Polarization Imaging: Principles and Integrated Polarimeters Andreas G
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James Clerk Maxwell
James Clerk Maxwell JAMES CLERK MAXWELL Perspectives on his Life and Work Edited by raymond flood mark mccartney and andrew whitaker 3 3 Great Clarendon Street, Oxford, OX2 6DP, United Kingdom Oxford University Press is a department of the University of Oxford. It furthers the University’s objective of excellence in research, scholarship, and education by publishing worldwide. Oxford is a registered trade mark of Oxford University Press in the UK and in certain other countries c Oxford University Press 2014 The moral rights of the authors have been asserted First Edition published in 2014 Impression: 1 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, without the prior permission in writing of Oxford University Press, or as expressly permitted by law, by licence or under terms agreed with the appropriate reprographics rights organization. Enquiries concerning reproduction outside the scope of the above should be sent to the Rights Department, Oxford University Press, at the address above You must not circulate this work in any other form and you must impose this same condition on any acquirer Published in the United States of America by Oxford University Press 198 Madison Avenue, New York, NY 10016, United States of America British Library Cataloguing in Publication Data Data available Library of Congress Control Number: 2013942195 ISBN 978–0–19–966437–5 Printed and bound by CPI Group (UK) Ltd, Croydon, CR0 4YY Links to third party websites are provided by Oxford in good faith and for information only. -
Mixing of Quantum States: a New Route to Creating Optical Activity Anvar S
www.nature.com/scientificreports OPEN Mixing of quantum states: A new route to creating optical activity Anvar S. Baimuratov1, Nikita V. Tepliakov1, Yurii K. Gun’ko1,2, Alexander V. Baranov1, Anatoly V. Fedorov1 & Ivan D. Rukhlenko1,3 Received: 7 June 2016 The ability to induce optical activity in nanoparticles and dynamically control its strength is of great Accepted: 18 August 2016 practical importance due to potential applications in various areas, including biochemistry, toxicology, Published: xx xx xxxx and pharmaceutical science. Here we propose a new method of creating optical activity in originally achiral quantum nanostructures based on the mixing of their energy states of different parities. The mixing can be achieved by selective excitation of specific states orvia perturbing all the states in a controllable fashion. We analyze the general features of the so produced optical activity and elucidate the conditions required to realize the total dissymmetry of optical response. The proposed approach is applicable to a broad variety of real systems that can be used to advance chiroptical devices and methods. Chirality is known to occur at many levels of life organization and plays a key role in many chemical and biolog- ical processes in nature1. The fact that most of organic molecules are chiral starts more and more affecting the progress of contemporary medicine and pharmaceutical industry2. As a consequence, a great deal of research efforts has been recently focused on the optical activity of inherently chiral organic molecules3, 4. It can be strong in the ultraviolet range, in which case it is difficult to study and use in practice. -
Applied Spectroscopy Spectroscopic Nomenclature
Applied Spectroscopy Spectroscopic Nomenclature Absorbance, A Negative logarithm to the base 10 of the transmittance: A = –log10(T). (Not used: absorbancy, extinction, or optical density). (See Note 3). Absorptance, α Ratio of the radiant power absorbed by the sample to the incident radiant power; approximately equal to (1 – T). (See Notes 2 and 3). Absorption The absorption of electromagnetic radiation when light is transmitted through a medium; hence ‘‘absorption spectrum’’ or ‘‘absorption band’’. (Not used: ‘‘absorbance mode’’ or ‘‘absorbance band’’ or ‘‘absorbance spectrum’’ unless the ordinate axis of the spectrum is Absorbance.) (See Note 3). Absorption index, k See imaginary refractive index. Absorptivity, α Internal absorbance divided by the product of sample path length, ℓ , and mass concentration, ρ , of the absorbing material. A / α = i ρℓ SI unit: m2 kg–1. Common unit: cm2 g–1; L g–1 cm–1. (Not used: absorbancy index, extinction coefficient, or specific extinction.) Attenuated total reflection, ATR A sampling technique in which the evanescent wave of a beam that has been internally reflected from the internal surface of a material of high refractive index at an angle greater than the critical angle is absorbed by a sample that is held very close to the surface. (See Note 3.) Attenuation The loss of electromagnetic radiation caused by both absorption and scattering. Beer–Lambert law Absorptivity of a substance is constant with respect to changes in path length and concentration of the absorber. Often called Beer’s law when only changes in concentration are of interest. Brewster’s angle, θB The angle of incidence at which the reflection of p-polarized radiation is zero. -
Polarization and Dichroism
Polarization and dichroism Amélie Juhin Sorbonne Université-CNRS (Paris) [email protected] 1 « Dichroism » (« two colors ») describes the dependence of the absorption measured with two orthogonal polarization states of the incoming light: Circular left Circular right k k ε ε Linear horizontal Linear vertical k k ε ε 2 By extension, « dichroism » also includes similar dependence phenomena, such as: • Low symmetry crystals show a trichroic dependence with linear light • Magneto-chiral dichroism (MχD) is measured with unpolarized light • Magnetic Linear Dichroism (MLD) is measured by changing the direction of magnetic ield and keeping the linear polarization ixed … Dichroism describes an angular and /or polarization behaviour of the absorption 3 Linear dichroism (LD) : difference measured with linearly polarized light Circular dichroism (CD) : difference measured with left / right circularly polarized light. Natural dichroism (ND) : time-reversal symmetry is conserved Non-Reciprocal (NR): time-reversal symmetry is not conserved Magnetic dichroism (MD) : measured in (ferro, ferri or antiferro) magnetic materials Dichroism Time reversal Parity symmetry symmetry Natural Linear (NLD) + + Magne6c Linear (MLD) + + Non Reciprocal Linear (NRLD) - - Natural Circular (NCD) + - Magne6c Circular (MCD) - + Magneto-op6cal (MχD) - - 4 The measurement of dichroism is often challenging… … but provides access to properties that cannot be measured in another way isotropic spectra polarized spectra 9 Al K edge Al K edge [6] beryl Al 6 6 corundum -Al O α -
Gem-Quality Tourmaline from LCT Pegmatite in Adamello Massif, Central Southern Alps, Italy: an Investigation of Its Mineralogy, Crystallography and 3D Inclusions
minerals Article Gem-Quality Tourmaline from LCT Pegmatite in Adamello Massif, Central Southern Alps, Italy: An Investigation of Its Mineralogy, Crystallography and 3D Inclusions Valeria Diella 1,* , Federico Pezzotta 2, Rosangela Bocchio 3, Nicoletta Marinoni 1,3, Fernando Cámara 3 , Antonio Langone 4 , Ilaria Adamo 5 and Gabriele Lanzafame 6 1 National Research Council, Institute for Dynamics of Environmental Processes (IDPA), Section of Milan, 20133 Milan, Italy; [email protected] 2 Natural History Museum, 20121 Milan, Italy; [email protected] 3 Department of Earth Sciences “Ardito Desio”, University of Milan, 20133 Milan, Italy; [email protected] (R.B.); [email protected] (F.C.) 4 National Research Council, Institute of Geosciences and Earth Resources (IGG), Section of Pavia, 27100 Pavia, Italy; [email protected] 5 Italian Gemmological Institute (IGI), 20123 Milan, Italy; [email protected] 6 Elettra-Sincrotrone Trieste S.C.p.A., Basovizza, 34149 Trieste, Italy; [email protected] * Correspondence: [email protected]; Tel.: +39-02-50315621 Received: 12 November 2018; Accepted: 7 December 2018; Published: 13 December 2018 Abstract: In the early 2000s, an exceptional discovery of gem-quality multi-coloured tourmalines, hosted in Litium-Cesium-Tantalum (LCT) pegmatites, was made in the Adamello Massif, Italy. Gem-quality tourmalines had never been found before in the Alps, and this new pegmatitic deposit is of particular interest and worthy of a detailed characterization. We studied a suite of faceted samples by classical gemmological methods, and fragments were studied with Synchrotron X-ray computed micro-tomography, which evidenced the occurrence of inclusions, cracks and voids. -
