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IAEA Nuclear Energy Series IAEA Nuclear No. NP-T-4.2No. Energy Hydrogen Production Using Nuclear IAEA Nuclear Energy Series No. NP-T-4.2 Basic Hydrogen Production Principles Using Nuclear Energy Objectives Guides Technical Reports INTERNATIONAL ATOMIC ENERGY AGENCY VIENNA ISBN 978–92–0–135110–4 ISSN 1995–7807 IAEA NUCLEAR ENERGY SERIES PUBLICATIONS STRUCTURE OF THE IAEA NUCLEAR ENERGY SERIES Under the terms of Articles III.A and VIII.C of its Statute, the IAEA is authorized to foster the exchange of scientific and technical information on the peaceful uses of atomic energy. The publications in the IAEA Nuclear Energy Series provide information in the areas of nuclear power, nuclear fuel cycle, radioactive waste management and decommissioning, and on general issues that are relevant to all of the above mentioned areas. The structure of the IAEA Nuclear Energy Series comprises three levels: 1 — Basic Principles and Objectives; 2 — Guides; and 3 — Technical Reports. The Nuclear Energy Basic Principles publication describes the rationale and vision for the peaceful uses of nuclear energy. Nuclear Energy Series Objectives publications explain the expectations to be met in various areas at different stages of implementation. Nuclear Energy Series Guides provide high level guidance on how to achieve the objectives related to the various topics and areas involving the peaceful uses of nuclear energy. Nuclear Energy Series Technical Reports provide additional, more detailed, information on activities related to the various areas dealt with in the IAEA Nuclear Energy Series. The IAEA Nuclear Energy Series publications are coded as follows: NG — general; NP — nuclear power; NF — nuclear fuel; NW — radioactive waste management and decommissioning. In addition, the publications are available in English on the IAEA’s Internet site: http://www.iaea.org/Publications/index.html For further information, please contact the IAEA at PO Box 100, Vienna International Centre, 1400 Vienna, Austria. All users of the IAEA Nuclear Energy Series publications are invited to inform the IAEA of experience in their use for the purpose of ensuring that they continue to meet user needs. Information may be provided via the IAEA Internet site, by post, at the address given above, or by email to [email protected]. HYDROGEN PRODUCTION USING NUCLEAR ENERGY The following States are Members of the International Atomic Energy Agency: AFGHANISTAN GUATEMALA PANAMA ALBANIA HAITI PAPUA NEW GUINEA ALGERIA HOLY SEE PARAGUAY ANGOLA HONDURAS PERU ARGENTINA HUNGARY PHILIPPINES ARMENIA ICELAND POLAND AUSTRALIA INDIA PORTUGAL AUSTRIA INDONESIA AZERBAIJAN IRAN, ISLAMIC REPUBLIC OF QATAR BAHRAIN IRAQ REPUBLIC OF MOLDOVA BANGLADESH IRELAND ROMANIA BELARUS ISRAEL RUSSIAN FEDERATION BELGIUM ITALY RWANDA BELIZE JAMAICA SAUDI ARABIA BENIN JAPAN SENEGAL BOLIVIA JORDAN SERBIA BOSNIA AND HERZEGOVINA KAZAKHSTAN SEYCHELLES BOTSWANA KENYA SIERRA LEONE BRAZIL KOREA, REPUBLIC OF BULGARIA KUWAIT SINGAPORE BURKINA FASO KYRGYZSTAN SLOVAKIA BURUNDI LAO PEOPLE’S DEMOCRATIC SLOVENIA CAMBODIA REPUBLIC SOUTH AFRICA CAMEROON LATVIA SPAIN CANADA LEBANON SRI LANKA CENTRAL AFRICAN LESOTHO SUDAN REPUBLIC LIBERIA SWAZILAND CHAD LIBYA SWEDEN CHILE LIECHTENSTEIN SWITZERLAND CHINA LITHUANIA COLOMBIA LUXEMBOURG SYRIAN ARAB REPUBLIC CONGO MADAGASCAR TAJIKISTAN COSTA RICA MALAWI THAILAND CÔTE D’IVOIRE MALAYSIA THE FORMER YUGOSLAV CROATIA MALI REPUBLIC OF MACEDONIA CUBA MALTA TOGO CYPRUS MARSHALL ISLANDS TRINIDAD AND TOBAGO CZECH REPUBLIC MAURITANIA TUNISIA DEMOCRATIC REPUBLIC MAURITIUS TURKEY OF THE CONGO MEXICO UGANDA DENMARK MONACO DOMINICA MONGOLIA UKRAINE DOMINICAN REPUBLIC MONTENEGRO UNITED ARAB EMIRATES ECUADOR MOROCCO UNITED KINGDOM OF EGYPT MOZAMBIQUE GREAT BRITAIN AND EL SALVADOR MYANMAR NORTHERN IRELAND ERITREA NAMIBIA UNITED REPUBLIC ESTONIA NEPAL OF TANZANIA ETHIOPIA NETHERLANDS UNITED STATES OF AMERICA NEW ZEALAND FIJI URUGUAY FINLAND NICARAGUA UZBEKISTAN FRANCE NIGER GABON NIGERIA VENEZUELA GEORGIA NORWAY VIETNAM GERMANY OMAN YEMEN GHANA PAKISTAN ZAMBIA GREECE PALAU ZIMBABWE The Agency’s Statute was approved on 23 October 1956 by the Conference on the Statute of the IAEA held at United Nations Headquarters, New York; it entered into force on 29 July 1957. The Headquarters of the Agency are situated in Vienna. Its principal objective is “to accelerate and enlarge the contribution of atomic energy to peace, health and prosperity throughout the world’’. IAEA NUCLEAR ENERGY SERIES No. NP-T-4.2 HYDROGEN PRODUCTION USING NUCLEAR ENERGY INTERNATIONAL ATOMIC ENERGY AGENCY VIENNA, 2013 COPYRIGHT NOTICE All IAEA scientific and technical publications are protected by the terms of the Universal Copyright Convention as adopted in 1952 (Berne) and as revised in 1972 (Paris). The copyright has since been extended by the World Intellectual Property Organization (Geneva) to include electronic and virtual intellectual property. Permission to use whole or parts of texts contained in IAEA publications in printed or electronic form must be obtained and is usually subject to royalty agreements. Proposals for non-commercial reproductions and translations are welcomed and considered on a case-by-case basis. Enquiries should be addressed to the IAEA Publishing Section at: Marketing and Sales Unit, Publishing Section International Atomic Energy Agency Vienna International Centre PO Box 100 1400 Vienna, Austria fax: +43 1 2600 29302 tel.: +43 1 2600 22417 email: [email protected] http://www.iaea.org/books © IAEA, 2013 Printed by the IAEA in Austria March 2013 STI/PUB/1577 IAEA Library Cataloguing in Publication Data Hydrogen production using nuclear energy. — Vienna : International Atomic Energy Agency, 2013. p. ; 29 cm. — (IAEA nuclear energy series, ISSN 1995–7807 ; no. NP-T-4.2) STI/PUB/1577 ISBN 978–92–0–135110–4 Includes bibliographical references. 1. Nuclear energy — Industrial applications. 2. Hydrogen as fuel — Research. I. International Atomic Energy Agency. II. Series. IAEAL 13–00792 FOREWORD One of the IAEA’s statutory objectives is to “seek to accelerate and enlarge the contribution of atomic energy to peace, health and prosperity throughout the world.” One way this objective is achieved is through the publication of a range of technical series. Two of these are the IAEA Nuclear Energy Series and the IAEA Safety Standards Series. According to Article III.A.6 of the IAEA Statute, the safety standards establish “standards of safety for protection of health and minimization of danger to life and property”. The safety standards include the Safety Fundamentals, Safety Requirements and Safety Guides. These standards are written primarily in a regulatory style, and are binding on the IAEA for its own programmes. The principal users are the regulatory bodies in Member States and other national authorities. The IAEA Nuclear Energy Series comprises reports designed to encourage and assist R&D on, and application of, nuclear energy for peaceful uses. This includes practical examples to be used by owners and operators of utilities in Member States, implementing organizations, academia, and government officials, among others. This information is presented in guides, reports on technology status and advances, and best practices for peaceful uses of nuclear energy based on inputs from international experts. The IAEA Nuclear Energy Series complements the IAEA Safety Standards Series. Nuclear generated hydrogen has important potential advantages over other sources that will be considered for a growing hydrogen share in a future world energy economy. Still, there are technical uncertainties in nuclear hydrogen processes that need to be addressed through a vigorous research and development effort. Safety issues as well as hydrogen storage and distribution are important areas of research to be undertaken to support a successful hydrogen economy in the future. The hydrogen economy is gaining higher visibility and stronger political support in several parts of the world. In recent years, the scope of the IAEA’s programme has been widened to include other more promising applications such as nuclear hydrogen production and higher temperature process heat applications. The OECD Nuclear Energy Agency, Euratom and the Generation IV International Forum have also shown interest in the non-electric applications of nuclear power based on future generation advanced and innovative nuclear reactors. This report was developed under an IAEA project with the objective of providing updated, balanced and objective information on the current status of hydrogen production processes using nuclear energy. It documents the state of the art of the development of hydrogen as an energy carrier in many Member States, as well as its corresponding production through the use of nuclear power. The report includes an introduction to the technology of nuclear process heat reactors as a means of producing hydrogen or other upgraded fuels, with a focus on high temperature reactor technology to achieve simultaneous generation of electricity and high temperature process heat and steam. Special emphasis is placed on the safety aspects of nuclear hydrogen production systems. This publication was compiled by K. Verfondern (Germany) based on evaluations of officially issued reports and published papers and presentations from major international conferences. The draft report was reviewed by the experts named at the end of the report. The IAEA officer responsible for this publication was I. Khamis of the Division of Nuclear Power. EDITORIAL NOTE This report