Safety data sheet
Page: 1/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017
1. Identification Product identifier
Pearl-Glo® SF PG1099
Chemical name: Pearl-Glo SF CAS Number: 7787-59-9
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: cosmetic ingredient
Details of the supplier of the safety data sheet
Company: BASF SE 67056 Ludwigshafen GERMANY
Telephone: +49 621 60-48799 E-mail address: [email protected]
Emergency telephone number
International emergency number: Telephone: +49 180 2273-112
2. Hazards Identification
Classification of the substance or mixture
According to UN GHS criteria
No need for classification according to GHS criteria for this product.
Page: 2/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Label elements
Globally Harmonized System (GHS)
The product does not require a hazard warning label in accordance with GHS criteria.
Other hazards
According to UN GHS criteria
No specific dangers known, if the regulations/notes for storage and handling are considered.
3. Composition/Information on Ingredients Substances
Chemical nature
INCI Name: BISMUTH OXYCHLORIDE
Contains: Bismuth chloride oxide CAS Number: 7787-59-9 EC-Number: 232-122-7
Hazardous ingredients (GHS) According to UN GHS criteria
No particular hazards known.
Mixtures
Not applicable
4. First-Aid Measures Description of first aid measures Remove contaminated clothing.
If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.
On skin contact: Wash thoroughly with soap and water.
Page: 3/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion: Rinse mouth and then drink plenty of water.
Most important symptoms and effects, both acute and delayed Symptoms: No significant reaction of the human body to the product known.
Hazards: No hazard is expected under intended use and appropriate handling.
Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: dry powder, foam
Unsuitable extinguishing media for safety reasons: carbon dioxide
Special hazards arising from the substance or mixture harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.
6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Avoid dust formation. Use personal protective clothing.
Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of.
Page: 4/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Avoid raising dust.
Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
7. Handling and Storage Precautions for safe handling Breathing must be protected when large quantities are decanted without local exhaust ventilation.
Protection against fire and explosion: No special precautions necessary.
Conditions for safe storage, including any incompatibilities
Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene (LDPE) Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Protect from direct sunlight.
Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.
8. Exposure Controls/Personal Protection Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with low efficiency for solid particles (e.g. EN 143 or 149, Type P1or FFP1)
Hand protection: See section 8 „General safety and hygiene measures“
Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Page: 5/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. In order to prevent contamination while handling, closed working clothes and working gloves should be used. Hands and/or face should be washed before breaks and at the end of the shift.
9. Physical and Chemical Properties Information on basic physical and chemical properties
Form: powder Colour: white to silver Odour: odourless Odour threshold: not applicable, odour not perceivable pH value: 4,0 - 8,0 (4 %(m)) (as aqueous suspension) Melting point: The substance / product decomposes. Boiling point: The product is a non-volatile solid. Flash point: not applicable Evaporation rate: The product is a non-volatile solid. Flammability: not flammable Flammability of Aerosol Products: not applicable, the product does not form flammable aerosoles Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Ignition temperature: not applicable Vapour pressure: not applicable Density: 7,7 g/ml (20 °C) Relative density: 7,7 Relative vapour density (air): The product is a non-volatile solid.
Page: 6/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Solubility in water: insoluble Partitioning coefficient n-octanol/water (log Kow): The value has not been determined because the substance is inorganic. Self ignition: Based on its structural properties the product is not classified as self- igniting.
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: not applicable, the product is a solid Viscosity, kinematic: not applicable, the product is a solid Explosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.
Other information
Self heating ability: It is not a substance capable of spontaneous heating.
Bulk density: 610 kg/m3 pKA: not applicable Surface tension: Based on chemical structure, surface activity is not to be expected. Grain size distribution: No data available. Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. No further information available.
10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals: Corrosive effects to metal are not anticipated. Formation of Remarks: Forms no flammable gases in the flammable gases: presence of water.
Chemical stability The product is chemically stable.
Page: 7/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated.
Conditions to avoid See MSDS section 7 - Handling and storage. Avoid dust formation. Avoid deposition of dust.
Incompatible materials
Substances to avoid: acids, oxidizing agents
Hazardous decomposition products
Hazardous decomposition products: hydrogen chloride
11. Toxicological Information Information on toxicological effects
Acute toxicity
Assessment of acute toxicity: Virtually nontoxic after a single ingestion. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.
