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Microstructures and Interlayering in Pyrophyllite from the Coastal Range of Central Chile: Evidence of a Disequilibrium Assemblage
Clay Minerals (2004) 39,439–452 Microstructures and interlayering in pyrophyllite from the Coastal Range of central Chile: evidence of a disequilibrium assemblage 1, 2 3 2 2 M. D. RUIZ C RUZ *,D. M ORATA ,E. P UGA ,L. A GUIRRE AND M. VERGARA 1 Departamento de Quı´mica Inorga´nica, Cristalografı´a y Mineralogı´a, Facultad de Ciencias, Universidad de Ma´laga, 29071 Ma´laga, Spain, 2 Departamento de Geologı´a, Universidad de Chile, Plaza Ercilla, 803, Santiago, Chile, and 3 Instituto Andaluz de Ciencias de la Tierra (C.S.I.C.-U.G.R.), Avda. Fuentenueva s/n, 18002 Granada, Spain (Received 5 December 2003; revised 19 April 2004) ABSTRACT: Pyrophyllite from a Triassic sedimentary formation from the Coastal Range of Chile has been investigated by transmission/analytical electron microscopy (TEM/AEM). The mineral assemblage includes pyrophyllite,muscovite,paragonite,a kaolin mineral,boehmite,rutile and hematite. The textures indicate that the protolith was a volcanoclastic rock. Petrographic evidence, chemistry,and the mineral assemblage suggest the intense leaching of the parent rock by a weathering process,before the metamorphic episode,to create the protolith for the pyrophyllite. Pyrophyllite always grows from the kaolin mineral,and both phases show close orientation relationships. The presence of parallel intergrowths of pyrophyllite and muscovite indicate that muscovite also grew from the kaolin mineral. Nevertheless,the composition of muscovite suggests that this phase must also form from another precursor,probably Al smectite. The AEM data and textural relationships between pyrophyllite and muscovite reveal the presence of two generations of muscovite and suggest that Na-rich muscovite recrystallized into a Na-free muscovite and paragonite. -
Geology and Age of the Lac a La Perdrix Fenite, Southern Gatineau District, Quebec
CA9700383 -4- Geology and age of the Lac a la Perdrix fenite, southern Gatineau district, Quebec D.D. Hogarth1 and Otto van Breemen2 Hogarth, D.D. and van Breemen, 0., 1996: Geology and age of the Lac a la Perdrix fenite, southern Gatineau district, Quebec; inRadiogenic Age and Isotopic Studies: Report 9; Geological Survey of Canada, Current Research 1995-F, p. 33-41. Abstract: The Lac a la Perdrix fenite lies in the Central Metasedimentary Belt of the Grenville Province. This 30 m wide fenite, adjacent to a narrow calciocarbonatite sill, replaces diopside-oligoclase gneiss and is composed of magnesio-arfvedsonite, aegirine, microcline, albite, and fluorapatite. Near the contact with carbonatite, it contains appreciable monazite and barite whereas aegirine virtually disappears. Fenitization probably took place early in the igneous stage of carbonatite development. A Pb/U monazite age of 1026 ± 2 Ma is thought to date fenite formation. Together with published data, this age shows that carbonatite intruded metamorphic rocks near the close of the Grenville Orogeny. Resume : La fenite de Lac a la Perdrix s'observe dans la ceinture metasedimentaire de la Province de Grenville. Cette fenite, mesurant 30 m de largeur et en position adjacente par rapport a un etroit filon-couche de calciocarbonatite, remplace un gneiss a diopside-oligoclase et se compose de magnesio-arfvedsonite, d'aegirine, de microcline, d'albite et de fluorapatite. Pres du contact avec la carbonatite, la fenite contient de la monazite et de la barytine en quantite appreciable, tandis que l'aegirine disparait pratiquement. La fenitisation a probablement eu lieu au debut de l'episode igne durant lequel s'est form6 la carbonatite. -
NOTE Synthesis of a Regularly Interstratified 2:1 Margarite And
