Nanomanufacturing Processes Using Mechanosynthesis Applications
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Diamondoid Mechanosynthesis Prepared for the International Technology Roadmap for Productive Nanosystems
IMM White Paper Scanning Probe Diamondoid Mechanosynthesis Prepared for the International Technology Roadmap for Productive Nanosystems 1 August 2007 D.R. Forrest, R. A. Freitas, N. Jacobstein One proposed pathway to atomically precise manufacturing is scanning probe diamondoid mechanosynthesis (DMS): employing scanning probe technology for positional control in combination with novel reactive tips to fabricate atomically-precise diamondoid components under positional control. This pathway has its roots in the 1986 book Engines of Creation, in which the manufacture of diamondoid parts was proposed as a long-term objective by Drexler [1], and in the 1989 demonstration by Donald Eigler at IBM that individual atoms could be manipulated by a scanning tunelling microscope [2]. The proposed DMS-based pathway would skip the intermediate enabling technologies proposed by Drexler [1a, 1b, 1c] (these begin with polymeric structures and solution-phase synthesis) and would instead move toward advanced DMS in a more direct way. Although DMS has not yet been realized experimentally, there is a strong base of experimental results and theory that indicate it can be achieved in the near term. • Scanning probe positional assembly with single atoms has been successfully demonstrated in by different research groups for Fe and CO on Ag, Si on Si, and H on Si and CNHCH3. • Theoretical treatments of tip reactions show that carbon dimers1 can be transferred to diamond surfaces with high fidelity. • A study on tip design showed that many variations on a design turn out to be suitable for accurate carbon dimer placement. Therefore, efforts can be focused on the variations of tooltips of many kinds that are easier to synthesize. -
Nanomedicine and Medical Nanorobotics - Robert A
BIOTECHNOLOGY– Vol .XII – Nanomedicine and Medical nanorobotics - Robert A. Freitas Jr. NANOMEDICINE AND MEDICAL NANOROBOTICS Robert A. Freitas Jr. Institute for Molecular Manufacturing, Palo Alto, California, USA Keywords: Assembly, Nanomaterials, Nanomedicine, Nanorobot, Nanorobotics, Nanotechnology Contents 1. Nanotechnology and Nanomedicine 2. Medical Nanomaterials and Nanodevices 2.1. Nanopores 2.2. Artificial Binding Sites and Molecular Imprinting 2.3. Quantum Dots and Nanocrystals 2.4. Fullerenes and Nanotubes 2.5. Nanoshells and Magnetic Nanoprobes 2.6. Targeted Nanoparticles and Smart Drugs 2.7. Dendrimers and Dendrimer-Based Devices 2.8. Radio-Controlled Biomolecules 3. Microscale Biological Robots 4. Medical Nanorobotics 4.1. Early Thinking in Medical Nanorobotics 4.2. Nanorobot Parts and Components 4.3. Self-Assembly and Directed Parts Assembly 4.4. Positional Assembly and Molecular Manufacturing 4.5. Medical Nanorobot Designs and Scaling Studies Acknowledgments Bibliography Biographical Sketch Summary Nanomedicine is the process of diagnosing, treating, and preventing disease and traumatic injury, of relieving pain, and of preserving and improving human health, using molecular tools and molecular knowledge of the human body. UNESCO – EOLSS In the relatively near term, nanomedicine can address many important medical problems by using nanoscale-structured materials and simple nanodevices that can be manufactured SAMPLEtoday, including the interaction CHAPTERS of nanostructured materials with biological systems. In the mid-term, biotechnology will make possible even more remarkable advances in molecular medicine and biobotics, including microbiological biorobots or engineered organisms. In the longer term, perhaps 10-20 years from today, the earliest molecular machine systems and nanorobots may join the medical armamentarium, finally giving physicians the most potent tools imaginable to conquer human disease, ill-health, and aging. -
Diamonds from the Sky -‐ C2CNT, the Inexpensive Transforma[On of CO2 To