Polarization Phenomena of Certain Fluorites
142 TIIE AMERICAN MINERALOGIST Pleochroic,e :colorless, ,:pale blue-green, It thus differs from the average vesuvianite only in slightly higher birefringence. The writer wishes to acknowledge his indebtedness to Col. Roebling, Mr. Gage, and Ward's Natural ScienceEstablishment for the privilege of examining specimensand to Dr. Larsen for the opticaldeterminations. POLARIZATION PHENOMENA OF CERTAIN FLUORITES A. L. PansoNs, Uniaersity oJ Toronto While determining the refractive index of fluorite by the method of minimum deviation the writer introduced a nicol prism before the telescopeof the goniometer to determine the plane of polarization of the refracted ray. On rotating the nicol no difference in the intensity of light could be observed,but on examining the reflected ray nearly complete polarization was obtained so that it was thought that the prism was not cut at the angle that should give polarization if Brewster's law applies to isometric crystals. A new prism was then cut from a crystal of fluorite from Madoc, Ontario, so that the angle between the reflected ray and the refracted ray should be ninety degrees. With this new prism the same phenomena were observed. A second nicol was now intro- duced between the collimator and the crystal so that the signal was extinguished. On rotating the two nicols simultaneously extinction was obtained throughout a complete rotation so that it would appear as though we may accept without question the state- ment that a ray of light passing through fluorite vibrates with equal facility in all directions at right angles to the direction of propagation and is not polarized. -
Investigation of Dichroism by Spectrophotometric Methods
Application Note Glass, Ceramics and Optics Investigation of Dichroism by Spectrophotometric Methods Authors Introduction N.S. Kozlova, E.V. Zabelina, Pleochroism (from ancient greek πλέον «more» + χρόμα «color») is an optical I.S. Didenko, A.P. Kozlova, phenomenon when a transparent crystal will have different colors if it is viewed from Zh.A. Goreeva, T different angles (1). Sometimes the color change is limited to shade changes such NUST “MISiS”, Russia as from pale pink to dark pink (2). Crystals are divided into optically isotropic (cubic crystal system), optically anisotropic uniaxial (hexagonal, trigonal, tetragonal crystal systems) and optically anisotropic biaxial (orthorhombic, monoclinic, triclinic crystal systems). The greatest change is limited to three colors. It may be observed in biaxial crystals and is called trichroic. A two color change may be observed in uniaxial crystals and called dichroic. Pleochroic is often the term used to cover both (2). Pleochroism is caused by optical anisotropy of the crystals Dichroism can be observed in non-polarized light but in (1-3). The absorption of light in the optically anisotropic polarized light it may be more pronounced if the plane of crystals depends on the frequency of the light wave and its polarization of incident light matches plane of polarization of polarization (direction of the electric vector in it) (3, 4). light that propagates in the crystal—ordinary or extraordinary Generally, any ray of light in the optical anisotropic crystal is wave. divided into two rays with perpendicular polarizations and The difference in absorbance of ray lights may be minor, but different velocities (v1, v2) which are inversely proportional to it may be significant and should be considered both when the refractive indices (n1, n2) (4). -
Investigation of Magnetic Circular Dichroism Spectra of Semiconductor Quantum Rods and Quantum Dot-In-Rods
