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Strontium Carbonate Safety Data Sheet

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Safety Data Sheet According to Commission Regulations (EU) 830/2015 Creation date 17/02/2012 Version No. 1 Revision date 29/07/2019 Revision No. 4 Strontium Carbonate SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product Identifier Commercial name Strontium Carbonate Chemical name Strontium Carbonate Synonyms Chemical formula SrCO3 Index number EU (Annex 1) Not applicable EC No. 216-643-7 CAS No. 1633-05-2 REACH registry number 01-2119502545-46-0002 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Manufacture of pyrotecnical products Use in welding electrode coating Glass industry Manufacture of glazes, frits and enamels Manufacture of ceramic and electro-ceramic materials Manufacture of other strontium compounds Use in zinc electrolysis Uses advised against None 1.3 Details of the supplier of the safey data sheet Company name QUÍMICA DEL ESTRONCIO, S.A.U. Company address Los Parales, s.n., Valle de Escombreras, 30350 Cartagena (Spain) Company phone number +34 968 167 700 Company e-mail for SDS [email protected] 1.4 Emergency phone number +34 968 167 700 / +1 800 424 9300 (only for USA) SECTION 2. Hazards identification 2.1 Classification of the substance* According to Regulation EC No. 1272/2008 [CLP/GHS] Not classified Hazard Pictogram Signal word Hazard statements Precautionary statements 2.2 Label elements None 2.3 Other Hazards Criteria PBT/mPmB According to annex XIII of Regulation (EC) No. 1907/2006, does not meet the criteria for PBT or mPmB substance No other hazards identified * For complete meaning of R phrases and/or hazard statements (H): see section 16 SECTION 3. Composition/ information on ingredients Specific Classification 3.1 Name EC No. CAS No. % (w/w) IUPAC name concentration Regulation 1272/2008 limits Strontium carbonate 216-643-7 1633-05-2 ≥ 97 % strontium carbonate Not classified Version 1. Rev.4 29/07/2019 Page 1 of 6 SECTION 4. First aid measures 4.1 Description of first aid measures General advice Remove contaminated clothes. Inhalation Breathe fresh air and rest. If symptoms remain get medical assistance. Ingestion If victim is conscious, rinse mouth with plenty of water. If symptoms remain get medical assistance. Skin contact Rinse immediately contaminated clothes and the skin with plenty of water, before removing the clothes. Flush eyes with plenty of water while keeping the eyelids wide open. Eye contact Get medical attention in case of continuous eye irritation. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5. Firefighting measures 5.1 Extinguishing media The product itself is not oxidizing. Use extinguishing measures that are appropriate to local circumstances and the surrounding Suitable Extinguishing media environment. Unsuitable Extinguishing media 5.2 Special hazards arising from the substance or mixture Special hazards Hazards from thermal decomposition and combustion products 5.3 Advice for the fire fighters Specific extinguishing media Special protection in fire fighting Use self-contained respiratory equipment in case of existence of smoke. SECTION 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Do not breathe dust. 6.2 Environmental precautions It has low solubility in water 6.3 Methods and material for containment and cleaning up Pick up and arrange disposal without creating dust. Wash the area with water 6.4 Reference to other sections Refer to section1 for contact data, refer to protection measures in section 8 and section 13 for more disposal considerations. SECTION 7. Handling and Storage 7.1 Precautions for safe handling Avoid dust formation. Do not breathe dust. Avoid contact with skin, eyes and clothes. 7.2 Conditions for safe storage, including any incompatibilities In the storage area general occupational hygiene measures are required to ensure safe handling of the substance. These measures involve good personal and housekeeping practices, no drinking, eating and smoking at the workplace. Store away from incompatible materials. Suitable/unsuitable packaging material Suitable packaging material: Paper and PE 7.3 Specific end use(s) See section 1.2 and annexes for exposure scenarios. Remark : Stability and reactivity, see Section 10 SECTION 8. Exposure controls / Personal protection 8.1 Control parameters Compound CAS Ocupational exposure limit values Strontium 1633-05-2 Undefined Carbonate Worker consumer systemic industrial professional oral long-term Not applicable Not applicable 0.8 mg/kg pc/day DNEL inhalation long-term 3.5 mg/m3 3.5 mg/m3 1 mg/m3 Derived from ISQ dermal long-term 27.9 mg/kg pc/day 27.9 mg/kg pc/day Not applicable Version 1. Rev.4 29/07/2019 Page 2 of 6 water air soil microbiological sediment oral PNEC Absence of fresh water: 2,065 mg/l 323,6 mg/kg 1781 mg/kg Not available ≥100 mg/l bioaccumulative sea water: not relevant. dry soil dry sediment potential 8.2 Exposure controls Provide appropriate exhaust