Clay Minerals (1998) 33, 363–367 NOTE Synthesis of a regularly interstratified 2:1 margarite and beidellite (34 A˚ phase) Regularly interstratified mica-smectites and The conditions of composition and temperature chlorite-smectites have been synthesized by Ueda under which the 34 A˚ phase formed as a single & Sudo (1966), Frank-Kamenetskij et al. (1972), phase were fairly limited. The compositions ranged Matsuda & Henmi (1973, 1974)and by Eberl from margarite to margarite and beidellite in a ratio (1978). Only a few studies have been carried out, of 2:1. The temperatures were 400À5008C, and run however, on regularly interstratified minerals whose durations were >2 weeks. The 25 A˚ phase often spacings exceed 30 A˚ (Lazarenko & Korolev, 1970; formed during short runs despite the optimal Sato & Kizaki, 1972). compositions for formation of the 34 A˚ phase. Regularly interstratified minerals with basal Experimental results at 4508C are shown in a ˚ ˚ spacings of 25 A and 30 A have been synthesized triangular diagram of CaOÀAl2O3ÀSiO2 with from kaolinite by means of hydrothermal treatments starting compositions (Fig. 1). As a Ca starting ˚ and by the addition of various oxides or carbonates material, CaCO3 formed the 34 A phase within a (Matsuda & Henmi, 1974, 1983). In these studies a shorter time than did CaO. Compositions richer in phase with a basal spacing of 33À34 A˚ was Ca and Al than ideal margarite led to margarite accompanied by a 25 A˚ mineral after hydrothermal formation at 400À5008C, and to the formation of treatment of kaolinite plus calcium carbonate. The the 25 A˚ phase and boehmite at lower temperatures. -
CM37 1239.Pdf
1239 TheCanaclian Mineralogist Vol. 37, pp.1239-1253(1999) CRYSTALLIZATIONAND ALTERATION HISTORY OF BRITHOLITE IN RARE.EARTH.ELEMENT.ENRICHEDPEGMATITIC SEGREGATIONS ASSOCIATED WITHTHE EDEN LAKE COMPLEX. MANITOBA. CANADA KYLA M. ARDEN ANDNORMAN M. HALDENS Departmentof GeologicalSciences, University of Manitoba,Winnipeg, Manitoba R3T 2N2,Canada ABSTRACT Pegmatitic segregationsand quartzofeldspathic veins associatedwith the Eden Lake Complex, Manitoba, Canada, contain significant abundancesof rare-earth elements (REE),U and Th, concentrated in minerais such as titanite, apatite, allanite and bdtholite. Titanite and apatite are typically found as discrete,zoned, and locally euhedral crystals. Allanite occurs both as discrete crystals as well as irregular segregations,whereas britholite occurs only as irregular masses.The allanite and britholite typically share sharp but irregular contacts with the host silicate minerals (aegirine-augite, K-feldspar and quartz). Allanite normally occurs between britholite and the silicate minerals, suggestingthat it formed as the result ofreaction between aREE-bearing fluid rich in P and F and the silicate minerals. Within the irregular massesof britholite, one sees an unusual polygonal mosaiclike texture with polygons ranging from 20 to 200 pm. Polygon boundariesare straight to slightly curved, intersect at triplejunctions, and converge at angles from 60 to 180'. This texture is likely the product ofreheating and annealing ofthe britholite However, as a result of metamictization, the britholite retains little -
Chemical Composition and Petrogenetic Implications of Eudialyte-Group Mineral in the Peralkaline Lovozero Complex, Kola Peninsula, Russia
