A Periodic Table of the Elements at Los Alamos National Laboratory Los Alamos National Laboratory's Chemistry Division Presents Periodic Table of the Elements
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Thallium-201 for Medical Use. I
THALLIUM-201 FOR MEDICAL USE. I E. Lebowitz, M. W. Greene, R. Fairchild, P. R. Bradley-Moore, H. 1. Atkins,A. N. Ansari, P. Richards,and E. Belgrave Brookhaven National Laboratory Thallium-201 merits evaluation for myocar tumors (7—9), the use of radiothallium should also dial visualization, kidney studies, and tumor be evaluated for this application. diagnosis because of its physical and biologic Thallium-201 decays by electron capture with a properties. A method is described for prepara 73-hr half-life. It emits mercury K-x-rays of 69—83 tion of this radiopharmaceutical for human use. keY in 98% abundance plus gamma rays of I 35 and A critical evaluation of 501T1 and other radio 167 keV in 10% total abundance. Because of its pharmaceuticals for myocardial visualization is good shelf-life, photon energies, and mode of decay, given. 201T1was the radioisotope of thallium chosen for development. Thallium-20 1 is a potentially useful radioisotope MATERIALS AND METHODS for various medical applications including myocardial Thallium-201 is produced by irradiating a natural visualization and possible assessment of physiology, thallium target in the external beam of the 60-in. as a renal medullary imaging agent, and for tumor Brookhaven cyclotron with 3 1-MeV protons. The detection. nuclear reaction is 203Tl(p,3n)201Pb. Lead-201 has The use of radiothallium in nuclear medicine was a half-life of 9.4 hr and is the parent of 201T1.The first suggested by Kawana, et al (1 ) . In terms of thallium target, fabricated from an ingot of 99.999% organ distribution (2) and neurophysiologic function pure natural thallium metal (29.5% isotopic abun (3), thallium is biologically similar to potassium. -
Table 2.Iii.1. Fissionable Isotopes1
FISSIONABLE ISOTOPES Charles P. Blair Last revised: 2012 “While several isotopes are theoretically fissionable, RANNSAD defines fissionable isotopes as either uranium-233 or 235; plutonium 238, 239, 240, 241, or 242, or Americium-241. See, Ackerman, Asal, Bale, Blair and Rethemeyer, Anatomizing Radiological and Nuclear Non-State Adversaries: Identifying the Adversary, p. 99-101, footnote #10, TABLE 2.III.1. FISSIONABLE ISOTOPES1 Isotope Availability Possible Fission Bare Critical Weapon-types mass2 Uranium-233 MEDIUM: DOE reportedly stores Gun-type or implosion-type 15 kg more than one metric ton of U- 233.3 Uranium-235 HIGH: As of 2007, 1700 metric Gun-type or implosion-type 50 kg tons of HEU existed globally, in both civilian and military stocks.4 Plutonium- HIGH: A separated global stock of Implosion 10 kg 238 plutonium, both civilian and military, of over 500 tons.5 Implosion 10 kg Plutonium- Produced in military and civilian 239 reactor fuels. Typically, reactor Plutonium- grade plutonium (RGP) consists Implosion 40 kg 240 of roughly 60 percent plutonium- Plutonium- 239, 25 percent plutonium-240, Implosion 10-13 kg nine percent plutonium-241, five 241 percent plutonium-242 and one Plutonium- percent plutonium-2386 (these Implosion 89 -100 kg 242 percentages are influenced by how long the fuel is irradiated in the reactor).7 1 This table is drawn, in part, from Charles P. Blair, “Jihadists and Nuclear Weapons,” in Gary A. Ackerman and Jeremy Tamsett, ed., Jihadists and Weapons of Mass Destruction: A Growing Threat (New York: Taylor and Francis, 2009), pp. 196-197. See also, David Albright N 2 “Bare critical mass” refers to the absence of an initiator or a reflector. -