Diamonds from the Sky - C2CNT, the inexpensive transformaon of CO2 to carbon nanotubes Stuart Licht, [email protected] presentaon to: the Naonal Academy Washington, DC, March 2018 Not for reproducon. All rights retained by George Washington University. Stuart Licht – 30 years solar chemistry & climate change mitigation expertise Academic credenals Deans’s Research Prof. George Washington Univ. Former NSF Program Director (Chemistry Division) Former Professor Technion Professor of Chemistry Former Chair – UMass Dept. of Chemistry Former Carlson Chair Assoc. Prof. of Chemsitry Postdoc: MIT (with Prof. Mark Wrighton) Ph.D. in chemistry: Weizmann Instute of Science B.Sc. & M.Sc. in chem&phys: Wesleyan University 2 Stuart Licht – 30 years solar chemistry & climate change mitigation expertise ~400 peer reviewed papers & patents 2014 3 Addressing climate change: What if we could convert CO2 to a product worth over 1,000 times more than coal? Money talks loudly. This would provide economic incenve to remove CO2. We can. We do it now. Today, we present an alternave transformaon of carbon dioxide into a compact, stable, valuable product. This process provides an economic incenve to remove the greenhouse gas carbon dioxide. 1 Introduc;on of a soluon to remove atmospheric carbon dioxide & migate climate change A novel, high-yield, low energy process is shown to remove the greenhouse gas carbon dioxide. We have found a chemistry to produce high-yield, high purity, carbon nanotubes and carbon nanofibers products directly from either atmospheric or smokestack CO2. Such carbons are used to make strong carbon composites, such as used in the Boeing Dreamliner, as well as in high-end sports equipment, wind turbine blades and a host of other lightweight, high strength, flexible, products. -
Carbon Nanofiber Mats for Electromagnetic Interference Shielding
Carbon 111 (2017) 529e537 Contents lists available at ScienceDirect Carbon journal homepage: www.elsevier.com/locate/carbon Carbon nanofiber mats for electromagnetic interference shielding * Xinghua Hong a, b, D.D.L. Chung a, a Composite Materials Research Laboratory, Department of Mechanical and Aerospace Engineering, University at Buffalo, The State University of New York, Buffalo, NY, 14260-4400, USA b Key Laboratory of Textile Science & Technology, Ministry of Education, College of Textiles, Donghua University, Shanghai, 201620, China article info abstract Article history: This paper reports the electromagnetic interference shielding effectiveness of carbon nanofiber (CNF, Received 13 September 2016 originally called carbon filament) mats made from 0.16-mm-diameter catalytically grown CNFs by the Received in revised form paper-making process (1.7e13.1 MPa compaction pressure). These low-cost lightweight binderless mats 13 October 2016 (2.9e5.4 mm thick, 0.13e0.22 g/cm3 bulk density, 6.1e10 vol% solid) provide high shielding effectiveness Accepted 14 October 2016 (SE,52e81 dB, 1.5 GHz) and high SE/density (370e470 dB cm3/g), though SE/thickness is low (14e18 dB/ Available online 14 October 2016 mm). Compared to the spun CNF mats of prior work, they exhibit higher SE, but lower SE/thickness. With consideration of SE, SE/thickness, and SE/density, the CNF mats are superior to graphene aerogel, reduced-graphene-oxide polyurethane foam and reduced-graphene-oxide aerogel of prior work, but are inferior to carbon nanotube mats, graphene film, carbon foam and flexible graphite of prior work. Ab- sorption is the dominant shielding mechanism of CNF mats, so both SE and absorption loss tend to decrease with decreasing thickness. -
Mechanosynthesis of Amides in the Total Absence of Organic Solvent from Reaction to Product Recovery
Mechanosynthesis of amides in the total absence of organic solvent from reaction to product recovery Thomas-Xavier Metro, Julien Bonnamour, Thomas Reidon, Jordi Sarpoulet, Jean Martinez, Frédéric Lamaty To cite this version: Thomas-Xavier Metro, Julien Bonnamour, Thomas Reidon, Jordi Sarpoulet, Jean Martinez, et al.. Mechanosynthesis of amides in the total absence of organic solvent from reaction to product re- covery. Chemical Communications, Royal Society of Chemistry, 2012, 48 (96), pp.11781-11783. 10.1039/c2cc36352f. hal-00784652 HAL Id: hal-00784652 https://hal.archives-ouvertes.fr/hal-00784652 Submitted on 12 Feb 2021 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. ChemComm Dynamic Article Links Cite this: Chem. Commun., 2012, 48, 11781–11783 www.rsc.org/chemcomm COMMUNICATION Mechanosynthesis of amides in the total absence of organic solvent from reaction to product recoverywz Thomas-Xavier Me´tro,* Julien Bonnamour, Thomas Reidon, Jordi Sarpoulet, Jean Martinez and Fre´de´ric Lamaty* Received 31st August 2012, Accepted 8th October 2012 DOI: 10.1039/c2cc36352f The synthesis of various amides has been realised avoiding the use added-value molecules production. Pursuing our interest in of any organic solvent from activation of carboxylic acids with CDI the development of solvent-free amide bond formation,6 we to isolation of the amides. -
