine oohairsprays 0 .5–4 .0% solids Methacrylate oohigh propellant tolerance and oopomades, waxes, Copolymer formulates into both high and low VOC pastes Advantage products 30% aqueous S Solution oono neutralization required solution polymer ooenables alcohol-free claims

oomedium hold Advantage VA/Butyl Maleate/ Clear pale ooexcellent high humidity ooaerosol hairsprays Plus Isobornyl Acrylate yellow curl retention 0 .5–5 .0% solids oonon-aerosol hairsprays polymer Copolymer solution oogood spray aesthetics with x y fast dry time

Hair Care Overview Guide / 3 description/ trade name INCI name structure features and benefits applications use levels form

Octylacrylamide/ v w x y z ooexcellent high humidity curl retention Acrylates/ ooexceptional stiffness Advantage™ ooaerosol hairsprays Butylaminoethyl Powder MeO HO O O oolong-lasting hold 0 .5–5 .0% solids 4910 polymer oonon-aerosol hairsprays Methacrylate oohigh propellant tolerance Copolymer NH ooworks in all VOC systems HO t-C4H9

H H H H ooprovides superior “stiff” hold ooaerosol hairsprays Aerosol sprays: Isobutylene/ CH3 CH3 40% solids C C C C oogood curl memory oonon-aerosol hairsprays 0 .25–5% solids Ethylmaleimide/ CH2 C CH2 C Aquaflex™ in hydro- ooexcellent high humidity curl retention oomousses Hydroxyethyl CH3 C C CH3 FX-64 polymer alcoholic O O O O ooshine oostyling creams/lotions Non-aerosol Maleimide N N solution oomanageability oopomades, waxes, sprays: 0 .25–7% Copolymer CH2CH3 CH2CH2OH x y oono neutralization required pastes solids

3 Aerosol sprays: CH2 CH CH2 CH C oocan be formulated at all VOC levels VP/Vinyl O 1 .0–5 .0% solids N O C=O oogood sprayability Aquaflex Caprolactam/ 40% solids in ooaerosol hairsprays NH ooexcellent high humidity curl retention y SF-40 polymer DMAPA Acrylates ethanol (CH2)3 oonon-aerosol hairsprays Non-aerosol X oolow-tack Copolymer N CH3 sprays: 0 .5–5 .0% oohigh propellant compatibility CH 3 z solids oogels oovolume and root boost oospray gels oosynergistic high humidity curl retention oospray mousses Aquaflex 30% aqueous when used with typical thickeners oopomades, waxes, Polyimide-1 0 .25–4 .0% solids XL-30 polymer solution ooflexibility gives style memory pastes oodurable hold ooshampoos oodry films on hair are smooth ooconditioners oohair treatments

oolong-lasting hold oostiff, strong hold with mechanical 30% solids in AquaStyle™ 300 durability hydroalcoholic polymer1 ooexcellent high humidity curl retention solution CH3 CH3 oogels ( ) ( ) ooenhances shine CH2 CH CH2 CH CH2 C CH2 C oomousses ooreduction of frizz N O N O C O C O oostyling creams/lotions ooaquaStyle 300 AF support alcohol-free Polyquaternium-69 NH NH oopomades, waxes, 0 .25–5 .0% solids (CH2)3 (CH2)3 claims, meets low-VOC requirements m n pastes N + N Cl- oosynergistic thickening with oostyling sprays H3C CH3 H3C CH3 hydrophobically modified gellants y z (non-aerosol) AquaStyle 300 30% aqueous C12H25 ooforms a sprayable polyelectrolyte matrix AF polymer1 solution when used in conjunction with one of the following rheology modifiers (Ashland™ 980/940 Carbomer, RapiThix A-60)

oodurable, all day hold oocrystal clear gels oogood initial stiffness oocream gels Acrylates ooexcellent high humidity curl retention oospray gels AquaStyle SH- Milky, white to Copolymer (and) O O O oosmooth comb-through oocreams and lotions 0 .5–2 .0% solids 100 polymer off-white liquid Water O O OH oono tack upon drying oowaxes and pomades R oono flaking oomousses oocontributes to viscosity in formulations oopatent pending

Hair Care Overview Guide / 4 description/ trade name INCI name structure features and benefits applications use levels form

Copolymer 845 ooaids wet and dry combing ooimparts smoothness, gloss, body and 20% aqueous CH3 oogels silky feel to hair solution oomousses CH2 CH CH2 C oogives smooth, conditioned feel to skin Copolymer 845 O ooblow-dry conditioners C=O oowater and alcohol compatible (Optiphen™ N O oostyling creams/lotions oocopolymer 845 is compatible with Preserved) VP/Dimethyla-minoethyl O oopomades, waxes, 0 .2–4 .0% carbomer and can be formulated into Methacrylate Copolymer y pastes solids (CH2)2 clear gels ooconditioning rinses ooforms a sprayable polyelectrolyte N oostyling sprays 20% aqueous matrix when used in conjunction with Copolymer 937 CH CH oolow-VOC sprays solution 3 3 z one of the following rheology modifiers (Ashland 980/940 Carbomer, RapiThix A-60) 50% solids in Copolymer 958 ethanol

oohairsprays Gaffix™ VC-713 oosuperior “natural feel” hold at low solids oogels Vinyl Caprolactam/VP/ polymer 37% solids in level oomousses 0 .5–4 .0% Dimethylaminoethyl (sold as Copolymer ethanol ooexcellent propellant compatibility oostyling creams/lotions solids Methacrylate Copolymer VC-713 in EU) oono neutralization required oopomades, waxes, pastes oogood wet and dry combing oogood curl retention oomousses ooclear, non-tacky films Flowable 30% oogels oobuilds body alcoholic oostyling sprays Gafquat™ 440 ooenhances hair luster 0 .25–8 .0% solution; oopomades, waxes, polymer oomanageability solids 100,000 avg . pastes ooeasy shampoo removability MW ooleave-in ooimproves foam aesthetics conditioning lotions oosmooth skin application with desirable after-feel

oothermal/mechanical protection Gafquat 755N oogood wet and dry combing polymer oogood curl retention in leave-on hair Polyquaternium-11 styling products ooclear, non-tacky films oomousses Gafquat oobuilds body oogels 755N-P polymer Highly viscous ooenhances hair luster oopomades, waxes, (phenoxyethanol- 20% aqueous n m oomanageability pastes 0 .25–4 .0% paraben solution; ooimproves foam aesthetics ooshampoos solids preserved) 1,000,000 avg . ooeasy shampoo removability ooconditioning rinses MW oosmooth skin application with desirable ooleave-in after-feel conditioning lotions Gafquat 755N- ooforms a sprayable polyelectrolyte oostyling sprays O polymer matrix when used in conjunction with ™ (Optiphen one of the following rheology modifiers preserved) (Ashland 980/940 carbomer, RapiThix A-60)

Hair Care Overview Guide / 5 description/ trade name INCI name structure features and benefits applications use levels form

oogood wet and dry combing Gafquat™ oogood curl retention in leave-on hair ooshampoos Shampoos/ HS-100 polymer styling products ooconditioners conditioners: ooclear, non-tacky films oostyling creams/lotions up to 1 .0% ooenhances hair luster oogels 20% aqueous solids Polyquaternium-28 ooexcellent stability at ph extremes oomousses solution Gafquat HS- ooforms a sprayable polyelectrolyte oopomades, waxes, pastes Styling: 100-0 polymer matrix when used in conjunction oostyling sprays 2 .0–4 .0% (Optiphen with one of the following rheology oopermanent wave preserved) solids n y modifiers (Ashland 980/940 solutions Carbomer, RapiThix A-60)

OCH3 ™ Gantrez A-425 Butyl Ester of PVM/MA 50% solids in CH2 CH CH CH polymer Copolymer ethanol O C C O

HO OCH4H9 x

OCH3

Gantrez ES-225 Ethyl Ester of PVM/MA 50% solids in CH2 CH CH CH polymer Copolymer ethanol O C C O

HO OCH2H3 x

OCH3

CH2 CH CH CH oohigh hold Gantrez ES-335 Isopropyl Ester of PVM/MA 50% solids in O C C O ooexcellent shine ooaerosol hairsprays polymer Copolymer isopropanol HO O oodurability oonon-aerosol hairsprays CH ootack-free H C CH 3 3 x oospritzer gels 0 .5–7 .0% oogood style retention oomousses solids oohumidity resistant OCH3 oostyling creams/lotions oogood propellant compatibility Gantrez ES-425 Butyl Ester of PVM/MA 50% solids in oopomades, waxes, pastes CH2 CH CH CH oopigment dispersant polymer Copolymer ethanol O C C O ooemulsion stabilizer HO OCH4H9 x