minerals Article Chemical Composition and Petrogenetic Implications of Eudialyte-Group Mineral in the Peralkaline Lovozero Complex, Kola Peninsula, Russia Lia Kogarko 1,* and Troels F. D. Nielsen 2 1 Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia 2 Geological Survey of Denmark and Greenland, 1350 Copenhagen, Denmark; [email protected] * Correspondence: [email protected] Received: 23 September 2020; Accepted: 16 November 2020; Published: 20 November 2020 Abstract: Lovozero complex, the world’s largest layered peralkaline intrusive complex hosts gigantic deposits of Zr-, Hf-, Nb-, LREE-, and HREE-rich Eudialyte Group of Mineral (EGM). The petrographic relations of EGM change with time and advancing crystallization up from Phase II (differentiated complex) to Phase III (eudialyte complex). EGM is anhedral interstitial in all of Phase II which indicates that EGM nucleated late relative to the main rock-forming and liquidus minerals of Phase II. Saturation in remaining bulk melt with components needed for nucleation of EGM was reached after the crystallization about 85 vol. % of the intrusion. Early euhedral and idiomorphic EGM of Phase III crystalized in a large convective volume of melt together with other liquidus minerals and was affected by layering processes and formation of EGM ore. Consequently, a prerequisite for the formation of the ore deposit is saturation of the alkaline bulk magma with EGM. It follows that the potential for EGM ores in Lovozero is restricted to the parts of the complex that hosts cumulus EGM. Phase II with only anhedral and interstitial EGM is not promising for this type of ore. -
Li in Minerals from the Ilimaussaq Alkaline Intrusion, South Greenland
Li in minerals from the Ilimaussaq alkaline intrusion, South Greenland J. C. BAILEY, H. BOHSE, R. GWOZDZ and J. ROSE-HANSEN Bailey, J.C., Bohse, H., Gwozdz, R. and Rose-Hansen, J. 1993. Li in minerals from the Ilfmaussaq alkaline intrusion, South Greenland. Bulletin of the Geological Society of Denmark, vol. 40, pp. 288-299. Copenhagen 1993-12-30. https://doi.org/10.37570/bgsd-1993-40-13 Li was analysed by instrumental neutron activation analysis and Cerenkov counting in 120 mineral samples (30 species) from the Ilfmaussaq alkaline intrusion, South Greenland. More than 0.23 wt.% Li (0.5 wt.% Li2O) is found in polylithionite, neptunite, riebeckite, Na-cookeite, ephesite, arfvedsonite, gerasimovskite and astro phyllite. Arfvedsonite (200-2500 ppm Li) carries the bulk of Li in most of the highly alkaline rocks. Li-Mg and Li-F relations indicate that the distribution of Li is con trolled by the structure of minerals, their absolute contents of Mg and F and the fractionation stage within the intrusion. Li is probably linked with Fin the fluid state and this linkage continues into crystallising phases where Li occupies sites which also accommodate Mg. Li/Mg and Li/F ratios of Ilfmaussaq rocks and minerals are higher than in equivalent materials from the Lovozero intrusion (Kola, Russia). The Li Mg-Fe2+ geochemical association at Ilfmaussaq (Fe2+>>Mg) and Lovozero (Fe2+>Mg) contrasts with the commercially important Li-rich but Mg-Fe2+-poor association found in certain granite pegmatites and greisenised granites. Bailey, J. C., Bohse, H., Gwozdz, R. & Rose-Hansen,- J. Division for Petrology, Geological Institute, v)ster Voldgade 10, DK-1350 Copenhagen K, Denmark. -
Stillwellite-(Ce) (Ce, La, Ca)Bsio
Stillwellite-(Ce) (Ce; La; Ca)BSiO5 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Hexagonal. Point Group: 3: As °at rhombohedral crystals, to 4 cm, and massive. Twinning: Observed about [100]. Physical Properties: Cleavage: One imperfect. Fracture: Conchoidal. Hardness = 6.5 D(meas.) = 4.57{4.60 D(calc.) = 4.67 » Optical Properties: Transparent to translucent. Color: Red-brown to pale pink; colorless in thin section. Streak: White. Optical Class: Uniaxial (+) to biaxial (+). ! = 1.765{1.784 ² = 1.780{1.787 2V(meas.) = 0±{6± Cell Data: Space Group: P 31: a = 6.841{6.844 c = 6.700{6.702 Z = 3 X-ray Powder Pattern: Mary Kathleen mine, Australia. 3.43 (s), 2.96 (s), 2.13 (ms), 4.44 (m), 1.864 (m), 2.71 (mw), 2.24 (mw) Chemistry: (1) (2) (1) (2) (1) (2) SiO2 22.40 22.06 La2O3 27.95 19.12 MgO 0.06 UO2 0.22 Ce2O3 33.15 30.82 CaO 0.95 0.34 ThO2 5.41 Pr2O3 1.82 F 0.30 + B2O3 12.23 [13.46] Nd2O3 5.36 H2O 0.85 Al2O3 0.42 Sm2O3 0.34 H2O¡ 0.10 Y2O3 0.74 0.28 Fe2O3 0.18 P2O5 0.67 Total [100.00] [99.26] (1) Mary Kathleen mine, Australia; recalculated to 100.00% after removal of very small amounts of uraninite and apatite determined by separate analysis. (2) Vico volcano, near Vetralla, Italy; by electron microprobe, B2O3 calculated from stoichiometry, original total given as 99.23%; corresponds to (Ce0:50La0:31Nd0:08Th0:05Pr0:03Ca0:02Sm0:01)§=1:00B1:02Si0:97O5: Occurrence: Locally abundant as a metasomatic replacement of metamorphosed calcareous sediments (Mary Kathleen mine, Australia); in alkalic pegmatites in syenite in an alkalic massif (Dara-i-Pioz massif, Tajikistan). -