Nanosystems, Edge Computing, and the Next Generation Computing Systems
sensors Review Nanosystems, Edge Computing, and the Next Generation Computing Systems Ali Passian * and Neena Imam Computing & Computational Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37830, USA; [email protected] * Correspondence: [email protected] Received: 30 July 2019; Accepted: 16 September 2019; Published: 19 September 2019 Abstract: It is widely recognized that nanoscience and nanotechnology and their subfields, such as nanophotonics, nanoelectronics, and nanomechanics, have had a tremendous impact on recent advances in sensing, imaging, and communication, with notable developments, including novel transistors and processor architectures. For example, in addition to being supremely fast, optical and photonic components and devices are capable of operating across multiple orders of magnitude length, power, and spectral scales, encompassing the range from macroscopic device sizes and kW energies to atomic domains and single-photon energies. The extreme versatility of the associated electromagnetic phenomena and applications, both classical and quantum, are therefore highly appealing to the rapidly evolving computing and communication realms, where innovations in both hardware and software are necessary to meet the growing speed and memory requirements. Development of all-optical components, photonic chips, interconnects, and processors will bring the speed of light, photon coherence properties, field confinement and enhancement, information-carrying capacity, and the broad spectrum of light into the high-performance computing, the internet of things, and industries related to cloud, fog, and recently edge computing. Conversely, owing to their extraordinary properties, 0D, 1D, and 2D materials are being explored as a physical basis for the next generation of logic components and processors. Carbon nanotubes, for example, have been recently used to create a new processor beyond proof of principle. -
Scanning Tunneling Microscope Control System for Atomically
Innovations in Scanning Tunneling Microscope Control Systems for This project will develop a microelectromechanical system (MEMS) platform technology for scanning probe microscope-based, high-speed atomic scale High-throughput fabrication. Initially, it will be used to speed up, by more than 1000 times, today’s Atomically Precise single tip hydrogen depassivation lithography (HDL), enabling commercial fabrication of 2D atomically precise nanoscale devices. Ultimately, it could be used to fabricate Manufacturing 3D atomically precise materials, features, and devices. Graphic image courtesy of University of Texas at Dallas and Zyvex Labs Atomically precise manufacturing (APM) is an emerging disruptive technology precision movement in three dimensions mechanosynthesis (i.e., moving single that could dramatically reduce energy are also needed for the required accuracy atoms mechanically to control chemical and coordination between the multiple reactions) of three dimensional (3D) use and increase performance of STM tips. By dramatically improving the devices and for subsequent positional materials, structures, devices, and geometry and control of STMs, they can assembly of nanoscale building blocks. finished goods. Using APM, every atom become a platform technology for APM and deliver atomic-level control. First, is at its specified location relative Benefits for Our Industry and an array of micro-machined STMs that Our Nation to the other atoms—there are no can work in parallel for high-speed and defects, missing atoms, extra atoms, high-throughput imaging and positional This APM platform technology will accelerate the development of tools and or incorrect (impurity) atoms. Like other assembly will be designed and built. The system will utilize feedback-controlled processes for manufacturing materials disruptive technologies, APM will first microelectromechanical system (MEMS) and products that offer new functional be commercialized in early premium functioning as independent STMs that can qualities and ultra-high performance. -
Methane Pyrolysis for Carbon Nanotubes and Cox‑Free H2 Over