OCH3

Gantrez ES-435 Butyl Ester of PVM/MA 50% in CH2 CH CH CH polymer Copolymer isopropanol O C C O

HO OCH4H9 x

OCH3

Gantrez SP-215 Ethyl Ester of PVM/MA 50% solids in CH2 CH CH CH polymer Copolymer ethanol O C C O

HO OCH2H3 x

oosuitable for low-VOC and anhydrous products

OCH3 oohigh hold ooexcellent shine ooaerosol hairsprays Omnirez™ 2000 Ethyl Ester of PVM/MA 50% solids CH 2 CH CH CH oodurability oonon-aerosol hairsprays 0 .5–8 .0% polymer Copolymer ethanol O C C O ootack-free oomousses solids oogood style retention oopomades, waxes, pastes HO OCH2CH3 X oohumidity resistant oogood propellant compatibility oolow solution viscosity

Hair Care Overview Guide / 6 description/ trade name INCI name structure features and benefits applications use levels form

oosoft, flexible films Primaflo™ oohigh strength films oolow- and no-VOC hair styling 2 .0–5 .0% HP22 polymer Hydroxypropylcellulose Solution oonon-tacky films gels, mousses and sprays solids solution

100% powder; 0 .25–6 .0% PVP K-15 8000 avg . MW solids in Daltons

oogels 30% solution; oostrong, stiff hold PVP K-15 oomousses 0 .25–6 .0% 8000 avg . MW oostabilizes emulsions, solution oostyling creams/lotions solids in Daltons dispersions and suspensions oohair colorants oofoam stabilizer oopomades, waxes, pastes ooexcellent compatibility with 100% powder; ooin addition, PVP K-15 acrylate thickeners 0 .25–6 .0% PVP K-30 60,000 avg . and PVP K-30 can be used in ooshine solids MW in Daltons hairsprays

30% solution; PVP K-30 0 .25–6 .0% 60,000 avg . solution solids MW in Daltons PVP 45% solution; PVP K-60 0 .25–6 .0% 400,000 avg . solution x solids MW in Daltons

100% powder; oostrong, stiff hold 0 .25–3 .0% PVP K-90 1,300,000 avg . oostabilizes emulsions, oogels solids MW in Daltons dispersions and suspensions oomousses oofoam stabilizer oostyling creams/lotions 20% solution; ooexcellent compatibility with oohair colorants PVP K-90 0 .25–3 .0% 1,300,000 avg . acrylate thickeners oopomades, waxes, pastes solution solids MW in Daltons ooshine

100% powder; PVP K-120 0 .25–3 .0% 3,000,000 avg . powder solids MW in Daltons

‡ Ratio (VP/VA)

Hair Care Overview Guide / 7 description/ trade name INCI name structure features and benefits applications use levels form

oogels oomousses White powder PVP/VA S-630 oostyling creams/lotions (60/40‡) oohair colorants oopomades, waxes, pastes

50% solution in PVP/VA E-335 ethanol (E) or ooaerosol hairsprays PVP/VA I-335 isopropanol (I), oonon-aerosol hairsprays (30/70‡)

50% solution in PVP/VA E-535 ethanol (E) or oohydroalcoholic styling lotions PVP/VA I-535 isopropanol (I), and hair thickeners (50/50‡) oostrong, stiff hold ooenhanced high humidity curl ooalcohol-free VP/VA Copolymer formulas (W) 0 .5–6 .0% 50% solution in retention oogels solids PVP/VA E-635 aqua (W) or oogood propellant compatibility oomousses PVP/VA W-635 ethanol (E) X Y oostyling creams/lotions (60/40‡) oohair colorants oopomades, waxes, pastes

oo“wet look” gels oowater-based aerosol mousses oo(E) and (I) used in anhydrous 50% solution aerosols PVP/VA E-735 in water (W), oo(W) in alcohol-free formulas PVP/VA I-735 ethanol (E) or oogels PVP/VA W-735 isopropanol (I) oomousses (70/30‡) oostyling creams/lotions oohair colorants oopomades, waxes, pastes

‡ Ratio (VP/VA)

Hair Care Overview Guide / 8 description/ trade name INCI name structure features and benefits applications use levels form Polyquaternium-28

CH3

CH2 CH CH2 CH N O C=O NH • yCI ooleave in conditioners ( oosplit end mending with mechanical CH2)3 oostyling creams and durability (proposed) H C N+ CH lotions Style Fusion™ 10% solid in 3 3 oocuticle smoothing Polyquaternium-28 (and) oorinse off conditioner 10–20% complex 1 water CH3 oopromotes shine PVM/MA Copolymer oocream gels oocontributes to styling: fiber alignment oomousses PVM/MA Copolymer oothermal protection ooserums

OCH3

CH2 CH CH CH O=C C=O OH OH

Polyquaternium - 11

CH3

CH2 CH CH2 C N O C=O O

CH2

CH2 N CH3CH2SO4 CH3 CH3 CH2CH3

Polyquaternium-55 oodurable smoothing with improved wash resistance enhanced through oocreams and lotions heat activation ooleave in and rinse off (proposed) oofrizz control conditioner Polyquaternium-11 (and) ooimproved manageability and fiber Style Fusion™ 10% solid in oocream gels Polyquaternium-55 (and) alignment 10–20% complex 2 water oomousses PVM/MA Copolymer oodelivers enhanced shine ooserums ooconditioned smooth hair feel oosprays (non-aerosol) ooprovides hold and curl retention under high humidity conditions

PVM/MA Copolymer

OCH3

CH2 CH CH CH O=C C=O OH OH

Hair Care Overview Guide / 9 description/ trade name INCI name structure features and benefits applications use levels form Guar Hydroxypropyltrimonium Chloride

oolong lasting high humidity curl retention oomousses oogood wet and dry detangling and combing (proposed) Guar oocombing ooimproved sustainability profile Style Fusion™ Hydroxypropyltrimonium 5% solid in creams ooimproved manageability and frizz reduction 30–60% complex 3 Chloride (and) Acrylates water ooserums and ooprovides natural hold with curl definition Copolymer lotions oovery smooth hair feel Acrylates Copolymer oocream gels ooimproves foam quality in mousses

O O OH R oosuperior, durable hold ooclear, non-tacky films CH3 oolong-lasting curl retention oogels oosubstantive to hair oomousses Styling: ooconditioning and bodying effects oostyling creams/ 0 .25–2 .0% ooshine lotions solids Styleze CC-10 VP/DMAPA Acrylates 10% aqueous oomanageability oopomades, H2C C NH polymer1 Copolymer solution ooclean feel waxes, pastes Shampoos/ H2C CH2 (CH2)3 oothermal protection oostyling sprays Conditioners: X oovolumizing effects in shampoos (non-aerosol) 0 .5–1 .0% N ooforms a sprayable polyelectrolyte matrix ooshampoos solids when used in conjunction with one of the ooconditioners H3C CH3 Y following rheology modifiers (Ashland 980/940 Carbomer, RapiThix A-60)

oofirm hold Styleze™ W-10 10% aqueous oolongevity of style oogels polymer1 solution oohigh humidity resistance oomousses Gels, oohigh flexibility oostyling creams/ Mousses, ooconditioning lotions Lotions: oolow-tack ooleave-in 0 .25–2 .0% Styleze W-17 17% aqueous oovolume conditioners solids Polyquaternium-55 polymer1 solution oocolor protection oopomades, oothermal protection waxes, pastes Shampoos/ ooforms a sprayable polyelectrolyte matrix oostyling sprays Conditioners: when used in conjunction with one of the (non-aerosol) 0 .25–1 .0% Styleze W-20 20% aqueous following rheology modifiers (Ashland ooshampoos solids polymer1 solution 980/940 Carbomer, RapiThix A-60, ooconditioners Stabileze SM)

oofrizz reduction ooenhances thermal styling, straight or curly

CH CH CH3 3 3 oothermal protection OCH3 CH2 CCHC CH CH2 HC CH CH2 C HC CH

CH2 CH CH CH oohumidity resistance oostyling creams/ CH3 OCC C O CH3 OCCO CH3 O CO Water (and) PVM/ O=C C=O N N OR OH ooshine lotions H3C CH (CH2)3 z OH OH Styleze XT3 MA Copolymer (and) xy 4 .0% solids 1 CH2 R=-H2-CH2CH3 oosmooth, touchable hair oogels polymer Polyimide-1 (and) O H3C CH3 (13 .5% as is) oolively, flowable texture oomousses Caprylyl Glycol H3C CH CH 2 m oolasting style hold oolotions O

