From Biomass to Biocarbon – Trends and Tradeoffs When Co- Firing
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Proceedings of the IASTED International Conference Environmental Management and Engineering (EME 2009) July 6 - 8, 2009 Banff, Canada FROM BIOMASS TO BIOCARBON – TRENDS AND TRADEOFFS WHEN CO- FIRING Hugh McLaughlin, PhD, PE Director of Biocarbon Research, Alterna Energy Inc. #102 3645 – 18th Avenue, Prince George, BC, Canada V2N 1A8 www.alternaenergy.ca, [email protected] ABSTRACT the utility location, and adapting the operations of the The challenges associated with co-firing a biofuel in an utility to accommodate the characteristics of the new fuel existing combustion train can be conceptually divided (Baxter, 2005). One popular strategy is to co-fire a into assembling a biofuel creation capability, transporting portion of the alternative biofuel with the historic fossil the biofuel to the utility location, and adapting the fuel. In general, the relative portion of biofuel that can be operations of the utility to accommodate the successfully co-fired with the historic fuel is dependent on characteristics of the new fuel. This analysis will develop the magnitude of the differences in physical and and compare the properties of three biofuels capable of combustion properties of the two fuels (Demirbas, 2003; being co-fired: dry wood pellets, torrefied wood pellets Kiel, 2008). and biocarbon pellets (carbonized biomass pellets). The The current programs to utilize renewable fuel physical properties and processing mass balances of these sources are considering a broad range of biomass sources renewable resources will be investigated. Additional that share a common property of all being characterizations will be provided that influence the “lignocellulosic” in composition, but vary widely in most transportation and utilization of the fuel by the utility in other properties, such as plant origin, bulk density, coal and lignite combustion processes. Utilizing recent moisture and ash properties. While ongoing research data from the literature on the production and includes all types of biomass, the vast majority of the transportation costs of biofuels produced in British historic work has focused on the starting biomass source Columbia and consumed by utilities in Sweden, the of wood residues and the thermal conversion to torrefied market value and associated maximum production cost, wood and onto biocarbon (also known as biochar and including profit, is discussed. It is concluded that if the charcoal). For the purposes of utilization as fuel, the overall biofuel supply chain includes significant thermal conversion processes stop at biocarbon (charcoal). transportation costs, relative to the cost of the raw Further processing at higher temperatures yield “bio- biomass and operating costs of the biofuel conversion coke” for metal refining. Additional specialized processes process, then higher energy density products, such as such as formal “activation” can yield activated carbons, biocarbon pellets, potentially represent the most cost- comparable with traditional coconut shell activated effective biofuel and present the most compatible biofuel carbons. for co-firing with coal. This analysis will compare two well-documented options for solid biomass-based fuels, dried wood pellets KEY WORDS and torrefied wood pellets, with a less well studied option, Sustainable Development, Co-firing Biomass, carbonized wood pellets (i.e. Biocarbon). Biocarbon fuels Biocarbon/Biochar Properties, Biofuel Supply Chain are processed at higher “carbonizing” temperatures to Economics produce a higher energy-density fuel per unit weight at lower overall mass yield. As will be discussed, the interaction of producing higher quality biofuels with 1. Introduction lower shipping weight influences the overall economics of the supply chain from biomass “on the stump” to The combination of heightened corporate environmental electricity flowing into the grid. stewardship, public and regulatory pressure to reduce GHG emissions, and supply chain concerns for traditional utility fossil fuels such as coal and lignite have created 2. Materials and Methods strong interest and motivation to utilize renewable biomass sources in traditional utility generating capacity. The underlying data utilized in the discussion that follows The challenges associated with utilizing a different fuel in have been culled from the existing literature and an existing combustion train occur at every step of the combined to isolate the phenomena of interest. As such, process, but can be conceptually divided into assembling the reader is recommended to review the original works to a biofuel creation capability, transporting the biofuel to evaluate the credibility of the raw data. References, 650-811 43 including web links if available, are provided for all 2.2 Predicting the energy content of biomass to literature resources utilized. biocarbon fuels – derived fuel metrics 2.1 Biomass to Biocarbon Properties