Experimental/calculated data: LD50 rat (oral): > 5.000 mg/kg
Irritation
Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.
Serious eye damage/irritation rabbit: non-irritant (Draize test) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Test conducted with a similar formulation.
Respiratory/Skin sensitization
Assessment of sensitization: There is no evidence of a skin-sensitizing potential.
Experimental/calculated data: other guinea pig: Non-sensitizing. (other) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Test conducted with a similar formulation.
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Germ cell mutagenicity
Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an effect.
Carcinogenicity
Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an effect.
Reproductive toxicity
Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for such an effect.
Developmental toxicity
Assessment of teratogenicity: No data was available concerning toxicity to development.
Specific target organ toxicity (single exposure)
Assessment of STOT single: Based on available Data, the classification criteria are not met.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity: Repeated dermal uptake of the substance did not cause substance-related effects. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.
Aspiration hazard
No aspiration hazard expected.
Other relevant toxicity information
Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses.
12. Ecological Information Toxicity
Assessment of aquatic toxicity:
Page: 9/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 There is a high probability that the product is not acutely harmful to aquatic organisms. The product has not been tested. The statement has been derived from the properties of the individual components.
Toxicity to fish: LC50 > 100 mg/l
Aquatic invertebrates: No data available.
Aquatic plants: No data available.
Microorganisms/Effect on activated sludge: EC0 > 100 mg/l
Chronic toxicity to fish: No data available.
Chronic toxicity to aquatic invertebrates: No data available.
Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity.
Persistence and degradability
Assessment biodegradation and elimination (H2O): Inorganic product which cannot be eliminated from water by biological purification processes.
The colourant is insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plant
Elimination information: No data available.
Assessment of stability in water: No data available. Bioaccumulative potential
Assessment bioaccumulation potential: The product will not be readily bioavailable due to its consistency and insolubility in water.
Mobility in soil
Assessment transport between environmental compartments: Volatility: not applicable
Results of PBT and vPvB assessment
Page: 10/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 According to Annex XIV of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very bioaccumulative) criteria. Self classification
Other adverse effects
The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer.
Additional information
Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations.
Other ecotoxicological advice: The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.
13. Disposal Considerations
Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations. Check for possible recycling.
Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents.
14. Transport Information
Land transport
ADR Not classified as a dangerous good under transport regulations UN number: Not applicable UN proper shipping name: Not applicable Transport hazard class(es): Not applicable Packing group: Not applicable Environmental hazards: Not applicable Special precautions for None known user
Page: 11/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 RID Not classified as a dangerous good under transport regulations UN number: Not applicable UN proper shipping name: Not applicable Transport hazard class(es): Not applicable Packing group: Not applicable Environmental hazards: Not applicable Special precautions for None known user
Inland waterway transport ADN Not classified as a dangerous good under transport regulations UN number: Not applicable UN proper shipping name: Not applicable Transport hazard class(es): Not applicable Packing group: Not applicable Environmental hazards: Not applicable Special precautions for None known user:
Transport in inland waterway vessel Not evaluated
Sea transport
IMDG Not classified as a dangerous good under transport regulations UN number: Not applicable UN proper shipping name: Not applicable Transport hazard class(es): Not applicable Packing group: Not applicable Environmental hazards: Not applicable Special precautions for None known user
Air transport
IATA/ICAO Not classified as a dangerous good under transport regulations UN number: Not applicable UN proper shipping name: Not applicable Transport hazard class(es): Not applicable
Page: 12/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Packing group: Not applicable Environmental hazards: Not applicable Special precautions for None known user
UN number See corresponding entries for “UN number” for the respective regulations in the tables above.
UN proper shipping name See corresponding entries for “UN proper shipping name” for the respective regulations in the tables above.
Transport hazard class(es) See corresponding entries for “Transport hazard class(es)” for the respective regulations in the tables above.
Packing group See corresponding entries for “Packing group” for the respective regulations in the tables above.
Environmental hazards See corresponding entries for “Environmental hazards” for the respective regulations in the tables above.
Special precautions for user See corresponding entries for “Special precautions for user” for the respective regulations in the tables above.
Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated
15. Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture
Not applicable
16. Other Information
Due to the merger of Engelhard Corp. and BASFGroup all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the
Page: 13/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Material Safety Data Sheets. In case you have questions concerning such changes please contact us under the address mentioned in Section I.
The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.