(CH ) oosmooth combing 2 2 n OCH3 ooenhances hair’s natural texture ooimproved hair alignment/manageability

Hair Care Overview Guide / 10 conditioning polymers

description/ trade name INCI name structure features and benefits applications use levels form

AquaCat™ 518 oolight conditioning cationic solution oovolumizing Guar Hydroxypropyl- Clear oovolumizing shampoos 0 .2–0 .4% trimonium Chloride solution oodaily shampoos

ooparaben-free AquaCat PF 618 oolight conditioning cationic solution oovolumizing

ChromoHance™ ooshampoos Clear 113 conditioning ooprovide consumer perceivable color protection ooconditioners Polyquaternium 113 Solution , 1 .0–5 .0% polymer oocompatible with most surfactant systems ooleave on treatments 20% active

oosuperior conditioning oogood deposition of silicon emulsions and other HO + O N CI oils OH oooutstanding clarity in clear shampoos and body HO O ooshampoos HO + OH O OH CI N washes . ClearHance™ C Cassia HO ooconditioners OH O HO White O OH oonaturally derived O O OH conditioning Hydroxypropyl O HO O oobody washes 0 .1–0 .5% powder HO O O HO O oocompatible in all surfactant systems polymer trimonium chloride O HO O O ooshower gels O HO O HO OH oolow in use cost HO O n ooliquid hand soaps HO ooprovides a luxurious creamy lather and texture OH and slip . ooeasy to process, no pH adjustment required oolow odor and color

oocompatible with a wide range of anionic, nonionic and cationic surfactants ooshampoos CH CH oostable over a wide pH range (pH 2–12) ooconditioners ooprovides excellent conditioning, wet and dry formulated especially Conditioneze™ 22 Clear C O- combability for damaged and Polyquaternium-22 1 .0–3 .0 % cationic solution solution O-Na+ ooleaves hair feeling soft and silky and contributes treated hair m to luster . oocolorant products N+ CI- ooleaves a smooth and silky feel in skin care ooethnic hair care H C CH products products n oopreserved with methyl and propyl parabens

ooprovides excellent conditioning and emulsion stabilization in hair and skin products Polyquaternium-37 ooeasy to incorporate into formulations with no Conditioneze 37 and propylene ooconditioners Opaque requirements for heating or neutralization PC (E) cationic Glycol Dicaprylate/ oohair masks 2 .0–4 .0 % liquid oocompatible with nonionic and cationic solution Dicaprate and oorheology surfactants PPG-1 Trideceth-6 ooefficiently build viscosity at low usage levels even at low pH levels

Hair Care Overview Guide / 11 description/ trade name INCI name structure features and benefits applications use levels form

Conditioneze™ CH NT-20 cationic 3 solution CH CH CH2 C ooshampoos 2 Shampoos/ ooexcellent wet and dry combing ooconditioners N O C=O Conditioners: oobuilds creamy, rich lather oostyling creams/lotions 20% aqueous NH 0 .25–1 .0% solids Conditioneze Polyquaternium-28 ooimparts body and manageability oogels solution NT-20-0 (CH3)3 without build-up oomousses Styling: cationic + oocold processable oopomades, waxes, pastes CH3 N CH3 2 .0–4 .0% solids solution CI- oopermanent wave solutions ™ CH (Optiphen X 3 Y preserved)

HO Hydroxypropyl OH O Clear ooprovides inner strengthening of hair fiber FiberHance™ Gluconamide (and) CH2 Solution, 50% CH2 oointernal bond creation ooshampoos 1% solids BM solution Hydroxypropyl active HO N CH2 O ooimproves manageability Ammonium Gluconate H OH OH

oocombines benefits of film-forming polymers and dimethicone while ooshampoos H C CH Styling: 1 .0–2 .0% 3 3 minimizing drawbacks associated with ooconditioners solids Gafquat™ HSi silicones such as greasy feel and build- ooconditioning treatments Polyquaternium-28 20% aqueous cationic H3C Si OSi CH3 up oogels (and) Dimethicone solution Shampoos/ solution ooconditioning oomousses Conditioners: oocompatible with anionic surfactants oopomades, waxes, pastes H3C CH3 n 0 .2–1 .0% solids oostabilizes foam oogood storage stability

n ooleave-on and rinse-off N-DurHance™ oohigh conditioning durability conditioners HN O A-1000 Polyacrylamidopropyl- oono build-up oohair masks Clear solution 0 .1–1 .0 % solids conditioning trimonium Chloride oopreservative free ooconditioning sprays polymer oocompatible with cationics and nonionics ooshampoos + CI- N

oohelps to revert hydrophobicity to original virgin state ooshampoos N-DurHance Polyacrylamidoprop- Clear oodurable long lasting conditioning oorinse-off and leave-on AA-2000 yltrimonium chloride/ solution, 20% oono build up conditioners 0 .1–1 .0 % solids conditioning acrylamide active oocompatible with cationic, non-ionic and oohair masks polymer some anionic surfactants ooconditioning sprays

ooethnic hair products Acrylamidopropyl oohighly damaged/ N-Hance Trimonium Chloride/ ooexcellent wet/dry combability in silicone bleached/treated hair 0 .1–0 .2% SP-100 polymer Acrylamide Copolymer CH2 - CH CH2 = CH and non-silicone formulations ooanti-dandruff shampoos oooptical clarity NH C = O oosilicone deposition Powder oofast detangling of hair Guar Hydroxypropyl- (CH2)3 NH2 ooleaves wet and dry hair noticeably silkier

N-Hance 4572 trimonium Chloride + H3C - N - CH3 oohigh deposition of actives (silicone, anti- n ooshampoos conditioning and Acrylamidopropyl Cl- dandruff, natural oils, etc ). 0 .15–0 .25% CH3 ooconditioners polymer Trimonium Chloride/ m Acrylamide Copolymer Hair Care Overview Guide / 12 description/ trade name INCI name structure features and benefits applications use levels form

ooshampoos/2-in-1 shampoos for ooethnic hair N-Hance™ BF17 oohighly damaged/ 0 .2–0 .4% cationic guar bleached/treated hair oohigh conditioning, wet and dry oosilicone deposition combing ooanti-dandruff shampoos ooactive deposition aid ooefficient silicone deposition oosofter hair feel oodeep conditioning oolather richness ooethnic hair products oohighly damaged/ N-Hance 3215 bleached/treated hair 0 .2–0 .4% cationic guar ooanti-dandruff shampoos oohigh active deposition oosilicone deposition

ooshampoos/2-in-1 shampoos for ooethnic hair N-Hance 3196 oohighly damaged/ 0 .2–0 .4% cationic guar bleached/treated hair Guar Hydroxypropyl- Powder oosilicone deposition trimonium Chloride ooanti-dandruff shampoos

oomedium conditioning, wet and dry combing oodamaged/bleached/ oomedium deposition aid treated hair oovirgin hair N-Hance™ BF13 ooefficient silicone deposition oosilicone deposition 0 .1–0 .4% cationic guar oosofter hair feel oolather richness ooactive deposition oodaily shampoos ooanti-dandruff shampoos

oodamaged/bleached/ treated hair N-Hance CG13 oovirgin hair 0 .2–0 .4% cationic guar oosilicone deposition ooactive deposition oodaily shampoos

oolight to medium conditioning, wet and dry combing ooclear systems N-Hance oomedium deposition aid oomildly damaged virgin hair CCG45 0 .2–0 .4% ooefficient silicone deposition oovolumizing shampoos cationic guar oosofter hair feel oodaily shampoos oolather richness

Hair Care Overview Guide / 13 description/ use trade name INCI name structure features and benefits applications form levels N-Hance™ oolow viscosity 3000/3299 oolow conditioning cationic guar

N-Hance C261 oolow viscosity oolight conditioning 0 .2–0 .4% Guar Hydroxypropyl- cationic guar Powder oolow conditioning shampoos trimonium Chloride ooself hydrating oovolumizing shampoos

N-Hance oolow viscosity 0 .2–0 .4% C261N cationic oolow conditioning guar rheology modifiers description/ use trade name INCI name structure features and benefits applications form levels

ooshampoos oorheology modifier Ashland™ 980/940/ oostyling Carbomer Powder oostabilization 0 .2–0 .5% 981/941 Carbomer products

Benecel™ HPMC oostabilizes complex surfactant mixtures ooincreases lather density ooshampoos Hydroxypropyl ooincreases lather volume Powder oostyling 0 .5–2 .0% Methylcellulose ooincreases lather stability Benecel E10 HPMC products oothickens soap-based shampoos ooBenecel K200M HPMC thickens hydroalcoholic systems Benecel K200M HPMC