New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
Optical Properties of Common Rock-Forming Minerals
AppendixA __________ Optical Properties of Common Rock-Forming Minerals 325 Optical Properties of Common Rock-Forming Minerals J. B. Lyons, S. A. Morse, and R. E. Stoiber Distinguishing Characteristics Chemical XI. System and Indices Birefringence "Characteristically parallel, but Mineral Composition Best Cleavage Sign,2V and Relief and Color see Fig. 13-3. A. High Positive Relief Zircon ZrSiO. Tet. (+) 111=1.940 High biref. Small euhedral grains show (.055) parallel" extinction; may cause pleochroic haloes if enclosed in other minerals Sphene CaTiSiOs Mon. (110) (+) 30-50 13=1.895 High biref. Wedge-shaped grains; may (Titanite) to 1.935 (0.108-.135) show (110) cleavage or (100) Often or (221) parting; ZI\c=51 0; brownish in very high relief; r>v extreme. color CtJI\) 0) Gamet AsB2(SiO.la where Iso. High Grandite often Very pale pink commonest A = R2+ and B = RS + 1.7-1.9 weakly color; inclusions common. birefracting. Indices vary widely with composition. Crystals often euhedraL Uvarovite green, very rare. Staurolite H2FeAI.Si2O'2 Orth. (010) (+) 2V = 87 13=1.750 Low biref. Pleochroic colorless to golden (approximately) (.012) yellow; one good cleavage; twins cruciform or oblique; metamorphic. Olivine Series Mg2SiO. Orth. (+) 2V=85 13=1.651 High biref. Colorless (Fo) to yellow or pale to to (.035) brown (Fa); high relief. Fe2SiO. Orth. (-) 2V=47 13=1.865 High biref. Shagreen (mottled) surface; (.051) often cracked and altered to %II - serpentine. Poor (010) and (100) cleavages. Extinction par- ~ ~ alleL" l~4~ Tourmaline Na(Mg,Fe,Mn,Li,Alk Hex. (-) 111=1.636 Mod. biref. -
Mineralogicai, Radiographic and Uranium Leaching Studies on the Uranium Ore from Kvanefjeld, Ilimaussaq Complex, South Greenland
T><2too/t6' Risø-R-416 Mineralogicai, Radiographic and Uranium Leaching Studies on the Uranium Ore from Kvanefjeld, Ilimaussaq Complex, South Greenland Milota Makovicky, Emil Makovicky, Bjarne Leth Nielsen, Svend Karup-Møller, and Emil Sørensen Risø National Laboratory, DK-4000 Roskilde, Denmark June 1980 RISØ-R-416 MINERALOGICAL, RADIOGRAPHIC AND URANIUM LEACHING STUDIES ON THE URANIUM ORE FROM KVANEFJELD, ILIMAUSSAQ. COMPLEX, 'SOUTH GREENLAND Milota Makovickyl , Emil Makovicky2, Bjarne Leth Nielsen-! , Sven Karuo-Møller^ and Emil Sørensen^ Abstract. 102 samples of low-grade uranium ore from 70 drill holes at Kvanefjeld, Ilimaussaq alkaline intrusion, South Green land were studied by means of autoradiography, fission-track investigations, microscopy, microprobe analyses and uranium- leaching experiments. The principal U-Th bearing mineral, steen- strupine, and several less common uranium minerals are dis seminated in lujavrite 'nepheline syenite) and altered volcanic rocks. Stenstrupine has a/erage composition Na6.7HxCai.n e Al (REE+Y)5.8(Th,l')o.5 ( ""1 . 6*" 1 . S^Q. 3^0. l 0. 2 ) Sii2036 (P4.3Si-) ,7 )024 (F,OH). nH20; n and x are variable. It either is of magmatic origin (type A) or connected with metasomatic processes (type B), or occurs in late veins (Type C). Preponder ance of grains are metamict (usually 2000-5000 ppm U3O8) or al tered (usually above 5000 ppm U3O8), sometimes zoned with both (continue on next page) June 1980 Pisø National Laboratory, DK-4000 Roskilde, Denmark components present. Occasionally they are extremely altered with U content falling to 500-5000 ppm U3O8 and local accumulations of high-U minerals formed. -