from the Solid biomass-based fuels are only recently being literature considered for commercial-scale utility fuels, except for a handful of dedicated applications in the pulp and paper Anyone familiar with biomass literature is compassionate industries, such as bark boilers, etc. Of paramount interest with the challenges of defining “typical” properties of to any utility application is the heating value of the fuel, thermally modified biomass. Further complicating the since the application fundamentally generates heat and characterization of carbonized biomass, or biocarbon, is converts that thermal energy into electricity. the variability created by the interactions between starting Heating value metrics come in two versions, gross or biomass and the reaction conditions. A recent review of higher heating value (GHV or HHV), and net or lower charcoal technology (Antal and Grønli, 2003) will provide heating value (NHV or LHV). Net Heating Value, NHV, the motivated reader with a sound overview and a taste of is a far more representative measure of how much useful the complexity of the well-documented interactions when energy the electricity-generating utility can extract from lignocellulosic biomass is thermally modified. the fuel and will be used for this analysis. The difference While there is no such thing as universally between the two measures involves the fate of the water representative biocarbon, the Antal review does contain a formed during combustion (either condensing to a liquid set of data contained in a doctoral dissertation that and relinquishing the heat of condensation or persisting as provides a reasonably coherent set of data to serve as the a vapour and leaving with said energy), and depends on basis for the discussion that follows (Schenkel, 1999). the fuel, with high quality coals and pure carbon Before dissecting the actual data, the reader is (graphite) having little or no difference and methane cautioned that biomass is intrinsically variable and one having a NHV 10% less than the GHV. Since biomass- can get into more trouble than it is worth attempting to based fuels contain significant amounts of hydrogen, one over-quantify the underlying trends. The phenomena finds significant differences between GHV and NHV (see depicted in the graphs of Schenkel’s work have been discussion by Spill-Sorb, 2008). tabulated to allow more facile manipulation as a The literature options for predicting the energy spreadsheet (please email [email protected] density of biofuels were reviewed. The well-established for a reprint, copy of the Excel spreadsheet, and the and historically utilized Dulong’s Formula was utilized, esoteric references cited herein). Since the original raw with the method described by Spill-Sorb to convert GHV data was not available and the original figures show to NHV at 15.6C (60F – which is the historic reference significant scatter in the data, some smoothing of the data temperature for heating value data). The calculated values was applied to emphasize the underlying trends, as shown are shown in Table 1. Table 1 also provides the energy in Figure 1. requirements to dry incoming biomass from some initial moisture content to a reference point of zero residual moisture, which is a state passed through on the way to higher treatment temperatures associated with torrefaction and carbonization. 100% Carbon Hydrogen 90% Oxygen Fuel Yield 80% Fixed Carbon % Fixed Carbon Yield 70% 60% 50% 40% Mass fraction (%) 30% 20% 10% 0% 200 250 300 350 400 450 500 Biomass Processing Temperature Celsius Figure 1. Trends on biocarbon properties with increasing carbonization temperatures 44 Table 1 Calculated energy content of biofuels and derived fuel metrics Moisture Fuel Yield Dulong's NHV Energy Yield % of dry wood Energy Density Content & wt fuel per GJ/te fuel GJ/te feedstock energy delivered dry wood=100% Temp C wt dry wood dry wood = 100% 50% 200.00% 6.08 12.17 83.98% 41.99% 40% 166.67% 7.76 12.94 89.32% 53.59% 30% 142.86% 9.44 13.49 93.13% 65.19% 20% 125.00% 11.13 13.91 95.99% 76.80% 10% 111.11% 12.81 14.23 98.22% 88.40% 0%, 200C 100.00% 14.49 14.49 100.00% 100.00% 250C 93.50% 15.14 14.16 97.72% 104.52% 300C 80.00% 16.83 13.47 92.95% 116.19% 350C 58.00% 20.86 12.10 83.51% 143.97% 400C 40.00% 24.10 9.64 66.56% 166.39% 450C 30.00% 26.57 7.97 55.03% 183.43% 500C 27.00% 27.49 7.42 51.23% 189.74% 200% Energy Yield (dry wood = 100%) Energy Density (dry wood = 100%) 180% Fuel Yield (wt fuel per wt dry wood) 160% 140% 120% 100% 80% 60% 40% 20% 0% 50% 40% 30% 20% 10% 200 250 300 350 400 450 500 Moisture Content 0% Highest Treatment Temperature Figure 2. Derived Fuel Metrics of Biofuels (dry wood = 100%) In Table 1, a number of metrics have been calculated The 250C and 300C rows represent the range of to allow the variations of biofuel properties to be metrics for torrefied wood and the 350C to 450C rows compared as they relate to actual utilization of the represent the range of biocarbon products. The 500C row biofuels in the utility industries.