Klucel™ hydroxy- ooalcohol-soluble thickener oostyling Hydroxypropylcellulose Powder 0 .2–1 .0% propylcellulose oofilm-former products

Natrosol™ ooconditioners hydroxyethylcellulose/ ooviscosity builder Hydroxyethylcellulose Powder oostyling 0 .2–1 .0% Natrosol 250 ME/ oostabilization products HR/HHR

Hair Care Overview Guide / 14 description/ use trade name INCI name structure features and benefits applications form levels

Natrosol™ Plus 330 CS cetyl modified hydroxyethylcellulose

ooshampoos ooprovides stability for complex ooconditioners Cetyl anionic, cationic or nonionic oostyling products Powder 0 .5–1 .5% Hydroxyethylcellulose surfactant systems ooNatrosol Plus 330 CS oothickens cationic emulsions can be used in APG- ™ PolySurf 67 based systems cetyl modified hydroxyethylcellulose

ooeasy-to-use emollient-based dispersion ooemulsifier-free products H H ooprovides soft, smooth feel oohair shine lotions Sodium Polyacrylate White milky CH2 CH oocan be post-added to adjust ooanti-frizz products Up to RapiThix™ A-60 (and) Hydrogenated dispersion CH3(CH2)12(OCH2CH2)nOH viscosity after emulsion forms and oostyling creams/lotions 3 .6% polymer Polydecene (and) (57–59% CO2Na n trideceth-6 cools ooconditioning creams solids Trideceth-6 solids) sodium polyacrylate (and) ooproduces instant crème gels at oopomades, waxes, room temperature pastes hydrogenated polydecene (and) oohigh shear not required oofully active white powder offering ooemulsifier-free products greater formulation flexibility oohair shine lotions CH CH ooprovides soft, smooth feel ooanti-frizz products RapiThix A-100 2 Sodium Polyacrylate White powder oono pre-set oil phase oostyling creams/lotions 0 .2–2 .5% polymer CO2Na n oomakes oil-free systems possible ooconditioning creams oohigh-solids content for higher oopomades, waxes, sodium polyacrylate efficiency pastes

ooshampoos ooself-wetting rheology modifier with oo2 in 1 shampoos improved electrolyte tolerance oobody washes Ultrathix™ 20 polymer ooimproved suspension in surfactant 0 .2–1 .5% oostyling creams 1 based system R oogels Acrylates/C10-30 Alkyl oohydroalcoholic systems Powder oolotions Acrylate Crosspolymer (CH2 CH)x (CH2 C)y C O C O ooself-wetting rheology modifier with oostyling creams improved electrolyte tolerance oogels Ultrathix 21 polymer OH OR2 ooexcellent sensorial properties oolotions 0 .2–1 .5% ooemulsion stabilization ooshampoos oohydroalcoholic systems oohand sanitizers

Hair Care Overview Guide / 15 conditioners

descrip- trade name INCI name structure features and benefits applications use levels tion/ form

oomild cationic with pronounced HO substantivity to hair ooshampoos Ceraphyl™ 60 60% OH OH O CH3 ooprovides detangling, anti-static ooconditioners cationic Quaternium-22 aqueous H2C CH CH CH CH C NH (CH2)3 N CH2 CH2OH Cl Up to 4 .8% solids and conditioning oogels solution solution OH OH CH3 oobinds moisture in hair care oomousses applications

oomild cationic with pronounced Ceraphyl 65 O CH3 substantivity to hair Up to 5 .0% (rinse- Quaternium-26 (and) ooshampoos cationic 55% solution ooprovides detangling, anti-static off application Propylene Glycol R C NH CH2 CH2 CH2 N CH2 CH OH Cl ooconditioners solution and conditioning only) CH3 oocationic emulsification

R= Mink fatty acids

oomild cationic ooshampoos 1 .0% solids oopronounced substantivity to skin ooconditioners for thermal and hair oomousses Ceraphyl 70 O CH3 O protection Quaternium-70 (and) ooprovides detangling, anti-static oocream gels cationic 54% solution Cl Propylene Glycol C17H35 C NH (CH2)3 N CH2 C O C14H29 and conditioning oopomades, solution Up to 0 .7% solids CH oocationic emulsification waxes, pastes 3 for rinse-off oothermal protection from curling oopermanent applications irons & blow dryers wave solutions

Hair Care Overview Guide / 16 description/ trade name INCI name structure features and benefits applications use levels form oocomposed of vegetal-based ooshampoos amphiphilic compounds ooconditioners oolamellar gel structurizing ingredient 1 .67–6 .67% by oostyling creams/lotions + that enhances formulation texture and weight when O CH3 oomousses Cetearyl Alcohol CI stability used for ootreatment applications (and) Behenyl RC NH (CH ) N CH ooprovides moisturization and conditioning 2 3 3 targeting damaged Alcohol (and) White to conditioning to hair ProLipid™ 161 and chemically 1 Hydroxyethyl cream ooease of wet and dry combing 4 .0–6 .0% by lamellar gel CH2 CH2 OH treated hair Cetearamidopropyl colored flakes oomakes hair feels soft and smooth weight when oohair colorants dimonium Chloride oobinder used as a and oopomades, waxes, CH3 (CH2)20 CH2OH CH3 (CH2)16 CH2OH CH3 (CH2)14 CH2OH oothickener structuring pastes ooopacifying agent agent (Behenyl Alcohol) (Cetearyl Alcohol) oopermanent wave ooanti-static solutions oosubstantive over a broad pH range oohair relaxers

Zenix™ 4617 oosilicone-like performance without ooshampoos phosphate ester Oleth-5 Phosphate Liquid P silicone when combined with cationic oo2-in-1 shampoos 2 .0–4 .0% surfactant R x guar

vincience™ biotHAIRapy™ biofunctionals

trade name INCI name description benefits

Capauxein G2 is associated with an increase in key biomarkers: ooKi67 and β1-integrin, markers of proliferation and communication respectively (in vitro, ex vivo) Water, Glycerin, Hydrolyzed Inspired by the “Hair Fullness ooversican and Noggin, highly expressed during the anagen phase in the dermal papilla (3D-spheres) Capauxein™ G2 Corn Protein, Adenosine, System™” associated with biofunctional Magnesium Ascorbyl Capauxein G2 clinical results on 39 panelists hair density Phosphate, Carnitine ooa healthier scalp with less visible oiliness and more hydration (in vivo) ooa visible maintenance of the anagen phase (in vivo) ooa visible improvement of hair density and fullness (in vivo)

ooassociated in vitro, ex vivo with an increase of tyrosinase (tyrosinase is involved in melanin production) ooassociated with the in vitro increase in TRP-1 (TRP-1 is known to participate in melanin synthesis) A flax seed extract inspired ooassociated with in vitro increase in Pmel 17 (Pmel 17 is associated with favorable conditions for Water (aqua) (and) Glycerin Chromafend™ by the “Hair Melanin melanin synthesis) (and) Hydrolyzed Linseed biofunctional System™” to help hair ooassociated with an in vitro increase of MITF (MITF is known to regulate melanin synthesis) Extract preserve its original color ooassociated with an in vitro increase of c-kit (c-kit is associated with melanin process) ooassociated with an in vitro increase of PAR-2 (PAR-2 helps transfer melanin into keratinocytes) ooex vivo, Chromafend is associated with an increase of the melanin in the hair cortex

Hair Care Overview Guide / 17 trade name INCI name description benefits ooconsumer-perceivable benefit for stronger, thicker, healthier hair feel (in vivo) A yeast extract inspired by ooassociated with ex vivo increase in key protein markers, keratin 14, keratin 17, keratin 71, trichohyalin, all of Water (aqua) (and) Glycerin Dynagen™ the “Hair Keratin System™” which are associated with minimization of hair fall (and) Hydrolyzed Yeast biofunctional for stronger and healthier ooassociated with ex vivo increase in collagen i Protein looking hair ooassociated with ex vivo increase in collagen IV and CD34 (both of these compounds are associated with healthy appearance of the hair) ooassociated ex vivo with an increase of catalase enzyme expression (a decrease in catalase activity is associated with environmental damage and hair aging) A pea extract inspired by ooassociated ex vivo with a maintenance of p63 expression in stress conditions (p63 is associated with cell Water (aqua) (and) Glycerin Procataline™ the “Hair Detox System™” for regeneration and is shown to be related to hair growth) (and) Pisum Sativum (pea) biofunctional healthier, younger looking ooassociated with a decrease of caspase-3 expression in stress conditions (caspases play a critical role in Extract hair apoptosis) (ex vivo)

ooex vivo, Procataline is associated with reduced signs of aging induced by H2O2 stress, such as maintenance of the melanin in the hair cortex

ooassociated with an increase in stem cells markers, key to the maintenance of hair growth capital (keratin A rice extract inspired by the 15, 6-Integrin, -Catenin and p63) (ex vivo) Protectagen™ Water (aqua) (and) Glycerin “Hair Stemness System™” to α β oomay help preserve hair follicle against harmful UV damage, evidenced by the lower expression of p53 biofunctional (and) Hydrolyzed Rice Protein mitigate stress and preserve markers (ex vivo) hair growth capital ooassociated ex vivo with an improved appearance of hair length