Cation Ordering and Pseudosymmetry in Layer Silicates'
I A merican M ineralogist, Volume60. pages175-187, 1975 Cation Ordering and Pseudosymmetryin Layer Silicates' S. W. BerI-nv Departmentof Geologyand Geophysics,Uniuersity of Wisconsin-Madison Madison, Wisconsin5 3706 Abstract The particular sequenceof sheetsand layers present in the structure of a layer silicate createsan ideal symmetry that is usually basedon the assumptionsof trioctahedralcompositions, no significantdistor- tion, and no cation ordering.Ordering oftetrahedral cations,asjudged by mean l-O bond lengths,has been found within the constraints of the ideal spacegroup for specimensof muscovite-3I, phengile-2M2, la-4 Cr-chlorite, and vermiculite of the 2-layer s type. Many ideal spacegroups do not allow ordering of tetrahedralcations because all tetrahedramust be equivalentby symmetry.This includesthe common lM micasand chlorites.Ordering oftetrahedral cations within subgroupsymmetries has not beensought very often, but has been reported for anandite-2Or, llb-2prochlorite, and Ia-2 donbassite. Ordering ofoctahedral cations within the ideal spacegroups is more common and has been found for muscovite-37, lepidolite-2M", clintonite-lM, fluoropolylithionite-lM,la-4 Cr-chlorite, lb-odd ripidolite, and vermiculite. Ordering in subgroup symmetries has been reported l-oranandite-2or, IIb-2 prochlorite, and llb-4 corundophilite. Ordering in local out-of-step domains has been documented by study of diffuse non-Bragg scattering for the octahedral catlons in polylithionite according to a two-dimensional pattern and for the interlayer cations in vermiculite over a three-cellsuperlattice. All dioctahedral layer silicates have ordered vacant octahedral sites, and the locations of the vacancies change the symmetry from that of the ideal spacegroup in kaolinite, dickite, nacrite, and la-2 donbassite Four new structural determinations are reported for margarite-2M,, amesile-2Hr,cronstedtite-2H", and a two-layercookeite. -
Nanoidentation Behavior of Clay Minerals and Clay-Based Nonstructured Multilayers" (2009)
Louisiana State University LSU Digital Commons LSU Doctoral Dissertations Graduate School 2009 Nanoidentation behavior of clay minerals and clay- based nonstructured multilayers Zhongxin Wei Louisiana State University and Agricultural and Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_dissertations Part of the Civil and Environmental Engineering Commons Recommended Citation Wei, Zhongxin, "Nanoidentation behavior of clay minerals and clay-based nonstructured multilayers" (2009). LSU Doctoral Dissertations. 3033. https://digitalcommons.lsu.edu/gradschool_dissertations/3033 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Doctoral Dissertations by an authorized graduate school editor of LSU Digital Commons. For more information, please [email protected]. NANOINDENTATION BEHAVIOR OF CLAY MINERALS AND CLAY-BASED NANOSTRUCTURED MULTILAYERS A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requirements for the degree of Doctor of Philosophy In The Department of Civil and Environmental Engineering by Zhongxin Wei B.S., Tsinghua University, China, 1989 M.S., Tsinghua University, China, 1994 December, 2009 DEDICATION To my parents and my wife ii ACKNOWLEDGEMENTS I would like to express my sincere thanks to Dr. Guoping Zhang, my advisor, who provided me the opportunity and guided me to pursue my Ph.D degree in the academic area of geotechnical engineering. I have learned a lot from his outstanding knowledge and professional attitude, and I am grateful of his patient guidance and multiaspect supports which attribute to the accomplishment of this dissertation.