nanomaterials Article Investigation of Magnetic Circular Dichroism Spectra of Semiconductor Quantum Rods and Quantum Dot-in-Rods Farrukh Safin 1,* , Vladimir Maslov 1, Yulia Gromova 2, Ivan Korsakov 1, Ekaterina Kolesova 1, Aliaksei Dubavik 1, Sergei Cherevkov 1 and Yurii K. Gun’ko 2 1 School of Photonics, ITMO University, 197101 St. Petersburg, Russia; [email protected] (V.M.); [email protected] (I.K.); [email protected] (E.K.); [email protected] (A.D.); [email protected] (S.C.) 2 School of Chemistry, Trinity College, Dublin 2 Dublin, Ireland; [email protected] (Y.G.); [email protected] (Y.K.G.) * Correspondence: farruhsafi[email protected] Received: 20 April 2020; Accepted: 12 May 2020; Published: 30 May 2020 Abstract: Anisotropic quantum nanostructures have attracted a lot of attention due to their unique properties and a range of potential applications. Magnetic circular dichroism (MCD) spectra of semiconductor CdSe/ZnS Quantum Rods and CdSe/CdS Dot-in-Rods have been studied. Positions of four electronic transitions were determined by data fitting. MCD spectra were analyzed in the A and B terms, which characterize the splitting and mixing of states. Effective values of A and B terms were determined for each transition. A relatively high value of the B term is noted, which is most likely associated with the anisotropy of quantum rods. Keywords: magnetic circular dichroism; quantum nanocrystals; quantum rods; Dot-in-Rods 1. Introduction Anisotropic colloidal semiconductor nanocrystals of various shapes have attracted a lot of attention over recent years due to their unique properties and potential applications. -
GEOL 221 Mineralogy and Mineral Optics Course Syllabus
SAN DIEGO STATE UNIVERSITY GEOL 221 Mineralogy and Mineral Optics Course Syllabus Instructor: Professor David L. Kimbrough Email: [email protected], Phone: 594-1385 Lecture: MW 1000-1050 CSL 422, Lab: W 1400-1640, Lab study: M 1400-1640 CSL 425 Office: GMCS-229A; Office hours: MW 1100-1200; T 1115-1215; by appointment TA: Mark Nahabidian GMCS-133 TBA Course Prerequisite: Chem 200 or concurrent registration. Credit or concurrent registration in OCEAN 100 or GEOL 100 and 101 or GEOL 104 and 101; Geol 200; Required Texts: Introduction to Mineralogy, William D. Nesse, Oxford University Press. Minerals in Thin Section, Perkins & Henke, Prentice Hall Recommended Text: Dictionary of Geological Terms, AGI Bates & Jackson eds. or similar, The Complete Guide to Rocks & Minerals by John Farndon or similar Other required materials: Hand lens; calculator Classroom management: Attendance is crucial. Please let me know if you’re going to be absent for any reason. Be on time for class, don’t participate in excessive side-chatter or cause disruptions during class. Always respond to the instructor, the Teaching Assistant, and your fellow students in a respectful and civil manner. Cheating or plagiarism is not tolerated. It’s easy to spot and constitutes serious academic misconduct. Helpful hints to make Mineralogy easier and more fun! Attend class: Studies show that the most valuable time commitment by students in a course is the time actually spent in the classroom. Class time is the most important determinant of student success and yields the greatest improvement in student learning outcomes. Information is covered in class that is not in the textbook, and parts of the book are hard to understand. -
Copper-Bearing (Paraíba-Type) Tourmaline from Mozambique
COPPER-BEARING (PARAÍBA-TYPE) TOURMALINE FROM MOZAMBIQUE Brendan M. Laurs, J. C. (Hanco) Zwaan, Christopher M. Breeding, William B. (Skip) Simmons, Donna Beaton, Kenneth F. Rijsdijk, Riccardo Befi, and Alexander U. Falster Copper-bearing tourmaline from Mozambique was first recovered in 2001, but its Cu content was not recognized until 2003, and it was not widely sold with its Mozambique origin disclosed until 2005. It has been mined from alluvial deposits in an approximately 3 km2 area near Mavuco in the eastern portion of the Alto Ligonha pegmatite district. Most of the production has come from arti- sanal mining, with hand tools used to remove up to 5 m of overburden to reach the tourmaline- bearing layer. The stones exhibit a wide range of colors, typically pink to purple, violet to blue, and blue to green or yellowish green. Heat treatment of all but the green to yellowish green stones typi- cally produces Paraíba-like blue-to-green hues by reducing absorption at ~520 nm caused by the presence of Mn3+. The gemological properties are typical for Cu-bearing tourmaline (including material from Brazil and Nigeria); the most common inclusions consist of partially healed fractures and elongate hollow tubes. With the exception of some green to yellow-green stones, the tourma- lines examined have relatively low Cu contents and very low amounts of Fe and Ti. Mechanized mining is expected to increase production from this region in the near future. opper-bearing tourmaline, in bright blue- deposit of Cu-bearing tourmaline, and the “neon” to-green hues, is one of the most sought- blue and green shown by the finest stones closely after colored stones in the gem market. -