Note: In the U .S . hair growth and hair loss prevention claims fall under an OTC drug monograph 21CFR Part 310 . Use of these claims requires a New Drug Application . Similar restrictions may exist in other parts of the world .

hair care product categories trade name INCI name hair aging at hair hair uv oxidative hair color the roots strength nourishment stress stress

Water (aqua) (and) Glycerin (and) Capauxein™ biofunctional Hydrolyzed Corn Protein l

Water (aqua) (and) Glycerin (and) Chromafend™ biofunctional Hydrolyzed Linseed Extract l l

Water (aqua) (and) Glycerin (and) Dynagen™ biofunctional Hydrolyzed Yeast Protein l l l

Water (aqua) (and) Glycerin (and) Procataline™ biofunctional Pisum Sativum (pea) Extract l l l

Water (aqua) (and) Glycerin (and) Protectagen™ biofunctional Hydrolyzed Rice Protein l l

Hair Care Overview Guide / 18 UV protectants

description/ trade name INCI name structure features and benefits applications use levels form

Escalol™ HP DimethylPABAmidopr-opyl UV filter1 Laurdimonium ooprotects hair from UV light oogels Tosylate + - oosubstantive oomousses 100% active O O ooconditions hair giving it body and oostyling sprays powder CH3 CH3 O S O N C NH (CH2)3 N manageability ooserums 0 .1–0 .5%

CH3 CH3 ooprovides detangling and anti-static oohair treatment solids Creamy waxy C H 12 25 CH3 properties to hair oopomades, waxes, DimethylPABAmidopr-opyl solid Escalol HP 610 UV Laurdimonium ooeasy to handle pastes filter1 Tosylate (and) Water (and) oobroad raw material compatibility ooconditioners Propylene Glycol Stearate preservatives

description/ trade name INCI name structure features and benefits applications use levels form ooshampoos Germaben™ II OH O oobroad-spectrum activity against gram- ooconditioners Propylene Glycol (and) H H preservative positive and gram-negative bacteria, oomousses Diazolidinyl Urea (and) HO N N O OR 0 .5–1 .0% Clear liquid yeast and mold oocreams Methylparaben (and) O N N OH R=CH3 HO ooeffective over broad pH range: oopomades, waxes, Germaben II-E Propylparaben CH2-CH2-CH3 OH preservative O Paraben(s) 3 .0 – 7 .5 pastes

X X X O oovery effective against gram-positive HN N X White, C ™ X and gram-negative bacteria ooshampoos Germall 115 free-flowing O Imidazolidinyl Urea O N CH2 HN N ooacts synergistically with other ooconditioners 0 .2–0 .6% preservative hygroscopic N C O X preservatives powder X O N N ooeffective over broad pH range: 3–9 X O

OH H H oobroad-spectrum activity against gram- White, HO N N O positive and gram-negative bacteria Germall II free-flowing ooshampoos Diazolidinyl Urea oosynergistic with other preservatives 0 .1–0 .3% preservative hygroscopic ooconditioners O ooeffective over broad pH range: 3–9 powder N N OH

OH O

OH H H HO N N O ooshampoos White, Diazolidinyl Urea (and) O N N OH oobroad-spectrum antimicrobial activity ooconditioners Germall™ Plus free-flowing 0 .05–0 .2% Iodopropynyl ooeffective over broad pH range: oogels preservative1 hygroscopic OH O Butylcarbamate 3–8 oostyling creams/ powder O lotions

I C CH 2O NH

† For country-specific details, please contact your account manager Hair Care Overview Guide / 19 description/ trade name INCI name structure features and benefits applications use levels form

OH H H HO N N O ooshampoos Propylene Glycol (and) O N N OH oobroad-spectrum antimicrobial activity ooconditioners Liquid Germall™ Diazolidinyl Urea (and) 0 .1–0 .5% Clear liquid ooeffective over broad pH range: oogels Plus preservative1 Iodopropynyl OH O 3–8 oostyling creams/ Butylcarbamate O lotions

I C CH 2O NH

ooshampoos ooeffective fungicide ooconditioners O Butylene Glycol ooworks over wide pH range: 4–9 oostyling creams/ LiquaGard™ (and) Iodopropynyl Liquid HOCH2CH2CHCH2 I C CCH2O C NH(CH2)3CH3 oocompatible with broad range of raw lotions 0 .1–0 .2%‡ preservative Butylcarbamate materials including surfactants and oohair colorants OH proteins oogels

OH O HO OH LiquaPar™ ME ooprovides similar efficiency to traditional Phenoxyethanol (and) preservative Colorless to paraben combinations oostyling creams/ Methylparaben (and) (Available in EU, light brown O O O ooeffective over broad pH range: lotions 0 .5–1 .0% Ethylparaben (and) CH3 LA, AP) solution 3 .0 –7 .5 ooanhydrous systems Caprylyl Glycol O ooglobal use† HO

O OH

LiquaPar MEP oobroad-spectrum activity against Phenoxyethanol (and) preservative Clear, bacteria, yeast and mold ooshampoos Methylparaben (and) (sold as Rokonsal™ yellowish O ooeffective over broad pH range: ooconditioners 0 .3–1 .0% Ethylparaben (and) MEP preservative solution 3 .0 –7 .5 ooanhydrous systems Propylparaben in EU) OR ooglobal use†

R=CH3 CH2-CH3 HO CH2-CH2-CH3

† For country-specific details, please contact your account manager

Hair Care Overview Guide / 20 description/ trade name INCI name structure features and benefits applications use levels form

Phenoxyethanol (and) O oobroad-spectrum activity against ™ Methylparaben (and) O LiquaPar PN OH OR bacteria, yeast and mold oostyling creams/lotions Ethylparaben (and) Clear liquid R=CH3 0 .5–1 .0% preservative CH2-CH2-CH3 ooeffective over broad pH range: 3 .0–7 .5 ooanhydrous systems Propylparaben (and) CH2CH3 ooglobal use† Butylparaben HO (CH2)3CH3

ooshampoos ooconditioners oobroad-spectrum activity against O oogels Optiphen™ 200 Phenoxyethanol (and) Clear to pale OH bacteria, yeast and mold 0 .75–1 .3% OH oomousses preservative Caprylyl Glycol straw liquid ooeffective over broad pH range: 4 .0–8 .0 OH oocreams ooglobal use† oopomades, waxes, pastes

ooshampoos Clear to pale oobroad-spectrum activity against ooconditioners straw liquid bacteria, yeast and mold – additional O oogels Optiphen Phenoxyethanol (and) OH OH fungicidal protection may be needed oomousses 0 .75–1 .5% preservative1 Caprylyl Glycol [EU: Colorless in difficult formulations OH oostyling creams/lotions to light yellow ooeffective over broad pH range: 4–8 oopomades, waxes, solution] ooglobal use† pastes

oomicrobiostatic spectrum of activity, in some formulations additional booster ooshampoos Propylene Carbonate is needed ooconditioners ooeffective up to pH 6 .0 oogels Optiphen DP (and) Benzoic Acid (and) Liquid ooglobal use† oomousses 0 .3–2 .0% preservative Dehydroacetic Acid oocost efficient preservative based on oostyling creams/lotions (and) Propanediol uncontroversial ingredients oopomades, waxes, oooptimized delivery system without pastes alcoholic antimicrobials

ooantifungal boosting activity at low levels; full antimicrobial spectra at ooshampoos high levels ooconditioners Propylene Carbonate ooeffective up to pH 6 .4 . oogels Optiphen DLP (and) Dehydroacetic Liquid ooglobal use† oomousses 0 .3–2 .0% preservative Acid oocost efficient preservative based on oostyling creams/lotions nature identical active ingredient oopomades, waxes, oooptimized delivery system without pastes alcoholic antimicrobials

† For country-specific details, please contact your account manager

Hair Care Overview Guide / 21 description/ trade name INCI name structure features and benefits applications use levels form

