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SAFETY DATA SHEET Product Trade Name: FDP-S1296-17

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SAFETY DATA SHEET Product Trade Name: FDP-S1296-17 SAFETY DATA SHEET Product Trade Name: FDP-S1296-17 Revision Date: 08-Mar-2018 Revision Number: 2 1. Identification 1.1. Product Identifier Product Trade Name: FDP-S1296-17 Synonyms None Chemical Family: Blend Internal ID Code HM008641 1.2 Recommended use and restrictions on use Application: Acid Corrosion Inhibitor Uses advised against Consumer use 1.3 Manufacturer's Name and Contact Details Manufacturer/Supplier Halliburton Energy Services, Inc. P.O. Box 1431 Duncan, Oklahoma 73536-0431 Telephone: 1-281-871-6107 Halliburton Energy Services, Inc. 645 - 7th Ave SW Suite 1800 Calgary, AB T2P 4G8 Canada Prepared By Chemical Stewardship Telephone: 1-281-871-6107 e-mail: [email protected] 1.4. Emergency telephone number: Emergency Telephone Number 1-866-519-4752 or 1-760-476-3962 Global Incident Response Access Code: 334305 Contract Number: 14012 2. Hazards Identification 2.1 Classification in accordance with paragraph (d) of §1910.1200 Acute Oral Toxicity Category 4 - H302 Acute toxicity - Dermal Category 3 - H311 Acute inhalation toxicity - vapor Category 3 - H331 Skin Corrosion / Irritation Category 2 - H315 Serious Eye Damage/Irritation Category 1 - H318 Reproductive Toxicity Category 1B - H360 Specific Target Organ Toxicity - (Single Exposure) Category 1 - H370 Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373 Acute Aquatic Toxicity Category 1 - H400 Chronic Aquatic Toxicity Category 3 - H412 Flammable liquids. Category 2 - H225 _____________________________________________________________________________________________ Page 1 / 12 FDP-S1296-17 Revision Date: 08-Mar-2018 _____________________________________________________________________________________________ 2.2. Label Elements Hazard Pictograms Signal Word: Danger Hazard Statements H225 - Highly flammable liquid and vapor H302 - Harmful if swallowed H311 - Toxic in contact with skin H315 - Causes skin irritation H318 - Causes serious eye damage H331 - Toxic if inhaled H360 - May damage fertility or the unborn child H370 - Causes damage to organs H373 - May cause damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life H412 - Harmful to aquatic life with long lasting effects Precautionary Statements Prevention P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed P240 - Ground and bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/equipment P242 - Use only non-sparking tools P243 - Take action to prevent static discharges. P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 - Rinse mouth P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P362 + P364 - Take off contaminated clothing and wash before reuse P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several _____________________________________________________________________________________________ Page 2 / 12 FDP-S1296-17 Revision Date: 08-Mar-2018 _____________________________________________________________________________________________ minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P391 - Collect spillage P370 + P378 - In case of fire: Use CO2, dry chemical, or foam Storage P405 - Store locked up P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P403 + P235 - Store in a well-ventilated place. Keep cool Disposal P501 - Dispose of contents/container in accordance with local/regional/national/international regulations 2.3 Hazards not otherwise classified None known 3. Composition/information on Ingredients Substances CAS Number PERCENT (w/w) GHS Classification - US Methanol 67-56-1 60 - 100% Acute Tox. 3 (H301) Acute Tox. 3 (H311) Acute Tox. 3 (H331) Repr. 1B (H360) STOT SE 1 (H370) Flam. Liq. 2 (H225) Modified thiourea polymer Proprietary 10 - 30% Acute Tox. 4 (H302) Eye Corr. 1 (H318) Aquatic Chronic 2 (H411) Combustible Dust Ethoxylated alcohols Proprietary 1 - 5% Acute Tox. 4 (H302) Skin Irrit. 2 (H315) Eye Corr. 1 (H318) Aquatic Acute 1 (H400) Aquatic Chronic 3 (H412) Propargyl alcohol 107-19-7 1 - 5% Acute Tox. 3 (H301) Acute Tox. 2 (H310) Acute Tox. 2 (H330) Skin Corr. 1B (H314) Eye Corr. 1 (H318) STOT RE 2 (H373) Aquatic Acute 2 (H401) Flam. Liq. 3 (H226) The specific chemical identity of the composition has been withheld as proprietary. The exact percentage (concentration) of the composition has been withheld as proprietary. 4. First Aid Measures 4.1. Description of first aid measures Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Seek immediate medical attention/advice. Do not do mouth-to-mouth resuscitation. Eyes In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Seek immediate medical attention/advice. Suitable emergency eye wash facility should be immediately available Skin In case of contact, immediately flush skin with plenty of soap and water for at least 30 minutes and remove contaminated clothing, shoes and leather goods immediately. Get medical attention immediately. _____________________________________________________________________________________________ Page 3 / 12 FDP-S1296-17 Revision Date: 08-Mar-2018 _____________________________________________________________________________________________ Ingestion Following ingestion, onset of symptoms may be delayed by 12 to 24 hours. Admission to hospital should be the first priority even if symptoms are absent. Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Obtain immediate medical attention. 4.2 Most important symptoms/effects, acute and delayed Causes severe eye irritation which may damage tissue. Causes skin irritation. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Potential reproductive hazard. May cause birth defects. May cause damage to internal organs. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Gastric lavage or emesis should be performed as soon as possible to minimize absorption, and is recommended within 4 hours of ingestion. Ethanol may be given intravenously to prevent build-up of toxic effects of methanol metabolites. Visual disturbances and metabolic acidosis may occur and dialysis, preferably hemodialysis may be employed to treat these complications. 5. Fire-fighting measures 5.1. Extinguishing media Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. Extinguishing media which must not be used for safety reasons Do NOT spray pool fires directly with water. A solid stream of water directed into hot burning liquid can cause splattering. 5.2 Specific hazards arising from the substance or mixture Special exposure hazards in a fire Decomposition in fire may produce harmful gases. Vapors are heavier than air and may accumulate in low areas. Vapors may travel along the ground to be ignited at distant locations. 5.3 Special protective equipment and precautions for fire-fighters Special protective equipment for firefighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use appropriate protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Remove sources of ignition. Take precautionary measures against static discharges All equipment used when handling the product must be grounded Avoid contact with skin, eyes and clothing. See Section 8 for additional information 6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. 6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Remove ignition sources and work with non-sparking tools. 7. Handling and storage 7.1. Precautions for safe handling Handling Precautions Do not breathe dust/fume/gas/mist/vapors/spray. Ensure adequate ventilation. Use appropriate protective equipment. Remove sources of ignition. Ground and bond containers when transferring from one container to another. Avoid _____________________________________________________________________________________________ Page 4 / 12 FDP-S1296-17 Revision Date: 08-Mar-2018 _____________________________________________________________________________________________ contact with eyes, skin, or clothing. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for
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