Article Cite This: Energy Fuels XXXX, XXX, XXX−XXX pubs.acs.org/EF ‑ Methane Pyrolysis for Carbon Nanotubes and COx Free H2 over Transition-Metal Catalysts † † I-Wen Wang, Deepa Ayillath Kutteri, Bingying Gao, Hanjing Tian, and Jianli Hu* Chemical & Biomedical Engineering Department, West Virginia University, Morgantown, West Virginia 26506, United States *S Supporting Information ABSTRACT: Recently, researchers at West Virginia University reported a promising catalyst innovation for nonoxidative thermochemical conversion of methane to CO2-free hydrogen and solid carbon nanotubes (CNTs). A catalyst system was discovered that promotes “base growth” CNT formation rather than conventional “tip growth”. This enables catalyst regenerability while also generating highly pure and crystalline carbon products. In this study, simultaneous productions of CNTs and CO2-free hydrogen were studied over Fe-based catalysts supported on Al2O3, SiO2, and H-ZSM-5. The experimental results showed that metal−support interaction played a key role in the base growth mechanism. Methane conversion and the property of CNTs depended significantly on metal loading and the type of support. To elucidate the formation mechanism of CNTs, the spent catalysts were characterized by a number of analytical instrumentations including transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Raman spectroscopy, and thermogravimetric analysis (TGA). The formation of the active intermediate phase, Fe3C, was discovered. The results of XPS analysis revealed that Fe/Al2O3 had a stronger interaction between metal particles and support than Fe/SiO2 and Fe/ZSM-5. The characterization result is consistent with the performance test results from the methane decomposition reaction. To further explore the fi application of the CNTs, separation and puri cation were carried out using spent Fe/Al2O3 and 9Ni-1Fe/SiO2 catalysts. -
Soft Machines: Copying Nature's Nanotechnology with Synthetic
From Fantastic Voyage to Soft Machines: two decades of nanotechnology visions (and some real achievements) Richard Jones University of Sheffield Three visions of nanotechnology… 1. Drexler’s mechanical vision 3. Quantum nanodevices 2. Biological/ soft machines … and two narratives about technological progress Accelerating change… …or innovation stagnation? Who invented nanotechnology? Richard Feynman (1918-1988) Theoretical Physicist, Nobel Laureate “There’s Plenty of Room at the Bottom” - 1959 Robert Heinlein? Norio Taniguchi? Coined the term “nanotechnology” in 1974 Don Eigler? 1994 – used the STM (invented by Binnig & Rohrer) to rearrange atoms “Engines of Creation” K. Eric Drexler 1986 The history of technology : increasing precision and miniaturisation Medieval macro- 19th century precision Modern micro-engineering engineering engineering MEMS device, Sandia Late medieval mine Babbage difference engine, pump, Agricola 1832 Where next? Nanotechnology as “the principles of mechanical engineering applied to chemistry” Ideas developed by K.Eric Drexler Computer graphics and simulation Technical objections to Drexler’s vision Drexler’s Nanosystems: More research required Josh Hall: “Noone has ever found a significant error in the technical argument. Drexler’s detractors in the political argument don’t even talk about it.” • Friction • Uncontrolled mechanosynthesis • Thermodynamic and kinetic stability of nanostructures • Tolerance • Implementation path • Low level mechanosynthesis steps “If x doesn’t work, we’ll just try y”, versus an ever- tightening design space. “Any material you like, as long as it’s diamond” • Nanosystems and subsequent MNT work concentrate on diamond – Strong and stiff (though not quite as stiff as graphite) – H-terminated C (111) is stable wrt surface reconstruction • Potential disadvantages – Not actually the thermodynamic ground state (depends on size and shape - clusters can reconstruct to diamond-filled fullerene onions) – Non-ideal electronic properties. -
Molecular Nanotechnology - Wikipedia, the Free Encyclopedia
Molecular nanotechnology - Wikipedia, the free encyclopedia http://en.wikipedia.org/wiki/Molecular_manufacturing Molecular nanotechnology From Wikipedia, the free encyclopedia (Redirected from Molecular manufacturing) Part of the article series on Molecular nanotechnology (MNT) is the concept of Nanotechnology topics Molecular Nanotechnology engineering functional mechanical systems at the History · Implications Applications · Organizations molecular scale.