Clear to pale O oobroad spectrum activity against bacteria, oomousses straw liquid OH OH yeast and mold Phenoxyethanol (and) ooshampoos Optiphen™ Plus OH ooideal for slightly acidic personal care Caprylyl Glycol ooconditioners 0 .75–1 .5% preservative1 [EU: Colorless products (and) Sorbic Acid CO2H oopomades, waxes, to light yellow ooeffective pH range up to 6 .0 pastes solution] ooglobal use†

H3C

oomicrobiostatic spectrum of activity Optiphen BD O O O against bacteria, mold and yeast Benzyl Alcohol (and) Colorless to oostyling creams/lotions preservative ooeffective up to pH 6 .4 Benzoic Acid (and) light yellow OH ooshampoos 0 .3–1 .0% (Available in EU, OH ooglobal use† Dehydroacetic Acid solution ooconditioners LA, AP) oonature-identical combination O O ooecocert-compliant

ooshampoos Optiphen BSB-N ooeffective against gram-positive and COOH ooconditioners preservative CO H gram-negative bacteria, yeast and mold Benzyl Alcohol (and) 2 oogels (sold as Rokonsal™ Colorless light ooeffective up to pH 5 .4 0 .3–1 .0% Glycerin (and) Benzoic oomousses 658-N preservative brown liquid OH ooglobal use† Acid (and) Sorbic Acid oostyling creams/lotions in EU) oonature-identical combination H3C oopomades, waxes, ooecocert-compliant pastes

ooshampoos O CO H COOH OH 2 ooeffective against gram-positive and gram- ooconditioners Phenoxyethanol (and) Optiphen BSP (Sold negative bacteria, yeast and mold oogels Propylene Glycol (and) Colorless light as Rokonsal BSP H3C ooeffective up to pH 5 .4 oomousses 0 .3–1 .0% Benzoic Acid (and) brown liquid preservative in EU) ooglobal use† oostyling creams/lotions Sorbic Acid OH oonature-identical combination oopomades, waxes, OH pastes

ooshampoos ooeffective against gram-positive and gram- Benzyl Alcohol (and) - + ooconditioners Optiphen BSB-W O O Na negative bacteria, yeast and mold Water (aqua) (and) O oogels preservative Colorless light OH ooeffective up to pH 5 .4 Sodium + oomousses 0 .3–1 .0% (Available in EU, brown liquid O K ooglobal use† Benzoate (and) oostyling creams/lotions LA, AP) oonature-identical combination Potassium Sorbate oopomades, waxes, ooecocert-compliant pastes ooshampoos ooconditioners oomainly effective against gram-positive Colorless to O oogels Optiphen MIT Methylisothiazolinone and gram-negative bacteria light yellow oomousses 0 .05–0 .1% preservative and Water (aqua) ooeffective between pH 2–10 solution oostyling creams/lotions S N ooglobal use† oopomades, waxes, pastes † For country-specific details, please contact your account manager Hair Care Overview Guide / 22 description/ trade name INCI name structure features and benefits applications use levels form

ooshampoos Methylisothiazolinone ooconditioners OH oobroad-spectrum activity against (and) Phenethyl oogels Optiphen™ MIT Colorless to light O bacteria, yeast and mold 0 .05–0 .2% Alcohol (and) PPG-2- O oomousses 2 O Plus preservative yellow solution S N OH ooeffective between pH 2–10 Methyl Ether and water oostyling creams/lotions ooglobal use† (Aqua) oopomades, waxes, pastes

ooshampoos ooconditioners Methylisothiazolinone oobroad-spectrum activity against OH oogels Optiphen MIT (and) Phenylpropanol Colorless to light O bacteria, yeast and mold oomousses 0 .05–0 .3% Ultra preservative2 (and) Propylene Glycol yellow solution ooeffective between pH 2–10 S N oostyling creams/lotions (and) Water (aqua) ooglobal use† CH3CHCH2OH oopomades, waxes,

OH pastes

Optiphen ND O ooshampoos COOH O oomicrobiostatic spectrum of activity preservative Phenoxyethanol (and) O ooconditioners Light yellow to OH against bacteria, mold and yeast (Sold as Rokonsal Benzoic Acid (and) C CH3 oocreams 0 .3–1 .0% yellow solution ooeffective up to pH 6 .4 ND preservative Dehydroacetic Acid oopomades, waxes, ooglobal use† in EU) H3C O O pastes

oobroad-spectrum activity against ™ Benzyl Alcohol (and) Rokonsal LJ-1 -O O I bacteria, with enhanced ooshampoos 2-Bromo-2-Nitropropane- + N OH preservative performance against fungi and ooconditioners † 1,3-Diol (and) Iodopropynyl Colorless to light OH 0 .1–0 .4% (Available in EU, Br O yeast oostyling creams/lotions Butylcarbamate (and) brown solution LA, AP) oofast-acting oopomades, waxes, Deceth-8 (and) PPG-2 O N HO H ooeffective up to pH 7 .0 max . pastes Methyl Ether ooglobal use†

-O O + N OH O Rokonsal SE-2 2-Bromo-2-Nitropropane- oobroad-spectrum activity against O ooshampoos preservative 1,3-Diol (and) Br bacteria, fungi and yeast Colorless to ooconditioners (Available in EU, Ethylparaben (and) HO oofast-acting 0 .1–0 .3% yellow solution oostyling creams/lotions LA, AP) Cetrimonium Bromide HO ooeffective up to pH 7 .0 max . + † (and) PPG-2 Methyl Ether - ooglobal use N Br

Rokonsal KS-4 Benzyl Alcohol (and) Me oobroad spectrum activity against Cl S preservative Methylchloroisothiazolinone OH bacteria, yeast and mold Colorless to N N ooshampoos (Available in EU, (and) O oofast-acting 0 .05–0 .12% yellow solution S ooconditioners LA, AP) Methylisothiazolinone O ooeffective up to pH 8 .0 max . (and) Propylene Glycol ooglobal use†

† For country-specific details, please contact your account manager Hair Care Overview Guide / 23 description/ trade name INCI name structure features and benefits applications use levels form

O H C O- Na+ oobroad-spectrum preservation ooshampoos oolong history of use for efficacy ooconditioners Suttocide™ A Sodium Clear to pale H C oofast-acting oogels 0 .5–1 .0% preservative Hydroxymethylglycinate yellow solution ooeffective pH: 3 .5–12 oostyling creams/ HN OH ooglobal use† lotions C H H aromatics with antimicrobial properties

trade name INCI name description/ form features and benefits applications use levels

Phenethyl Alcohol (and) Caprylyl oomild rose-like aroma, containing naturally derived and ooshampoos nature identical ingredients ooconditioners Conarom™ P-2 Glycol (and) Propanediol (and) Nature-identical fragrance ooaromatic ingredient that provides broad-spectrum oogels aromatic Polyglyceryl-4 Laurate/Sebacate additive with naturally 0 .3–2 .0% protection oomousses (and) Polyglyceryl-6 Caprylate/ derived emulsifier system oocomplements aroma of final product oostyling creams/lotions Caprate (and) Aqua (Water) ooeffective pH range 4–8 oopomades, waxes, pastes

opacifiers/pearlizers

description/ trade name INCI name structure features and benefits applications use levels form

ooconditioners ooopacifier Antara™ 430 CH2 CH CH2 CH ooacid rinses ooforms strong, light-stable films with polymer Fluid, milky white oopermanent wave N high water resistance Up to 1 .0% (Sold as Polectron™ Styrene/VP Copolymer emulsion; 40% solutions O oohigh acid tolerance solids in the USA) solids oogels oodye acceptor in hair color oohair colorants preparations x y oocream developers

CH3(CH2)16C OCH2CH2OH Cerasynt™ IP Glycol Stearate (and) White to cream ooshampoos Up to 2 .0% ooimparts pearlescence and opacity stearate ester Stearamide AMP colored flakes O CH3 oostyling creams/lotions solids

CH3(CH2)16C NHCCH2OH

CH3

O OH Cerasynt PA White to cream ooshampoos Up to 2 .0% Propylene Glycol Stearate ooimparts pearlescence and opacity stearate ester colored flakes oostyling creams/lotions solids C17H35 C O CH2 CH CH3

Hair Care Overview Guide / 24 emulsifiers

description/ trade name INCI name structure features and benefits applications use levels form

O OH C H C O CH CH CH OH 17 35 2 2 ooNonionic primary emulsifier ooHair straighteners Cerasynt™ 945 Glyceryl Stearate (and) Flake ooHigh pH tolerance ooStyling creams/lotions 1 .0–3 .0% stearate ester Laureth-23 CH3 CH CHCONCH2 CH3 ooForms opaque gels with mineral oil ooConditioners CH3