ventilation at places where dust is formed. Appropriate engineering When handling do not eat, drink or smoke. and hygienic controls Wash your hands after handling the product and before eating, drinking or smoking. Wash your hands before the breaks and when finishing working. Individual protection Use chemical safety goggles with side shields to prevent eye irritation and/or full-face shield where dusting or splashing of solutions is Eye possible. Skin and body Working clothing. Hands Wear canvas or rubber gloves when handling the product for long-term. Respiratory In case of high dust formation and/or inadequate ventilation, wear an approved dust mask. Thermal Environmental exposure controls See section 6. Personal protective advice apply to high exposure levels. Choosing personal protection adapted to the exposure risks. SECTION 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Solid, white powder Colour White Olor Odourless Molecular weight 147,63 g/mol pH pH aqueous solution (10g/l) > 5 Boiling point Not applicable. Melting point 1497 °C Flash point Non flammable Flammability Non flammable Explosive limits Non-explosive substance Auto ignition temperature Non flammable Decomposition temperature 1100 ºC Low explosive limit Not applicable High explosive limit Not applicable Oxidising properties Non-oxidising Bulk density at 20°C 3,79 Vapour pressure at 20°C Not applicable Vapour density Not applicable Partition coefficient n-octanol/water Not applicable Viscosity Not applicable Solubility in water 20ºC (0,011 g/l) 9.2 Other information Particle size: Powder d50 8-10 µm Version 1. Rev.4 29/07/2019 Page 3 of 6 SECTION 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Stable under normal conditions of storage, handling and use. 10.3 Possibility of hazardous reactions May react violently with acids 10.4 Conditions to avoid To avoid thermal decomposition, do not overheat. 10.5 Incompatible materials Acids 10.6 Hazardous decomposition products CO2 SECTION 11. Toxicological Information 11.1 Information on toxicological effects Acute toxicity Compound CAS No. Method Species Route Result OECD 423 rat oral LD50: >2000 mg / Kg pc. Strontium Carbonate 1633-05-2 dermal Not required OECD 403 rat inhalation LC50(4h): >4,5 mg/L. Skin corrosion or irritation / Serious eye damage or irritation Compound CAS No. Method Species Route Result OECD 404 skin Not irritating Strontium Carbonate 1633-05-2 rabbit OECD 405 eye Not irritating Respiratory or skin sensitisation Compound CAS No. Method Species Route Result Strontium Carbonate 1633-05-2 OECD 406 Guinea pig skin Non-sensitiser Germ cell mutation Compound CAS No. Method Species Routet Result OECD 471 bacteria Negative. No mutagenicity . Ames Test OECD 487 chromosome aberration Negative. No mutagenicity Strontium Carbonate 1633-05-2 OECD 476 mammalian cell mutation Negative. No mutagenicity Carcinogenicity Compound CAS No. Method Species Route Result Strontium Carbonate 1633-05-2 rat all Non-carcinogenic Toxicity for reproduction Compound CAS No. Method Species Route Result Sub -Effects on fertility: Not available Strontium Carbonate 1633-05-2 rat cutaneous -Developmental toxicity: Not available Specific target organ toxicity (STOT)-single exposure Compound CAS No. Method Species Route Result - - - Non-toxic Strontium Carbonate 1633-05-2 Specific target organ toxicity (STOT)-repeated exposure Compound CAS No. Method Species Route Result Oral route. NOAEL>50 mg/kg corporal weight/day. Strontium Carbonate 1633-05-2 rat Inhalation route: Not required. Skin route: Not required. Aspiration hazard Compound CAS No. Method Species Route Result Strontium Carbonate 1633-05-2 - - - No hazard expected. Version 1. Rev.4 29/07/2019 Page 4 of 6 SECTION 12. Ecological Information 12.1 Toxicity Aquatic Toxicity Compound CAS No. Fish Crustacea Algae LC50(96h) ≥ 97,45 mg/l. EC50/LC50 (48h) = 125 mg/l NOEC(72h) ≥ 43,3 mg/l Short-term (Cyprinus carpio) (Daphnia magna) (Pseudokirchneriella subcapitata) Strontium Carbonate 1633-05-2 LC50(7 days) 8,58 mg/l. NOEC(21days) = 60 mg/l Long-term (Carassius auratus) (Daphnia magna) Terrestrial Toxicity Compound CAS No. Macro-organisms Micro-organisms Terrestrial plants Other organisms NOEC = 15000 ppm of Sr Strontium Carbonate 1633-05-2 No reliable data No reliable data No reliable data (in birds) Microbiological activity in sewage treatment plants Compound CAS No. Toxicity to activated sludge Strontium Carbonate 1633-05-2 PNEC ≥100 mg/l 12.2 Persistence and degradability Compound CAS No. Strontium Carbonate 1633-05-2 Not relevant for inorganic substances such us SrCO3 12.3 Bioaccumulative potential Partition coefficient n- Bioaccumulative factor Compound CAS No. Remarks octanol/water (Kow) (BCF) Strontium Carbonate 1633-05-2 Not applicable. Inorganic Substance. Low bioaccumulative factor 12.4 Mobility in soil Compound CAS No. Result Strontium Carbonate 1633-05-2 Not available 12.5 Results of PBT and vPvB assessment Not required.
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