[1] An equivalent definition would be Molecular assembler Popular culture · List of topics "machines at the molecular scale designed and built Mechanosynthesis Subfields and related fields atom-by-atom". This is distinct from nanoscale Nanorobotics Nanomedicine materials. Based on Richard Feynman's vision of Molecular self-assembly Grey goo miniature factories using nanomachines to build Molecular electronics K. Eric Drexler complex products (including additional Scanning probe microscopy Engines of Creation Nanolithography nanomachines), this advanced form of See also: Nanotechnology Molecular nanotechnology [2] nanotechnology (or molecular manufacturing ) Nanomaterials would make use of positionally-controlled Nanomaterials · Fullerene mechanosynthesis guided by molecular machine systems. MNT would involve combining Carbon nanotubes physical principles demonstrated by chemistry, other nanotechnologies, and the molecular Nanotube membranes machinery Fullerene chemistry Applications · Popular culture Timeline · Carbon allotropes Nanoparticles · Quantum dots Colloidal gold · Colloidal -
Numerical Investigation of Carbon Nanotube Thin-Film Composites and Devices
NUMERICAL INVESTIGATION OF CARBON NANOTUBE THIN-FILM COMPOSITES AND DEVICES A Dissertation Presented to The Academic Faculty By Man Prakash Gupta In Partial Fulfillment Of the Requirements for the Degree Doctor of Philosophy in Mechanical Engineering Georgia Institute of Technology May 2015 Copyright © Man Prakash Gupta 2015 NUMERICAL INVESTIGATION OF CARBON NANOTUBE THIN-FILM COMPOSITES AND DEVICES Approved by: Dr. Satish Kumar, Adviser Dr. Abhijit Chatterjee School of Mechanical Engineering School of Electrical and Computer Georgia Institute of Technology Engineering Georgia Institute of Technology Dr. Alexander Alexeev Dr. Manos Tentzeris School of Mechanical Engineering School of Electrical and Computer Georgia Institute of Technology Engineering Georgia Institute of Technology Dr. Baratunde Cola School of Mechanical Engineering Georgia Institute of Technology Date Approved: December 5, 2014 ACKNOWLEDGEMENTS The period of last five years during my PhD program has been profoundly transformational for me in many ways. Looking back, I find that it has been truly an enjoyable and intellectually satisfying journey which was made possible by the help and support of a number of people. Among them first and foremost, I would like to thank my mentor and adviser Dr. Satish Kumar for providing the necessary guidance and constant encouragement. He has been incredibly patient and supportive during the entire program. Needless to say, he has been a role model for me and I consider it my privilege to be one of the first graduate students in his research group. I am grateful to my collaborators Dr. Saibal Mukhopadhyay, Dr. Eric Pop, Dr. Minki Cho, Dr. David Estrada and Dr. Ashkan Behnam for allowing me to work with them and having fruitful discussions. -
Carbon Nanotube-Based Three-Dimensional Monolithic Optoelectronic Integrated System
ARTICLE Received 14 Aug 2016 | Accepted 15 Apr 2017 | Published 8 Jun 2017 DOI: 10.1038/ncomms15649 OPEN Carbon nanotube-based three-dimensional monolithic optoelectronic integrated system Yang Liu1, Sheng Wang2, Huaping Liu3,4 & Lian-Mao Peng1,2 Single material-based monolithic optoelectronic integration with complementary metal oxide semiconductor-compatible signal processing circuits is one of the most pursued approaches in the post-Moore era to realize rapid data communication and functional diversification in a limited three-dimensional space. Here, we report an electrically driven carbon nanotube-based on-chip three-dimensional optoelectronic integrated circuit. We demonstrate that photovoltaic receivers, electrically driven transmitters and on-chip electronic circuits can all be fabricated using carbon nanotubes via a complementary metal oxide semiconductor-compatible low-temperature process, providing a seamless integration platform for realizing monolithic three-dimensional optoelectronic integrated circuits with diversified functionality such as the heterogeneous AND gates. These circuits can be vertically scaled down to sub-30 nm and operates in photovoltaic mode at room temperature. Parallel optical communication between functional layers, for example, bottom-layer digital circuits and top-layer memory, has been demonstrated by mapping data using a 2 Â 2 transmitter/receiver array, which could be extended as the next generation energy-efficient signal processing paradigm. 1 Key Laboratory for the Physics and Chemistry of Nanodevices and Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China. 2 Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871, China. 3 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.