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Safety Data Sheet Safety data sheet Page: 1/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 1. Identification Product identifier Pearl-Glo® SF PG1099 Chemical name: Pearl-Glo SF CAS Number: 7787-59-9 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: cosmetic ingredient Details of the supplier of the safety data sheet Company: BASF SE 67056 Ludwigshafen GERMANY Telephone: +49 621 60-48799 E-mail address: [email protected] Emergency telephone number International emergency number: Telephone: +49 180 2273-112 2. Hazards Identification Classification of the substance or mixture According to UN GHS criteria No need for classification according to GHS criteria for this product. Page: 2/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Label elements Globally Harmonized System (GHS) The product does not require a hazard warning label in accordance with GHS criteria. Other hazards According to UN GHS criteria No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/Information on Ingredients Substances Chemical nature INCI Name: BISMUTH OXYCHLORIDE Contains: Bismuth chloride oxide CAS Number: 7787-59-9 EC-Number: 232-122-7 Hazardous ingredients (GHS) According to UN GHS criteria No particular hazards known. Mixtures Not applicable 4. First-Aid Measures Description of first aid measures Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. Page: 3/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water. Most important symptoms and effects, both acute and delayed Symptoms: No significant reaction of the human body to the product known. Hazards: No hazard is expected under intended use and appropriate handling. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Special hazards arising from the substance or mixture harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Avoid dust formation. Use personal protective clothing. Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Page: 4/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Avoid raising dust. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. 7. Handling and Storage Precautions for safe handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: No special precautions necessary. Conditions for safe storage, including any incompatibilities Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene (LDPE) Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Protect from direct sunlight. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. 8. Exposure Controls/Personal Protection Control parameters Components with occupational exposure limits No occupational exposure limits known. Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with low efficiency for solid particles (e.g. EN 143 or 149, Type P1or FFP1) Hand protection: See section 8 „General safety and hygiene measures“ Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Page: 5/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust). General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. In order to prevent contamination while handling, closed working clothes and working gloves should be used. Hands and/or face should be washed before breaks and at the end of the shift. 9. Physical and Chemical Properties Information on basic physical and chemical properties Form: powder Colour: white to silver Odour: odourless Odour threshold: not applicable, odour not perceivable pH value: 4,0 - 8,0 (4 %(m)) (as aqueous suspension) Melting point: The substance / product decomposes. Boiling point: The product is a non-volatile solid. Flash point: not applicable Evaporation rate: The product is a non-volatile solid. Flammability: not flammable Flammability of Aerosol Products: not applicable, the product does not form flammable aerosoles Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Ignition temperature: not applicable Vapour pressure: not applicable Density: 7,7 g/ml (20 °C) Relative density: 7,7 Relative vapour density (air): The product is a non-volatile solid. Page: 6/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Solubility in water: insoluble Partitioning coefficient n-octanol/water (log Kow): The value has not been determined because the substance is inorganic. Self ignition: Based on its structural properties the product is not classified as self- igniting. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: not applicable, the product is a solid Viscosity, kinematic: not applicable, the product is a solid Explosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing. Other information Self heating ability: It is not a substance capable of spontaneous heating. Bulk density: 610 kg/m3 pKA: not applicable Surface tension: Based on chemical structure, surface activity is not to be expected. Grain size distribution: No data available. Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. No further information available. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Formation of Remarks: Forms no flammable gases in the flammable gases: presence of water. Chemical stability The product is chemically stable. Page: 7/13 BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 23.10.2017 Version: 2.0 Product: Pearl-Glo® SF PG1099 (ID no. 30322522/SDS_COS_00/EN) Date of print 24.10.2017 Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid See MSDS section 7 - Handling and storage. Avoid dust formation. Avoid deposition of dust. Incompatible materials Substances to avoid: acids, oxidizing agents Hazardous decomposition products Hazardous decomposition products: hydrogen chloride 11. Toxicological Information Information on toxicological effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Experimental/calculated data: LD50 rat (oral): > 5.000 mg/kg Irritation Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Serious eye damage/irritation rabbit: non-irritant (Draize test) The product
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