O OH Cerasynt SD ooNonionic auxiliary emulsifier ooStyling creams/lotions Glyceryl Stearate Flake 0 .25–3 .0% stearate ester ooEmulsion stabilizer ooConditioners C17H35 C O CH2 CH CH2 OH

emollients

trade name INCI name description/ form structure features and benefits use level shampoos products shine conditioners styling hairsprays pomades, pastes waxes, esters based on alpha hydroxy acids

O ooplasticizing and de-tackifying agent Ceraphyl™ 31 Lauryl Lactate Liquid oohighly effective emolliency with lubricity 0 .3–5 .0% l l l ester CH3CHC OCH2(CH2)10CH3 ooimproves product slip upon application OH O ooeffective de-tackifying agent oospreads easily when applied Ceraphyl 41 C12-15 Alkyl CH CHC OR Liquid 3 oodry initial feel with non-oily after-feel 0 .3–5 .0% ester Lactate l ooprovides viscosity building and lather OH creaminess to shampoos R = C12-15 Mixed Alcohols

O Ceraphyl 50 Myristyl Soft ooimparts lubricity 0 .3–5 .0% l l l ester Lactate solid CH3CHC OCH2(CH2)12CH3 OH

Hair Care Overview Guide / 25

description/ form use level shampoos products shine conditioners styling hairsprays pomades, trade name INCI name structure features and benefits pastes waxes, light, dry feeling esters

ooexcellent spreadability with dry initial feel Ceraphyl™ 140A Isodecyl H3C O Liquid oodrier feel than Ceraphyl 140 due to branching 0 .3–5 .0% ester Oleate l C8H17 C O C C7H17 CH CH C8H17 oovery little residual after-feel ooeffective plasticizer and de-tackifier CH3 O O CH3 ooreduces greasiness of high-oil products Ceraphyl 230 Diisopropyl oospreads rapidly Liquid 0 .3–5 .0% l l l l ester Adipate CH O C (CH2)4 C O CH ooimparts dry initial feel with little to no residual after-feel CH3 CH3 oocoupling agent for hydroalcoholic preparations general purpose esters

O oonon-occlusive oonon-oily after-feel Ceraphyl 368M Ethylhexyl Liquid CH (CH ) CH CH O C (CH ) CH oosuitable mineral oil replacement for beach 0 .3–5 .0% ester Palmitate 3 2 3 2 2 14 3 l protection formulations CH2CH3 oono impact on absorbance curves of uv actives

O Ceraphyl 494 Isocetyl ooall-purpose lubricant which imparts dry, Liquid CH (CH ) C O CH CH C H 0 .3–5 .0% ester Stearate 3 2 16 2 8 17 emollient feel l l l l

C6H13 esters that impart body

Myristyl O ooenhances spreadability and reduces drag upon Ceraphyl 424 Waxy Myristate (and) product application 0 .3–5 .0% ester solid l l l Myristyl Laurate CH3 (CH2)12 C O (CH2)13 CH3 ooliquifies upon contact with the body

esters with elegant feel

O CH3 Ceraphyl 55 Tridecyl Liquid H C O C C CH ooimparts elegant, light, non-oily feel 0 .3–5 .0% ester Neopentanoate 27 13 3 l

CH3

C H CH O CH 8 17 2 3 ooimproves product spreadability Ceraphyl 375 Isostearyl Liquid and playtime 0 .3–5 .0% l ester Neopentanoate HC CH2 O C C CH3 ooimparts elegant, light, non-oily feel C6H13 CH2 CH3

Hair Care Overview Guide / 26

trade name INCI name description/ form structure features and benefits use level shampoos products shine conditioners styling hairsprays pomades, pastes waxes,

O ooimparts dry initial feel, luxurious mid-feel with a silky after-feel Ceraphyl™ ODS Octyldodecyl Liquid ooenhances product spreadability 0 .3–5 .0% ester Stearate CH3(CH2)16C OCH2CH(CH2)9CH3 l l l ooexceptional powder binding properties when CH2(CH2)6CH3 blended with Ceraphyl 847 (1:1) esters for maximum after-feel

Ceraphyl 791 O C H O C H ester (complies 6 13 6 13 Isocetyl Stearoyl ooimparts dry initial feel with lubricious after-feel to organic Liquid 0 .3–5 .0% l Stearate C17H35 C O CH (CH2)10 C O CH2 CH oolong-lasting emollient certifications, like Ecocert) C8H17

O O Ceraphyl 847 oooffers dry initial feel with long-lasting cushiony, ester (complies rich after-feel Octyldodecyl CH2 O C (CH2)10 CH O C C17H35 to organic Liquid ooexceptional pigment dispersing and binding 0 .3–5 .0% Stearoyl Stearate l l certifications, like CH C8H17 C6H13 properties when blended with Ecocert) Ceraphyl ODS (1:1) C10H21 esters with natural appeal O Caprylic/Capric CH2 OCR Triglyceride Orchid™ O ooenhances product spreadability (and) Cymbidium Liquid 0 .3–5 .0% l Complex OS CH OCR1 oooffers smooth, light, silky after-feel Grandiflorum Flower Extract O 11 R = Caprylic/Capric Acid CH2 OCR esters for rinse-off products O O

O O OH Ceraphyl oooffers clinically-proven moisturization in rinse- Castoryl Maleate Liquid O 0 .3–5 .0% RMT ester O OH off products l

O O OH

O esters with solubilizing capability

oohigh solubilizing capacity O ooshine enhancement X-Tend™ Phenethyl ooexcellent skin feel Liquid 0 .3–5 .0% 226 ester Benzoate O ooincreases the critical wavelength and the l l UVA/UVB ratio ooboosts polymeric shine in hairsprays

Hair Care Overview Guide / 27 lubricants

description/ trade name INCI name structure features and benefits applications use levels form

Lubrajel™** II XD Glycerin and Glyceryl 2 .0–25 .0% hydrogel Polyacrylate

Glycerin and Glyceryl oosuperior moisturization Lubrajel** CG Acrylate/Acrylic Acid ooimparts an inviting after-feel and slip 5 .0–25 .0% hydrogel Copolymer and Propylene ooexcellent lubricity, spreadability and Glycol emolliency oobroad formulation compatibility and Clear gels long shelf life Glycerin and Glyceryl oogood auxiliary thickening, suspending Lubrajel** DV Acrylate/Acrylic Acid power and viscosity enhancement 5 .0–25 .0% hydrogel Copolymer and Propylene oowater-soluble Glycol oocold-processable

Glycerin and Glyceryl Lubrajel** MS Acrylate/Acrylic Acid 2 .0–25 .0% hydrogel Copolymer and Propylene Glycol

Carboxyvinyl Glycerin backbone Lubrajel** Natural skin Glycerin, Beta-Glucan, oohair treatment gels 0 .3–50 .0% conditioning gel Algin, Xanthan Gum

Glycerin and Glyceryl Lubrajel** NP Acrylate/Acrylic Acid Theoretical structure: 2 .0–25% hydrogel Copolymer Glyceryl Acetate/Acrylic Acid Copolymer

Glycerin and Glyceryl oomultifunctional ingredient providing Acrylate/Acrylic Acid sensory and stabilization benefits Lubrajel** Oil Very pale Copolymer and Propylene ooconsumer pleasing aesthetics with a 0 .2–5 .0% hydrogel yellow viscous Glycol and PVM/MA natural ingredient gel Copolymer ooconforms to ecocert natural and organic cosmetic standard Lubrajel** PF Glycerin and Glyceryl hydrogel (Paraben- Acrylate/Acrylic Acid 5 .0–25 .0% free version of Copolymer Lubrajel CG)

Propylene Glycol and Lubrajel** TW Glycerin and Glyceryl 2 .0–25 .0% hydrogel Acrylate/Acrylic Acid Copolymer

*Also available in paraben-free version **Lubrajel and Lubrasil are registered trademarks of United-Guardian, Inc .