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Recent IUPAC technical reports and recommendations that aff ect the many fi elds of pure and applied chemistry. Making an imPACt See also www.iupac.org/what-we-do/journals/ Standard Atomic Weight of Hafnium elements. For example, radioactive decay of lutetium Revised alters the isotopic composition of hafnium by produc- ing the light isotope of hafnium-176. Thus, some rare The IUPAC Com- terrestrial materials can have abnormal isotopic com- mission on Isotopic positions of hafnium with the most extreme known Abundances and case being sedimentary chert from South Africa hav- Atomic Weights ing atomic-weight value of 178.447. (CIAAW) met under The CIAAW continues to evaluate literature data the chairmanship of which leads to identifi cation of developments in the Dr. Juris Meija (Can- measurement science, recognition of new discover- ada), at the Federal ies, and remains committed to modernize its technical Institute for Mate- guidelines and work towards further expansion of its rials Research and website to include more historical databases. These Testing (bam.de), changes and considerations will be published in Pure Berlin Germany, in and Applied Chemistry [2] and can be found online at June 2019. As IUPAC celebrates its centennial in 2019, the website of The CIAAW (ciaaw.org). its oldest body, the CIAAW, turns 120 with its beginnings tracing back to Berlin in 1899 [1]. Following its 2019 Notes meeting, the CIAAW recommended changes to the stan- 1. For a historical account of the CIAAW, see J.R. De dard atomic weight (i.e. relative atomic mass) of hafnium Laeter and J. -
Monitored Natural Attenuation of Inorganic Contaminants in Ground
Monitored Natural Attenuation of Inorganic Contaminants in Ground Water Volume 3 Assessment for Radionuclides Including Tritium, Radon, Strontium, Technetium, Uranium, Iodine, Radium, Thorium, Cesium, and Plutonium-Americium EPA/600/R-10/093 September 2010 Monitored Natural Attenuation of Inorganic Contaminants in Ground Water Volume 3 Assessment for Radionuclides Including Tritium, Radon, Strontium, Technetium, Uranium, Iodine, Radium, Thorium, Cesium, and Plutonium-Americium Edited by Robert G. Ford Land Remediation and Pollution Control Division Cincinnati, Ohio 45268 and Richard T. Wilkin Ground Water and Ecosystems Restoration Division Ada, Oklahoma 74820 Project Officer Robert G. Ford Land Remediation and Pollution Control Division Cincinnati, Ohio 45268 National Risk Management Research Laboratory Office of Research and Development U.S. Environmental Protection Agency Cincinnati, Ohio 45268 Notice The U.S. Environmental Protection Agency through its Office of Research and Development managed portions of the technical work described here under EPA Contract No. 68-C-02-092 to Dynamac Corporation, Ada, Oklahoma (David Burden, Project Officer) through funds provided by the U.S. Environmental Protection Agency’s Office of Air and Radiation and Office of Solid Waste and Emergency Response. It has been subjected to the Agency’s peer and administrative review and has been approved for publication as an EPA document. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. All research projects making conclusions or recommendations based on environmental data and funded by the U.S. Environmental Protection Agency are required to participate in the Agency Quality Assurance Program. This project did not involve the collection or use of environmental data and, as such, did not require a Quality Assurance Plan. -
The Development of the Periodic Table and Its Consequences Citation: J
Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1. -
Potassium-40 What Is It? Potassium Is a Soft, Silver-White Metal