Limits on Fluorescence Detected Circular Dichroism of Single Helicene Molecules
6213 2009, 113, 6213–6216 Published on Web 05/13/2009 Limits on Fluorescence Detected Circular Dichroism of Single Helicene Molecules Yiqiao Tang,† Timothy A. Cook,‡,§ and Adam E. Cohen*,†,‡ Department of Physics, HarVard UniVersity, Cambridge, Massachusetts 02138, and Department of Chemistry and Chemical Biology, HarVard UniVersity, Cambridge, Massachusetts 02138 ReceiVed: April 19, 2009; ReVised Manuscript ReceiVed: May 6, 2009 Fluorescent imaging of single helicene molecules is applied to study the optical activity of chiral fluorophores. In contrast to the previous report by Hassey et al. (Science 2006, 314, 1437), the dissymmetry factors of single chiral fluorophores are found not to differ significantly from the bulk value of |g| < 10-4 at 457 nm. Linear dichroism and birefringence of the dichroic mirror inside the fluorescence microscope change the polarization state of the incoming laser beam significantly; i.e., circular polarized light sent into the microscope becomes highly elliptically polarized after reflection from the dichroic mirror. Compensation for this effect should be made to avoid artifacts brought by linear dichroism in single immobilized molecules. Single-molecule measurements have been used to probe the H )-µ · E - θ:∇E - m · B states and dynamics of a huge variety of biophysical and condensed matter systems,2-4 and often yield information that where µ is the electric dipole operator, θ is the electric is missed by bulk, ensemble-averaged techniques. In particular, quadrupole operator, and m is the magnetic dipole operator; E measurements at ambient and low temperatures provide detailed is the electric field, and B is the magnetic field. The rate of information about the interactions between single fluorescent excitation from an initial state i to a final state f involves the 2 molecules and their local environment. -
B.Sc.( Srmester-3) Subject: Physics Course: US03CPHY01 Title: Optics
B.Sc.( Srmester-3) Subject: Physics Course: US03CPHY01 Title: Optics UNIT – III Polarization Introduction:- • Interference and diffraction phenomena proved that light is a wave motion. These phenomena are used to find wavelength of light. However, they do not give any indication regarding the character of waves. • Maxwell developed electromagnetic theory and suggested that light-waves are electromagnetic waves. Electromagnetic waves are transverse waves, so it is obvious that light waves are also transverse waves. • Longitudinal waves are waves in which particles of medium oscillate along the direction of propagation of wave (e.g. sound wave). • Transverse waves are waves in which particles of medium oscillate perpendicular to the direction of propagation of wave. (e.g. Electromagnetic waves.) • Polarization is possible in transverse wave. • Unpolarized Light is the light is which the planes of vibration are symmetrically distributed about the propagation direction of the wave. • Plane Polarized light is a wave in which the electric vector is everywhere confined to a single plane. • A linearly polarized light wave is a wave in which the electric vector oscillates in a given constant orientation. Production of Linearly Polarized Light: Linearly polarized light may be produced from unpolarized light using following optical phenomena. (i) Reflection (ii) Refraction (iii) Scattering (iv) Selective absorption (v) Double reflection. Polarized light has many important applications in industry and engineering. One of the most important applications is in liquid crystal displays (LCDs) which are widely used in wristwatches, calculators, T.V. Screens etc. An understanding of polarization is essential for understanding the propagation of electromagnetic waves guided through wave-guides and optical fibers.