Hair Care Overview Guide / 28 description/ trade name INCI name structure features and benefits applications use levels form

Propylene Glycol (and) Glycerin (and) Glyceryl Lubrajel™** WA Acrylate/Acrylic Acid 25 .0–25 .0% hydrogel Copolymer (and) Poloxamer 184

Glycerin and Glyceryl Acrylate/Acrylic Acid Copolymer and Lubrasil™** Polysorbate 20 and 5 .0–25 .0% microemulsion Cyclopentasiloxane and oosuperior moisturization Propylene Glycol and ooimparts an inviting after-feel and slip Dimethiconol ooexcellent lubricity, spreadability and Carboxyvinyl emolliency Glycerin backbone oobroad formulation compatibility and Clear gels oohair treatment gels long shelf life oogood auxiliary thickening, suspending power and viscosity enhancement Glycerin (and) Glyceryl oowater-soluble Acrylate/Acrylic Acid Theoretical structure: Lubrasil** II DM oocold-processable Copolymer (and) Glyceryl Acetate/Acrylic Acid 2 .5–10 .0% microemulsion Laureth-23 (and) Copolymer Dimethicone

Glycerin (and) Glyceryl Acrylate/Acrylic Acid Lubrasil** II SB Copolymer (and) 3 .0–15 .0% microemulsion Laureth-23 (and) Cyclopentasiloxane (and) Dimethiconol

**Lubrajel and Lubrasil are registered trademarks of United-Guardian, Inc .

Hair Care Overview Guide / 29 encapsulates

Trade Name Size (microns) INCI Description / Benefit Captivates™ visible 500 - 700 Water (Aqua) (and) Butyrospermum Parkii (Shea Butter) (and) Ultramarines (C .I . Moisturizing Shea Butter Capsule HC0001 77007) (and) Gelatin (and) Acacia Senegal Gum (and) Titanium Dioxide (C .I . Blue shea butter capsules . Suitable for 77891) (and) Propylene Glycol (and) Diazolidinyl urea (and) Xanthan Gum (and) emulsions (creams and lotions) but also Methylparaben (and) Propylparaben shower, shampoo, conditioner

Captivates visible 1250 Paraffinum Liquidum (and) Water (Aqua) (and) Gelatin (Marine, fish) (and) Universal Pearl Capsule HC0002 Acacia Senegal Gum (and) Tocopherol Acetate (and) Prunus Persica (Peach) Pigmented blend of mineral oil, Vitamin E Kernel Oil (and) Mica (and) Titanium Dioxide (and) Propylene Glycol (and) acetate and peach kernel oil . Typical Rinse off Xanthan gum (and) Diazolidinyl Urea (and) Methylparaben (and) Propylparaben capsule

Captivates visible 1500 Paraffinum Liquidum (and) Water (Aqua) (and) Gelatin (and) Acacia Senegal Green/Blue Iridescent Capsule HC0009 gum (and) Propylene Glycol (and) Ethylhexyl Methoxycinnamate (and) Contains a microencapsulated, dyed and Titanium Dioxide (C .I . 77891) (and) Xanthan Gum (and) Mica (C I. . 77019) pigmented blend of mineral oil, vitamin E (and) Phenoxyethanol (and) Methylparaben (and) Tocopherol Acetate (and) acetate and Escalol 557 Chromium Oxide Greens (C .I . 77288) (and) Green 6 (C I. . 61565) (and) Ferric Ferrocyanide (C .I . 77510)

Captivates visible 1250 Water (Aqua) (and) Butyrospermum Parkii (Shea Butter) (and) Gelatin (and) Moisturizing Shea Butter Capsule HC0012 Acacia Senegal Gum (and) Mica (and) Helianthus Annuus (Sunflower) seed Contains pigmented shea butter . Thin wall . oil (and) Titanium Dioxide (and) Phenoxyethanol (and) Xanthan Gum (and) Suitable for leave on and rinse-off Red 30 (C .I . 73360) (and) Carmine (C .I . 75470) (and) Benzoic Acid (and) Dehydroacetic Acid

Captivates visible 750 - 1000 Water (Aqua) (and) Trimethylsiloxyphenyl Dimethicone (and) Gelatin (and) Hair Shine Bubble Capsule HC4408 Acacia Senegal Gum (and) Phenoxyethanol (and) Xanthan Gum (and) Benzoic Contains Si-Tec PTM 1000 for hair shine . Acid (and) Dehydroacetic Acid Colorless capsule looks like air bubbles

Captivates visible 1300 Water (Aqua) (and) Bambusa Arundinacea Stem Extract (and) Algin (and) C .I . Exfoliation Bead GL7833 77007 (Ultramarines) (and) Phenoxyethanol (and) Caprylyl Glycol (and) Calcium Blue bead filled with bamboo . The beads Chloride (and) Chondrus Crispus (Carrageenan) (and) Hydrochloric Acid break upon usage and releases the bamboo as scrub particles . Face cleansing and shampoos . Alginate/Agar drop in matrix for shower gels

Captivates visible 1000 Water (Aqua) (and) C .I . 77288 Chromium Oxide Green) (and) Algin (and) Color Burst Bead GL7542 Calcium Chloride (and)Phenoxyethanol (and) Agar (and) Benzoic Acid (and) Universal Green Dehydroacetic Acid (and) Sodium Hydroxide For use in surfactant systems such as shower gels and shampoos . The beads break during usage and color the foam green .

Hair Care Overview Guide / 30 encapsulates

Trade Name Size (microns) INCI Description / Benefit Captivates™ visible 1000 Water (Aqua) (and) Algin (and) C .I . 73360 (Red 30) (and) Calcium Chloride Color Burst Bead GL7990 (and) Gellan Gum (and) Glycerin (and) Phenoxyethanol (and) Caprylyl Glycol Universal Red (and) PVP For use in surfactant systems such as shower gels and shampoos . The beads break during usage and color the foam red .

Captivates visible 1000 Water (Aqua) (and) C .I . 77007 (Ultramarines) (and) Algin (and) Calcium Color Burst Bead GL7975 Chloride (and) Gellan Gum (and) Phenoxyethanol (and) Caprylyl Glycol (and) Universal Blue Butylated PVP For use in surfactant systems such as shower gels and shampoos . The beads break during usage and color the foam blue .

Captivates visible 1000 Water (Aqua) (and) Mica (and) C .I . 77891 (Titanium Dioxide) (and) Color Shift Bead GL7620 Phenoxyethaol (and) Caprylyl Glycol (and) Algin (and) Hydroethylcellulose White bead that transitions to pink on rub out (and) Calcium Chloride (and) Gellan Gum (and) C .I . 73360 (Red 30) (and) Glycerin (and) PVP

Captivates visible 3500 Water (Aqua) (and) C .I . 77891 (Titanium Dioxide) (and) Algin (and) C .I . 73360 Pink Shimmer Bead GL7878 (Red 30) (and) Phenoxyethaol (and) Caprylyl Glycol (and) Chondrus Crispus Releases pink pearlescent shimmer on rub out . (Carrageenan) (and) Calcium Chloride (and) Glycerin (and) PVP

Captivates visible 1300 Water (Aqua) (and) Chondrus Crispus (Carrageenan) (and) Phenoxyethanol Visual Bead GL7615 (and) Agar (and) Mica (and) Potassium Chloride (and) C .I . 77891 (Titanium Golden Carrageenan/Agar bead . Softens in Dioxide) (and) C .I . 77491 (Iron Oxides) (and) Benzoic Acid (and) Silica (and) hair gels . Dehydroacetic Acid (and) Xanthan Gum (and) Glucose (and) Tin Oxide

Captivates visible 1300 Water (Aqua) (and) Algin (and) Mica (and) Agar (and) Calcium Chloride (and) Visual Bead GL7661 C .I . 77891 (Titanium Dioxide (and) Phenethyl Alcohol (and) PPG-2 Methyl Ether Pink bead with Carrageenan/Agar drop in (and) C .I 73360 (Red 30) (and) Glycerin (and) Methylisothiazolinone (and) PVP matrix, for most shower gels and shampoos . (and) Phenoxyethanol Imparts nice visual effect to the formulation . Purely aesthetics, no functionality

Hair Care Overview Guide / 31 GLOBAL HEADQUARTERS The information contained in this brochure and the various products described are intended Ashland LLC for use only by persons having technical skill 50 East RiverCenter Blvd . and at their own discretion and risk after they have performed necessary technical Covington, KY 41012-0391 U .S .A . investigations, tests and evaluations of the Tel: +1 859 815 3333 products and their uses. Certain end uses of these products may be regulated pursuant to rules or regulations governing medical devices, REGIONAL CENTERS drug uses, or pesticidal or antimicrobial uses. It is the end user’s responsibility to determine the Asia Pacific— Singapore applicability of such regulations to its products. Tel: +65 6775 5366 All statements, information, and data presented Shanghai, P .R . China herein are believed to be accurate and reliable, Tel: +86 21 6090 6606 but are not to be taken as a guarantee of fitness for a particular purpose, or representation, express or implied, for which seller assumes Europe — Barcelona, Spain legal responsibility. No freedom to use any Tel: +34 93 298 0700 patent owned by Ashland, its subsidiaries, or its suppliers is to be inferred.

Middle East/Africa/India Footnotes Turkey 1 - Patented technology 2 - Patent pending Tel: +90 216 538 08 00

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