Human Health Fact Sheet ANL, October 2001 Potassium-40 What Is It? Potassium is a soft, silver-white metal. An important constituent of soil, it is widely distributed in nature and is present in all Symbol: K(-40) plant and animal tissues. Potassium-40 is a naturally occurring Atomic Number: 19 radioactive isotope of potassium. (An isotope is a different form of an (protons in nucleus) element that has the same number of protons in the nucleus but a different number of neutrons.) Two stable (nonradioactive) isotopes of Atomic Weight: 39 potassium exist, potassium-39 and potassium-41. Potassium-39 (naturally occurring) comprises most (about 93%) of naturally occurring potassium, and potassium-41 accounts for essentially all the rest. Radioactive postassium-40 comprises a very small fraction (about 0.012%) of naturally occurring potassium. Several radioactive isotopes of potassium exist in addition to potassium-40. These isotopes all have half- lives of less than one day Radioactive Properties of Potassium-40 so they are not Natural Specific Radiation Energy (MeV) Half-Life Decay of concern for Isotope Abundance Activity (yr) Mode Alpha Beta Gamma Department of (%) (Ci/g) (α) (β) (γ) Energy (DOE) K-40 1.3 billion 0.012 0.0000071 β, EC - 0.52 0.16 environmental management EC = electron capture, Ci = curie, g = gram, and MeV = million electron volts; a dash means sites such as that the entry is not applicable. (See the companion fact sheet on Radioactive Properties, Hanford. The Internal Distribution, and Risk Coefficients for explanation of terms and interpretation of radiation energies.) Potassium-40 decays by both emitting a beta particle (89%) and electron half-life of capture (11%). -
Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life
Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life Item Type text; Electronic Dissertation Authors Pasek, Matthew Adam Publisher The University of Arizona. Rights Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. Download date 07/10/2021 06:16:37 Link to Item http://hdl.handle.net/10150/194288 PHOSPHORUS AND SULFUR COSMOCHEMISTRY: IMPLICATIONS FOR THE ORIGINS OF LIFE by Matthew Adam Pasek ________________________ A Dissertation Submitted to the Faculty of the DEPARTMENT OF PLANETARY SCIENCE In Partial Fulfillment of the Requirements For the Degree of DOCTOR OF PHILOSOPHY In the Graduate College UNIVERSITY OF ARIZONA 2 0 0 6 2 THE UNIVERSITY OF ARIZONA GRADUATE COLLEGE As members of the Dissertation Committee, we certify that we have read the dissertation prepared by Matthew Adam Pasek entitled Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life and recommend that it be accepted as fulfilling the dissertation requirement for the Degree of Doctor of Philosophy _______________________________________________________________________ Date: 04/11/2006 Dante Lauretta _______________________________________________________________________ Date: 04/11/2006 Timothy Swindle _______________________________________________________________________ Date: 04/11/2006 -
Planetary Science : a Lunar Perspective
APPENDICES APPENDIX I Reference Abbreviations AJS: American Journal of Science Ancient Sun: The Ancient Sun: Fossil Record in the Earth, Moon and Meteorites (Eds. R. 0.Pepin, et al.), Pergamon Press (1980) Geochim. Cosmochim. Acta Suppl. 13 Ap. J.: Astrophysical Journal Apollo 15: The Apollo 1.5 Lunar Samples, Lunar Science Insti- tute, Houston, Texas (1972) Apollo 16 Workshop: Workshop on Apollo 16, LPI Technical Report 81- 01, Lunar and Planetary Institute, Houston (1981) Basaltic Volcanism: Basaltic Volcanism on the Terrestrial Planets, Per- gamon Press (1981) Bull. GSA: Bulletin of the Geological Society of America EOS: EOS, Transactions of the American Geophysical Union EPSL: Earth and Planetary Science Letters GCA: Geochimica et Cosmochimica Acta GRL: Geophysical Research Letters Impact Cratering: Impact and Explosion Cratering (Eds. D. J. Roddy, et al.), 1301 pp., Pergamon Press (1977) JGR: Journal of Geophysical Research LS 111: Lunar Science III (Lunar Science Institute) see extended abstract of Lunar Science Conferences Appendix I1 LS IV: Lunar Science IV (Lunar Science Institute) LS V: Lunar Science V (Lunar Science Institute) LS VI: Lunar Science VI (Lunar Science Institute) LS VII: Lunar Science VII (Lunar Science Institute) LS VIII: Lunar Science VIII (Lunar Science Institute LPS IX: Lunar and Planetary Science IX (Lunar and Plane- tary Institute LPS X: Lunar and Planetary Science X (Lunar and Plane- tary Institute) LPS XI: Lunar and Planetary Science XI (Lunar and Plane- tary Institute) LPS XII: Lunar and Planetary Science XII (Lunar and Planetary Institute) 444 Appendix I Lunar Highlands Crust: Proceedings of the Conference in the Lunar High- lands Crust, 505 pp., Pergamon Press (1980) Geo- chim. -
Paul Scherrer Institut
C^ZOOCt^ CO l 9 19 icht r r — — l-Be £3tobe I J Paul Scherrer Institut Labor für Werkstoffe und nukleare Verfahren Programm Entsorgung Chemistry of the Rectox Sensitive Elements Literature Review D.Suter Paul Scherrer Institut Telefon 056/99 2111 Würenlingen und Villigen Telex82 7414psich CH-5232 Villigen PSI Telefax 056/982327 PSI CH PSI-Bericht Nr. 113 Chemistry of the Redox Sensitive Elements Literature Review Daniel Suter Wiirenlingen and Villigen, October 1991 Preface In the framework of its Waste Management Programme the Paul Scherrer Institute is performing work to increase the understanding of radionuclide transport in the geosphere. These investigations arc performed in close cooperation with, and with the financial support of, NAGRA. The present report is issued simultaneously as a PSI report and a NAGRA NTB. TABLE OF CONTENTS Summary 2 Zusammenfassung 3 Resume 4 1. Introduction 5 2. Redox Conditions 8 3. Selenium 11 3.1 Solution Chemistry 11 3.2 Sorption Studies 13 3.3 Geochemistry 15 3.4 Experiments 18 3.5 Analytical Methods 20 4. Technetium 26 4.1 Solution Chemistry 26 4.2 Sorption Studies 29 4.3 Geochemistry 31 4.4 Experiments 32 4.5 Analytical Methods 33 5. Palladium 35 5.1 Solution Chemistry 35 5.2 Sorption Studies 36 5.3. Geochemistry 37 5.4 Experiments 38 5.5 Analytical Methods 39 6. Tin 42 6.1 Solution Chemistry 42 6.2 Sorption Studies 42 6.3 Geochemistry 43 6.4 Experiments 44 6.5 Analytical Methods 44 7. Neptunium 46 7.1 Solution Chemistry 46 7.2 Sorption Studies 48 7.3 Geochemistry 49 7.4 Experiments 51 7.5 Analytical Methods 51 8. -
Procedure for Determining Uranium, Plutonium and Americium by Extraction-Chromatographic Procedures
Procedure for determining uranium, plutonium and americium by extraction-chromatographic procedures H-U/Pu/Am-AWASS-01 Authors: M. Beyermann D. Obrikat Federal coordinating office for drinking water, groundwater, wastewater, sludge, waste and wastewater of nuclear power plants (Leitstelle für die Überwachung der Radioaktivität in Trinkwasser, Grundwasser, Abwasser, Klärschlamm, Reststoffen und Abfällen) ISSN 1865-8725 Version October 2000 Procedures manual for monitoring of radioactive substances in the environment and of external radiation (Messanleitungen für die „Überwachung radioaktiver Stoffe in der Umwelt und externer Strahlung“) H-U/Pu/Am-AWASS-01-01 Procedure for determining uranium, plutonium and americium by means of extraction- chromatographic procedures 1 Scope This procedure serves to simultaneously determine the uranium isotopes U-234, U-235 and U-238, the plutonium isotopes Pu-238, Pu-239 and Pu-240, as well as the americium isotope Am-241 in samples of wastewater from nuclear facilities. It furthermore offers an option of determining the curium isotopes Cm-242 and Cm-244 without further effort. For determining Pu-241, reference is made to pro- cedure H-Pu-241-AWASS-01 of these measuring instructions. 2 Sampling As far as sampling is concerned, reference is made to procedure H-SPEKT- AWASS-01 of these measuring instructions. The sample of the wastewater to be analysed is acidified with ca. 10 ml of concentrated nitric acid (14 mol·l-1) per litre to a pH of about 1. The stability of the acidic reaction needs to be monitored, in particular if the sample is stored for an extended period of time. This procedure ensures that a detection limit of 0,05 Bq·l-1 for alpha-emitters is reached in a sample volume of 0,1 litres to 0,25 litres and thus complies with the nuclear safety standard 1504 of the Nuclear Safety Standards Commission (1). -
(12) Patent Application Publication (10) Pub. No.: US 2008/0232532 A1 Larsen Et Al
US 20080232532A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2008/0232532 A1 Larsen et al. (43) Pub. Date: Sep. 25, 2008 (54) APPARATUS AND METHOD FOR Related U.S. Application Data GENERATION OF ULTRA LOW MOMENTUM NEUTRONS (60) Provisional application No. 60/676,264, filed on Apr. 29, 2005. Provisional application No. 60/715,622, filed on Sep. 9, 2005. (76) Inventors: Lewis G. Larsen, Chicago, IL (US); Alan Widom, Brighton, MA (US) Publication Classification (51) Int. Cl. Correspondence Address: H05H 3/06 (2006.01) COOK, ALEX, MCFARRON, MANZO, (52) U.S. Cl. .............................................................. 376/108 CUMMINGS & MEHLER LTD (57) ABSTRACT SUTE 28SO Method and apparatus for generating ultra low momentum 2OO WESTADAMS STREET neutrons (ULMNS) using Surface plasmon polariton elec CHICAGO, IL 60606 (US) trons, hydrogen isotopes, Surfaces of metallic Substrates, col Appl. No.: 11/912,793 lective many-body effects, and weak interactions in a con (21) trolled manner. The ULMNs can be used to trigger nuclear PCT Filed: Apr. 28, 2006 transmutation reactions and produce heat. One aspect of the (22) present invention effectively provides a “transducer mecha (86) PCT NO.: PCT/US06/16379 nism that permits controllable two-way transfers of energy back-and-forth between chemical and nuclear realms in a S371(c)(1), Small-scale, low-energy, Scalable condensed matter system at (2), (4) Date: Oct. 26, 2007 comparatively modest temperatures and pressures. 1222222 Patent Application Publication Sep. 25, 2008 Sheet 1 of 8 US 2008/0232532 A1 Patent Application Publication Sep. 25, 2008 Sheet 3 of 8 US 2008/0232532 A1 & N. -
Stable Isotopes of Niobium Properties of Niobium
Stable Isotopes of Niobium Isotope Z(p) N(n) Atomic Mass Natural Abundance Nuclear Spin Nb-93 41 52 92.906376 100% 9/2+ Niobium was discovered in 1801 by Charles Hatchett. Its name comes from the Greek name Niobe, meaning “daughter of Tantalus” (tantalum is closely related to niobium in the periodic table of elements). Because the niobium was discovered in an ore called columbite, it was known temporarily as columbium. Niobium, a gray or silvery soft metal, is ductile and very malleable at room temperature and does not tarnish or oxidize at room temperature. It only reacts with oxygen and halogens when heated. It is less corrosion- resistant than tantalum is at high temperatures. Niobium is not attacked by nitric acid up to 100 °C but is vigorously attacked by the mixture of nitric and hydrofluoric acids. It is unaffected at room temperature by most acids and by aqua regia. It is attacked by alkaline solutions, to some extent, at all temperatures. Niobium becomes a superconductor at 9.15 °K. It is insoluble in water, hydrochloric acid, nitric acid and aqua regia; soluble in hydrofluoric acid; and soluble in fused alkali hydroxide. At ordinary temperatures niobium does not react with most chemicals; however, the metal is slowly attacked by hydrofluoric acid and dissolves and is attacked by hydrogen fluoride and fluorine gases, forming niobium pentafluoride. Niobium is oxidized by air at 350 ºC, first forming a pale yellow oxide film of increasing thickness, which changes its color to blue. On further heating to 400 ºC, it converts to a black film of niobium dioxide.